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Geology topics

J.G. Moore

Publications and source records attributed to J.G. Moore.

At least 37 records · Page 2Linked to original sources
USGS1982

Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano, Hawaii

Eighteen basalts and some volcanic gases from the submarine and subaerial parts of Kilauea volcano were analyzed for the concentration and isotope ratios of sulfur. By means of a newly developed technique, sulfide and sulfate sulfur in the basalts were separately but simultaneously determined. The submarine basalt has 700 ± 100 ppm total sulfur with δ 34 S Σs of 0.7 ± 0.1 ‰ ">‰ 0.7 ± 0.1 ‰ . The sulfate/sulfide molar ratio ranges from 0.15 to 0.56 and the fractionation factor between sulfate and sulfide is +7.5 ± 1.5‰ ">‰ +7.5 ± 1.5‰ . On the other hand, the concentration and δ 34 S Σs values of the total sulfur in the subaerial basalt are reduced to 150 ± 50 ppm and −0.8 ± 0.2‰ ">‰ −0.8 ± 0.2‰ , respectively. The sulfate to sulfide ratio and the fractionation factor between them are also smaller, 0.01 to 0.25 and +3.0‰, respectively. Chemical and isotopic evidence strongly suggests that sulfate and sulfide in the submarine basalt are in chemical and isotopic equilibria with each other at magmatic conditions. Their relative abundance and the isotope fractionation factors may be used to estimate the ƒo 2 "> ƒo 2 and temperature of these basalts at the time of their extrusion onto the sea floor. The observed change in sulfur chemistry and isotopic ratios from the submarine to subaerial basalts can be interpreted as degassing of the SO 2 from basalt thereby depleting sulfate and 34 S in basalt. The volcanic sulfur gases, predominantly SO 2 , from the 1971 and 1974 fissures in Kilauea Crater have δ 34 S values of 0.8 to 0.9%., slightly heavier than the total sulfur in the submarine basalts and definitely heavier than the subaerial basalts, in accord with the above model. However, the δ 34 S value of sulfur gases (largely SO 2 ) from Sulfur Bank is 8.0%., implying a secondary origin of the sulfur. The δ 34 S values of native sulfur deposits at various sites of Kilauea and Mauna Loa volcanos, sulfate ions of four deep wells and hydrogen sulfide from a geothermal well along the east rift zone are also reported. The high δ 34 S values (+5 to +6%. o ) found for the hydrogen sulfide might be an indication of hot basalt seawater reaction beneath the east rift zone.

Geochimica et Cosmochimica Acta↗
USGS1980

Late Cenozoic volcanic rocks of the southern Sierra Nevada, California: I. Geology and petrology: Summary

The geology and petrology of the Cenozoic volcanic rocks of the region of California between 38° and 35°45'N latitude and 117°30' and 120°W longitude, including the rocks of a major potassic magmatic province on the west slope of the Sierra Nevada, have been described in Part I (Moore and Dodge, 1980) of this study. The geochemical features of these rocks may provide clues to their origin and aid in comparing and contrasting the Sierra Nevada potassic province with other localized potassic provinces elsewhere in the world. Basaltic rocks occur in numerous small lava-flow remnants, dikes, and plugs that intrude the predominantly granitic terrain of the western slope of the southern Sierra Nevada. Leucite-bearing rocks are present at several localities in this western region. More voluminous basalt, commonly associated with rhyolite, is present east of the range in the Basin and Range province. However, leucite-bearing rocks have been found-at only one locality in this region. Most of the late Cenozoic volcanic rocks in the southern Sierra Nevada eastward through Owens Valley and in the extreme western Basin-Range occur in five rather distinctive areas—the San Joaquin-Kings, Kern, Big Pine, and Coso volcanic fields, and the Mono-Long Valley volcanic center (Fig. 1).

