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J. S. Stacey

Publications and source records attributed to J. S. Stacey.

31 records · Page 2Linked to original sources

Late Proterozoic island-arc complexes and tectonic belts in the southern part of the Arabian Shield, Kingdom of Saudi Arabia

Two main subdivisions of layered rocks are recognized in the southern Arabian Shield south of lat 22? N. These are an older ensimatic-arc complex, which formed 1100-800 m.y. ago, and a younger marginal-arc complex, which formed 800-690 m.y. ago. The older ensimatic-arc complex, located in the southwestern part of the Shield, includes graywacke and mafic to intermediate volcanic rocks of the essentially contemporaneous Baish, Bahah, and Jiddah groups. Although the younger arc complex is also dominantly ensimatic in character, it is also partly superimposed over the older ensimaticarc complex. The superimposed portions of the younger arc complex are represented by the Ablah, Samran, and possibly the Ararat groups. The ensimatic portion of the younger arc group is represented by the Halaban group, which was deposited to the east and northeast of the older ensimatic-arc complex. The Halaban group includes andesitic and dacitic volcanic rocks and associated clastic sedimentary rocks. The layered rocks of both arc complexes are intruded by dioritic (quartz diorite, tonalite, trondhjemite) plutonic rocks. The southern Shield is also subdivided into a number of structurally bounded, north-trending tectonic belts. Within the older ensimatic complex, three belts are recognized. From west to east, these are the Lith, Bidah, and Tayyah belts. Within these three belts, progressive facies changes indicate a gradation from deep-water facies in the south to shallow-water or-terrestrial facies in the north. The distribution of dioritic batholiths, as well as the distribution of layered-rock facies, suggests a northwest-trending axis for the older ensimatic-arc complex. The younger arc complex is present within six belts, the Makkah source papers. In Fleck and others (1980), the term 'quartz diorite' includes both tonalite and quartz diorite as defined in the International Union of Geological Sciences (IUGS) system of plutonic rock classification (Streckeisen, 1973). Initial 87Sr/86Sr ratios are not included in the appendix, but all rocks more than 660 m.y. old have initial ratios in the range 0.7021-0.7035, with only two greater than 0.7030. Thus, nothing in the Rb-Sr data suggests involvement of an older continental crust during the evolution of the southern Shield. A lead isotope study of ore minerals and potassium feldspars of the Arabian Shield by Stacey and others (1980) also suggests that no older (Archean to early Proterozoic) evolved continental-type crust underlies the southern Shield. An early summary of mapping (Schmidt and others, 1973) suggests that older sialic basement underlies the late Proterozoic layered rocks in the southern Shield. However, subsequent-mapping and the isotopic studies cited above have established that all of these rocks are of late Proterozoic age and that all rocks of the southern Shield that are more than 660 m.y. old have ensimatic or mantle isotopic characteristics. Figure 2 shows, with only two exceptions, that rocks more than 800 m.y. old are present west of the boundary separating the Tayyah and Khadra belts. The exceptions are two poorly controlled Rb-Sr ages obtained by Fleck (1980) on two quartz diorite plutons in the Malahah region (appendix 1, localities 26 and 27). Preliminary uranium-thorium zircon data of Stacey now suggest that one of these quartz diorite plutons (locality 26) has an age of approximately 640 m.y. Therefore, we prefer to discount the two dates of Fleck until further information is available. As noted earlier and as described below, most of the rocks of the southern Arabian Shield have characteristics typical of those formed in the island-arc environment by subduction-related processes. We shall refer to the group of rocks in the western part of the southern Shield, which formed from 1100 to 800 m.y. ago, as the 'older ensimatic-arc complex' and those in the eastern and northwestern parts, which formed from 800 to 690 m.y. ago, as the 'younger marginal-arc compl

Open-File Report↗

A five-collector system for the simultaneous measurement of argon isotope ratios in a static mass spectrometer

