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Geology topics

Heather Lowers

Publications and source records attributed to Heather Lowers.

At least 19 recordsLinked to original sources
USGS2015

Evaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes

A comparison study of selected static leaching and acid–base accounting (ABA) methods using a mineralogically diverse set of 12 modern-style, metal mine waste samples was undertaken to understand the relative performance of the various tests. To complement this study, in-depth mineralogical studies were conducted in order to elucidate the relationships between sample mineralogy, weathering features, and leachate and ABA characteristics. In part one of the study, splits of the samples were leached using six commonly used leaching tests including paste pH, the U.S. Geological Survey (USGS) Field Leach Test (FLT) (both 5-min and 18-h agitation), the U.S. Environmental Protection Agency (USEPA) Method 1312 SPLP (both leachate pH 4.2 and leachate pH 5.0), and the USEPA Method 1311 TCLP (leachate pH 4.9). Leachate geochemical trends were compared in order to assess differences, if any, produced by the various leaching procedures. Results showed that the FLT (5-min agitation) was just as effective as the 18-h leaching tests in revealing the leachate geochemical characteristics of the samples. Leaching results also showed that the TCLP leaching test produces inconsistent results when compared to results produced from the other leaching tests. In part two of the study, the ABA was determined on splits of the samples using both well-established traditional static testing methods and a relatively quick, simplified net acid–base accounting (NABA) procedure. Results showed that the traditional methods, while time consuming, provide the most in-depth data on both the acid generating, and acid neutralizing tendencies of the samples. However, the simplified NABA method provided a relatively fast, effective estimation of the net acid–base account of the samples. Overall, this study showed that while most of the well-established methods are useful and effective, the use of a simplified leaching test and the NABA acid–base accounting method provide investigators fast, quantitative tools that can be used to provide rapid, reliable information about the leachability of metals and other constituents of concern, and the acid-generating potential of metal mining waste.

Applied Geochemistry↗
USGS2015

Lithostratigraphic, borehole-geophysical, hydrogeologic, and hydrochemical data from the East Bay Plain, Alameda County, California

The U.S. Geological Survey, in cooperation with the East Bay Municipal Utility District, carried out an investigation of aquifer-system deformation associated with groundwater-level changes at the Bayside Groundwater Project near the modern San Francisco Bay shore in San Lorenzo, California. As a part of the Bayside Groundwater Project, East Bay Municipal Utility District proposed an aquifer storage and recovery program for 1 million gallons of water per day. The potential for aquifer-system compaction and expansion, and related subsidence, uplift, or both, resulting from aquifer storage and recovery activities were investigated and monitored in the Bayside Groundwater Project. In addition, baseline analysis of groundwater and substrata properties were performed to assess the potential effect of such activities. Chemical and physical data, obtained from the subsurface at four sites on the east side of San Francisco Bay in the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California, were collected during the study. The results of the study were provided to the East Bay Municipal Utility District and other agencies to evaluate the chemical and mechanical responses of aquifers underlying the East Bay Plain to the future injection and recovery of imported water from the Sierra Nevada of California. Among 4 sites, 14 piezometers and 2 extensometers were installed in 6 boreholes, which ranged in depth from 460 to 1,040 feet. The lithology of drill cuttings, collected at 5- or 10-foot intervals, was described for grain size and any other noticeable features, such as wood or shell fragments. Borehole geophysical logging was performed at each site in the deepest borehole, immediately following drilling. Drill-core samples, totaling 284 feet, were collected at the Bayside site. The drill-core sediment was subsampled to determine pore-water chemistry, vertical hydraulic conductivity, and physical and mechanical properties at different depths. Depositional environment and age were determined by luminescence geochronology and fossil identification. The elemental composition of the drill-core sediments was determined by inductively coupled plasma mass spectroscopy and instrumental neutron activation by abbreviated count analysis. Mineral composition was determined by X-ray diffraction and scanning electron microscopy analysis. Groundwater samples were collected from all 14 piezometers as part of either the USGS Groundwater Ambient Monitoring and Assessment or the USGS National Water Quality Assessment program for water-quality analyses. Sample analytes included nutrients, major and minor ions, trace elements, isotopic ratios of hydrogen and oxygen in water, carbon-14, and tritium. Water-level and aquifer-system-compaction measurements, which indicated diurnal and seasonal fluctuations, were made at the Bayside Groundwater Project site. Slug tests were performed at the Bayside piezometers and nine pre-existing wells to estimate hydraulic conductivity.

