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J. N. Aleinikoff

Publications and source records attributed to J. N. Aleinikoff.

At least 19 recordsLinked to original sources
USGS2011

U-Pb SHRIMP-RG zircon ages and Nd signature of lower Paleozoic rifting-related magmatism in the Variscan basement of the Eastern Pyrenees

The ages of orthogneisses exposed in massifs of the Variscan chain can determine whether they are part of a pre-Neoproterozoic basement, a Neoproterozoic, Panafrican arc, or are, in fact, lower Paleozoic, and their isotopic compositions can be used to probe the nature of their source rocks, adding to the understanding of the types, distribution, and tectonic evolution of peri-Gondwanan crystalline basement. .Using SHRIMP U-Pb zircon geochronology and Nd isotopic analysis, pre-Variscan metaigneous rocks from the Núria massif in the Eastern Pyrenean axial zone and the Guilleries massif, 70 km to the south, have been dated and their Nd signatures characterized.. All dated orthogneisses from the Núria massif have the same age within error, ~457 Ma, including the Ribes granophyre, interpreted as a subvolcanic unit within Caradocian sediments contemporaneous with granitic magmas intruded into Cambro-Ordovician sediments at deeper levels. Orthogneisses in the Guilleries massif record essentially continuous magmatic activity during the Ordovician, beginning at the Cambro-Ordovician boundary (488 ± 3 Ma) and reaching a peak in the volume of magma in the early Late Ordovician (~ 460 Ma). Metavolcanic rocks in the Guilleries massif were extruded at 452 ± 4 Ma and appear to have their intrusive equivalent in thin, deformed veins of granitic gneiss (451 ± 7 Ma) within metasedimentary rocks. In orthogneisses from both massifs, the cores of some zircons yield Neoproterozoic ages between ~ 520 and 900 Ma. The age of deposition of a pre-Late Ordovician metapelite in the Guilleries massif is bracketed by the weighted average age of the youngest detrital zircon population, 582 ± 11 Ma, and the age of cross-cutting granitic veins, 451 ± 7 Ma. Older detrital zircons populations in this metapelite include Neoproterozoic (749–610 Ma; n = 10), Neo- to Mesoproterozoic (1.04–0.86 Ga; n = 7), Paleoproterozoic (2.02–1.59 Ga; n = 5), and Neoarchean (2.74–2.58 Ga; n = 3). Nd isotopic analyses of the Núria and Guilleries orthogneisses yielded negative ε Nd values ranging between − 2.1 and − 5.2 at 450 Ma, the same as Ediacaran sediments from northwestern Iberia. We interpret these slightly negative ε Nd values as a signature of Panafrican arc rocks, mixed with an older crustal component as indicated by the inherited and detrital zircon ages we analyzed. The crustal level in which Ordovician melting occurred has not been recognized and the absence of pre-Neoproterozoic basement is a striking feature of the southern part of the Variscan Chain.

LITHOS↗
USGS2009

SHRIMP U-Pb dating of recurrent Cryogenian and Late Cambrian-Early Ordovician alkalic magmatism in central Idaho: Implications for Rodinian rift tectonics

Composite alkalic plutonic suites and tuffaceous diamictite, although discontinuously exposed across central Idaho in roof pendants and inliers within the Idaho batholith and Challis volcanic-plutonic complex, define the >200-km-long northwest-aligned Big Creek-Beaverhead belt. Sensitive highresolution ion microprobe (SHRIMP) U-Pb zircon dates on these igneous rocks provide direct evidence for the orientation and location of the Neoproterozoic-Paleozoic western Laurentian rift margin in the northern U.S. Cordillera. Dating delimits two discrete magmatic pulses at ca. 665-650 Ma and 500-485 Ma at the western and eastern ends, respectively, of this belt. Together with the nearby 685 Ma volcanic rocks of the Edwardsburg Formation, there is a 200 Ma history of recurrent extensional magmatic pulses along the belt. A similar history of recurrent uplift is reflected in the stratigraphic record of the associated miogeoclinal and cratonal platform basins, suggesting that the Big Creek-Beaverhead belt originated as a border fault during continental rift events. The magmatic belt is paired with the recurrently emergent Lemhi Arch and narrow miogeoclinal facies belts and it lies inboard of a northwest-striking narrow zone of thinned continental crust. These features define a northeast-extending upper-plate extensional system between southeast Washington and southeast Idaho that formed a segment of the Neoproterozoic-Paleozoic miogeocline. This segment was flanked on the north by the St. Mary-Moyie transform zone (south of a narrow southern Canadian upper-plate margin) and on the south by the Snake River transfer zone (north of a broad Great Basin lower-plate margin). These are the central segments of a zigzagshaped Cordilleran rift system of alternating northwest-striking extensional zones offset by northeast-striking transfers and transforms. The data substantiate polyphase rift and continental separation events that included (1) pre-and syn-Windermere rifting, (2) Windermere margin subsidence, (3) late Ediacaran-Cambrain rifting, and (4) welldeveloped late Ediacaran-Devonian passive margin subsidence and deposition. Timing and geometries support synchronous but opposing divergence along Cordilleran and Atlantic rifts with a junction in Southern California-Sonora. ?? 2010 Geological Society of America.