A system is described that utilizes five separate Faraday-cup collector assemblies, aligned along the focal plane of a mass spectrometer, to collect simultaneous argon ion beams at masses 36–40. Each collector has its own electrometer amplifier and analog-to-digital measuring channel, the outputs of which are processed by a minicomputer that also controls the mass spectrometer. The mass spectrometer utilizes a 90° sector magnetic analyzer with a radius of 23 cm, in which some degree of z -direction focussing is provided for all the ion beams by the fringe field of the magnet. Simultaneous measurement of the ion beams helps to eliminate mass-spectrometer memory as a significant source of measurement error during an analysis. Isotope ratios stabilize between 7 and 9 s after sample admission into the spectrometer, and thereafter changes in the measured ratios are linear, typically to within ±0.02%. Thus the multi-collector arrangement permits very short extrapolation times for computation of initial ratios, and also provides the advantages of simultaneous measurement of the ion currents in that errors due to variations in ion beam intensity are minimized. A complete analysis takes less than 10 min, so that sample throughput can be greatly enhanced. In this instrument, the factor limiting analytical precision now lies in short-term apparent variations in the interchannel calibration factors.

International Journal of Mass Spectrometry and Ion↗

A lead isotope study of mineralization in the Saudi Arabian Shield

New lead isotope data are presented for some late Precambrian and early Paleozoic vein and massive sulfide deposits in the Arabian Shield. Using the Stacey Kramers (1975) model for lead isotope evolution, isochron model ages range between 720 m.y. and 420 m.y. Most of the massive sulfide deposits in the region formed before 680 m.y. ago, during evolution of the shield. Vein type mineralization of higher lead content occurred during the Pan African event about 550 m.y. ago and continued through the Najd period of extensive faulting in the shield that ended about 530 m.y. ago. Late post-tectonic metamorphism may have been responsible for vein deposits that have model ages less than 500 m.y. Alternatively some of these younger model ages may be too low due to the mineralizing fluids acquiring radiogenic lead from appreciably older local crustal rocks at the time of ore formation. The low207Pb/204Pb ratios found for the deposits in the main part of the shield and for those in north-eastern Egypt, indicate that the Arabian craton was formed in an oceanic crustal environment during the late Precambrian. Involvement of older, upper-crustal material in the formation of the ore deposits in this part of the shield is precluded by their low207Pb/204Pb and208Pb/204Pb characteristics. In the eastern part of the shield, east of longitude 44??20???E towards the Al Amar-Idsas fault region, lead data are quite different. They exhibit a linear207Pb/204Pb-206Pb/204Pb relationship together with distinctly higher208Pb/204Pb characteristics. These data imply the existence of lower crustal rocks of early Proterozoic age that apparently have underthrust the shield rocks from the east. If most of the samples we have analyzed from this easterly region were mineralized 530 m.y. ago, then the age of the older continental rocks is 2,100??300 m.y. (2??). The presence of upper crustal rocks, possibly also of early Proterozoic age, is indicated by galena data from Hailan in South Yemen and also from near Muscat in Oman. These data are the first to indicate such old continental material in these regions. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Genesis of ore deposits in the San Juan Volcanic Field, Southwestern Colorado-lead isotope evidence