Geological Society of America Bulletin, Part I↗
USGS1977

CO2-filled vesicles in mid-ocean basalt

Volatile-filled vesicles are present in minor amounts in all samples of mid-ocean basalt yet collected (and presumably erupted) down to depths of 4.8 km. When such vesicles are pierced in liquid under standard conditions, the volume expansion of the gas is 0.2 ?? 0.05 times the eruption pressure in bars or 20 ?? 5 times the eruption depth in km. Such expansion could be used as a measure of eruption depth. A variety of techniques: (1) vacuum crushing and gas chromatographic, freezing separation, and mass spectrographic analyses; (2) measurements of phase changes on a freezing microscope stage; (3) microscopic chemical and solubility observations; and (4) volume change measurements, all indicate that CO2 comprises more than 95% by volume of the vesicle gas in several submarine basalt samples from the Atlantic and Pacific. The CO2 held in vesicles is present in quantities about equal to or greater than that presumed to be dissolved in the glass (melt) and amounts to 400-900 ppm of the rock. The rigid temperature of the glass is 800-1000??C and increases for shallower samples. A sulfur gas was originally present in subordinate amounts in the vesicles, but has largely reacted with iron in the vesicle walls to produce sulfide spherules. ?? 1977.

Journal of Volcanology and Geothermal Research↗
USGS1976

Volcanic rocks and processes of the Mid-Atlantic Ridge rift valley near 36 ° 49′ N

Eighty samples of submarine basaltic lava were sampled from an 8 km segment of the floor and walls of the inner rift valley of the Mid-Atlantic Ridge during the French American Mid-Ocean Undersea Study (project Famous). The samples were collected from outcrops and talus slopes by the three submersibles: Alvin, Archimede, and Cyana at water depths of about 2600 meters. The early formed mineral content of the pillow lavas' glassy margins enables classification of the rocks into 5 types: (1) olivine basalt, (2) picritic basalt, (3) plagioclase-olivine-pyroxene basalt, (4) aphyric basalt, and (5) plagioclase-rich basalt. Chemical and mineralogical study indicates that at least 4 types are directly interrelated and that types (1) and (2) are higher-temperature, primitive lavas, and types (3) and (4) are lower-temperature, differentiated lavas derived from the primitive ones by crystal-liquid differentiation. The plagioclase-rich basalts also have a chemical composition of their glass comparable to that of the most differentiated basalts (types 3 and 4) but they differ in their greater amount of early formed plagioclase (12–35%). In general, the mineralogical variation across the rift valley shows an assymetrical distribution of the major basalt types. Despite the mineralogical diversity of the early formed crystals, the chemistry of the basalt glasses indicates a symmetrical and a gradual compositional change across the rift valley. Based primarily on their chemistry, the rock types 1 and 2 occupy an axial zone 1.1 km wide and make up the central volcanic hills. Differentiated lavas (types 3, 4) occupy the margins and walls of the inner rift valley and also occur near the center of the rift valley between the central hills. FeO/MgO ratios of olivine and coexisting melt indicate that the average temperature of eruption was 40 ° C higher for the primitive melts (types 1 and 2). Aside from major elements trends, the higher temperature character of the primitive basalts is shown by their common content of chrome spinel. The thickness of manganese oxide and palagonite on glassy lava provide an estimate of age. In a general fashion the relative age of the various volcanic events follow the compositional zoning observed in the explored area. Most of the youngest samples are olivine basalt of the axial hills. Most older samples occur in the margins of the rift valley (West and N.E. part of explored area) but are significantly younger than the spreading age of the crust on which they are erupted. Intermediate lava types occur mainly east of the rift valley axis and in other areas where plagioclase—olivine—pyroxene basalt and aphyric basalt are present. The above relations indicate that the diverse lava types were erupted from a shallow, zoned magma chamber from fissures distributed over the width of the inner rift valley and elongate parallel to it. Differentiation was accomplished by cooling and crystallization of plagioclase, olivine, and clinopyroxene toward the margins of the chamber. The centrally located hills were built by the piling up of frequent eruption of mainly primitive lavas which also are the youngest flows. In contrast smaller and less frequent eruptions of more differentiated lavas were exposed on both sides of the rift valley axis.