Geological Society of America Bulletin↗
USGS2008

Coolwater culmination: Sensitive high-resolution ion microprobe (SHRIMP) U-Pb and isotopic evidence for continental delamination in the Syringa Embayment, Salmon River suture, Idaho

During dextral oblique translation along Laurentia in western Idaho, the Blue Mountains superterrane underwent clockwise rotation and impinged into the Syringa embayment at the northern end of the Salmon River suture. Along the suture, the superterrane is juxtaposed directly against western Laurentia, making this central Cordilleran accretionary-margin segment unusually attenuated. In the embayment, limited orthogonal contraction produced a crustal wedge of oceanic rocks that delaminated Laurentian crust. The wedge is exposed through Laurentian crust in the Coolwater culmination as documented by mapping and by sensitive high-resolution ion microprobe U-Pb, Sri, and ??Nd data for gneisses that lie inboard of the suture. The predominant country rock is Mesoproterozoic paragneiss overlying Laurentian basement. An overlying Neoproterozoic (or younger) paragneiss belt in the Syringa embayment establishes the form of the Cordilleran miogeocline and that the embayment is a relict of Rodinia rifting. An underlying Cretaceous paragneiss was derived from arc terranes and suture-zone orogenic welt but also from Laurentia. The Cretaceous paragneiss and an 86-Ma orthogneiss that intruded it formed the wedge of oceanic rocks that were inserted into the Laurentian margin between 98 and 73 Ma, splitting supracrustal Laurentian rocks from their basement. Crustal thickening, melting and intrusion within the wedge, and folding to form the Coolwater culmination continued until 61 Ma. The embayment formed a restraining bend at the end of the dextral transpressional suture. Clockwise rotation of the impinging superterrane and overthrusting of Laurentia that produced the crustal wedge in the Coolwater culmination are predicted by oblique collision into the Syringa embayment. Copyright 2008 by the American Geophysical Union.

Tectonics↗
USGS2008

On the origin and age of the Great Sand Dunes, Colorado

Over the past 100??yr, several hypotheses have been proposed for the origin and age of the Great Sand Dunes. These hypotheses differ widely in the descriptions of dune morphometry, the immediate source of eolian sand, and when sand transport occurred. The primary purpose of this paper is to evaluate these hypotheses and, where warranted, to present new ideas about the origin and age of the Great Sand Dunes. To evaluate the previous hypotheses, we had to develop more detailed information about the surficial geology of the northern San Luis Valley. Thus, we mapped the surficial geology of an area extending several tens of kilometers north, south, and west of the Great Sand Dunes and examined subsurface stratigraphy in more than 200 wells and borings. In addition, we used relative-dating criteria and several radiocarbon and OSL ages to establish the chronology of surficial deposits, and we determined the U-Pb ages of detrital zircons to obtain information about the sources of the sand in the Great Sand Dunes. The first principal finding of this study is that the lower part of the closed basin north of the Rio Grande, referred to here as the sump, is the immediate source of the sand in the Great Sand Dunes, rather than the late Pleistocene flood plain of the Rio Grande (the most widely accepted hypothesis). A second principal finding is that the Great Sand Dunes are older than late Pleistocene. They postdate the draining of Lake Alamosa, which began ??? 440??ka, and predate the time when streams draining the west flank of the Sangre de Cristo Mountains were deflected by incipient dunes that formed near the mountain front. Geomorphic and stratigraphic evidence indicate that this deflection occurred prior to the end of the next to last glaciation (Bull Lake), i.e., prior to ??? 130??ka.

Geomorphology↗
USGS2008

Mineral chemistry and shrimp U-Pb Geochronology of mesoproterozoic polycrase-titanite veins in the sullivan Pb-Zn-Ag Deposit, British Columbia

