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Ingrid M. Verstraeten

Publications and source records attributed to Ingrid M. Verstraeten.

At least 19 recordsLinked to original sources

Rare earth element and rare metal inventory of central Asia

Rare earth elements (REE), with their unique physical and chemical properties, are an essential part of modern living. REE have enabled development and manufacture of high-performance materials, processes, and electronic technologies commonly used today in computing and communications, clean energy and transportation, medical treatment and health care, glass and ceramics, aerospace and defense, and metallurgy and chemical refining. Central Asia is an emerging REE and rare metals (RM) producing region. A newly compiled inventory of REE-RM-bearing mineral occurrences and delineation of areas-of-interest indicate this region may have considerable undiscovered resources.

Fact Sheet↗

Sustainability of water-supply at military installations, Kabul Basin, Afghanistan

The Kabul Basin, including the city of Kabul, Afghanistan, is host to several military installations of Afghanistan, the United States, and other nations that depend on groundwater resources for water supply. These installations are within or close to the city of Kabul. Groundwater also is the potable supply for the approximately four million residents of Kabul. The sustainability of water resources in the Kabul Basin is a concern to military operations, and Afghan water-resource managers, owing to increased water demands from a growing population and potential mining activities. This study illustrates the use of chemical and isotopic analysis, groundwater flow modeling, and hydrogeologic investigations to assess the sustainability of groundwater resources in the Kabul Basin. Water supplies for military installations in the southern Kabul Basin were found to be subject to sustainability concerns, such as the potential drying of shallow-water supply wells as a result of declining water levels. Model simulations indicate that new withdrawals from deep aquifers may have less of an impact on surrounding community water supply wells than increased withdrawals from near- surface aquifers. Higher rates of recharge in the northern Kabul Basin indicate that military installations in that part of the basin may have fewer issues with long-term water sustainability. Simulations of groundwater withdrawals may be used to evaluate different withdrawal scenarios in an effort to manage water resources in a sustainable manner in the Kabul Basin.

Kabul↗

Groundwater resources of Mosteiros basin, island of Fogo, Cape Verde, West Africa

Groundwater resources in Cape Verde provide water for agriculture, industry, and human consumption. These resources are limited and susceptible to contamination. Additional groundwater resources are needed for continued agricultural development, particularly during times of drought, but increased use and (or) climatic change may have adverse effects on the quantity and quality of freshwater available. In volcanic island aquifers such as those of Cape Verde, a lens of fresh groundwater typically ?floats? upon a layer of brackish water at the freshwater/saltwater boundary, and increased pumping may cause salt water intrusion or other contamination. A recent U.S. Geological Survey study assessed baseline groundwater conditions in watersheds on three islands of Cape Verde to provide the scientific basis for sustainably developing water resources and minimizing future groundwater depletion and contamination.

Island of Fogo, Mosteiros Basin↗

Groundwater resources of Ribeira Paúl basin, island of Santo Antão, Cape Verde, West Africa

Groundwater resources in Cape Verde provide water for agriculture, industry, and human consumption. These resources are limited and susceptible to contamination. Additional groundwater resources are needed for continued agricultural development, particularly during times of drought, but increased use and (or) climatic change may have adverse effects on the quantity and quality of freshwater available. In volcanic island aquifers such as those of Cape Verde, a lens of fresh groundwater typically ?floats? upon a layer of brackish water at the freshwater/saltwater boundary, and increased pumping may cause salt water intrusion or other contamination. A recent U.S. Geological Survey study assessed baseline groundwater conditions in watersheds on three islands of Cape Verde to provide the scientific basis for sustainably developing water resources and minimizing future groundwater depletion and contamination.

Island of Santo Antão, Ribeira Paúl Basin↗

Groundwater resources of Ribeira Fajã basin, island of São Nicolau, Cape Verde, West Africa

Groundwater resources in Cape Verde provide water for agriculture, industry, and human consumption. These resources are limited and susceptible to contamination. Additional groundwater resources are needed for continued agricultural development, particularly during times of drought, but increased use and (or) climatic change may have adverse effects on the quantity and quality of freshwater available. In volcanic island aquifers such as those of Cape Verde, a lens of fresh groundwater typically ?floats? upon a layer of brackish water at the freshwater/saltwater boundary, and increased pumping may cause salt water intrusion or other contamination. A recent U.S. Geological Survey study assessed baseline groundwater conditions in watersheds on three islands of Cape Verde to provide the scientific basis for sustainably developing water resources and minimizing future groundwater depletion and contamination.