California↗
USGS2014

Characterisation of a natural quartz crystal as a reference material for microanalytical determination of Ti, Al, Li, Fe, Mn, Ga and Ge

A natural smoky quartz crystal from Shandong province, China, was characterised by laser ablation ICP-MS, electron probe microanalysis (EPMA) and solution ICP-MS to determine the concentration of twenty-four trace and ultra trace elements. Our main focus was on Ti quantification because of the increased use of this element for titanium-in-quartz (TitaniQ) thermobarometry. Pieces of a uniform growth zone of 9 mm thickness within the quartz crystal were analysed in four different LA-ICP-MS laboratories, three EPMA laboratories and one solution-ICP-MS laboratory. The results reveal reproducible concentrations of Ti (57 ± 4 μg g -1 ), Al (154 ± 15 μg g -1 ), Li (30 ± 2 μg g -1 ), Fe (2.2 ± 0.3 μg g -1 ), Mn (0.34 ± 0.04 μg g -1 ), Ge (1.7 ± 0.2 μg g -1 ) and Ga (0.020 ± 0.002 μg g -1 ) and detectable, but less reproducible, concentrations of Be, B, Na, Cu, Zr, Sn and Pb. Concentrations of K, Ca, Sr, Mo, Ag, Sb, Ba and Au were below the limits of detection of all three techniques. The uncertainties on the average concentration determinations by multiple techniques and laboratories for Ti, Al, Li, Fe, Mn, Ga and Ge are low; hence, this quartz can serve as a reference material or a secondary reference material for microanalytical applications involving the quantification of trace elements in quartz.

Geostandards and Geoanalytical Research↗
USGS2014

Assessment of the geoavailability of trace elements from selected zinc minerals

This assessment focused on five zinc-bearing minerals. The minerals were subjected to a number of analyses including quantitative X-ray diffraction, optical microscopy, leaching tests, and bioaccessibility and toxicity studies. Like a previous comprehensive assessment of five copper-bearing minerals, the purpose of this assessment was to obtain structural and chemical information and to characterize the reactivity of each mineral to various simulated environmental and biological conditions. As in the copper minerals study, analyses were conducted consistent with widely accepted methods. Unless otherwise noted, analytical methods used for this study were identical to those described in the investigation of copper-bearing minerals. Two sphalerite specimens were included in the zinc-minerals set. One sphalerite was recovered from a mine in Balmat, New York; the second came from a mine in Creede, Colorado. The location and conditions of origin are significant because, as analyses confirmed, the two sphalerite specimens are quite different. For example, data acquired from a simulated gastric fluid (SGF) study indicate that the hydrothermally formed Creede sphalerite contains orders of magnitude higher arsenic, cadmium, manganese, and lead than the much older metamorphic Balmat sphalerite. The SGF and other experimental results contained in this report suggest that crystallizing conditions such as temperature, pressure, fluidization, or alteration processes significantly affect mineral properties—properties that, in turn, influence reactivity, solubility, and toxicity. The three remaining minerals analyzed for this report—smithsonite, hemimorphite, and hydrozincite—are all secondary minerals or alteration products of zinc-ore deposits. In addition, all share physical characteristics such as tenacity, density, streak, and cleavage. Similarities end there. The chemical composition, unit-cell parameters, acid-neutralizing potential, and other observable and quantifiable properties indicate very different minerals. Only one of each of these minerals was studied. Had this assessment included multiples of these minerals, geochemical and mineralogical distinctions would have emerged, similar to the results for the two sphalerite specimens.