Small polycrase-titanite veins 0.1-2 mm thick cut the tourmalinite feeder zone in the deep footwall of the Sullivan Pb-Zn-Ag deposit, southeastern British Columbia. Unaltered, euhedral crystals of polycrase and titanite 50-100 ??m in diameter are variably replaced by a finer-grained alteration-induced assemblage composed of anhedral polycrase and titanite with local calcite, albite, epidote, allanite, and thorite or uranothorite (or both). Average compositions of the unaltered and altered polycrase, as determined by electron-microprobe analysis, are (Y0.38 REE0.49 Th0.10 Ca0.04 Pb0.03 Fe0.01U0.01) (Ti1.48 Nb0.54 W0.04 Ta0.02)O6 and (Y0.42 REE0.32 Th0.15 U0.06 Ca0.04 Pb0.01 Fe0.01) (Ti1.57 Nb0.44 W0.04 Ta0.02)O6, respectively. The unaltered titanite has, in some areas, appreciable F (to 0.15 apfu), Y (to 0.40 apfu), and Nb (to 0.13 apfu). SHRIMP U-Pb geochronology of eight grains of unaltered polycrase yields a weighted 207Pb/206Pb age of 1413 ?? 4 Ma (2??) that is interpreted to be the age of vein formation. This age is 50-60 m.y. younger than the ca. 1470 Ma age of synsedimentary Pb-Zn-Ag mineralization in the Sullivan deposit, which is based on combined geological and geochronological data. SHRIMP ages for altered polycrase and titanite suggest later growth of minerals during the ???1370-1320 Ma East Kootenay and ???1150-1050 Ma Grenvillian orogenies. The 1413 ?? 4 Ma age for the unaltered polycrase in the veins records a previously unrecognized post-ore (<1470 Ma) and premetamorphic (>1370 Ma) mineralizing event in the Sullivan deposit and vicinity. The SHRIMP U-Pb age of the polycrase and high concentrations of REE, Y, Ti, Nb, and Th in the veins, together with elevated F in titanite and the absence of associated sulfides, suggest transport of these high-field-strength elements (HFSE) by F-rich and S-poor hydrothermal fluids unrelated to the fluids that formed the older Fe-Pb-Zn-Ag sulfide ores of the Sullivan deposit. Fluids containing abundant REE, HFSE, and F may have been derived from a geochemically specialized magma such as those that form alkaline granites, pegmatites, or carbonatites. In an alternative model. preferred here, these fluids were associated with a rift-related, crustal metasomatic event in the region. Determination of a Mesoproterozoic age for the polycrase-titanite veins establishes the first known occurrence of pre-Grenvillian REE-rich mineralization in the Belt-Purcell basin.

Canadian Mineralogist↗
USGS2007

Ages and origins of rocks of the Killingworth dome, south-central Connecticut: Implications for the tectonic evolution of southern New England

The Killingworth dome of south-central Connecticut occurs at the southern end of the Bronson Hill belt. It is composed of tonalitic and trondhjemitic orthogneisses (Killingworth complex) and bimodal metavolcanic rocks (Middletown complex) that display calc-alkaline affinities. Orthogneisses of the Killingworth complex (Boulder Lake gneiss, 456 ?? 6 Ma; Pond Meadow gneiss, ???460 Ma) were emplaced at about the same time as eruption and deposition of volcanic-sedimentary rocks of the Middletown complex (Middletown Formation, 449 ?? 4 Ma; Higganum gneiss, 459 ?? 4 Ma). Hidden Lake gneiss (339 ?? 3 Ma) occurs as a pluton in the core of the Killingworth dome, and, on the basis of geochemical and isotopic data, is included in the Killingworth complex. Pb and Nd isotopic data suggest that the Pond Meadow, Boulder Lake, and Hidden Lake gneisses (Killingworth complex) resulted from mixing of Neoproterozoic Gander terrane sources (high 207Pb/204Pb and intermediate ??Nd) and less radiogenic (low 207Pb/204Pb and low ??Nd) components, whereas Middletown Formation and Higganum gneiss (Middletown complex) were derived from mixtures of Gander basement and primitive (low 207Pb/204Pb and high ??Nd) sources. The less radiogenic component for the Killingworth complex is similar in isotopic composition to material from Laurentian (Grenville) crust. However, because published paleomagnetic and paleontologic data indicate that the Gander terrane is peri-Gondwanan in origin, the isotopic signature of Killingworth complex rocks probably was derived from Gander basement that contained detritus from non-Laurentian sources such as Amazonia, Baltica, or Oaxaquia. We suggest that the Killingworth complex formed above an east-dipping subduction zone on the west margin of the Gander terrane, whereas the Middletown complex formed to the east in a back-arc rift environment. Subsequent shortening, associated with the assembly of Pangea in the Carboniferous, resulted in Gander cover terranes over the Avalon terrane in the west; and in the Middletown complex over the Killingworth complex in the east. Despite similarities of emplacement age, structural setting, and geographic continuity of the Killingworth dome with Oliverian domes in central and northern New England, new and published isotopic data suggest that the Killingworth and Middletown complexes were derived from Gander crust, and are not part of the Bronson Hill arc that was derived from Laurentian crust. The trace of the Ordovician Iapetan suture (the Red Indian line) between rocks of Laurentian and Ganderian origin probably extends from Southwestern New Hampshire west of the Pelham dome of northcentral Massachusetts and is coverd by Mesozoic rocks of the Hartford basin.