Island of São Nicolau, Ribeira Fajã Basin↗

Relation of landscape position and irrigation to concentrations of alachlor, atrazine, and selected degradates in regolith in northeastern Nebraska

Concentrations of alachlor, its ethanesulfonic acid degradate, atrazine and its degradates, deethylatrazine and deisopropylatrazine, in the upper regolith and associated shallow aquifers were determined in relation to landscape position (floodplains, terraces, and uplands) and irrigation (nonirrigated and irrigated corn cropland) in 1992. Irrigated and nonirrigated sites were located on each landscape position. Samples were collected from three depths. Canonical discriminant and multivariate analyses were used to interpret data. Herbicides and their degradation products tended to be present in soils with high percent organic matter, low pH, and low sand content. Atrazine was present more frequently on the floodplain at all depths than the other compounds. Atrazine (maximum 17.5 µg/kg) and ethanesulfonic acid (maximum 10 µg/kg) were associated with landscape position, but not with irrigation. Alachlor (maximum 24 µg/kg), deethylatrazine (maximum 1.5 µg/kg), and deisopropylatrazine (maximum 3.5 µg/kg) were not significantly associated with either landscape position or irrigation. Ground-water analytical results suggested that concentrations of these herbicides and degradates in ground water did not differ among landscape position or between irrigated and nonirrigated corn cropland.

ACS Symposium Series↗

Oxygen, hydrogen, and helium isotopes for investigating groundwater systems of the Cape Verde Islands, West Africa

Stable isotopes (?? 18 O, ?? 2 H), tritium ( 3 H), and helium isotopes ( 3 He, 4 He) were used for evaluating groundwater recharge sources, flow paths, and residence times of three watersheds in the Cape Verde Islands (West Africa). Stable isotopes indicate the predominance of high-elevation precipitation that undergoes little evaporation prior to groundwater recharge. In contrast to other active oceanic hotspots, environmental tracers show that deep geothermal circulation does not strongly affect groundwater. Low tritium concentrations at seven groundwater sites indicate groundwater residence times of more than 50 years. Higher tritium values at other sites suggest some recent recharge. High 4 He and 3 He/ 4 He ratios precluded 3 H/ 3 He dating at six sites. These high 3 He/ 4 He ratios (R/R a values of up to 8.3) are consistent with reported mantle derived helium of oceanic island basalts in Cape Verde and provided end-member constraints for improved dating at seven other locations. Tritium and 3 H/ 3 He dating shows that S??o Nicolau Island's Ribeira Faj?? Basin has groundwater residence times of more than 50 years, whereas Fogo Island's Mosteiros Basin and Santo Ant??o Island's Ribeira Paul Basin contain a mixture of young and old groundwater. Young ages at selected sites within these two basins indicate local recharge and potential groundwater susceptibility to surface contamination and/or salt-water intrusion. ?? Springer-Verlag 2009.

Hydrogeology Journal↗

Effects of surface-water irrigation on sources, fluxes, and residence times of water, nitrate, and uranium in an alluvial aquifer

Effects of surface-water irrigation on an alluvial aquifer were evaluated using chemical and isotopic data including δ 2 H, δ 18 O, 3 H, δ 3 He, Ar, Ne, N 2 , δ 15 N, and 234 U/ 238 U activity ratios in a transect of nested wells in the North Platte River valley in western Nebraska, USA. The data were used to evaluate sources and fluxes of H 2 O, NO 3 - "> NO3- and U, all of which were strongly affected by irrigated agriculture. Combined results indicate that the alluvial aquifer was dominated by irrigation water that had distinctive chemical and isotopic features that were inherited from the North Platte River or acquired from agricultural soils or recharge processes. Values of δ 2 H, δ 18 O, Ar and Ne indicate that most of the ground water in the alluvial aquifer was irrigation water that was derived from the North Platte River and distributed during the growing season. The irrigation water was identified by an evaporated isotopic signature that was acquired by the river in major upstream reservoirs in Wyoming, and by relatively warm gas-equilibration temperatures related to warm-season recharge. Apparent 3 H– 3 He ages indicate that the ground water in the alluvium was stratified and mostly <30 a old, with apparent recharge rates varying widely from about 0.2 to >3.0 m/a. Age gradients and NO 3 - "> NO3- concentrations indicate that recharge occurred by a combination of focused leakage from irrigation canals (rapid local recharge, low NO 3 - "> NO3- ) and distributed infiltration beneath the irrigated agricultural fields (lower recharge, high NO 3 - "> NO3- ). Large amounts of U with relatively low 234 U/ 238 U activity ratios were present in the alluvial aquifer as a result of irrigation with U-bearing river water, and minor amounts of U with higher 234 U/ 238 U activity ratios were added locally from basal and underlying volcanic-rich sediments. Distributions of NO 3 - "> NO3- , &#x3B4; 15 N [ NO 3 - ] "> δ15N[NO3-] , dissolved gases, and ground-water ages indicate that NO 3 - "> NO3- concentrations increased and &#x3B4; 15 N [ NO 3 - ] "> δ15N[NO3-] values decreased in distributed recharge in the last few decades, possibly in relation to a documented increase in the agricultural use of artificial fertilizers. Canal leakage caused substantial dilution of NO 3 - "> NO3- within the alluvial aquifer, whereas denitrification occurred mainly near the bottom of the alluvium. The average residence time of the irrigation water within the aquifer was relatively short (about 9 a) and reactions such as respiration, denitrification and U exchange in the saturated zone had relatively little effect on the overall composition of the alluvial ground water in comparison to what they might have had in the absence of irrigation recharge.