Contributions to Mineralogy and Petrology↗
USGS1976

Man against volcano: The eruption on Heimaey, Vestmann Islands, Iceland

The U.S. Geological Survey carries out scientific studies in the geological, hydrological, and cartographic sciences generally within the 50 states, but also in cooperation with scientific organizations in many foreign countries for the investigation of unusual earth science phenomena throughout the world. The following material discusses the impact of the 1973 volcanic eruption of Eldfell on the fishing port of Vestmannaeyjar on the island of Heimaey, Iceland. Before the eruption was over, approximately one-third of the town of Vestmannaeyjar had been obliterated but, more importantly, the potential damage had been reduced markedly by the spraying of seawater onto the advancing lava flows, causing them to be slowed, stopped, or diverted from the undamaged portion of the town. The Survey's interest and involvement in the Heimaey eruption in Iceland was occasioned by the possibility that the procedures used to control the course of the flowing lava and to reduce the damage in a modern town may some day be needed in Hawaii and possibly even in the continental United States. This publication is based on the observations of two USGS geologists, Richard S. Williams, Jr. and James G. Moore, as well as on information from the Icelandic Ministry for Foreign Affairs, Icelandic scientists' reports through the Center for Short-Lived Phenomena, and other published scientific reports. A number of Icelandic scientists studied the scientific aspects of the eruption and the engineering aspects of the control of lava flows, in particular, Professors Thorbjb'rn Sigurgeirsson and Sigurdur Thorarinsson of the University of Iceland Science Institute. Also, Icelandic governmental officials provided logistical and other support, in particular, Mr. Steingnmur Hermannsson, Director, Icelandic National Research Council and Professor Magnus Magnusson, Director, University of Iceland Science Institute.

Vestmannaeyjar↗
USGS1976

Earthquakes and related catastrophic events, Island of Hawaii, November 29, 1975: A preliminary report

The largest earthquake in over a century--magnitude 7.2 on the Richter Scale--struck Hawaii the morning of November 29, 1975, at 0448. It was centered about 5 km beneath the Kalapana area on the southeastern coast of the island at 19° 20.1 ' N., long 155° 01.4 ' W.). The earthquake was preceded by numerous foreshocks, the largest of which was a 5.7-magnitude jolt at 0336 the same morning, and was accompanied, or closely followed, by a tsunami seismic sea wave), massive ground movements, hundreds of aftershocks, and a volcanic eruption. The tsunami reached a height of 12.2-14.6 m above sea level on the southeastern coast about 25 km west of the earthquake center, elsewhere generally 8 m or less. The south flank of Kilauea Volcano, which forms the southeastern part of the island, was deformed by dislocations along old and new faults along a 25-km long zone. Downward and seaward fault displacements resulted in widespread subsidence, locally as much as 3.5 m, leaving coconut palms standing in the sea and nearly submerging a small, near-shore island. A brief, small-volume volcanic eruption, triggered by the earthquake and associated ground movements occurred at Kilauea's summit about three-quarters of an hour later. The earthquake, together with the tsunami it generated, locally caused severe property damage in the southeastern part of the island; the tsunami also caused two deaths. Damage from the earthquake and related catastrophic events is estimated by the Hawaii Civil Defense Agency at about $4.1 million. The 1975 Kalapana earthquake and accompanying events represent the latest events in a recurring pattern of behavior for Kilauea. A large earthquake of about the same magnitude, tsunami, subsidence, and eruption occurred at Kilauea in 1868, and a less powerful earthquake and similar related processes are believed to have occurred in 1823. Indeed, the geologic evidence suggests that such events have been repeated many times in Kilauea's past and will continue. The 1975 events serve as a critical, though tragic, reminder of the dynamic nature of the volcano and point up the need for careful land-use planning and adequate building codes to minimize damage and loss of life from similar events in the future. Detailed scientific study of the cause and effects of the November 29, 1975, event will take many months. This report summarizes information available in February 1976.