American Journal of Science↗
USGS2007

SHRIMP U-Pb evidence for a Late Silurian age of metasedimentary rocks in the Merrimack and Putnam-Nashoba terranes, eastern New England

U-Pb ages of detrital, metamorphic, and magmatic zircon and metamorphic monazite and titanite provide evidence for the ages of deposition and metamorphism of metasedimentary rocks from the Merrimack and Putnam-Nashoba terranes of eastern New England. Rocks from these terranes are interpreted here as having been deposited in the middle Paleozoic above Neoproterozoic basement of the Gander terrane and juxtaposed by Late Paleozoic thrusting in thin, fault-bounded slices. The correlative Hebron and Berwick formations (Merrimack terrane) and Tatnic Hill Formation (Putnam-Nashoba terrane), contain detrital zircons with Mesoproterozoic, Ordovician, and Silurian age populations. On the basis of the age of the youngest detrital zircon population (???425 Ma), the Hebron, Berwick and Tatnic Hill formations are no older than Late Silurian (Wenlockian). The minimum deposition ages of the Hebron and Berwick are constrained by ages of cross-cutting plutons (414 ?? 3 and 418 ?? 2 Ma, respectively). The Tatnic Hill Formation must be older than the oldest metamorphic monazite and zircon (???407 Ma). Thus, all three of these units were deposited between ???425 and 418 Ma, probably in the Ludlovian. Age populations of detrital zircons suggest Laurentian and Ordovician arc provenance to the west. High grade metamorphism of the Tatnic Hill Formation soon after deposition probably requires that sedimentation and burial occurred in a fore-arc environment, whereas time-equivalent calcareous sediments of the Hebron and Berwick formations probably originated in a back-arc setting. In contrast to age data from the Berwick Formation, the Kittery Formation contains primarily Mesoproterozoic detrital zircons; only 2 younger grains were identified. The absence of a significant Ordovician population, in addition to paleocurrent directions from the east and structural data indicating thrusting, suggest that the Kittery was derived from peri-Gondwanan sources and deposited in the Fredericton Sea. Thus, the Kittery should not be considered part of the Laurentian-derived Merrimack terrane; it more likely correlates with the early Silurian Fredericton terrane of northeastern New England and Maritime Canada.

American Journal of Science↗
USGS2007

Origin of the Lyme Dome and implications for the timing of multiple Alleghanian deformational and intrusive events in southern Connecticut

Geologic mapping, structural analysis, and geochronology in the area of the Lyme dome, southern Connecticut provides constraints on the origin of the rocks in the core of the dome, the absolute timing of the principal deformational and thermal events attributed to Alleghanian orogenesis, and the processes that generated the dome. Detrital zircon geochronology in combination with ages on intrusive rocks brackets the deposition of quartzite in the core of the dome sometime between ca. 925 and 620 Ma. Granite and granodiorite intruded the Neoproteorozic metasedimentary rocks in the core of the dome at ca. 620 to 610 Ma. Four major early Permian events associated with the Alleghanian orogeny affected the rocks in the Lyme dome area. Syn-tectonic migmatization and widespread penetrative deformation (D1, ca. 300 - 290 Ma) included emplacement of alaskite at 290 ?? 4 Ma during regional foliation development and aluminosilicate-orthoclase metamorphic conditions. Rocks of the Avalon terrane may have wedged between Gander cover rocks and Gander basement in the core of the Lyme during D1. Limited structural evidence for diapiric uplift of the Lyme dome indicates that diapirism started late in D1 and was completed by D2 (ca. 290 - 280 Ma) when horizontal WNW contractional stresses dominated over vertical stresses. Second sillimanite metamorphism continued and syn-tectonic D2 granite pegmatite (288 ?? 4 Ma) and the Joshua Rock Granite Gniess (284 ?? 3 Ma) intruded at this time. North-northwest extension during D3 (ca. 280 - 275 Ma) led to granitic pegmatite intrusion along S3 cleavage planes and in extensional zones in boudin necks during hydraulic failure and decompression melting. Intrusion of a Westerly Granite dike at 275 ?? 4 Ma suggests that D3 extension was active, and perhaps concluding, by ca. 275 Ma. Late randomly oriented but gently dipping pegmatite dikes record a final stage of intrusion during D4 (ca. 275 - 260 Ma), and a switch from NNW extension to vertical unloading and exhumation. Monazite and metamorphic zircon rim ages record this event at ca. 259 Ma. The evolution of the Lyme dome involved D1 mylonitization, intrusion, and migmatization during north-directed contraction, limited late D1 diapirism, D2 migmatization during WNW contraction with associated flexural flow and fold interference, D3 NNW horizontal extension and decompression melting, and final D4 vertical extension and rapid exhumation. Late regional uplift, extension, and normal faulting at higher crustal levels may have been caused by diapiric rise of the lower crust, below the structural level of the Lyme dome. The rocks record no evidence of Acadian metamorphism or deformation, suggesting that the Gander zone here was not tectonically juxtaposed with Avalon until the Alleghanian orogeny.