Nebraska↗

Evaluation of baseline ground-water conditions in the Mosteiros, Ribeira Paul, and Ribeira Fajã Basins, Republic of Cape Verde, West Africa, 2005-06

This report documents current (2005-06) baseline ground-water conditions in three basins within the West African Republic of Cape Verde (Mosteiros on Fogo, Ribeira Paul on Santo Antão, and Ribeira Fajã on São Nicolau) based on existing data and additional data collected during this study. Ground-water conditions (indicators) include ground-water levels, ground-water recharge altitude, ground-water discharge amounts, ground-water age (residence time), and ground-water quality. These indicators are needed to evaluate (1) long-term changes in ground-water resources or water quality caused by planned ground-water development associated with agricultural projects in these basins, and (2) the feasibility of artificial recharge as a mitigation strategy to offset the potentially declining water levels associated with increased ground-water development. Ground-water levels in all three basins vary from less than a few meters to more than 170 meters below land surface. Continuous recorder and electric tape measurements at three monitoring wells (one per basin) showed variations between August 2005 and June 2006 of as much as 1.8 meters. Few historical water-level data were available for the Mosteiros or Ribeira Paul Basins. Historical records from Ribeira Fajã indicate very large ground-water declines during the 1980s and early 1990s, associated with dewatering of the Galleria Fajã tunnel. More-recent data indicate that ground-water levels in Ribeira Fajã have reached a new equilibrium, remaining fairly constant since the late 1990s. Because of the scarcity of observation wells within each basin, water-level data were combined with other techniques to evaluate ground-water conditions. These techniques include the quantification of ground-water discharge (well withdrawals, spring discharge, seepage to springs, and gallery drainage), field water-quality measurements, and the use of environmental tracers to evaluate sources of aquifer recharge, flow paths, and ground-water residence times. In the Mosteiros Basin, measured well and spring discharge is about 220,000 cubic meters per year. For the Ribeira Paul Basin, measured well discharge, spring discharge, and ground-water seepage to springs is about 1,600,000 cubic meters per year. Ribeira Fajã Basin is the driest of the three basins with a precipitation rate of about half that of the other two basins. The only measurable ground-water discharge from this basin is from Galleria Fajã, estimated to be about 150,000 cubic meters per year. Measured discharge for all three basins does not include submarine outflow or agricultural/phreatophyte consumptive use (Paul Basin, only) and is assumed to be less than total ground-water discharge. Ground-water ages indicate that recharge to wells and springs occurred from more than 50 years ago at some locations to within the past decade at other sites. Ground water in Paul is younger than that in the other two basins, indicating that recharge generally occurred within the past 50 years. Ground water at all the dateable sites using tritium/helium in both the Mosteiros and Ribeira Fajã Basins show that recharge occurred more than 50 years before the sampling dates. Ground-water tritium/helium age dating was not possible at some sites in Mosteiros and Ribeira Fajã Basins because of the presence of helium in the aquifer derived from the mantle or aquifer matrix. However, this helium was useful for accurate age dating of the unaffected ground-water sites. Dissolved gases indicate that most ground-water recharge occurs at mid and high altitudes within all three basins; calculated recharge altitudes ranged from 700 to more than 2,000 meters. In the Mosteiros and Ribeira Fajã Basins, recharge altitudes are much higher than the wells and springs. This suggests that it may take many years for artificial recharge to result in a beneficial impact on the aquifer in areas where the agricultural projects are implemented. Recharge altitudes in Paul Basin also were generally higher than their respective ground-water discharge sampling sites except for one spring, Seladinha. This spring, in combination with generally younger ground-water ages in Paul, indicates the existence of some short flow paths where artificial recharge may possibly enhance available water resources within a few years. The salinity of wells and springs is generally low in the Ribeira Paul and Ribeira Fajã Basins, but somewhat higher in Mosteiros Basin. Specific-conductance measurements of wells and springs in Ribeira Paul and Ribeira Fajã ranged from about 200 to 700 microsiemens per centimeter at 25 degrees Celsius. Although the Monte Vermelho spring in Mosteiros Basin also has very low salinity (200 microsiemens per centimeter at 25 degrees Celsius), water from the wells along the coastal plain has specific-conductance measurements of as much as 16,000 microsiemens per centimeter at 25 degrees Celsius. These higher values indicate some brackish water intrusion. Additional ground-water development of the Mosteiros coastal plain may exacerbate this situation.