Arizona;Chihuahua;Colorado;New York↗
USGS2013

Linking geology and health sciences to assess childhood lead poisoning from artisanal gold mining in Nigeria

Background: In 2010, Médecins Sans Frontières discovered a lead poisoning outbreak linked to artisanal gold processing in northwestern Nigeria. The outbreak has killed approximately 400 young children and affected thousands more. Objectives: Our aim was to undertake an interdisciplinary geological- and health-science assessment to clarify lead sources and exposure pathways, identify additional toxicants of concern and populations at risk, and examine potential for similar lead poisoning globally. Methods: We applied diverse analytical methods to ore samples, soil and sweep samples from villages and family compounds, and plant foodstuff samples. Results: Natural weathering of lead-rich gold ores before mining formed abundant, highly gastric-bioaccessible lead carbonates. The same fingerprint of lead minerals found in all sample types confirms that ore processing caused extreme contamination, with up to 185,000 ppm lead in soils/sweep samples and up to 145 ppm lead in plant foodstuffs. Incidental ingestion of soils via hand-to-mouth transmission and of dusts cleared from the respiratory tract is the dominant exposure pathway. Consumption of water and foodstuffs contaminated by the processing is likely lesser, but these are still significant exposure pathways. Although young children suffered the most immediate and severe consequences, results indicate that older children, adult workers, pregnant women, and breastfed infants are also at risk for lead poisoning. Mercury, arsenic, manganese, antimony, and crystalline silica exposures pose additional health threats. Conclusions: Results inform ongoing efforts in Nigeria to assess lead contamination and poisoning, treat victims, mitigate exposures, and remediate contamination. Ore deposit geology, pre-mining weathering, and burgeoning artisanal mining may combine to cause similar lead poisoning disasters elsewhere globally.

Environmental Health Perspectives↗
USGS2013

Epidote from the Zard Mountains, Kharan, Balochistan, Pakistan

The authors received two unusual crystals of epidote from Rock Currier, Jewel Tunnel Imports, in 2012. The mineral specimens were collected at Zard Mountain (Zard Koh), in the central part of the Ruskoh Mountains (Rusk Koh), west of Kharan, Balochistan, Pakistan (written communication, Rock Currier, 2013). The epidote locality was most likely discovered in 2010. These epidote crystals were unusual in both form and composition. The large crystals were flat tabular and pseudohexagonal in shape which is an uncommon crystal form for a monoclinic mineral (fig. 1). Other specimens from the same locality have been described as pseudo-octahedral in shape. The two crystals range in size from 5.5 to 6.5 centimeters (2.2 to 2.6 inches) and are slightly magnetic. The epidote crystals have a core matrix that resembles a weathered igneous rock. Some micro brown- to reddish-titanite crystals were observed under a binocular microscope on the surface and core areas of the crystals (figs. 2 and 3). Other minerals observed in the core areas include feldspar, biotite, and quartz. The crystals display evidence of cluster-growth with points of attachment to other crystals. The epidotes were most likely collected in pockets of a weathered igneous-skarn deposit.

