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Geology topics

J.T. Turk

Publications and source records attributed to J.T. Turk.

At least 19 recordsLinked to original sources

Seasonal inorganic nitrogen release in alpine lakes on the Colorado western slope

In the Rocky Mountains, the association of increases in acidic deposition with increased atmospheric loading of sulfate and direct changes in surface water chemistry has been well established. The importance, though, of increased nitrogen (N) deposition in the episodic acidification of alpine lakes and N saturation in alpine ecosystems is only beginning to be documented. In alpine areas of the Colorado Front Range, modest loadings of N in deposition have been associated with leakage of N to surface waters. On the Colorado western slope, however, no leakage of N to surface waters has been reported. A 1995 study that included early season under-ice water samples that were not available in earlier studies showed that there is, in fact, N leakage to surface waters in some western slope basins. Under-ice nitrate (NO - 3 ) concentrations were as high as 10.5 μeq L -1 and only decreased to detection limits in September. Landscape type appears to be important in leakage of N to surface waters, which is associated with basins having steep slopes, thin soils, and large amounts of exposed bedrock. NO - 3 leakage compounds the existing sensitivity to episodic acidification from low acid neutralizing capacity (ANC), which is less than 40 μeq L -1 in those basins.

Colorado↗

Effects of sulfur dioxide emissions on stream chemistry in the western United States

A 20-year record of water chemistry for seven headwater streams in the Rocky Mountain region of the western United States is compared to estimates of local and regional sulfur dioxide emissions for the same period. Emissions from smelters in the region comprise a significant part of sulfur dioxide emissions for the 11 states upwind of acid-sensitive watersheds in the Rocky Mountains, but smelter emissions have steadily decreased since 1970. Analysis of stream chemistry indicates conservative behavior of watershed sulfate, with atmospheric deposition as the dominant source of sulfate. No relation between regional stream chemistry and smelter or regional sulfur dioxide emissions is detected for the watersheds. Local emissions trends, however, do appear to affect sulfate concentrations in the streams. Year-to-year variability in stream sulfate concentration is much greater than any long-term trends that might be inferred.

Water Resources Research↗

Trends in snowpack chemistry and comparison to National Atmospheric Deposition Program results for the Rocky Mountains, US, 1993-2004

Seasonal snowpack chemistry data from the Rocky Mountain region of the US was examined to identify long-term trends in concentration and chemical deposition in snow and in snow-water equivalent. For the period 1993-2004, comparisons of trends were made between 54 Rocky Mountain Snowpack sites and 16 National Atmospheric Deposition Program wetfall sites located nearby in the region. The region was divided into three subregions: Northern, Central, and Southern. A non-parametric correlation method known as the Regional Kendall Test was used. This technique collectively computed the slope, direction, and probability of trend for several sites at once in each of the Northern, Central, and Southern Rockies subregions. Seasonal Kendall tests were used to evaluate trends at individual sites. Significant trends occurred during the period in wetfall and snowpack concentrations and deposition, and in precipitation. For the comparison, trends in concentrations of ammonium, nitrate, and sulfate for the two networks were in fair agreement. In several cases, increases in ammonium and nitrate concentrations, and decreases in sulfate concentrations for both wetfall and snowpack were consistent in the three subregions. However, deposition patterns between wetfall and snowpack more often were opposite, particularly for ammonium and nitrate. Decreases in ammonium and nitrate deposition in wetfall in the central and southern rockies subregions mostly were moderately significant (p<0.11) in constrast to highly significant increases in snowpack (p<0.02). These opposite trends likely are explained by different rates of declining precipitation during the recent drought (1999-2004) and increasing concentration. Furthermore, dry deposition was an important factor in total deposition of nitrogen in the region. Sulfate deposition decreased with moderate to high significance in all three subregions in both wetfall and snowpack. Precipitation trends consistently were downward and significant for wetfall, snowpack, and snow-telemetry data for the central and southern rockies subregions (p<0.03), while no trends were noted for the Northern Rockies subregion.

