Geology topics
Publications and source records attributed to Irving Friedman.
The necessity to use a dry box when loading silicate samples into reaction vessels prior to fluorination is eliminated by the use of a simple loading technique. Data presented show the reproducibility of the fluorination reaction using this technique. Sodium fluoride, when added to saline waters prior to fluorination, improves the precision of the overall technique.
Macusanite, originally believed to be a type of tektite because of its sculpture, is shown to be related to sillar of the Macusani region, Peru. K-Ar measurements establish identical Pliocene ages (4.2 m.y.) for macusanite and sillar and relate these deposits to the extensive ash flows of the southern Andes. These rocks are unique for glassy rocks in that lithium, boron, and arsenic contents are very high; cesium, rubidium, tellurium, fluorine, and tin are higher than normal; zinc, copper, chromium, and zirconium are lower than normal; and high-alumina minerals such as andalusite are present.
Carbon isotopic ratios and weight percentages of carbon were measured in 15 samples of slate, phyllite, and schist of the approximately 1500- to 1600-m.y.-old Uncompahgre Formation of the Needle Mountains, southwestern Colorado. Rocks with less than 1 percent total carbon, all of which is reduced, have δC 13 values of −23 to −28 per mil, whereas those with 1 to 6.4 percent carbon have δC 13 from −29 to −31 per mil. In general, the slates and phyllites contain more carbon and isotopically lighter carbon than do the schists of higher metamorphic rank. Increasing loss of C 12 -enriched methane with increasing intensity of metamorphism is suggested to account for these differences.