American Journal of Science↗
USGS2006

Deciphering igneous and metamorphic events in high-grade rocks of the Wilmington complex, Delaware: Morphology, cathodoluminescence and backscattered electron zoning, and SHRIMP U-Pb geochronology of zircon and monazite

High-grade rocks of the Wilmington Complex, northern Delaware and adjacent Maryland and Pennsylvania, contain morphologically complex zircons that formed through both igneous and metamorphic processes during the development of an island-arc complex and suturing of the arc to Laurentia. The arc complex has been divided into several members, the protoliths of which include both intrusive and extrusive rocks. Metasedimentary rocks are interlayered with the complex and are believed to be the infrastructure upon which the arc was built. In the Wilmingto n Complex rocks, both igneous and metamorphic zircons occur as elongate and equant forms. Chemical zoning, shown by cathodoluminescence (CL), includes both concentric, oscillatory patterns, indicative of igneous origin, and patchwork and sector patterns, suggestive of metamorphic growth. Metamorphic monazites are chemically homogeneous, or show oscillatory or spotted chemical zoning in backscattered electron images. U-Pb geochronology by sensitive high resolution ion microprobe (SHRIMP) was used to date complexly zoned zircon and monazite. All but one member of the Wilmington Complex crystallized in the Ordovician between ca. 475 and 485 Ma; these rocks were intruded by a suite of gabbro-to-granite plutonic rocks at 434 ?? Ma. Detrital zircons in metavolcanic and metasedimentary units were derived predominantly from 0.9 to 1.4 Ga (Grenvillian) basement, presumably of Laurentian origin. Amphibolite to granulite facies metamorphism of the Wilmington Complex, recorded by ages of metamorphic zircon (428 ?? 4 and 432 ?? 6 Ma) and monazite (429 ?? 2 and 426 ?? 3 Ma), occurred contemporaneously with emplacement of the younger plutonic rocks. On the basis of varying CL zoning patterns and external morphologies, metamorphic zircons formed by different processes (presumably controlled by rock chemistry) at slightly different times and temperatures during prograde metamorphism. In addition, at least three other thermal episodes are recorded by monazite growth at 447 ?? 4, 411 ?? 3, and 398 ?? 3 Ma. ?? 2006 Geological Society of America.

Geological Society of America Bulletin↗
USGS2006

Grenvillian magmatism in the northern Virginia Blue Ridge: Petrologic implications of episodic granitic magma production and the significance of postorogenic A-type charnockite

Grenvillian (1.2 to 1.0 Ga) plutonic rocks in northern Virginia preserve evidence of episodic, mostly granitic magmatism that spanned more than 150 million years (m.y.) of crustal reworking. Crystallization ages determined by sensitive high resolution ion microprobe (SHRIMP) U-Pb isotopic analyses of zircon and monazite, combined with results from previous studies, define three periods of magmatic activity at 1183-1144 Ma (Magmatic Interval I), 1120-1111 Ma (Magmatic Interval II), and 1078-1028 Ma (Magmatic Interval III). Magmatic activity produced dominantly tholeiitic plutons composed of (1) low-silica charnockite, (2) leucogranite, (3) non-leucocratic granitoid (with or without orthopyroxene (opx)), and (4) intermediate biotite-rich granitoid. Field, petrologic, geochemical, and geochronologic data indicate that charnockite and non-charnockitic granitoids were closely associated in both space and time, indicating that presence of opx is related to magmatic conditions, not metamorphic grade. Geochemical and Nd isotopic data, combined with results from experimental studies, indicate that leucogranites (Magmatic Intervals I and III) and non-leucocratic granitoids (Magmatic Intervals I and II) were derived from parental magmas produced by either a high degree of partial melting of isotopically evolved tonalitic sources or less advanced partial melting of dominantly tonalitic sources that also included a more mafic component. Post-orogenic, circa 1050 Ma low-silica charnockite is characterized by A-type compositional affinity including high FeOt/(FeOt + MgO), Ga/Al, Zr, Nb, Y, and Zn, and was derived from parental magmas produced by partial melting of potassic mafic sources in the lower crust. Linear geochemical trends defined by leucogranites, low-silica charnockite, and biotite-rich monzogranite emplaced during Magmatic Interval III reflect differences in source-related characteristics; these features do not represent an igneous fractionation sequence. A compositional gap between circa 1160 Ma magnesian low-silica charnockite and penecontemporaneous higher silica lithologies likewise precludes a fractionation relationship among plutons intruded during Magmatic Interval I. Correspondence in timing of magmatic activity between the Blue Ridge and neighboring Mesoproterozoic terranes underscores the widespread nature of Grenvillian processes in the region.

