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Geology topics

Gregory A. Wandless

Publications and source records attributed to Gregory A. Wandless.

4 recordsLinked to original sources

Shallow marine response to global climate change during the Paleocene-Eocene Thermal Maximum, Salisbury Embayment, USA

The Paleocene-Eocene Thermal Maximum (PETM) was an interval of extreme warmth that caused disruption of marine and terrestrial ecosystems on a global scale. Here we examine the sediments, flora, and fauna from an expanded section at Mattawoman Creek-Billingsley Road (MCBR) in Maryland and explore the impact of warming at a nearshore shallow marine (30–100 m water depth) site in the Salisbury Embayment. Observations indicate that at the onset of the PETM, the site abruptly shifted from an open marine to prodelta setting with increased terrestrial and fresh water input. Changes in microfossil biota suggest stratification of the water column and low-oxygen bottom water conditions in the earliest Eocene. Formation of authigenic carbonate through microbial diagenesis produced an unusually large bulk carbon isotope shift, while the magnitude of the corresponding signal from benthic foraminifera is similar to that at other marine sites. This proves that the landward increase in the magnitude of the carbon isotope excursion measured in bulk sediment is not due to a near instantaneous release of 12 C-enriched CO 2 . We conclude that the MCBR site records nearshore marine response to global climate change that can be used as an analog for modern coastal response to global warming.

Maryland, New Jersey, Pennsylvania, Virginia

The role of ridge subduction in determining the geochemistry and Nd–Sr–Pb isotopic evolution of the Kodiak batholith in southern Alaska

The Paleocene Kodiak batholith, part of the Sanak&ndash;Baranof belt of Tertiary near-trench intrusive rocks, forms an elongate body (~ 150 km long) that transects Kodiak Island from SW to NE. The batholith consists of three zones (Southern, Central, and Northern) of kyanite-, muscovite-, and garnet-bearing biotite tonalite and granodiorite and less abundant granite that intruded an accretionary prism (Kodiak Formation, and Ghost Rocks Formation). Small and likely coeval bodies (Northern, Western, and Eastern satellite groups) of quartz gabbro, diorite, tonalite, granodiorite, and leucogranite flank the batholith. The batholith is calc-alkalic, has an aluminum saturation index of > 1.1, FeO t /(FeO t + MgO) ~ 0.65 (at SiO 2 = 65 wt.%), and increases in SiO 2 (~ 61 wt.%&ndash;73 wt.%) and decreases in TiO 2 (~ 0.9 wt.%&ndash;0.3 wt.%) from SW to NE. As a group, the granitic rocks have light REE-enriched chondrite-normalized patterns with small or no negative Eu anomalies, primitive mantle-normalized negative anomalies for Nb and Ti, and positive anomalies for Pb. Small to large negative anomalies for Th are also distinctive. The quartz gabbros and diorites are generally characterized by generally flat to light REE chondrite-normalized patterns (no Eu anomalies), and mantle-normalized negative anomalies for Nb, Ti, and P. Pb isotopic compositions ( 206 Pb/ 204 Pb = 18.850&ndash;18.960; 207 Pb/ 204 Pb = 15.575&ndash;15.694; 208 Pb/ 204 Pb = 38.350&ndash;39.039) are intermediate between depleted mantle and average continental crust. The Southern zone and a portion of the Central zone are characterized by negative &epsilon; Nd values of &minus; 3.7 to &minus; 0.3 and T DM ages ranging from ~ 838 Ma to 1011 Ma. Other granitic rocks from the Central and Northern zones have higher &epsilon; Nd values of &minus; 0.4 to + 4.7 and younger T DM ages of ~ 450 to 797 Ma. Granitic and mafic plutons from the Eastern satellites show a wide range of &epsilon; Nd values of &minus; 2.7 to + 6.4, and T DM ages from 204 Ma to 2124 Ma. 87 Sr/ 86 Sr values of the Southern and Central zones overlap and tend to be slightly more radiogenic ( 87 Sr/ 86 Sr > 0.70426) than the Northern zone ( 87 Sr/ 86 Sr < 0.70472). 206 Pb/ 204 Pb values increase slightly from the Southern and Central zones toward the Northern zone. There is no clear correlation of the major or trace elements with &epsilon; Nd , Pb or Sr isotopic values. Kodiak Formation and the Ghost Rocks Formation overlap the isotopic compositions (e.g., 206 Pb/ 204 Pb = 18.978 to 19.165, 87 Sr/ 86 Sr of 0.705715 to 0.707118, and &epsilon; Nd of &minus; 6.7 to &minus; 1.5 at 59 Ma) and T DM values (959 to 1489 Ma) of the batholith. Production of large volumes of granitic rocks in the Sanak&ndash;Baranof belt, and particularly on Kodiak Island, reflects a sequence of processes that includes underplating of mantle-derived mafic (possibly from the mantle wedge) and intermediate rocks under the accretionary flysch, interlayering of mantle-derived and flyschoid rocks, and partial melting of the mixed lithologic assemblages. Limited degrees of fractional crystallization or assimilation and fractional crystallization influenced compositions of the granitic rocks. The contribution of mantle-derived rocks that resided in the accretionary prism for only a short period of time prior to partial melting likely exceeds 40% (up to 80%). The balance (60 to 20%) is from a recently recycled crustal component represented by the Kodiak Formation. This type of progressive intracrustal melting from mixed sources controlled the geochemical character of the batholith and is most consistent with the hypothesis that the granitic rocks are associated with a slab-window produced by collision of a spreading oceanic center and a subduction zone and migration beneath the accretionary prism.

