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Geology topics

J. M. Thompson

Publications and source records attributed to J. M. Thompson.

23 records · Page 2Linked to original sources

Determination of dissolved boron in fresh, estuarine, and geothermal waters by d.c. argon-plasma emission spectrometry

A d.c. argon-plasma emission spectrometer is used to determine dissolved boron in natural (fresh and estuarine) water samples. Concentrations ranged from 0.02 to 250 mg l -1 . The emission—concentration function is linear from 0.02 to 1000 mg l -1 . Achievement of a relative standard deviation of ⩽ 3% requires frequent restandardization to offset sensitivity changes. Dilution may be necessary to overcome high and variable electron density caused by differences in alkali-metal content and to avoid quenching of the plasma by high solute concentrations of sodium and other easily ionized elements. The proposed method was tested against a reference method and found to be more sensitive, equally or more precise and accurate, less subject to interferences, with a wider linear analytical range than the carmine method. Analyses of standard reference samples yielded results in all cases within one standard deviation of the means.

Analytica Chimica Acta

Phosphorus in hydrothermal waters of Yellowstone National Park, Wyoming

Ninety-seven hot-spring and geyser samples (field acidified to pH<1.4 with HCl or HNO 3 ) from Yellowstone National Park, Wyo., were analyzed for PO 4 -P using reduced molybdenum-blue and the selective arsenate reducing agent, metabisulfite-thiosulfate. The PO 4 -P concentrations ranged from below detection limit (~1-73 micrograms per liter). Twenty-five springs had PO 4 -P concentrations exceeding 6.8 &mu; g/L; seven spring samples exceeded 20 &mu;g/L. Elevated PO 4 -P contents were invariably associated with mixed springs, as evidenced by diluted chloride concentrations and, commonly, subboiling temperatures, low pH's, and elevated calcium concentrations. Alkaline high-chloride (>400 milligrams per liter) hydrothermal waters from Upper and Norris Geyser Basins had PO 4 -P concentrations below 2 &mu;g/L and represent the low end of the range of PO 4 -P contents in natural waters.

Wyoming