Precambrian Research↗
USGS2006

Early Paleozoic development of the Maine-Quebec boundary Mountains region

Pre-Silurian bedrock units played key roles in the early Paleozoic history of the Maine-Quebec Appalachians. These units represent peri-Laurentian material whose collision with the craton deformed the Neoproteozoic passive margin and initiated the Appalachian mountain-building cycle. We present new field, petrological, geochronological, and geochemical data to support the following interpretations related to these units. (1) The Boil Mountain Complex and Jim Pond Formation do not represent part of a coherent ophiolite. (2) Gabbro and tonalite of the Boil Mountain Complex intruded the Chain Lakes massif at ca. 477 Ma. (3) The Skinner pluton, an arc-related granodiorite, intruded the Chain Lakes massif at ca. 472 Ma. (4) The Attean pluton, with a reconfirmed age of ca. 443 Ma, is unrelated to Early Ordovician orogenesis. (5) The most likely timing for the juxtaposition of the Jim Pond Formation and the Boil Mountain Complex was during regional Devonian deformation. These interpretations suggest that the Boundary Mountains were once part of a series of arcs extending at least from central New England through Newfoundland. ?? 2006 NRC Canada.

Canadian Journal of Earth Sciences↗
USGS2005

Foliation development and reaction softening by dissolution and precipitation in the transformation of granodiorite to orthogneiss, Glastonbury Complex, Connecticut, U.S.A

Textures, microstructures, and patterns of chemical zoning in minerals in a granodioritic orthogneiss in the Glastonbury Complex, Connecticut, lead to the interpretation that foliation development was facilitated by retrograde hydration reactions in the presence of an aqueous fluid. Incomplete replacement of the metastable magmatic minerals K-feldspar + hastingsite + magnetite produced foliation-defining biotite + epidote + quartz. These reaction products did not replace K-feldspar – hastingsite interfaces; rather, either biotite or epidote replaced the amphibole, and plagioclase replaced K-feldspar. Biotite and epidote precipitated syntectonically in discrete layers that define the foliation in the orthogneiss, whereas quartz precipitated primarily in ribbons, further enhancing the fabric. Metastable REE-rich igneous titanite also dissolved, and was incompletely replaced by REE-poor, Al-bearing metamorphic titanite. The similar concentrations of the REE in epidote and titanite show that the REE released by titanite dissolution were precipitated locally as the allanite component in adjacent grains of epidote. The entire process was syntectonic, with most grains showing multiple overgrowths in the direction of extension as defined by stretched xenoliths. Sufficient U was present in the titanite overgrowths to allow SHRIMP dating of cores, mantles, and rims. These results suggest at least three retrograde Alleghanian events of growth in a span of ~30 m.y. Thus the dissolution – transportation –precipitation process not only describes the reaction mechanism but also leads to the redistribution of reaction products into nearly monomineralic layers, thus contributing to metamorphic differentiation and to the development of the foliation. The resulting orthogneiss was much weaker that the granodiorite protolith, owing to this reaction and textural softening.

Connecticut↗
USGS2004

Improved 206Pb/238U microprobe geochronology by the monitoring of a trace-element-related matrix effect; SHRIMP, ID-TIMS, ELA-ICP-MS and oxygen isotope documentation for a series of zircon standards

Precise isotope dilution-thermal ionisation mass spectrometry (ID-TIMS) documentation is given for two new Palaeozoic zircon standards (TEMORA 2 and R33). These data, in combination with results for previously documented standards (AS3, SL13, QGNG and TEMORA 1), provide the basis for a detailed investigation of inconsistencies in 206Pb/238U ages measured by microprobe. Although these ages are normally consistent between any two standards, their relative age offsets are often different from those established by ID-TIMS. This is true for both sensitive high-resolution ion-microprobe (SHRIMP) and excimer laser ablation-inductively coupled plasma-mass spectrometry (ELA-ICP-MS) dating, although the age offsets are in the opposite sense for the two techniques. Various factors have been investigated for possible correlations with age bias, in an attempt to resolve why the accuracy of the method is worse than the indicated precision. Crystallographic orientation, position on the grain-mount and oxygen isotopic composition are unrelated to the bias. There are, however, striking correlations between the 206Pb/238U age offsets and P, Sm and, most particularly, Nd abundances in the zircons. Although these are not believed to be the primary cause of this apparent matrix effect, they indicate that ionisation of 206Pb/238U is influenced, at least in part, by a combination of trace elements. Nd is sufficiently representative of the controlling trace elements that it provides a quantitative means of correcting for the microprobe age bias. This approach has the potential to reduce age biases associated with different techniques, different instrumentation and different standards within and between laboratories. Crown Copyright ?? 2004 Published by Elsevier B.V. All rights reserved.