Hawaii↗
USGS1973

Vesicles, water, and sulfur in Reykjanes Ridge basalts

Dredge hauls of fresh submarine basalt collected from the axis of the Reykjanes Ridge (Mid-Atlantic Ridge) south of Iceland were taken aboard R/ V TRIDENT in 1967 and 1971. The samples show systematic changes as the water depth of collection (and eruption) decreases: radially elongate vesicles and concentric zones of vesicles appear at about 700 m depth and are conspicuous to shallow water; the smoothed volume percent of vesicles increases from 5% at 1000 m, 10% at 700 m, to 16% at 500 m, and the scatter in degree of vesicularity increases in shallower water; specific gravity decreases from 2.7±0.1 at 1000 m to 2.3±0.3 at 100 m. Bulk sulfur content for the outer 2 cm averages 843 ppm up to a depth of 200 m, then drops off rapidly in shallower water owing to degassing. Sulfur content below 200 m is independent of depth (or geographic position), and the melt is apparently saturated with sulfur, but the excess cannot escape the lava unless another vehicle carries it out. Only shallower than 200 m, where intense vesiculation of other gases occurs can excess sulfur be lost from the lava erupting on the sea floor. H 2 O +110° averages about 0.35 percent and H 2 O +150° about 0.25 percent, and both apparently decrease in water shallower than 200 m as a result of degassing. H 2 O + (below 200 m) decreases with distance from Iceland or increasing depth, presumably as a result of either adsorption of water on the surface of shallower, more vesicular rocks; or more likely due to the presence of the Iceland hot mantle plume supplying undifferentiated primordial material, relative to lavas of the Reykjanes Ridge supplied from the low velocity layer already depleted in volatiles and large lithophile elements. The H 2 O +110° /S ratio of lava erupting below 200 m water depth ranges from 3 to 5 which is comparable to reliable gas analyses from oceanic basaltic volcanoes.

Contributions to Mineralogy and Petrology↗
USGS1971

An estimate of the juvenile sulfur content of basalt

Sulfur analyses by X-ray fluorescence give an average content of 107 ppm for 9 samples of fresh subaerially-erupted oceanic basalt and 680 ppm for 38 samples of submarine erupted basalt. This difference is the result of retention of sulfur in basalt quenched on the sea floor and loss of sulfur in basalt by degassing at the surface. The outer glassy part of submarine erupted basalt contains 800±150 ppm sulfur, and this amount is regarded as an estimate of the juvenile sulfur content of the basalt melt from the mantle. The slower cooled interiors of basalt pillows are depleted relative to the rims owing to degassing and escape through surface fractures. Available samples of deep-sea basalts do not indicate a difference in original sulfur content between low-K tholeiite, Hawaiian tholeiite, and alkali basalt.

Contributions to Mineralogy and Petrology↗
USGS1970

Water content of basalt erupted on the ocean floor

Deep sea pillow basalts dredged from the ocean floor show that vesicularity changes with composition as well as with depth. Alkalic basalts are more vesicular than tholeiitic basalts erupted at the same depth. The vesicularity data, when related to experimentally determined solubility of water in basalt, indicate that K-poor oceanic tholeiites originally contained about 0.25 percent water, Hawaiian tholeiites of intermediate K-content, about 0.5 percent water, and alkali-rich basalts, about 0.9 percent water. Analyses of fresh basalt pillows show a systematic increase of H 2 O + as the rocks become more alkalic. K-poor oceanic tholeiites contain 0.06–0.42 percent H 2 O + , Hawaiian tholeiites, 0.31–0.60 percent H 2 O + , and alkali rich basalts 0.49–0.98 percent H 2 O + . The contents of K 2 O, P 2 O 5 , F, and Cl increase directly with an increase in H 2 O + content such that at 1.0 weight percent H 2 O + , K 2 O is 1.58 percent, P 2 O 5 is 0.55 percent, F is 0.07 percent, and Cl is 0.1 percent. The measured weight percent of deuterium on the rim of one Hawaiian pillow is −6.0 (relative to SMOW); this value, which is similar to other indications of magmatic water, suggests that no appreciable sea water was absorbed by the pillow during or subsequent to eruption on the ocean floor. Concentrations of volatile constituents in the alkali basalt melts relative to tholeiitic melts can be explained by varying degrees of partial melting of mantle material or by fractional crystallization of a magma batch.