Atmospheric Environment↗

Sensitivity to acidification of subalpine ponds and lakes in north-western Colorado

Although acidifying deposition in western North America is lower than in many parts of the world, many high-elevation ecosystems there are extremely sensitive to acidification. Previous studies determined that the Mount Zirkel Wilderness Area (MZWA) has the most acidic snowpack and aquatic ecosystems that are among the most sensitive in the region. In this study, spatial and temporal variability of ponds and lakes in and near the MZWA were examined to determine their sensitivity to acidification and the effects of acidic deposition during and after snowmelt. Within the areas identified as sensitive to acidification based on bedrock types, there was substantial variability in acid-neutralizing capacity (ANC), which was related to differences in hydrological flowpaths that control delivery of weathering products to surface waters. Geological and topographic maps were of limited use in predicting acid sensitivity because their spatial resolution was not fine enough to capture the variability of these attributes for lakes and ponds with small catchment areas. Many of the lakes are sensitive to acidification (summer and autumn ANC < 100 µeq L −1 ), but none of them appeared to be threatened immediately by episodic or chronic acidification. In contrast, 22 ponds had minimum ANC < 30 µeq L −1 , indicating that they are extremely sensitive to acidic deposition and could be damaged by episodic acidification, although net acidity (ANC < 0) was not measured in any of the ponds during the study. The lowest measured pH value was 5·4, and pH generally remained less than 6·0 throughout early summer in the most sensitive ponds, indicating that biological effects of acidification are possible at levels of atmospheric deposition that occurred during the study. The aquatic chemistry of lakes was dominated by atmospheric deposition and biogeochemical processes in soils and shallow ground water, whereas the aquatic chemistry of ponds was also affected by organic acids and biogeochemical processes in the water column and at the sediment–water interface. These results indicate that conceptual and mechanistic acidification models that have been developed for lakes and streams may be inadequate for predicting acidification in less-understood systems such as ponds.

Hydrological Processes↗

Isotopic study of sulfate sources and residence times in a subalpine watershed

Stable sulfur and oxygen isotope ratios and naturally occurring 35 S SO4 activities were used to examine sulfate sources, address the role of sulfur dynamics, and estimate residence times of atmospherically derived sulfate in Loch Vale Watershed, Colorado. In 1996, surface water samples from small streams flowing through talus, forest, and wetland areas had δ 34 S SO4 values ranging from 1.8 to 3.7‰. Values of δ 18 O SO4 at the three sites ranged from –1.3 to 3.7‰. Average δ 34 S SO4 and δ 18 O SO4 values in Loch Vale precipitation (1991–1999) are higher (5.2 and 13.6, respectively) than surface water values, indicating that some of the deposited sulfate is transformed and/or mixed with other sulfur sources in the watershed (e.g. mineral and organic sulfur). Sulfate ages determined by 35 S SO4 activities support this and show that deposited sulfate may be stored on a timescale of 1 year or more prior to being released to surface waters.

Environmental Geology↗

Use of stable sulfur isotopes to identify sources of sulfate in Rocky Mountain snowpacks

Stable sulfur isotope ratios and major ions in bulk snowpack samples were monitored at a network of 52 high-elevation sites along and near the Continental Divide from 1993 to 1999. This information was collected to better define atmospheric deposition to remote areas of the Rocky Mountains and to help identify the major source regions of sulfate in winter deposition. Average annual ??34S values at individual sites ranged from + 4.0 to + 8.2??? and standard deviations ranged from 0.4 to 1.6???. The chemical composition of all samples was extremely dilute and slightly acidic; average sulfate concentrations ranged from 2.4 to 12.2 ??eql-1 and pH ranged from 4.82 to 5.70. The range of ??34S values measured in this study indicated that snowpack sulfur in the Rocky Mountains is primarily derived from anthropogenic sources. A nearly linear relation between ??34S and latitude was observed for sites in New Mexico, Colorado, and southern Wyoming, which indicates that snowpack sulfate in the southern part of the network was derived from two isotopically distinct source regions. Because the major point sources of SO2 in the region are coal-fired powerplants, this pattern may reflect variations in the isotopic composition of coals burned by the plants. The geographic pattern in ??34S for sites farther to the north in Wyoming and Montana was much less distinct, perhaps rflecting the paucity of major point sources of SO2 in the northern part of the network.