In the San Juan volcanic area of southwestern Colorado, the isotopic composition of lead in ores and ore prospects of Cenozoic age ranges widely: 17.72 to 21.13 for 206 Pb/ 204 Pb; 15.50 to 15.81 for 207 Pb/ 204 Pb; and 37.21 to 38 for 208 Pb/ 204 Pb. Examination of the lead isotope data indicates that once deposition of lead minerals begins, further exchange of lead between fluid and wall rock is insignificant. This conclusion is supported by the relatively constant isotopic composition of the lead in these ores, which is not affected by the grade of ore mineralization or type of wall rock. The values of 206 Pb/ 204 Pb in some vein-type deposits exceed the maximum value known for all Mesozoic and Cenozoic igneous rocks of the Rocky Mountain region. These isotopic relations show that if ore-forming solutions are composed of meteoric water, as indicated in studies of light stable isotopes, they must have penetrated deep enough to acquire lead from Pre-cambrian rocks or sediments derived from them. The fact that some of these vein ores are now in Cenozoic igneous rocks indicates the ore fluid had an upward vertical component to its movement. The lead isotope data therefore support a circulating cell hypothesis for these kinds of ores, as suggested by many recent studies of light stable isotopes as related to mineralization. Some other deposits (Summitville, Jasper, Red Mountain district) have values of 206 Pb/ 204 Pb similar to those of the large volumes of altered rock that enclose them ( 206 Pb/ 204 Pb ∼ 18.5), suggesting that in places the lead may have been locally derived by leaching of the adjacent rocks or from magmatogenic fluids. When the lead isotope data are treated in detail, the rocks and galenas of the Platoro caldera complex, of the central San Juan caklera complex, and of the Baughman Creek center appear to contain significant components derived from 1,400- to l,500-m.y.-old and 1,700- to 1,800 m.y.-old source materials. These also are the ages of the two main groups of rocks that comprise the Precambrian basement under the San Juan volcanic area. Although the data from the western San Juan caldera complex scatter considerably, the only obvious source for the lead seems to be the 1,700- to l,800-m.y.-old rocks or detritus of such age in Phanerozoic sediments. Where the involvement of 1,400- to l,500-m.y.-old sources is greatest, the Th/U ratio in the source material is small (calculated to be about 0.7), whereas the Th/U ratio of the 1,700- to l,800-m.y.-old source material appears to be 2.3 to 3.3. The largest Th/U values are from the western San Juan caldera complex. © 1979 Society of Economic Geologists, Inc.

Colorado↗

An evaluation of the zircon method of isotopic dating in the Southern Arabian Craton

A zircon study has been made on eleven samples of igneous rocks from the Saudi Arabian Craton. Ages of sized and magnetic fractions of zircon concentrates show variable degrees of discordance which seem to result from a very young disturbance that produces linear arrays in the Concordia plot. Model age calculations based on a statistically and geologically reasonable lower intercept produce very consistent internal relationships. The Pan African Orogeny, considered to be responsible for loss of radiogenic argon and strontium from minerals of many rocks, does not appear to have affected the zircon data, even though uplift had exposed the rocks of the Arabian Shield at that time. Tonalite, granodiorite, and crosscutting leucoadamellite bodies in the southern part of the An Nimas Bathylith yield ages in the time range 820-760 Ma. A narrow time range of 660 to 665 million years was indicated for ages of widely separated and compositionally different intrusive bodies all to the east of the An Nimas Bathylith. This work suggests that the younger end of the age spectrum established from regional K-Ar and Rb-Sr measurements may be underestimated, and that magmatic activity could be more episodic than previously assumed.

Contributions to Mineralogy and Petrology↗

An evaluation of the zircon method of isotopic dating in the southern Arabian Craton, Kingdom of Saudi Arabia

A zircon study has been made on 11 samples of igneous rocks from the Saudi Arabian craton. Ages of sized and magnetic fractions of zircon concentrates show variable degrees of discordance, which seem to result from a very young disturbance that produces linear arrays in the Concordia plot. Model age calculations based on a statistically and geologically reasonable lower intercept produce very consistent internal relationships. The Pan African Orogeny, considered to be responsible for loss of radiogenic argon and strontium from minerals of many rocks, does not appear to have affected the zircon data, even though uplift had exposed the rocks of the Arabian Shield at that time. Tonalite, granodiorite, and crosscutting leuco-adamellite bodies in the southern part of the An Nimas batholith yield ages in the time range 820-760 m.y. A narrow time range of 660 to 665 million years was indicated for ages of widely separated and compositionally different intrusive bodies all to the east of the An Nimas batholith. This work suggests that the younger end of the age spectrum established from regional K-Ar and Rb-Sr measurements may be underestimated, and that magmatic activity could have been more episodic than previously assumed.