Contributions to Mineralogy and Petrology↗
USGS1970

Relationship between subsidence and volcanic load, Hawaii

A computer analysis of tide-gage records in the northeast Pacific indicates that the active volcanic islands of eastern Hawaii are subsiding at a rate considerably faster than the eustatic rise of sea level. The rate of absolute subsidence increases progressively toward the center of current activity on the Island of Hawaii. Honolulu, Oahu, appears to be stable; Kahului, Maui, is subsiding at 1.7 mm per year; and Hilo, Hawaii, is subsiding at 4.8 mm per year. This subsidence is apparently related to downbowing of the crust throughout a zone 400 km in diameter by the weight of volcanic material added to the crust by active volcanoes, principally Mauna Loa and Kilauea on the Island of Hawaii. The Hawaiian Arch encircles the subsiding zone and may be uplifted by material moving down and outward from the zone of subsidence. The annual volume of subsidence is about 270×10 6 m 3 , whereas the average annual volume of erupted basalt on the Island of Hawaii (based on historic records back to about 1820) is about 50×10 6 m 3 . The great excess of subsidence over volcanic addition cannot be reconciled by isostatic models, and is apparently the result of other processes operating in the volcano and its basement thet are poorly understood. Probably the more important of these processes are intrusions and submarine volcanism, both of which are providing additional unseen load on the volcanoes. Furthermore, the rate of eruption may be uplifted by material moving down and outward from the zone of subsidence may be overestimated due to localized downslope movement of the margins of the islands.

Hawaii↗
USGS1970

Submarine basalt from the Revillagigedo Islands region, Mexico

Ocean-floor dredging and submarine photography in the Revillagigedo region off the west coast of Mexico reveal that the dominant exposed rock of the submarine part of the large island-forming volcanoes (Roca Partida and San Benedicto) is a uniform alkali pillow basalt; more siliceous rocks are exposed on the upper, subaerial parts of the volcanoes. Basalts dredged from smaller seamounts along the Clarion fracture zone south of the Revillagigedo Islands are tholeiitic pillow basalts. Pillows of alkali basalts are more vesicular than Hawaiian tholeiitic pillows collected from the same depths. This difference probably reflects a higher original volatile content of the alkali basalts. Manganese-iron oxide nodules common in several dredge hauls generally contain nucleii of rhyolitic pumice or basalt pillow fragments. The pumice floated to its present site from subaerial eruptions, became waterlogged and sank, and was then coated with manganese-iron oxides. The thickness of palagonite rinds on the glassy pillow fragments is proportional to the thickness of manganese-iron oxide layers, and both are a measure of the age of the nodule. Both oldest basalts (10–100 m.y.) and youngest (less than 1 m.y.) are along the Clarion fracture zone, whereas basalts from Roca Partida and San Benedicto volcanoes are of intermediate age.

Marine Geology↗
USGS1968

Argon-40: Excess in submarine pillow basalts from Kilauea Volcano, Hawaii

Submarine pillow basalts from Kilauea Volcano contain excess radiogenic argon-40 and give anomalously high potassium-argon ages. Glassy rims of pillows show a systematic increase in radiogenic argon-40 with depth, and a pillow from a depth of 2590 meters shows a decrease in radiogenic argon-40 inward from the pillow rim. The data indicate that the amount of excess radiogenic argon-40 is a direct function of both hydrostatic pressure and rate of cooling, and that many submarine basalts are not suitable for potassium-argon dating.