Balochistan, Zard Mountains↗
USGS2012

Multiple age components in individual molybdenite grains

Re–Os geochronology of fractions composed of unsized, coarse, and fine molybdenite from a pod of unusual monazite–xenotime gneiss within a granulite facies paragneiss, Hudson Highlands, NY, yielded dates of 950.5 ± 2.5, 953.8 ± 2.6, and 941.2 ± 2.6 Ma, respectively. These dates are not recorded by co-existing zircon, monazite, or xenotime. SEM–BSE imagery of thin sections and separated grains reveals that most molybdenite grains are composed of core and rim plates that are approximately perpendicular. Rim material invaded cores, forming irregular contacts, probably reflecting dissolution/reprecipitation. EPMA and LA-ICP-MS analyses show that cores and rims have different trace element concentrations (for example, cores are relatively enriched in W). On the basis of inclusions of zircon with metamorphic overgrowths, we conclude that molybdenite cores and rims formed after high-grade regional metamorphism. The discovery of cores and rims in individual molybdenite grains is analogous to multi-component U-Pb geochronometers such as zircon, monazite, and titanite; thus, molybdenite should be carefully examined before dating to ensure that the requirement of age homogeneity is fulfilled.

New York↗
USGS2012

Preparation and characterization of "Libby Amphibole" toxicological testing material

The U.S. Environmental Protection Agency (USEPA) began work in Libby, Mont. in 1999 when an Emergency Response Team was sent to investigate local concern and media reports regarding asbestos-contaminated vermiculite. Since that time, the site has been granted Superfund status and site remediation to a safe level of asbestos has been ongoing. The amphibole asbestos from the Vermiculite Mountain vermiculite deposit near Libby, Mont. (Libby amphibole) is unusual in the sense that it is currently not classified as one of the regulated six asbestos minerals—chrysotile (a serpentine mineral) and the amphibole minerals amosite (asbestiform cummingtonite-grunerite), crocidolite (asbestiform riebeckite), asbestiform anthophyllite, asbestiform tremolite, and asbestiform actinolite. The amphiboles from the Vermiculite Mountain vermiculite deposit, primarily winchite and richterite, are related to tremolite and in the past have been referred to as sodium-rich tremolite or soda tremolite (Larsen, 1942; Boettcher, 1966; Wylie and Verkouteren, 2000; Gunter and others, 2003; Meeker and others, 2003). The public health issues in Libby, Mont. have brought to light many of the inconsistencies in the literature regarding fiber characteristics, nomenclature, and toxicology. To better understand the toxicological characteristics of the Libby amphibole, investigators require a sufficient quantity of material representing the range of fibrous amphiboles present in the vicinity of Vermiculite Mountain to use in toxicology studies. The material collected in 2000 (Meeker and others, 2003) has been exhausted and a second collection and preparation effort, funded by the USEPA, was conducted in 2007. Both the 2000 (LA2000) and 2007 (LA2007) materials were generated to support research needs identified by the USEPA and the National Toxicology Program, and new in-vivo and in-vitro toxicology studies are underway. This Open-File Report describes the process of preparation and summarizes the chemistry and mineralogy of the LA2007 toxicological testing material.

Libby, Montana↗
USGS2012

Geologic and mineralogic controls on acid and metal-rich rock drainage in an alpine watershed, Handcart Gulch, Colorado