Mosteiros basin, Ribeira Fajã basin, Ribeira Paul ↗

Use of tracers and isotopes to evaluate vulnerability of water in domestic wells to septic waste

In Nebraska, a large number (>200) of shallow sand‐point and cased wells completed in coarse alluvial sediments along rivers and lakes still are used to obtain drinking water for human consumption, even though construction of sand‐point wells for consumptive uses has been banned since 1987. The quality of water from shallow domestic wells potentially vulnerable to seepage from septic systems was evaluated by analyzing for the presence of tracers and multiple isotopes. Samples were collected from 26 sand‐point and perforated, cased domestic wells and were analyzed for bacteria, coliphages, nitrogen species, nitrogen and boron isotopes, dissolved organic carbon (DOC), prescription and nonprescription drugs, or organic waste water contaminants. At least 13 of the 26 domestic well samples showed some evidence of septic system effects based on the results of several tracers including DOC, coliphages, NH 4 + , NO 3 − , N 2 , δ 15 N[NO 3 − ] and boron isotopes, and antibiotics and other drugs. Sand‐point wells within 30 m of a septic system and <14 m deep in a shallow, thin aquifer had the most tracers detected and the highest values, indicating the greatest vulnerability to contamination from septic waste.

Ground Water Monitoring and Remediation↗

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios, in a riverbank filtration study, Platte River, Nebraska, 2001 to 2003, Volume 1

Although studied extensively in recent years in Europe, the occurrence of endocrine disrupters and other organic wastewater compounds in the environment in the United States is not well documented. To better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment, a study was conducted during 2001-2003 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. This study provides information that will be useful for (1) increased understanding of the processes and factors important in controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and data collected during the study. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and three vertical wells), and drinking-water sites (raw and finished). Field water-quality properties were measured in samples from these sites. Pharmaceutical compounds were detected often in the wastewater-treatment plant effluent. Surface and ground water showed low-level concentrations of pharmaceuticals. Finished drinking-water samples did not contain detectable concentrations of pharmaceuticals except for low levels of cotinine and caffeine. Antibiotics were found in some of the wastewater samples and twice in Salt Creek. Antibiotics were not detected in any samples from the Platte River or the well field. Surface-water samples were analyzed for total organic carbon and ground-water samples were analyzed for dissolved organic carbon. Samples from all sites were analyzed for major ions. Herbicides commonly detected in surface, ground, and drinking water included acetachlor, alachlor, atrazine, and metolachlor as well as degradates of these compounds. Most of the samples from wastewater sites were found to contain predominantly acetamide degradates. High concentrations of several organic wastewater indicator compounds were detected at the wastewater sites and in Salt Creek. Several organic wastewater indicator compounds were detected multiple times in samples from the Platte River. Bromoform, a by-product of disinfection in the treatment plant, was found in samples from the finished drinking water. Stable hydrogen isotope ratios show a range in seasonal variation of -73.6 per mill to -38.1 per mill relative to Vienna Standard Mean Ocean Water (VSMOW) reference water and -69.2 per mill to -46.5 per mill for surface water and ground water, respectively. Oxygen isotope ratios for surface-water samples varied between -9.86 per mill and -5.05 per mill. Stable oxygen isotope ratios of ground waters varied between -9.62 per mill and -5.81 per mill.