Chemical Geology↗
USGS2004

Neoproterozoic A-type granitoids of the central and southern Appalachians: Intraplate magmatism associated with episodic rifting of the Rodinian supercontinent

Emplacement of compositionally distinctive granitic plutons accompanied two pulses (765-680 and 620-550Ma) of crustal extension that affected the Rodinian craton at the present location of the central Appalachians during the Neoproterozoic. The dominantly metaluminous plutons display mineralogical and geochemical characteristics of A-type granites including high FeO t/MgO ratios, high abundances of Nb, Zr, Y, Ta, and REE (except Eu), and low concentrations of Sc, Ba, Sr, and Eu. These dike-like, sheet complexes occur throughout the Blue Ridge province of Virginia and North Carolina, and were emplaced at shallow levels in continental crust during active extension, forming locally multiple-intrusive plutons elongated perpendicular to the axis of extension. New U-Pb zircon ages obtained from the Polly Wright Cove (706??4Ma) and Suck Mountain (680??4Ma) plutons indicate that metaluminous magmas continued to be replenished near the end of the first pulse of rifting. The Suck Mountain body is presently the youngest known igneous body associated with earlier rifting. U-Pb zircon ages for the Pound Ridge Granite Gneiss (562??5Ma) and Yonkers Gneiss (563??2Ma) in the Manhattan prong of southeastern New York constitute the first evidence of plutonic felsic activity associated with the later period of rifting in the U.S. Appalachians, and suggest that similar melt-generation processes were operative during both intervals of crustal extension. Fractionation processes involving primary minerals were responsible for much of the compositional variation within individual plutons. Compositions of mapped lithologic units in a subset of plutons studied in detail define overlapping data arrays, indicating that, throughout the province, similar petrologic processes operated locally on magmas that became successively more chemically evolved. Limited variation in source-sensitive Y/Nb and Yb/Ta ratios is consistent with results of melting experiments and indicates that metaluminous granitoids of the supersuite likely were derived through melting of lower crustal sources. Mildly peralkaline rocks of the Robertson River batholith and Irish Creek pluton may be derived from more chemically primitive sources similar in composition to ocean-island basalts. Blue Ridge granitoids define a plutonic episode that occurred during an unsuccessful pulse of crustal extension which predated opening of Iapetus by more than 100 million years. Granitoid gneisses in New York were emplaced during an extension-related, dominantly mafic magmatic episode that ultimately led to development of Iapetus. ?? 2003 Elsevier B.V. All rights reserved.

Precambrian Research↗
USGS2003

TEMORA 1: A new zircon standard for Phanerozoic U-Pb geochronology

The role of the standard is critical to the derivation of reliable U-Pb zircon ages by micro-beam analysis. For maximum reliability, it is critically important that the utilised standard be homogeneous at all scales of analysis. It is equally important that the standard has been precisely and accurately dated by an independent technique. This study reports the emergence of a new zircon standard that meets those criteria, as demonstrated by Sensitive High Resolution Ion MicroProbe (SHRIMP), isotope dilution thermal ionisation mass-spectrometry (IDTIMS) and excimer laser ablation- inductively coupled plasma-mass-spectrometry (ELA-ICP-MS) documentation. The TEMORA 1 zircon standard derives from the Middledale Gabbroic Diorite, a high-level mafic stock within the Palaeozoic Lachlan Orogen of eastern Australia. Its 206Pb/238U IDTIMS age has been determined to be 416.75??0.24 Ma (95% confidence limits), based on measurement errors alone. Spike-calibration uncertainty limits the accuracy to 416.8??1.1 Ma for U-Pb intercomparisons between different laboratories that do not use a common spike. ?? 2003 Published by Elsevier Science B.V. All rights reserved.

Chemical Geology↗
USGS2003

Stratigraphy, geochronology, and accretionary terrane settings of two Bronson Hill arc sequences, northern New England