Gulf of Alaska

delta 15N and non-carbonate delta 13C values for two petroleum source rock reference materials and a marine sediment reference material

Samples of United States Geological Survey (USGS) Certified Reference Materials USGS Devonian Ohio Shale (SDO-1), and USGS Eocene Green River Shale (SGR-1), and National Research Council Canada (NRCC) Certified Marine Sediment Reference Material (PACS-2), were sent for analysis to four separate analytical laboratories as blind controls for organic rich sedimentary rock samples being analyzed from the Red Dog mine area in Alaska. The samples were analyzed for stable isotopes of carbon (delta13Cncc) and nitrogen (delta15N), percent non-carbonate carbon (Wt % Cncc) and percent nitrogen (Wt % N). SDO-1, collected from the Huron Member of the Ohio Shale, near Morehead, Kentucky, and SGR-1, collected from the Mahogany zone of the Green River Formation are petroleum source rocks used as reference materials for chemical analyses of sedimentary rocks. PACS-2 is modern marine sediment collected from the Esquimalt, British Columbia harbor. The results presented in this study are, with the exceptions noted below, the first published for these reference materials. There are published information values for the elemental concentrations of 'organic' carbon (Wt % Corg measured range is 8.98 - 10.4) and nitrogen (Wt % Ntot 0.347 with SD 0.043) only for SDO-1. The suggested values presented here should be considered 'information values' as defined by the NRCC Institute for National Measurement Reference Materials and should be useful for the analysis of 13C, 15N, C and N in organic material in sedimentary rocks.

Open-File Report

Oceanic Pb-isotopic sources of Proterozoic and Paleozoic volcanogenic massive sulfide deposits on Prince of Wales Island and vicinity, southeastern Alaska

Volcanogenic massive sulfide (VMS) deposits on Prince of Wales Island and vicinity in southeastern Alaska are associated with Late Proterozoic through Cambrian volcanosedimentary rocks of the Wales Group and with Ordovician through Early Silurian felsic volcanic rocks of the Moira Sound unit (new informal name). The massive sulfide deposits in the Wales Group include the Big Harbor, Copper City, Corbin, Keete Inlet, Khayyam, Ruby Tuesday, and Stumble-On deposits, and those in the Moira Sound unit include the Barrier Islands, Moira Copper, Niblack, and Nichols Bay deposits. Pb-isotopic signatures were determined on sulfide minerals (galena, pyrite, chalcopyrite, pyrrhotite, and sphalerite) to constrain metal sources of the massive sulfides and for comparison with data for other deposits in the region. Except for the Ruby Tuesday deposit, galena is relatively rare in most of these deposits. Pb-isotopic signatures distinguish the mainly Cu+Zn&plusmn;Ag&plusmn;Au massive sulfide deposits in the Wales Group from the Zn+Cu&plusmn;Ag&plusmn;Au massive sulfide deposits in the Moira Sound unit. Among the older group of deposits, the Khayyam deposit has the widest variation in Pb-isotopic ratios ( 206 Pb/ 204 Pb=17.169&ndash;18.021, 207 Pb/ 204 Pb=15.341&ndash;15.499, 208 Pb/ 204 Pb=36.546&ndash;37.817); data for the other massive sulfide deposits in the Wales Group overlap the isotopic variations in the Khayyam deposit. Pb-isotopic ratios for both groups of deposits are lower than those on the average crustal Pbevolution curve (&micro;=9.74), attesting to a large mantle influence in the Pb source. All the deposits show no evidence for Pb evolution primarily in the upper or lower continental crust. Samples from the younger group of deposits have scattered Pb-isotopic compositions and plot as a broad band on uranogenic and thorogenic Pb diagrams. Data for these deposits overlap the trend for massive sulfide deposits in the Wales Group but extend to significantly more radiogenic Pb-isotopic values. Pb-isotopic ratios of samples from the massive sulfide deposits in the Moira Sound unit plot on a different trend ( 206 Pb/ 204 Pb=17.375&ndash;19.418, 207 Pb/ 204 Pb=15.361&ndash;15.519, 208 Pb/ 204 Pb=36.856&ndash;37.241) from the steep slope defined by the massive sulfide deposits in the Wales Group. In comparison, the Pb-isotopic ratios of Devonian polymetallic (Pb-Zn-Au-Ag) quartz-sulfide veins vary widely ( 206 Pb/ 204 Pb=18.339&ndash;18.946, 207 Pb/ 204 Pb=15.447&ndash;15.561, 208 Pb/ 204 Pb=37.358&ndash;38.354), straddling the slope defined by the massive sulfide deposits in the Moira Sound unit. The general decrease in 207 Pb/ 204 Pb ratio in these deposits, relative to the average crustal Pb-evolution curve, suggests that the most likely lead sources were those associated with oceanic volcanic rocks. The massive sulfide deposits in the Wales Group may have resided within an intraoceanic tectonic setting where the mantle was the predominant contributor of metals. Some contribution from reworked arc material or recycled older, hydrothermally altered oceanic crust (including pelagic sediment) is also possible. Lead sources of the massive sulfide deposits in the Moira Sound unit also included an older source region, possibly a Late Proterozoic or Cambrian volcanosedimentary sequence and the massive sulfide deposits in the Wales Group. Preliminary regional comparison of the Pb-isotopic data indicates that the Greens Creek (Admiralty Island, Alaska) and Windy Craggy (northern British Columbia) deposits probably did not share a common lead source with the VMS deposits on Prince of Wales Island. Other sulfide occurrences on Admiralty Island are also more radiogenic than those on Prince of Wales Island. Large differences in 207 Pb/ 204 Pb ratio suggest that the lead in the VMS deposits in different parts of the Alexander terrane evolved from sources with heterogeneous U/Pb ratios, resulting from mixing of mantle and crustal components.

Alaska