The surface and subsurface geology, hydrothermal alteration, and mineralogy of the Handcart Gulch area was studied using map and drill core data as part of a multidisciplinary approach to understand the hydrology and affects of geology on acid-rock drainage in a mineralized alpine watershed. Handcart Gulch was the locus of intense hydrothermal alteration that affected an area of nearly 3 square kilometers. Hydrothermal alteration and accompanied weak mineralization are spatially and genetically associated with small dacite to low-silica rhyolite stocks and plugs emplaced about 37-36 Ma. Felsic lithologies are commonly altered to a quartz-sericite-pyrite mineral assemblage at the surface, but alteration is more variable in the subsurface, ranging from quartz-sericite-pyrite-dominant in upper core sections to a propylitic variant that is more typical in deeper drill core intervals. Late-stage, hydrothermal argillic alteration [kaolinite and(or) smectite] was superimposed over earlier-formed alteration assemblages in the felsic rocks. Smectite in this late stage assemblage is mostly neoformed resulting from dissolution of chlorite, plagioclase, and minor illite in more weakly altered rocks. Hydrothermally altered amphibolites are characterized by biotitic alteration of amphibole, and subsequent alteration of both primary and secondary biotite to chlorite. Whereas pyrite is present both as disseminations and in small veinlets in the felsic lithologies, it is mostly restricted to small veinlets in the amphibolites. Base-metal sulfides including molybdenite, chalcopyrite, sphalerite, and galena are present in minor to trace amounts in the altered rocks. However, geologic data in conjunction with water geochemical studies indicate that copper mineralization may be present in unknown abundance in two distinct areas. The altered rocks contain an average of 8 weight percent fine pyrite that is largely devoid of metals in the crystal structure, which can be a significant source of trace metals in other areas with acid rock drainage. Thus, elevated base-metal concentrations in the trunk stream and discrete springs in the study area, as determined in previous studies, are likely derived from discrete metal-rich sources, rather than the abundant pyrite veins or disseminations. Pyrite is oxidized in nearly all outcrops examined. Drill core data show that zones of pyrite oxidation range in depth from 100 meters below the surface at higher elevations to just a few meters depth at the lowest elevations in the study area. However, discrete pyrite oxidation zones are present in drill core to depths of several hundred meters below the pervasive near-surface oxidation zones. These deeper discrete oxidation zones, which are present where fresh pyrite predominates, are spatially associated with fractures, small faults, and breccias. Quartz-sericite-pyrite-altered rocks containing unoxidized pyrite likely have the highest acid-generating capacity of all alteration assemblages in the study area. Hydrothermal alteration has left these rocks base-cation leached and thus acid-neutralizing potential is negligible. In contrast, propylitic-altered felsic rocks commonly contain trace to minor calcite and abundant chlorite, which provide some amount of acid-neutralization despite the presence of a few percent pyrite.

Colorado↗
USGS2011

Visualizing trace element distribution in quartz using cathodoluminescence, electron microprobe, and laser ablation-inductively coupled plasma-mass spectrometry

Cathodoluminescent (CL) textures in quartz reveal successive histories of the physical and chemical fluctuations that accompany crystal growth. Such CL textures reflect trace element concentration variations that can be mapped by electron microprobe or laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Trace element maps in hydrothermal quartz from four different ore deposit types (Carlin-type Au, epithermal Ag, porphyry-Cu, and MVT Pb-Zn) reveal correlations among trace elements and between trace element concentrations and CL textures. The distributions of trace elements reflect variations in the physical and chemical conditions of quartz precipitation. These maps show that Al is the most abundant trace element in hydrothermal quartz. In crystals grown at temperatures below 300 °C, Al concentrations may vary by up to two orders of magnitude between adjacent growth zones, with no evidence for diffusion. The monovalent cations Li, Na, and K, where detectable, always correlate with Al, with Li being the most abundant of the three. In most samples, Al is more abundant than the combined total of the monovalent cations; however, in the MVT sample, molar Al/Li ratios are ~0.8. Antimony is present in concentrations up to ~120 ppm in epithermal quartz (~200–300 °C), but is not detectable in MVT, Carlin, or porphyry-Cu quartz. Concentrations of Sb do not correlate consistently with those of other trace elements or with CL textures. Titanium is only abundant enough to be mapped in quartz from porphyry-type ore deposits that precipitate at temperatures above ~400 °C. In such quartz, Ti concentration correlates positively with CL intensity, suggesting a causative relationship. In contrast, in quartz from other deposit types, there is no consistent correlation between concentrations of any trace element and CL intensity fluctuations.

American Mineralogist↗
USGS2010

Chemical and morphological comparison of erionite from Oregon, North Dakota, and Turkey

Erionite, a fibrous zeolite, occurs in pediment gravel deposits near Killdeer Mountain, North Dakota. Material from these pediment deposits has been excavated for use as roadbed throughout Dunn County, North Dakota. Erionite also occurs in the Cappadocian region of Turkey, where a link between malignant mesothelioma and inhalation of this mineral has been established. The U.S. Environmental Protection Agency (EPA), Region 8, requested that the U.S. Geological Survey (USGS) compare the chemistry and morphology of erionite collected from the Killdeer Mountains to those collected from villages in Turkey and from Rome, Oregon, which has also been linked to disease in animal studies.

