USGS ScienceSearch

Geology topics

J.J. Collins

Publications and source records attributed to J.J. Collins.

3 recordsLinked to original sources

Evaluation of chemical data from selected sites in the Surface-Water Ambient Monitoring Program (SWAMP) in Florida

A cooperative study between the Florida Department of Environmental Protection (FDEP) and the U.S. Geological Survey was conducted to assess the integrity of selected water-quality data collected at 150 sites in the FDEP Surface-Water Ambient Monitoring Program (SWAMP) in Florida. The assessment included determining the consistency of the water-quality data collected statewide, including commonality of monitoring procedures and analytes, screening of the gross validity of a chemical analysis, and quality assurance and quality control (QA/QC) procedures. Four tests were used to screen data at selected SWAMP sites to estimate the gross validity of selected chemical data: (1) the ratio of dissolved solids (in milligrams per liter) to specific conductance (in microsiemens per centimeter); (2) the ratio of total cations (in milliequivalents per liter) multiplied by 100 to specific conductance (in microsiemens per centimeter); (3) the ratio of total anions (in milliequivalents per liter) multiplied by 100 to specific conductance (in microsiemens per centimeter); and (4) the ionic charge-balance error. Although the results of the four screening tests indicate that the chemical data generally are quite reliable, the extremely small number of samples (less than 5 percent of the total number of samples) with sufficient chemical information to run the tests may not provide a representative indication of the analytical accuracy of all laboratories in the program. In addition to the four screening tests, unusually low or high values were flagged for field and laboratory pH (less than 4.0 and greater than 9.0) and specific conductance (less than 10 and greater than 10,000 microsiemens per centimeter). The numbers of flagged data were less than 1 percent of the 19,937 water samples with pH values and less than 0.6 percent of the 16,553 water samples with specific conductance values. Thirty-four agencies responded to a detailed questionnaire that was sent to more than 60 agencies involved in the collection and analysis of surface-water-quality data for SWAMP. The purpose of the survey was to evaluate quality assurance methods and consistency of methods statewide. Information was compiled and summarized on monitoring network design, data review and upload procedures, laboratory and field sampling methods, and data practices. Currently, most agencies that responded to the survey follow FDEP-approved QA/QC protocol for sampling and have quality assurance practices for recording and reporting data. Also, most agencies responded that calibration procedures were followed in the laboratory for analysis of data, but no responses were given about the specific procedures. Approximately 50 percent of the respondents indicated that laboratory analysis methods have changed over time. With so many laboratories involved in analyzing samples for SWAMP, it is difficult to compare water quality from one site to another due to different reporting conventions for chemical constituents and different analytical methods over time. Most agencies responded that calibration methods are followed in the field, but no specific details were provided. Grab samples are the most common method of collection. Other data screening procedures are necessary to further evaluate the validity of chemical data collected at SWAMP sites. High variability in the concentration of targeted constituents may signal analytical problems, but more likely changes in concentration are related to hydrologic conditions. This underscores the need for accurate measurements of discharge, lake stage, tidal stage at the time of sampling so that changes in constituent concentrations can be properly evaluated and fluxes (loads) of nutrients or metals, for example, can be calculated and compared over time.

Florida

Reconnaissance of water quality at four swine farms in Jackson County, Florida, 1993