Open-File Report↗

A program for mass spectrometer control and data processing analyses in isotope geology; written in BASIC for an 8K Nova 1120 computer

A system is described which uses a minicomputer to control a surface ionization mass spectrometer in the peak switching mode, with the object of computing isotopic abundance ratios of elements of geologic interest. The program uses the BASIC language and is sufficiently flexible to be used for multiblock analyses of any spectrum containing from two to five peaks. In the case of strontium analyses, ratios are corrected for rubidium content and normalized for mass spectrometer fractionation. Although almost any minicomputer would be suitable, the model used was the Data General Nova 1210 with 8K memory. Assembly language driver program and interface hardware-descriptions for the Nova 1210 are included.

Open-File Report↗

Some triple-filament lead isotope ratio measurements and an absolute growth curve for single-stage leads

Triple-filament analyses of three standard lead samples are used to calibrate a mass spectrometer in an absolute sense. The bias we measure is 0.0155 percent per mass unit, and the precision (for 95% confidence limits) is ±0.13% or less for all ratios relative to 204 Pb. Although its precision is not quite so good as that of the lead-tetramethyl method in the analysis of large samples, the triple-filament method is less complex and is an attractive alternative for smaller sample sizes down to 500 μg. Triple-filament data are presented for six possibly single-stage lead ores and one feldspar. These new data for ores are combined with corrected tetramethyl data for stratiform lead deposits to compute absolute parameters for a universal single-stage lead isotope growth curve. Absolute isotopic ratios for primeval lead have been determined by Oversby and because all the previous data for both meteorites and lead ores were similarly fractionated, the absolute value of 238 U 204 Pb= 9.09 ± 0.06 for stratiform leads is little different from the value 8.99 ± 0.05 originally computed by Ostic, Russell and Stanton. Absolute values for lead isotope ratios for all interlaboratory standard samples presently available from the literature are tabulated.

Earth and Planetary Science Letters↗

A lead isotope study of galenas and selected feldspars from mining Districts in Utah

The leads in feldspars from the main Tertiary intrusive bodies in each of three mining regions in Utah are isotopically similar to the lead deposits immediately associated with them. These deposits are the largest and also the least radiogenic in each region, whereas the smaller deposits are more radiogenic. Throughout each region the 'ore leads appear to be mixtures in various proportions of lead derived from the intrusive magma and a radiogenic lead component derived from the upper crustal rocks through which the mineralizing fluids passed. Linear relationships are exhibited between the lead isotope ratios within each mining region, and these enable the ages of the upper crustal basement rocks to be determined. A simple tvo-stage model theory for the development of the lead ores yields the folloving data: Oquirrh Mountains region, t 1,650 4-150 m.y., p-Cottonwood-Park City region, t = 2,415 4-30 m.y., p- = 8.87. Tintlc region, t 2,075 4-30 m.y., Milford region, t 1 765 4-70 m.y., p-T ( Us ) = , = 8.83. An alternative "mixing" model is also proposed which requires only 1,650-m.y. and 2,400-m.y. events in these regions. In either case these ages confirm and supplement our present geochronological knowledge of the basement rocks of Utah .

Utah↗

Precision measurement of lead isotopes ratios: preliminary analyses from the U.S. mine, Bingham Canyon, Utah

A gas-source mass spectrometer has been constructed for the precise measurement of lead isotope ratios. Sixteen analyses on 4 different preparations of the same galena made over a period of 2 months gave 95% confidence limits (per analysis) of 206 Pb/ 204 Pb= 0.080%, 207 Pb/ 206 Pb= 0.042%and 208 Pb/ 206 Pb= 0.046% . Eight samples from the U.S. mine in the Bingham district have a linear relationship over the 1% range of their 206 Pb/ 204 Pb ratios. The simplest model fitting these data suggests that the lead was separated from a primary system (μ=8.98) 1630±150m.y. ago and subsequently mixed with a radiogenic lead of similar age; biotite K-Ar dates for altered intrusive rocks associated with the ores provide an apparent age of mineralization and suggest that isotopic evolution of the lead was terminated about 36 m.y. ago.

Utah↗