Open-File Report↗
USGS2009

Materials characterization of dusts generated by the collapse of the World Trade Center

The major inorganic components of the dusts generated from the collapse of the World Trade Center buildings on September 11, 2001 were concrete materials, gypsum, and man-made vitreous fibers. These components were likely derived from lightweight Portland cement concrete floors, gypsum wallboard, and spray-on fireproofing and ceiling tiles, respectively. All of the 36 samples collected by the USGS team had these materials as the three major inorganic components of the dust. Components found at minor and trace levels include chrysotile asbestos, lead, crystalline silica, and particles of iron and zinc oxides. Other heavy metals, such as lead, bismuth, copper, molybdenum, chromium, and nickel, were present at much lower levels occurring in a variety of chemical forms. Several of these materials have health implications based on their chemical composition, morphology, and bioaccessibility.

Book chapter↗
USGS2009

Particle Size Characterization of Water-Elutriated Libby Amphibole 2000 and RTI International Amosite

This report presents data on particle characterization analyzed by scanning electron microscopy on Libby amphibole collected by the U.S. Geological Survey in 2000 (LA2000) and amosite material collected by RTI International (RTI amosite). The particle characterization data were generated to support a portion of the Libby Action Plan. Prior to analysis, the raw LA2000 and RTI amosite materials were subjected to a preparation step. Each sample was water-elutriated by U.S. Environmental Protection Agency (USEPA) Office of Research and Development, Research Triangle Park using the methods generally described in another published report and then delivered to the U.S. Geological Survey, Denver Microbeam Laboratory for analysis. Data presented here represent analyses performed by the U.S. Geological Survey, Denver Microbeam Laboratory and USEPA National Enforcement Investigations Center. This report consists of two Excel spreadsheet files developed by USEPA, Region 8 Superfund Technical Assistance Unit and describe the particle size characterization of the LA2000 and RTI amosite, respectively. Multiple tabs and data entry cells exist in each spreadsheet and are defined herein.

Open-File Report↗
USGS2008

Preliminary analytical results for a mud sample collected from the LUSI Mud Volcano, Sidoarjo, East Java, Indonesia

On May 29, 2006, mud and gases began erupting unexpectedly from a vent 150 meters away from a hydrocarbon exploration well near Sidoarjo, East Java, Indonesia. The eruption, called the LUSI (Lumpur 'mud'-Sidoarjo) mud volcano, has continued since then at rates as high as 160,000 m3 per day. At the request of the United States Department of State, the U.S. Geological Survey (USGS) has been providing technical assistance to the Indonesian Government on the geological and geochemical aspects of the mud eruption. This report presents initial characterization results of a sample of the mud collected on September 22, 2007, as well as inerpretive findings based on the analytical results. The focus is on characteristics of the mud sample (including the solid and water components of the mud) that may be of potential environmental or human health concern. Characteristics that provide insights into the possible origins of the mud and its contained solids and waters have also been evaluated.

East Java↗
USGS2008

Petrology of the 2004-2006 Mount St. Helens lava dome -- implications for magmatic plumbing and eruption triggering