Hawaii↗
USGS1967

Base surge in recent volcanic eruptions

A base surge, first identified at the Bikini thermonuclear undersea explosion, is a ring-shaped basal cloud that sweeps outward as a density flow from the base of a vertical explosion column. Base surges are also common in shallow underground test explosions and are formed by expanding gases which first vent vertically and then with continued expansion rush over the crater lip (represented by a large solitary wave in an underwater explosion), tear ejecta from it, and feed a gas-charged density flow, which is the surge cloud. This horizontally moving cloud commonly has an initial velocity of more than 50 meters per second and can carry clastic material many kilometers. Base surges are a common feature of many recent shallow, submarine and phreatic volcanic eruptions. They transport ash, mud, lapilli, and blocks with great velocity and commonly sandblast and knock down trees and houses, coat the blast side with mud, and deposit ejecta at distances beyond the limits of throw-out trajectories. Close to the eruption center, the base surge can erode radial channels and deposit material with dune-type bedding.

Bulletin Volcanologique↗
USGS1966

Crystallization of tholeiitic basalt in Alae Lava Lake, Hawaii

The eruption of Kilauea Volcano August 21–23, 1963, left 600,000 cubic meters of basaltic lava in a lava lake as much as 15 meters deep in Alae pit crater. Field studies of the lake began August 27 and include repeated core drilling, measurements of temperature in the crust and melt, and precise level surveys of the lake surface. The last interstitial melt in the lake solidified late in September 1964; by mid August 1965 the maximum temperature was 690°C at a depth of 11.5 meters. Pumice air-quenched from about 1140°C contains only 5 percent crystals — clinopyroxene, cuhedral olivine ( Fo 80 ), and a trace of plagioclase, ( An 70 ). Drill cores taken from the zone of crystallization in the lake show that olivine continued crystallizing to about 1070°C; below that it reacts with the melt, becoming corroded and mantled by pyroxene and plagioclase. Below 1070°C, pyroxene and plagioclase crystallized at a constant ratio. Ilmenite first appeared at about 1070°C and was joined by magnetite at about 1050°C; both increased rapidly in abundance to 1000°C. Apatite first appeared as minute needles in interstitial glass at 1000°C. Both the abundance and index of refraction of glass quenched from melt decreased nearly linearly with falling temperature. At 1070°C the quenched lava contains about 65 percent dark-brown glass with an index of 1.61; at 980°C it contains about 8 percent colorless glass with an index of 1.49. Below 980°C, the percentage of glass remained constant. Progressive crystallization forced exsolution of gases from the melt fraction; these formed vesicles and angular pores, causing expansion of the crystallizing lava and lifting the surface of the central part of the lake an average of 19.5 cm. The solidified basalt underwent pneumatolitic alteration, including deposition of cristobalite at 800°C, reddish alteration of olivine at 700°C, tarnishing of ilmenite at 550°C, deposition of anhydrite at 250°C, and deposition of native sulfur at 100°C. Ferric-ferrous ratios suggest that oxidation with maximum intensity between 550°C and 610°C moved downward in the crust as it cooled; this was followed by reduction at a temperature of about 100°C. The crystallized basalt is a homogeneous fine-grained rock containing on the average 48.3 percent by volume intergranular pyroxene (augite > pigeonite), 34.2 percent plagioclase laths (An 60 70 ), 7.9 percent interstitial glass, 6.9 percent opaques (ilmenite > magnetite), 2.7 percent olivine (Fo 70 80 ), and a trace of apatite. Chemical analyses of 18 samples, ranging from initially quenched pumice to lava cored more than a year after the eruption from the center and from near the base of the lake, show little variation from silica-saturated tholeiitic basalt containing 50.4 percent SiO 2 , 2.4 percent Na 2 O, and 0.54 percent K 2 O. Apparently there was no significant crystal settling and no appreciable vapor-phase transport of these components during the year of crystallization. However, seven samples of interstitial liquid that had been filter-pressed into gash fractures and drill holes from partly crystalline mush near the base of the crust show large differences from the bulk composition of the solidified crust—lower MgO, CaO, and Al 2 O 3 ; and higher total iron, TiO 2 , Na 2 O, K 2 O, P 2 O 5 , and F, and, in most samples, SiO 2 . The minor elements Ba, Ga, Li, Y, and Yb and possibly Cu tend to be enriched in the filter-pressed liquids, and Cr and possibly Ni tend to be depleted.

Hawaii↗