Atmospheric Environment↗

Major-ion chemistry of the Rocky Mountain snowpack, USA

During 1993-97, samples of the full depth of the Rocky Mountain snowpack were collected at 52 sites from northern New Mexico to Montana and analyzed for major-ion concentrations. Concentrations of acidity, sulfate, nitrate, and calcium increased from north to south along the mountain range. In the northern part of the study area, acidity was most correlated (negatively) with calcium. Acidity was strongly correlated (positively) with nitrate and sulfate in the southern part and for the entire network. Acidity in the south exceeded the maximum acidity measured in snowpack of the Sierra Nevada and Cascade Mountains. Principal component analysis indicates three solute associations we characterize as: (1) acid (acidity, sulfate, and nitrate), (2) soil (calcium, magnesium, and potassium), and (3) salt (sodium, chloride, and ammonium). Concentrations of acid solutes in the snowpack are similar to concentrations in nearby wetfall collectors, whereas, concentrations of soil solutes are much higher in the snowpack than in wetfall. Thus, dryfall of acid solutes during the snow season is negligible, as is gypsum from soils. Snowpack sampling offers a cost-effective complement to sampling of wetfall in areas where wetfall is difficult to sample and where the snowpack accumulates throughout the winter. Copyright ?? 2001 .

Atmospheric Environment↗

Use of cosmogenic 35S for comparing ages of water from three alpine-subalpine basins in the Colorado Front Range

High-elevation basins in Colorado are a major source of water for the central and western United States; however, acidic deposition may affect the quality of this water. Water that is retained in a basin for a longer period of time may be less impacted by acidic deposition. Sulfur-35 (35S), a short-lived isotope of sulfur (t( 1/2 ) = 87 days), is useful for studying short-time scale hydrologic processes in basins where biological influences and water/rock interactions are minimal. When sulfate response in a basin is conservative, the age of water may be assumed to be that of the dissolved sulfate in it. Three alpine-subalpine basins on granitic terrain in Colorado were investigated to determine the influence of basin morphology on the residence time of water in the basins. Fern and Spruce Creek basins are glaciated and accumulate deep snowpacks during the winter. These basins have hydrologic and chemical characteristics typical of systems with rapid hydrologic response times. The age of sulfate leaving these basins, determined from the activity of 35S, averages around 200 days. In contrast, Boulder Brook basin has broad, gentle slopes and an extensive cover of surficial debris. Its area above treeline, about one-half of the basin, is blown free of snow during the winter. Variations in flow and solute concentrations in Boulder Brook are quite small compared to Fern and Spruce Creeks. After peak snowmelt, sulfate in Boulder Brook is about 200 days older than sulfate in Fern and Spruce Creeks. This indicates a substantial source of older sulfate (lacking 35S) that is probably provided from water stored in pore spaces of surficial debris in Boulder Brook basin.

Geomorphology↗

The use of bulk collectors in monitoring wet deposition at high-altitude sites in winter

Concentrations of dissolved ions from samples collected by wet/dry collectors were compared to those collected by bulk collectors at Halfmoon Creek and Ned Wilson Lake in western Colorado to determine if bulk collectors can be used to monitor wet deposition chemistry in remote, high-altitude regions in winter. Hydrogen-ion concentration was significantly lower (p < 0.05) in the bulk collectors. All other ion concentrations were significantly higher (p < 0.05) in the bulk collectors except for ammonium (p > 0.05) at Halfmoon Creek. Wet deposition concentrations were predicated from bulk deposition concentrations through linear regression analysis. Results indicate that anions (chloride, nitrate and sulfate) can be predicted with a high degree of confidence. Lack of significant differences between seasonal (winter and summer) ratios of bulk to wet deposition concentrations indicates that at sites where operation of a wet/dry collector during the winter is not practical, wet deposition concentrations can be predicted from bulk collector samples through regression analysis of wet and bulk deposition data collected during the summer.