Eighteen years after dome-forming eruptions ended in 1986, and with little warning, Mount St. Helens began to erupt again in October 2004. During the ensuing two years, the volcano extruded more than 80×10 6 m 3 of gas-poor, crystal-rich dacite lava. The 2004-6 dacite is remarkably uniform in bulk-rock composition and, at 65 percent SiO 2 , among the richest in silica and most depleted in incompatible elements of the magmas erupted at Mount St. Helens during the past 500 years. Since shortly after the first spine of lava appeared, samples have been collected using a steel box dredge (“Jaws”) suspended 20-35 m below a helicopter and, occasionally, by hand sampling. As of the spring of 2006, 25 age-controlled samples have been collected from the seven spines of the new lava dome. Samples were obtained from both the interiors of spines and from their carapaces, which are composed of fault gouge and cataclasite 1-2 m thick. The dacite lava is crystal rich, with 40-50 percent phenocrysts. The groundmass is extensively crystallized to a cotectic assemblage of quartz, tridymite, and Na- and K-rich feldspar microlites, raising the total crystal content to more than 80 percent on a vesicle-free basis in all but the earliest erupted samples. Early samples and those collected from near the spine margin are more glassy and vesicular that those collected later and from the interior of the spines. Oxide thermobarometer determinations for the earliest erupted samples we collected cluster at temperatures of approximately 850&deg;C and at an oxygen fugacity one log unit above the nickel-nickel oxide (NNO) buffer curve. In contrast, samples from relatively glass-poor samples erupted in late 2004 and early 2005 have zoned oxides with apparent temperatures that range to greater than 950&deg;C. The higher temperatures in these microlite-rich rocks are attributed to latent heat evolved during extensive and rapid groundmass crystallization. Low volatile contents of matrix glasses and presence of tridymite and quartz in the high-silica rhyolite matrix glass indicate extensive shallow (<1 km) crystallization of the matrix, driven by degassing of water and solidifying the magma below the level of the vent. The mode of eruption of the dacite as a series of fault-gouge-mantled spines is explained by this process of extensive subvent degassing and solidification. Although the dacite from this eruption is more silica rich than 1980-86 dome rocks, most major and trace element concentrations of the 1980-86 and 2004-6 magma batches are similar, and magmatic gas emissions have been low and have had similar ratios to those of the 1980s, raising the possibility that the magma might be residual from the 1980–86 reservoir. However, titanium and chromium are enriched slightly relative to the most recent 1980-86 and Goat Rocks (A.D. 1800-1857) eruptive cycles, and heavy rare-earth-element abundances are slightly depleted relative to those erupted during the past 500 years at Mount St. Helens. These data suggest either addition of new gas-poor dacite magma or tapping of a region of the preexisting reservoir that was not erupted previously. A relatively low pressure of last phenocryst growth suggests that the magma was derived from near the apex of the Mount St. Helens magma reservoir at a depth of about 5 km. Viewed in the context of seismic, deformation, and gas-emission data, the petrologic and geochemical data can be explained by ascent of a geochemically distinct batch of magma into the apex of the reservoir during the period 1987-97, followed by upward movement of magma into a new conduit beginning in late September 2004. The question of new versus residual magma has implications for the long-term eruptive behavior of Mount St. Helens, because arrival of a new batch of dacitic magma from the deep crust could herald the beginning of a new long-term cycle of eruptive activity. It is also important to our understanding of what triggered the eruption and its future course. Two hypotheses for triggering are considered: (1) top-down fracturing related to the shallow groundwater system and (2) an increase in reservoir pressure brought about by recent magmatic replenishment. With respect to the future course of the eruption, similarities between textures and character of eruption of the 2004-6 dome and the long-duration (greater than 100 years) pre-1980 summit dome, along with the low eruptive rate of the current eruption, suggest that the eruption could continue sluggishly or intermittently for years to come.

