USGS Science⌕ Search

Geology topics

J.R. Evans

Publications and source records attributed to J.R. Evans.

26 records · Page 2Linked to original sources
USGS1989

Comparison of several analytical methods for the determination of tin in geochemical samples as a function of tin speciation

Accurate and precise determinations of tin in geological materials are needed for fundamental studies of tin geochemistry, and for tin prospecting purposes. Achieving the required accuracy is difficult because of the different matrices in which Sn can occur (i.e. sulfides, silicates and cassiterite), and because of the variability of literature values for Sn concentrations in geochemical reference materials. We have evaluated three methods for the analysis of samples for Sn concentration: graphite furnace atomic absorption spectrometry (HGA-AAS) following iodide extraction, inductively coupled plasma atomic emission spectrometry (ICP-OES), and energy-dispersive X-ray fluorescence (EDXRF) spectrometry. Two of these methods (HGA-AAS and ICP-OES) required sample decomposition either by acid digestion or fusion, while the third (EDXRF) was performed directly on the powdered sample. Analytical details of all three methods, their potential errors, and the steps necessary to correct these errors were investigated. Results showed that similar accuracy was achieved from all methods for unmineralized samples, which contain no known Sn-bearing phase. For mineralized samples, which contain Sn-bearing minerals, either cassiterite or stannous sulfides, only EDXRF and fusion ICP-OES methods provided acceptable accuracy. This summary of our study provides information which helps to assure correct interpretation of data bases for underlying geochemical processes, regardless of method of data collection and its inherent limitations. ?? 1989.

Chemical Geology↗
USGS1989

Oxygen-isotope composition of ground water and secondary minerals in Columbia Plateau basalts: Implications for the paleohydrology of the Pasco Basin

Concentrations of 18 O and deuterium in ground waters beneath the Hanford Reservation, Washington State, suggest that the meteoric waters recharging the basalt aquifers have been progressively depleted in these isotopes since at least Pleistocene time. This conclusion is supported by oxygen-isotope analyses of low-temperature secondary minerals filling vugs and fractures in the basalts, which are used to approximate the 18 O content of ground water at the time the mineral assemblage formed. A fossil profile of δ 18 O values projected for ground water in a 1500 m vertical section beneath the reservation suggests that the vertical mixing of shallow and deep ground water indicated by present-day hydrochemical data was also occurring during Neogene time. These data also suggest that a unidirectional depletion of 18 O and deuterium recorded in Pleistocene ground waters may have extended considerably further back in time. This shift is tentatively attributed to the orographic depletion of 18 O associated with the progressive uplift of the Cascade Range since the middle Miocene.

Geology↗
USGS1984

Upwarp of anomalous asthenosphere beneath the Rio Grande rift

Continental rifts are possible analogues of mid-ocean ridges, although major plate tectonic features are less clearly observed1. Current thermal models of mid-ocean ridges2-4 consist of solid lithospheric plates overlying the hotter, less viscous asthenosphere, with plate thickness increasing away from the ridge axis. The lithospheric lower boundary lies at or near the melting point isotherm, so that at greater depths higher temperatures account for lower viscosity, lower seismic velocities and possibly partial melting. Upwarp of this boundary at the ridge axis concentrates heat there, thus lowering densities by expansion and raising the sea floor to the level of thermal isostatic equilibrium. At slow spreading ridges, a major central graben forms owing to the mechanics of magma injection into the crust5. Topography, heat flow, gravity and seismic studies support these models. On the continents, a low-velocity channel has been observed, although it is poorly developed beneath ancient cratons6-9. Plate tectonic models have been applied to continental basins and margins10-12, but further similarities to the oceanic models remain elusive. Topographic uplift is often ascribed to Airy type isostatic compensation caused by crustal thickening, rather than thermal compensation in the asthenosphere. Here we discuss the Rio Grande rift, in southwestern United States. Teleseismic P-wave residuals show that regional uplift is explained by asthenosphere uplift rather than crustal thickening. ?? 1984 Nature Publishing Group.

Nature↗