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Gregory T. Connock

Publications and source records attributed to Gregory T. Connock.

3 recordsLinked to original sources

Water-quality indicators of surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia

The U.S. Geological Survey, in cooperation with the West Virginia Department of Health and Human Resources, studied surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia for the purpose of understanding the influence of surface water on groundwater chemistry. Public groundwater supplies obtained from these aquifers receive substantial recharge from surface-water sources and are highly susceptible to degradation from water-soluble contaminants. Water samples were collected from 4 sites in the Ohio River and 23 groundwater wells in the alluvial aquifer from June 2019 to January 2020. Surface-water influence was assessed through characterization of groundwater quality, determination of recharge sources, estimation of groundwater age, and estimation of the fraction of Ohio River water entering groundwater pumped by wells in the alluvial aquifers. Hydrogeochemical processes controlling solute concentrations in the Ohio River alluvial aquifer were evaluated with multivariate statistical analysis and identified to be primarily controlled by redox processes, input from sources of salinity, and carbonate dissolution. Meteoric recharge from the Ohio River and precipitation on the alluvium are the main sources of water entering the aquifer. The age of groundwater in the system was determined to be primarily from a modern source. Groundwater samples from every well included in this study had detections for at least one geochemical indicator of surface-water influence, and every well was determined to be susceptible and vulnerable to contamination from surface sources. Results from binary mixing models and inverse geochemical models showed that sulfate, silica, and bicarbonate concentrations predict the fraction of Ohio River water entering alluvial wells for preliminary determination of surface-water influence when compared to fractions predicted using a numerical groundwater-flow model. In the absence of extensive analytes and geochemical or groundwater modeling capabilities, preliminary assessment of the fraction of Ohio River water entering groundwater wells in the Ohio River alluvium can be estimated for most sites using a linear relation between the equivalent ratio of bicarbonate to sulfate and the fraction of water computed by the average of the three geochemical models presented in this report. This approximation of the fraction of Ohio River water, coupled with information on the hydrogeological framework and geochemical indicators of surface-water influence, may be sufficient for preliminary assessment of surface-water influence in the absence of more detailed site information or reaction-transport models.

West Virginia

Groundwater quality in abandoned underground coal mine aquifers across West Virginia

Abandoned underground coal mine aquifers cover a large part of West Virginia and could supply substantial quantities of water for agricultural, industrial, residential, and public use. Several Federal, State, and academic institutions have studied the availability and quality of water stored in abandoned underground coal mine aquifers for a variety of applications, such as economic development, geothermal energy, aquaculture, and wastewater disposal. However, the spatial and stratigraphic controls on water quality produced from abandoned underground coal mine aquifers are still poorly constrained on a state-wide basis. In response to these knowledge gaps, the U.S. Geological Survey initiated a study, in cooperation with the West Virginia Department of Environmental Protection, to understand the applicability of using existing secondary source data for understanding water quality in abandoned underground coal mine aquifers across the State. Results from the calculation of net alkalinity indicated that Upper Pennsylvanian coal beds primarily produce net acidic waters and Lower Pennsylvanian coal beds primarily produce net alkaline waters. Multivariate statistical analysis of elemental data supports the conclusion that abandoned underground coal mine aquifers in the northern part of the State generally produce poor water quality and abandoned underground coal mine aquifers in southern West Virginia primarily produce good water quality. These results substantiate the potential benefits of leveraging abandoned underground coal mine aquifers as a multifaceted resource in West Virginia and can be used as a reconnaissance tool for water managers to characterize abandoned underground coal mine aquifers on a local scale.

West Virginia

Occurrence of per- and polyfluoroalkyl substances and inorganic analytes in groundwater and surface water used as sources for public water supply in West Virginia

Per- and polyfluoroalkyl substances (PFAS) are widely observed anthropogenic compounds found in water supplies worldwide and increasingly linked with adverse health effects in humans. In 2019, the West Virginia Legislature recognized the contamination risk to public source-water supplies posed by PFAS and passed a resolution that required a statewide PFAS study. The purpose of the resolution was to understand the occurrence and distribution of PFAS contamination throughout the State’s rivers, lakes, and groundwater aquifers. The U.S. Geological Survey has worked in cooperation with the West Virginia Department of Environmental Protection and West Virginia Department of Health and Human Resources to collect raw-water samples at 279 public-water systems across West Virginia. Public-water systems sampled for this study were identified by the West Virginia Department of Health and Human Resources and included all community water systems in the State and all daycares and schools that operate their own water systems. Raw source water was sampled for both groundwater and surface-water sites at the first available tap in the public-water system, prior to any treatment. One hundred and seventy-three samples were collected from groundwater sources and 106 samples were collected from surface-water sources. Parameters collected at the time of sampling included pH, specific conductance, water temperature, dissolved oxygen, turbidity, and alkalinity. PFAS was analyzed at all 279 sites, major ions and trace elements were analyzed at 272 sites, and nutrients were analyzed at 270 sites. The type of source water used for public supply in West Virginia is generally dependent on geology with more groundwater sites sampled in high-yield aquifers such as karst and alluvium. Surface-water sites were more evenly distributed throughout the State and are often the only source used in areas underlain by lower-yielding fractured-rock aquifers. Twenty-four percent of the sites sampled for this study had at least 1 PFAS detected, 47 of which were in groundwater sources and 20 in surface-water sources. Five sites exceeded the U.S. Environmental Protection Agency’s health advisory for combined perfluorooctanoate and perfluorooctanesulfonate concentrations of 70 nanograms per liter. These sites were located in highly susceptible karst and alluvial groundwater aquifers on the east and west sides of the State. Higher PFAS concentrations were more commonly found in groundwater than surface-water sources, and high concentrations and PFAS detections were generally concentrated in the Ohio River Valley and West Virginia’s eastern panhandle. PFAS was rarely detected in groundwater sites in fractured-rock aquifers and abandoned underground coal-mine aquifers in the Appalachian Plateaus Physiographic Province had very little PFAS detected. These data represent a baseline summary of source water in West Virginia. Additional studies may be needed to understand exposure to private homeowners with domestic-water sources, variability of PFAS concentrations over time, and PFAS in finished drinking water as evaluated by current and future drinking-water regulations.

West Virginia