The Ammonoosuc Volcanics, Partridge Formation, and the Oliverian and Highlandcroft Plutonic Suites of the Bronson Hill anticlinorium (BHA) in axial New England are widely accepted as a single Middle to Late Ordovician magmatic arc that was active during closure of Iapetus. Mapping and U–Pb dating indicate, however, that the BHA contains two volcano-sedimentary-intrusive sequences of probable opposite subduction polarity, here termed the Ammonoosuc and Quimby sequences. The Ammonoosuc sequence is defined by the Middle Ordovician Ammonoosuc Volcanics near Littleton, NH, the type area, northeast to Milan, NH, and Oquossoc, ME; it also includes black slate of the Partridge Formation ( C. bicornis ––zone graptolites, ∼457 Ma). Related metamorphosed intrusives are the tonalitic Joslin Turn pluton (469 ± 2 Ma), the Cambridge Black granitic pluton (468 ± 3 Ma), and gabbro, tonalite (467 ± 4 Ma), and sheeted diabase of the Chickwolnepy intrusions. These intrusives cut lowermost Ammonoosuc (therefore >469 Ma). Probable uppermost Ammonoosuc is dated at 465 ± 6 and 461 ± 8 Ma. Successively below the Ammonoosuc are the Dead River and Hurricane Mountain Formations (flysch and melange), and the Jim Pond Formation (484 ± 5 Ma) and Boil Mountain Complex (both ophiolite), which are structurally underlain by the Neoproterozoic(?) Chain Lakes massif. The Quimby sequence is defined by the Lower Silurian(?) to Upper Ordovician Quimby Formation, composed of bimodal volcanics (443 ± 4 Ma) and sulfidic shale and graywacke that lie conformably to unconformably above the Ammmonoosuc Volcanics and Partridge Formation. Also in the Quimby sequence are several granitic to sparsely gabbroic plutons of the Highlandcroft (441–452 Ma) and Oliverian (435–456 Ma) Plutonic Suites, which intrude the Dead River, Ammonoouc and Partridge, but not the Quimby Formation. Based on faunal, paleolatitude, and isotopic data, the Ammonoosuc sequence and its correlatives and underlying sequences formed off the southern Laurentian margin, but northwest of the principal Iapetan suture, or Red Indian line. The Boil Mountain-Jim Pond-Hurricane Mountain sequence was ramped northwestward over the Chain Lakes massif at ∼475 Ma, on the basal Boil Mountain surface. This obduction probably occurred slightly before obduction on the Baie Vert-Brompton surface (BBL), farther NW, over the Laurentian margin, and was followed by Dead River flysch sedimentation, which ended with the abrupt onset of Ammonoosuc-sequence arc magmatism at ∼470 Ma. Ammonoosuc eruptions probably ended at ∼460 Ma, when Iapetus closed along the Red Indian line. During a following magmatic hiatus of ∼3–5 m.y., now represented by portions of the Partridge Formation that overlie the Ammonoosuc Volcanics, subduction polarity reversed, and subduction resumed below the northwest-dipping Brunswick subduction complex (BSC) of New Brunswick, Canada. Quimby-sequence magmatism (∼456–435 Ma) on the newly accreted Laurentian margin occurred above the BSC, whose footwall is now buried to the southeast by mainly Silurian clastic sediments of the Merrimack-Fredericton trough, deposited in the “Fredericton Sea”. In Silurian to Early Devonian time, the NW-dipping BSC footwall was paired with a SE-dipping subduction zone that produced arc magmas of the Coastal Volcanic belt, built on the composite Avalon and adjacent peri-Avalonian terranes. Orogen-normal extension produced by rapid rollback of both subduction zones narrowed the Fredericton Sea, produced the Central Maine and Connecticut Valley-Gaspé basins, and culminated in the Acadian orogeny when the sea completely closed in Early Devonian time.

Maine, New Hampshire↗
USGS2003

SHRIMP U-Pb geochronology of Neoproterozoic Windermere Supergroup, central Idaho: Implications for rifting of western Laurentia and synchroneity of Sturtian glacial deposits

In central Idaho roof pendants, a northwest-trending belt of metamorphosed strata, correlative with the Windermere Supergroup, links northern and southern segments of the western Laurentia Neoproterozoic rift belt. Nine newly named formations within the Gospel Peaks sequence-A through Gospel Peaks sequence-D record Cryogenian preglacial, rift-glacial, and postglacial events as well as Neoproterozoic III glacial and rift events. The Edwardsburg Formation of Gospel Peaks sequence B includes interfingered bimodal rift-related volcanic and glaciogenic diamictite strata. Zircons from a rhyodacite flow in the lower Edwardsburg Formation and from a rhyolite flow at its top, dated by using the sensitive high-resolution ion microprobe (SHRIMP), yielded a weighted average of 685 ± 7 Ma and 684 ± 4 Ma. Reevaluation of geochronology and correlations indicates that Cryogenian rifting may have been (1) protracted between 780 and 685 Ma, (2) diachronous along the Cordillera, and/or (3) stepwise with a Cordilleran-wide event at ca. 685 Ma that initiated the formation of the Cordilleran miogeocline and set its geometry. Reevaluation of the Cryogenian glacial record indicates that (1) two associated ca. 685 Ma glacial intervals in the Edwardsburg Formation correlate with the Rapitan glaciation, (2) the Sturtian snowball Earth event must be reevaluated on the basis of revision of Rapitan glaciation from 750–700 Ma to ca. 685 Ma, and (3) there were older Cryogenian glaciations or Cryogenian glaciations were not globally synchronous. New dates and correlations significantly impact the number and synchroneity of possible snowball Earth events and the paleolatitudes of Cryogenian glaciations. Western Laurentian events at ca. 685 Ma particularily affect Neoproterozoic paleocontinental reconstructions by indicating diachronous and multi step breakup of supercontinent Rodinia.

Idaho↗