Water, Air, & Soil Pollution↗

Use of chemistry and stable sulfur isotopes to determine sources of trends in sulfate of Colorado lakes

The chemistry of lakes in the Mt. Zukel Wilderness Area (MZWA) and the Weminuche Wilderness Area (WWA) of Colorado has been monitored since 1985. The initial results indicate that changes have occurred in the chemistry of some lakes in both areas. Increased concentration of sulfate in lakes may be related to increased atmospheric deposition of sulfate or to changes of sulfate released by weathering and to changing dilution of sulfate by snowmelt. Stable S isotopes seem to be capable of separating the fraction of change in sulfate that is related to atmospheric and watershed sources. Because of the short period of record, it is not possible to determine whether the changes are part of a long-term trend or are merely natural fluctuations about some baseline.The chemistry of lakes in th Mt. Zirkel Wilderness Area (MZWA) and Weminche Wilderness Area (WWA) of Colorado has been monitored since 1985. The initial results indicate that changes have occurred in the chemistry of some lakes in both areas. Increased concentration of sulfate in lakes may be related to increased atmospheric deposition of sulfateor to changes of sulfate released by weathering and to changing dilution of sulfate by snowmelt. Stable S isotopes seem to be capable of separating the fraction of change in sulfate that is related to atmospheric and watershed sources. Because of the short period of record, it is not possible to determine whether the changes are part of long-term or are merely natural fluctuations about some baseline.

Water, Air, & Soil Pollution↗

Natural variance in pH as a complication in detecting acidification of lakes

Natural variance in the pH of three dilute lakes in the Flat Tops Wilderness Area, Colorado, complicates the detection of acidification. Variations in pH during July-September of 1983 were: 0.95 (Ned Wilson Lake), 1.36 (Upper Island Lake), and 1.53 (Oyster Lake). Mean diurnal variations in pH during 1983 were: 0.37 (Ned Wilson Lake), 0.54 (Upper Island Lake), and 0.39 (Oyster Lake). Replicate pH measurements indicate that pH can be measured with a mean variance due to measurement error of ?? 0.005. Regression analysis indicates that samples collected on the same day of different years may differ because of time of day and percentage of cloud cover. Differences in wind duration and intensity and primary productivity also may cause the pH to differ between years. Such differences can be either random or systematic. Comparisons of pH among 3 yr of data from Ned Wilson Lake indicate that natural variations in pH are much larger than variations in Colorado Lakes previously attributed to acidification by precipitation.

Water, Air, & Soil Pollution↗

Precision of a field method for determination of pH in dilute lakes

Replicate pH measurements in three dilute lakes made during extreme conditions indicate that pH can be measured in the field with a variance due to measurement error of 0.005 unit. Error of the field technique in measuring the pH of dilute solutions in the laboratory ranges from less than 0.01 unit in dilute strong-acid solutions to about 0.05 unit in air-saturated deionized water.

Water, Air, & Soil Pollution↗

Methods for hydrologic monitoring of surface mining in the central-western United States

The regulations promulgated pursuant to the Surface Mining Control and Reclamation Act require the monitoring of potentially impacted hydrologic systems before, during, and after mining operations. This report details characteristics and processes that commonly determine the most acceptable approaches to hydrologic monitoring in the arid and semiarid central-western United States. No single approach is best for all hydrologic systems; consideration of basin characteristics, regulatory requirements, and regional patterns in hydrologic systems is necessary in any well-designed monitoring program for hydrologic-impact assessment. This report describes processes and characteristics that control the surface and subsurface hydraulics, as well as the water quality, of typical hydrological systems being mined in the central-western United States. After a discussion of these processes and characteristics, three examples are presented that describe acceptable, but nonexclusive, approaches to hydrologic monitoring network design. (USGS)

Open-File Report↗

Estimation of evaporation from Ned Wilson Lake, Flat Tops Wilderness Area, Colorado

As part of an effort to define the hydrology and water quality of Ned Wilson Lake, evaporation rates were estimated for the summer periods of 1983 and 1984. Mass-transfer and energy-budget techniques and the Morton model were used to estimate evaporation using data collected at the lake and data collected at a meteorological station 0.1 mile from the lake. The estimate of evaporation for July 29 through September 27, 1983, using the mass-transfer technique, was 9.50 inches; the estimate using the energy-budget technique was 8.10 inches; the estimate using the Morton model was 9.90 inches. The evaporation estimate for July 18 through September 25, 1984, using the mass-transfer technique was 8.71 inches; the estimate using the energy-budget technique was 7.88 inches; the estimate using the Moron model was 10.49 inches. These estimates will provide values to be used in future analyses of the interaction of lake and groundwater; however, refinement of data collection will be necessary to determine specifically the rate of evaporation. (USGS)

Water-Resources Investigations Report↗