Geology topics

H.D. Glass

Publications and source records attributed to H.D. Glass.

3 recordsLinked to original sources

USGS2024

Fluoride content of clay minerals and argillaceous earth materials

A reliable method, utilizing a fluoride ion-selective electrode, is described for the determination of fluoride in clays and shales. Interference by aluminum and iron is minimal. The reproducibility of the method is about ±5% at different levels of fluoride concentration. Data are presented for various clay minerals and for the <2-µm fractions of marine and nonmarine clays and shales. Fluoride values range from 44 ppm (0.0044%) for nontronite from Colfax, WA, to 51,800 ppm (5.18%) for hectorite from Hector, CA. In general, clays formed under hydrothermal conditions are relatively high in fluoride content, provided the hydrothermal waters are high in fluoride content. Besides hectorite, dickite from Ouray, CO, was found to contain more than 50 times as much fluoride (6700 ppm) as highly crystalline geode kaolinite (125 ppm). The clay stratum immediately overlying a fluorite mineralized zone in southern Illinois was found to have a higher fluoride content than the same stratum in a nonmineralized zone approximately 1 mile away. Nonmarine shales in contact with Australian coals were found to be lower in fluoride content than were marine shales in contact with Illinois coals. It is believed that, in certain instances, peak shifts on DTA curves of similar clay minerals are the result of significant differences in their fluoride content.

Clays and Clay Minerals↗

USGS2017

Pleistocene stratigraphy of the Boston Harbor drumlins, Massachusetts

Evidence from the Boston Harbor drumlins indicates that two superposed tills were deposited during glacier advances which were separated by a long nonglacial interval. At Long and Peddocks Islands, argillans and truncated clay-filled fractures, along with discontinuities in clay-mineral composition, define the till contacts. Physical indicators separating the tills are not apparent at other exposures, where till boundaries were defined solely by discontinuities in clay-mineral composition. The weathering profile in the upper part of the lower till indicates extensive weathering under a climate similar to that of today, and probably similar to that of the Sangamon Interglaciation. The depth of the weathering profile, the sequence of clay-mineral alteration products, and the presence of pedogenic features in the upper part of the lower till are comparable to Sangamonian weathering profiles in the midwestern United States, implying that the lower till is Illinoian or older. ?? 1990.

Quaternary Research↗

USGS1997

Tapir ( Tapirus ) enteroliths

Enterolith fragments from two tapir species and horses were subjected to x-ray diffraction analysis. Tapir enteroliths were formed as layers of mineral deposited around a foreign nidus. The structure was similar to that of equine enteroliths except that tapir enteroliths lacked a central region of radially symmetrical coarse crystals. The enteroliths from tapirs were composed primarily of vivianite [Fe 3 (PO 4 ) 2 · 8H 2 O] and newberyite [MgH(PO 4 ) · 3H 2 O], instead of the struvite [Mg(NH 4 )(PO 4 ) · 6H 2 O] of enteroliths from horses. The reason for this difference is not known. Based on the chemistry of these mineral precipitates and information from other species, it was concluded that dietary manipulation to maximize carbohydrate fermentation and minimize protein fermentation in the large intestine may help prevent enterolithiasis in tapirs.

Illinois, Minnesota↗