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Geology topics

J. J. Fitzpatrick

Publications and source records attributed to J. J. Fitzpatrick.

12 recordsLinked to original sources
USGS2017

Late-Holocene climate evolution at the WAIS Divide site, West Antarctica: Bubble number-density estimates

A surface cooling of ∼1.7°C occurred over the ∼two millennia prior to ∼1700 CE at the West Antarctic ice sheet (WAIS) Divide site, based on trends in observed bubble number-density of samples from the WDC06A ice core, and on an independently constructed accumulation-rate history using annual-layer dating corrected for density variations and thinning from ice flow. Density increase and grain growth in polar firn are both controlled by temperature and accumulation rate, and the integrated effects are recorded in the number-density of bubbles as the firn changes to ice. Number-density is conserved in bubbly ice following pore close-off, allowing reconstruction of either paleotemperature or paleo-accumulation rate if the other is known. A quantitative late-Holocene paleoclimate reconstruction is presented for West Antarctica using data obtained from the WAIS Divide WDC06A ice core and a steady-state bubble number-density model. The resultant temperature history agrees closely with independent reconstructions based on stable-isotopic ratios of ice. The ∼1.7°C cooling trend observed is consistent with a decrease in Antarctic summer duration from changing orbital obliquity, although it remains possible that elevation change at the site contributed part of the signal. Accumulation rate and temperature dropped together, broadly consistent with control by saturation vapor pressure.

Journal of Glaciology↗
USGS2017

Fabric and texture at Siple Dome, Antarctica

Preferred c-axis orientations are present in the firn at Siple Dome, West Antarctica, and recrystallization begins as shallow as 200 m depth in ice below –20°C, based on digital analysis of c-axis fabrics, grain-sizes and other characteristics of 52 vertical thin sections prepared in the field from the kilometer-long Siple Dome ice core. The shallowest section analyzed, from 22 m, shows clustering of c axes toward the vertical. By 200 m depth, girdle fabric and other features of recrystallized ice are evident in layers (or regions), separated by layers (regions) of typically finer-grained ice lacking evidence of recrystallization. Ice from about 700–780m depth, which was deposited during the last ice age, is especially fine-grained, with strongly vertical c axes, but deeper ice shows much larger crystals and strong evidence of recrystallization. Azimuthal asymmetry of some c -axis fabrics, trends in grain-size, and other indicators reveal additional information on processes and history of ice flow at Siple Dome.

Journal of Glaciology↗
USGS2017

Conditions for bubble elongation in cold ice-sheet ice

Highly elongated bubbles are sometimes observed in ice-sheet ice. Elongation is favored by rapid ice deformation, and opposed by diffusive processes. We use simple models to show that vapor transport dominates diffusion except possibly very close to the melting point, and that latent-heat effects are insignificant. Elongation is favored by larger bubbles at pore close-off, but is nearly independent of bubble compression below close-off. The simple presence of highly elongated bubbles indicates only that a critical ice-strain rate has been exceeded for significant time, and provides no information on possible disruption of stratigraphic continuity by ice deformation.

Journal of Glaciology↗
USGS2016

The geochemical record in rock glaciers

A 9.5 m ice core was extracted from beneath the surficial debris cover of a rock glacier at Galena Creek, northwestern Wyoming. The core contains clean, bubble-rich ice with silty debris layers spaced at roughly 20 cm intervals. The debris layers are similar in appearance to those in typical alpine glaciers, reflecting concentration of debris by melting at the surface during the summer ablation season. Profiles of stable isotope concentrations and electrical conductivity measurements provide independent evidence for melting in association with debris layers. These observations are consistent with a glacial origin for the ice, substantiating the glacigenic model for rock glacier formation. The deuterium excess profile in the ice indicates that the total depth of meltwater infiltration is less than the thickness of one annual layer, suggesting that isotope values and other geochemical signatures are preserved at annual resolution. This finding demonstrates the potential for obtaining useful paleoclimate information from rock glacier ice.

Geografiska Annaler, Series A: Physical Geography↗
USGS2010

History of the Greenland Ice Sheet: paleoclimatic insights

Paleoclimatic records show that the GreenlandIce Sheet consistently has lost mass in response to warming, and grown in response to cooling. Such changes have occurred even at times of slow or zero sea-level change, so changing sea level cannot have been the cause of at least some of the ice-sheet changes. In contrast, there are no documented major ice-sheet changes that occurred independent of temperature changes. Moreover, snowfall has increased when the climate warmed, but the ice sheet lost mass nonetheless; increased accumulation in the ice sheet's center has not been sufficient to counteract increased melting and flow near the edges. Most documented forcings and ice-sheet responses spanned periods of several thousand years, but limited data also show rapid response to rapid forcings. In particular, regions near the ice margin have responded within decades. However, major changes of central regions of the ice sheet are thought to require centuries to millennia. The paleoclimatic record does not yet strongly constrain how rapidly a major shrinkage or nearly complete loss of the ice sheet could occur. The evidence suggests nearly total ice-sheet loss may result from warming of more than a few degrees above mean 20th century values, but this threshold is poorly defined (perhaps as little as 2 °C or more than 7 °C). Paleoclimatic records are sufficiently sketchy that the ice sheet may have grown temporarily in response to warming, or changes may have been induced by factors other than temperature, without having been recorded.