Nebraska↗

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios in a riverbank filtration study, Platte River, Nebraska, 2002 to 2005, Volume 2

This document is the second volume of a data series report that describes the data collected during a study conducted during 2001 through 2005 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. The data were collected as part of a study designed to help researchers better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment. This study provides information that will be useful for (1) increased understanding of the processes and factors controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and additional data for pharmaceuticals, dissolved organic carbon (DOC), ultraviolet absorbance at 254 nanometer (nm) wavelength (UV254), specific ultraviolet absorbance (SUVA), nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), nonylphenol ethoxycarboxylates (NPECs), and stable hydrogen and oxygen isotope ratios that were not available at the time of publication of Volume 1 in the data series. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and five vertical wells), and drinking-water sites (raw and finished). Field water-quality properties also were measured in samples from these sites. Pharmaceuticals detected at least once in samples collected from the Platte River included 1,7-dimethylxanthine, acetaminophen, caffeine, carbamazapine, and cotinine. Among the ground-water samples, pharmaceutical compounds detected at low concentrations in at least one sample included 1,7-dimethylxanthine, acetaminophen, carbamazapine, and trimethoprim. When analyzing for non-pharmaceutical compounds in samples from the wastewater sites, the wastewater-treatment plant effluent samples had the highest concentrations of each of NTA, EDTA, and NPECs compounds. Surface-water samples from Salt Creek had higher concentrations of EDTA and NPECs than samples from the Platte River. NTA was not detected in any samples from the ground-water sites. EDTA was detected in all samples from all wells. Detectable concentrations of EDTA were also observed in all samples from the raw water and finished water.

Nebraska↗

Occurrence of endocrine-disrupting and other wastewater compunds during water treatment with case studies from Lincoln, Nebraska and Berlin, Germany

Research on the fate and transport of endocrine-disrupting compounds and other organic wastewater compounds released into the environment and their potential presence in drinking water is in its infancy. Studies conducted during the last decade in Lincoln, Nebraska, and Berlin, Germany, indicate that removal of less polar compounds probably can be obtained through bank filtration, ground-water enrichment, and additional drinking-water and wastewater treatment processes. Polar compounds, such as atrazine and some metabolites, occur in drinking water obtained from contaminated surface water or ground water, but at concentrations generally lower than those occurring in wastewater and surface water. The results of the studies also suggest that concentrations of nonpolar estrogenic compounds decrease during drinking-water pretreatment processes such as bank filtration and ground-water enrichment.

Practice Periodical of Hazardous, Toxic, and Radio↗

Changes in concentrations of triazine and acetamide herbicides by bank filtration, ozonation, and chlorination in a public water supply

The changes in triazine and acetamide concentrations in water during natural and artificial treatment by bank filtration, ozonation, filtration, and chlorination were measured at the well field and drinking water treatment plant of Lincoln, Nebraska, USA. The city's groundwater supply is affected by induced infiltration and transport of triazines and acetamide herbicides from the Platte River in late spring and early summer. The objective of the study was to evaluate the effect of infiltration and treatment on the presence of triazines and acetamides in drinking water. Samples of river water, well water, and public supply water at various stages of water treatment were collected from 1997-1999 during spring-runoff when the presence of herbicides in the Platte River is largest. In 1999, parent compounds were reduced by 76% of the concentration present in river water (33% by bank filtration, 41% by ozonation, and 1.5% by chlorination). Metabolites of herbicides for which analytical techniques existed were reduced by 21% (plus 26% by bank filtration, minus 23% by ozonation, and minus 24% by chlorination). However, increases in concentrations of specific metabolite compounds were identified after bank filtration and ozonation. After bank filtration, increases in cyanazine amide, cyanazine acid, and deethylcyanazine acid were identified. After ozonation, concentrations of deisopropylatrazine, deethylatrazine, didealkylatrazine, atrazine amide-I, hydroxydeethylatrazine, hydroxydeisopopylatrazine, deethylcyanazine acid, and deethylcyanazine increased. Concentrations of cyanazine acid and ethanesulfonic and oxanilic acids of acetamides decreased during ozonation. Our findings suggest that bank filtration and ozonation of water in part can shift the assessment of risk to human health associated with the consumption of the water from the parent compounds to their degradation products.

Journal of Hydrology↗

Use of environmental tracers and isotopes to evaluate sources of water, nitrate, and uranium in an irrigated alluvial valley, Nebraska

The effects of irrigation canals and the North Platte River on ground-water movement and quality in an irrigated alluvial valley, western Nebraska, were evaluated using environmental tracers. The results indicated that most of the ground water in the alluvium was derived from the North Platte River and generally was less than 30 years old. Ground-water-recharge rates varied substantially from about 0.6 to 9 feet per year with the larger recharge rates reflecting localized canal seepage. Younger water had higher nitrate concentrations than older water. Increases in nitrate concentrations in recharging ground water over time may be associated with an increase in nitrogen fertilizer use over time. Denitrification was limited in the ground water in the alluvium. Uranium concentrations in ground water resulted from dissolution of volcanic ash or other sediments in the underlying bedrock or incorporated in the alluvium. High uranium concentrations in the North Platte River during the winter months were a result of the addition of uranium-rich water from local tributaries and seepage of uranium-rich ground water.

Nebraska↗