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Geology topics

J.A. Fitzpatrick

Publications and source records attributed to J.A. Fitzpatrick.

6 recordsLinked to original sources

Climatic/Hydrologic Oscillations since 155,000 yr B.P. at Owens Lake, California, Reflected in Abundance and Stable Isotope Composition of Sediment Carbonate

Sediment grain size, carbonate content, and stable isotopes in 70-cm-long (∼1500-yr) channel samples from Owens Lake core OL-92 record many oscillations representing climate change in the eastern Sierra Nevada region since 155,000 yr B.P. To first order, the records match well the marine δ 18 O record. At Owens Lake, however, the last interglaciation appears to span the entire period from 120,000 to 50,000 yr B.P., according to our chronology, and was punctuated by numerous short periods of wetter conditions during an otherwise dry climate. Sediment proxies reveal that the apparent timing of glacial–interglacial transitions, notably the penultimate one, is proxy-dependent. In the grain-size and carbonate-content records this transition is abrupt and occurs at ∼120,000 yr B.P. In contrast, in the isotopic records the transition is gradual and occurs between 145,000 and 120,000 yr B.P. Differences in timing of the transition are attributed to variable responses by proxies to climate change.

Quaternary Research

Migration and rearing histories of chinook salmon (Oncorhynchus tshawytscha) determined by ion microprobe Sr isotope and Sr/Ca transects of otoliths

Strontium isotope and Sr/Ca ratios measured in situ by ion microprobe along radial transects of otoliths of juvenile chinook salmon ( Oncorhynchus tshawytscha ) vary between watersheds with contrasting geology. Otoliths from ocean-type chinook from Skagit River estuary, Washington, had prehatch regions with 87 Sr/ 86 Sr ratios of ~0.709, suggesting a maternally inherited marine signature, extensive fresh water growth zones with 87 Sr/ 86 Sr ratios similar to those of the Skagit River at ~0.705, and marine-like 87 Sr/ 86 Sr ratios near their edges. Otoliths from stream-type chinook from central Idaho had prehatch 87 Sr/ 86 Sr ratios ≥0.711, indicating that a maternal marine Sr isotopic signature is not preserved after the ~1000- to 1400-km migration from the Pacific Ocean. 87 Sr/ 86 Sr ratios in the outer portions of otoliths from these Idaho juveniles were similar to those of their respective streams (~0.708–0.722). For Skagit juveniles, fresh water growth was marked by small decreases in otolith Sr/Ca, with increases in Sr/Ca corresponding to increases in 87 Sr/ 86 Sr with migration into salt water. Otoliths of Idaho fish had Sr/Ca radial variation patterns that record seasonal fluctuation in ambient water Sr/Ca ratios. The ion microprobe's ability to measure both 87 Sr/ 86 Sr and Sr/Ca ratios of otoliths at high spatial resolution in situ provides a new tool for studies of fish rearing and migration.

Canadian Journal of Fisheries and Aquatic Sciences

Ikaite precipitation by mixing of shoreline springs and lake water, Mono Lake, California, USA

Metastable ikaite (CaCO 3 ·6H 2 O) forms abundantly during winter months along the south shoreline of Mono Lake where shoreline springs mix with lake water. Ikaite precipitates because of its decreased solubility at low temperature and because of orthophosphate-ion inhibition of calcite and aragonite. During the spring some of the ikaite is transformed to anhydrous CaCO 3 and is incorporated into tufa, but most is dispersed by wave action into the lake where it reacts to form gaylussite (Na 2 Ca(CO 3 ) 2 · 5H 2 O). Spring waters have low pH values, are dominantly Ca-Na-HCO 3 , have low radiocarbon activities, and are mixtures of deep-seated geothermal and cold groundwaters. Chemical modeling reveals that precipitation of CaCO 3 can occur over a broad range of mixtures of spring and lake water with a maximum production occurring at 96% spring water and 4% lake water. Under these conditions all the Ca and a significant fraction of the CO 3 of the precipitate is spring supplied. A radiocarbon age of 19,580 years obtained on a natural ikaite sample supports this conclusion. With the springs supplying a large and probably variable portion of the carbonate, and with apparent 14 C age of the carbonate varying from spring to spring, tufa of similar actual antiquity may yield significantly different 14 C dates, making tufa at this location unsuitable for absolute age dating by the radiocarbon method.

Geochimica et Cosmochimica Acta