Greenland Ice Sheet↗
USGS2006

Developing a bubble number-density paleoclimatic indicator for glacier ice

Past accumulation rate can be estimated from the measured number-density of bubbles in an ice core and the reconstructed paleotemperature, using a new technique. Density increase and grain growth in polar firn are both controlled by temperature and accumulation rate, and the integrated effects are recorded in the number-density of bubbles as the firn changes to ice. An empirical model of these processes, optimized to fit published data on recently formed bubbles, reconstructs accumulation rates using recent temperatures with an uncertainty of 41% (P < 0.05). For modern sites considered here, no statistically significant trend exists between mean annual temperature and the ratio of bubble number-density to grain number-density at the time of pore close-off; optimum modeled accumulation-rate estimates require an eventual ∼2.02 ± 0.08 (P < 0.05) bubbles per close-off grain. Bubble number-density in the GRIP (Greenland) ice core is qualitatively consistent with independent estimates for a combined temperature decrease and accumulation-rate increase there during the last 5 kyr.

Journal of Glaciology↗
USGS2002

Ordonezite from the Theodoso Soto Mine, Sapioris, Durango, Mexico: New data and structure refinement

A new occurrence of the rare mineral species ordonezite has been found at the Theodoso Soto tin mine, near Sapioris, Durango, Mexico. The average composition of the samples is (Zn 0.98 Fe 0.02 ) &Sigma;1.00 Sb 2.00 O 6 ; the core of the crystals is slightly richer in Fe than the rim. The mineral is uniaxial (+), with all n greater than 2.30 (n calc is 2.38 at 589 nm); D obs 6.66 g/cm 3 , D calc 6.67 g/cm 3 . It is isostructural with ferrotapiolite, with a 4.668(2), c 9.269(6) A (from powder-diffraction data), space group P4 2 /mnm, and is twinned on {103}. Its crystal structure, refined to R=4.1, wR=4.3% using 163 observed reflections, is fully cation-ordered.

Durango↗
USGS1997

Additional studies on mixed uranyl oxide-hydroxide hydrate alteration products of uraninite from the palermo and ruggles granitic pegmatites, grafton county, New Hampshire

Additional studies on an incompletely characterized secondary uranium "mineral" from the Ruggles and Palermo granitic pegmatites, New Hampshire, referred to as mineral "A" by Frondel (1956), reveal a mixture of schoepite-group minerals and related uranyl oxide-hydroxide hydrated compounds. A composite chemical analysis yielded (in wt.%): PbO 4.85 (EMP), UO3 83.5 (EMP), BaO 0.675 (av. of EMP and ICP), CaO 0.167 (av. of EMP and ICP), K2O 2.455 (av. of EMP and ICP), SrO 0.21 (ICP), ThO2 0.85 (ICP), H2O 6.9, ??99.61. Powder-diffraction X-ray studies indicate a close resemblance in patterns between mineral "A" and several uranyl oxide-hydroxide hydrated minerals, including the schoepite family of minerals and UO2(OH)2. The powder-diffraction data for mineral "A" are most similar to those for synthetic UO2.86??1.5H2O and UO2(OH)2, but other phases are likely present as well. TGA analysis of both mineral "A" and metaschoepite show similar weight-loss and first derivative curves. The dominant losses are at 100??C, with secondary events at 400?? and 600??C. IR spectra show the presence of (OH) and H2O. Uraninite from both pegmatites, analyzed by LAM-ICP-MS, shows the presence of Th, Pb, K and Ca.

Canadian Mineralogist↗
USGS1991

Boromuscovite, a new member of the mica group, from the Little Three mine pegmatite, Ramona district, San Diego County, California

Boromuscovite, ideally KAl2(Si3B)O10(OH,F)2, in which [4]Al is replaced by B relative to muscovite, occurs as a late-stage, postpocket rupture mineral within the New Spaulding Pocket, main Little Three pegmatite dike. The mineral is white to cream colored and occurs as a porcelaneous veneer and coating on primary minerals. The average grain size is less than 3-4 ??m, but the coatings may be as much as 1 cm or more thick. Fragments of topaz, albite, elbaite, and other pocket minerals are included in the coating. The boromuscovite precipitated from a late-stage hydothermal fluid; it occurs only as a snowlike coating. Chemical composition, unit-cell parameters, Mohs hardness, cleavage, fracture, and optical properties are reported. -from Authors

American Mineralogist↗
USGS1989

Borax in the supraglacial moraine of the Lewis Cliff, Buckley Island quadrangle--first Antarctic occurrence

During the 1987-1988 austral summer field season, membersof the south party of the antarctic search for meteorites south-ern team* working in the Lewis Cliff/Colbert Hills region dis-covered several areas of unusual mineralization within theLewis Cliff ice tongue and its associated moraine field (figure1). The Lewis Cliff ice tongue (84&deg;15'S 161&deg;25'E) is a meteorite-stranding surface of ablating blue ice, about 2.3 by 7.0 kilo-meters, bounded on the west by the Lewis Cliff, on the northand northeast by a large supraglacial moraine, and on the eastby the Colbert Hills. To the south it opens to the Walcott N&eacute;v&eacute;.Because it is a meteorite-stranding surface, the major component of ice motion in the area is believed to be vertical(Whillans and Cassidy 1983). The presence of Thule-Baffinmoraines at the northern terminus of the blue ice tends tosupport the hypothesis that the area underlying the moraineis essentially stagnant and that ice arriving from the south ispiling up against it. Areas containing mineral deposits werefound within the moraine field to the north and east of theblue ice margin and also along the east margins of the blue iceitself. Subsequent X-ray diffraction analyses of these depositshave shown that they are composed predominantly of nah-colite (NaHCO 3 ), trona [Na 3 (CO 3 )(HCO 3 ) &middot; 2H 2 0], borax[Na 2 B 4 0 5 (OH) 4 &middot; 8H 2 0], and a new hexagonal hydrous sulfatespecies. This paper reports the details of the borax occurrence,because it is the first known on the continent.

Antarctic Journal of the United States↗