Washington↗
USGS2008

Chemistry, mineralogy, and petrology of amphibole in Mount St. Helens 2004-2006 dacite

Textural, compositional, and mineralogical data are reported and interpreted for a large population of clinoamphibole phenocrysts in 22 samples from the seven successive dacite spines erupted at Mount St. Helens between October 2004 and January 2006. Despite the uniformity in bulk composition of magma erupted since 2004, there is striking textural and compositional diversity among amphibole phenocrysts and crystal fragments that have grown from, partly dissolved in, or been accidentally incorporated in the new dacite. This study demonstrates that magma erupted throughout the current dome-building episode is the end product of small-scale, thorough mixing of multiple generations of crystal-laden magma. The mixed amphibole population provides important clues to magma conditions within the dacite magma reservoir prior to ascent and, to some extent, the dynamics of mixing and ascent. The predominant amphibole in new dome rock ranges from moderate- to high-alumina tschermakite and magnesiohastingsite compositions. As substantiated by major- and trace-element geochemistry and barometry calculations, this compositional range of crystals, along with plagioclase, orthopyroxene, and iron-titanium oxide, is likely to have precipitated from dacite magma over a range of pressures and temperatures consistent with experimentally determined phase relations (~900&deg;C to ~800&deg;C between 100 MPa and ~350-400 MPa or ~4-km and 13.5-15-km depth). Along with traceelement characteristics, textural and compositional data help to distinguish some low-alumina magnesiohornblende crystals as xenocrysts. The diverse range in composition of amphibole in all samples of 2004-6 dacite, and the complex zonation observed in many phenocrysts, suggests a well-mixed source magma with components that are subjected to repeated heating and (or) pressurization within this pressure-temperature window. Amphibole textural and compositional diversity suggest dynamic conditions in the upper-reservoir zone, which has been tapped steadily during ~2 years of continuous and monotonous eruption. This well-mixed crystal mush is likely to have been subjected to repeated injection of hotter magma into cooler crystal-laden magma while simultaneously assimilating earlier generations of dacitic roof material and surrounding gabbroic rock. Decompression-related reaction rims around subhedral, rounded, resorbed, and fragmented amphibole phenocrysts, regardless of composition, indicate that this mixed-crystal assemblage was being broken, abraded, and dissolved in the magma as a result of mechanical mixing before and during early stages of ascent from conduit roots extending into a mushy cupola of the shallow reservoir. In the earliest lava samples (October 2004), amphiboles with <3-&mu;m rims associated with a glassier matrix than later samples suggest a slightly faster ascent rate consistent with the relatively high eruptive flux of the earliest phases of dome extrusion. Reaction rim widths of ~5 &mu;m on amphibole in all subsequently extruded lava result from a steady influx and upward transport of magma from 3.5-2.5-km to ~1-km depth at rates of ~600 to ~1,200 m/day, through a conduit less than 10 m in radius. Slower ascent rates inferred from volumetric-flux and matrixcrystallization parameters are explained by a widening of the conduit to greater than 60 m radius within 1 km of the surface.

Washington↗
USGS2007

Compositional Data for Bengal Delta Sediment Collected from a Borehole at Rajoir, Bangladesh

Processes active within sediment of the Bengal basin have attracted world concern because of the locally high content of arsenic dissolved in ground water drawn from that sediment. Sediment samples were collected from a borehole in the town of Rajoir, Rajoir upazila, Madaripur district, Bangladesh, to investigate the processes contributing to arsenic contamination. The samples were mineralogically and chemically analyzed to determine compositional variations related to the arsenic content of the sediment. Mineralogy of the sediment was determined using powder X-ray diffraction. Bulk chemical composition was measured by Combustion; Inductively Coupled Plasma Atomic Emission Spectroscopy; Energy Dispersive X-ray Fluorescence; and Hydride Generation Atomic Absorption Spectrophotometry. Sediment was treated with 0.5 N HCl and resulting solutions were analyzed, primarily to evaluate the abundance and oxidation state of acid-soluble iron. Acid-volatile sulfide, acid-soluble sulfate, and reducible sulfide were also measured on a few samples. Sediment sampled at Rajoir is typically unlithified, gray, micaceous, feldspathic arenaceous sand with a few silt and clay layers. Arsenic content of the sediment ranges from 0.6 to 21 ppm with a median of 1.2 ppm.

Open-File Report↗