The quality of ground water on four typical swine farms in Jackson County, Florida, was studied by analyzing water samples from wastewater lagoons, monitoring wells, and supply wells. Water samples were collected quarterly for 1 year and analyzed for the following dissolved species: nitrate, nitrite, ammonium nitrogen, phosphorus, potassium, sulfate, chloride, calcium, magnesium, fluoride, total ammonium plus organic nitrogen, total phosphorus, alkalinity, carbonate, and bicarbonate. Additionally, the following field constituents were determined in the water samples: temperature, specific conductance, pH, dissolved oxygen, and fecal streptococcus and fecal coliform bacteria. Chemical changes in swine waste as it leaches and migrates through the saturated zone were examined by comparing median values and ranges of water- quality data from farm wastewater in lagoons, shallow pond, shallow monitoring wells, and deeper farm supply wells. The effects of hydrogeologic settings and swine farmland uses on shallow ground-water quality were examined by comparing the shallow ground-water-quality data set with the results of the chemical analyses of water from the Upper Floridan aquifer, and to land uses adjacent to the monitoring wells. Substantial differences occur between the quality of diluted swine waste in the wastewater lagoons, and that of the water quality found in the shallow pond, and the ground water frm all but two of the monitoring wells of the four swine farms. The liquid from the wastewater lagoons and ground water from two wells adjacent to and down the regional gradient from a lagoon on one site, have relatively high values for the following properties and constituents: specific conductance, dissolved ammonia nitrogen, dissolved potassium, and dissolved chloride. Ground water from all other monitoring wells and farm supply wells and the surface water pond, have relatively much lower values for the same properties and constituents. To determine the relation between land uses and ground-water quality on the four swine farms, ground-water-quality data were divided according to the following land uses: confined operations in which swine are kept in houses and not allowed to roam freely, and unconfined operations in which swine are allowed to roam freely in determined areas. Confined operations had lagoons to receive the diluted swine wastes washed from the houses.

Florida

Statistical summaries of ground-water level data collected in the Suwannee River Water Management District, 1948 to 1994

Since 1948, ground-water level data have beensystematically collected from selected wells in theSuwannee River Water Management District (SRWMD) by the U.S. Geological Survey (USGS),the SRWMD, and other agencies. Records of waterlevels in the SRWMD (fig. 1), collected by the USGS and SRWMD through 1990, and by the SRWMD from 1990 to 1994, have been published for many years in the USGS annual report series "Water Resources Data for Florida." However, no systematic statistical summaries of water levels in the SRWMD have been previously published. The need for such statistical summary data forevaluations of drought severity, ground-water supplyavailability, and minimum water levels for regulatory purposes increases daily as demands for ground-water usage increase. Also, much of the base flow of the Suwannee River is dependent upon ground water. As the population and demand for ground water for drinking water and irrigation purposes increase, the ability to quickly and easily predict trends in ground-water availability will become paramount. In response to this need, the USGS, in cooperation with the SRWMD, compiled this report. Ground-water sta tistics for 136 sites are presented as well as figures showing water levels that were measured in wells from 1948 through September 1994. In 1994, the SRWMD and the USGS began a long- term program of cooperative studies designed tobetter understand minimum and maximum streamflows and ground-water levels in the SRWMD. Minimum and maximum flows and levels are needed by the district to manage the surface- and ground-water resources of the SRWMD and to maintain or improve the various ecosystems. Data evaluation was a necessary first step in the long- term SRWMD ground-water investigations program, because basic statistics for ground-water levels are not included in the USGS annual data reports such as "Water Resources Data for Florida, Water Year 1994" (Fran klin and others, 1995). Statistics included in this report were generated using the USGS computer pro gram ADAPS (Automatic Data Processing System) to characterize normal ground-water levels and depar tures from normal. The report has been organized so that the statisti cal analyses of water levels in the wells are presentedfollowing this introductory material, a description ofthe hydrogeology in the study area, and a description of the statistics used to present the water-level data. Specifically, the report presents statistical analyses for each well, as appropriate, in the following manner: Description of the well.Hydrographs of ground-water levels for the period of record, for the last 10 years of record, and for the last 5 years of record. Graphs of maximum, minimum, and mean of monthly mean ground-water levels for wells with 5 or more years of record.Frequency hydrographs (25, 50, and 75 percent) of monthly mean ground-water levels for wells with 5 or more years of record. Water-level data and statistical plots are grouped by county and sorted within the county by ascendingsite identification number. Well locations are plottedon county maps preceding the well descriptions andhydrographs.

Open-File Report