USGS ScienceSearch

Geology topics

Greg A. Ludvigson

Publications and source records attributed to Greg A. Ludvigson.

15 recordsLinked to original sources

Ibex Hollow Tuff from ca. 12 Ma supereruption, southern Idaho, identified across North America, eastern Pacific Ocean, and Gulf of Mexico

The Ibex Hollow Tuff, 12.08 ± 0.03 Ma ( 40 Ar/ 39 Ar), is a widespread tephra layer erupted from the Bruneau-Jarbidge volcanic field of southern Idaho. Tephra from this eruption was deposited across much of western and central North America and adjacent ocean areas. We identified the Ibex Hollow Tuff at Trapper Creek, Idaho, near its eruption site, and at 15 distal sites, from the Pacific Ocean to the Gulf of Mexico, by the chemical composition of its glass shards, using electron-microprobe analysis, instrumental neutron activation analysis, and laser-ablation–inductively coupled plasma–mass spectrometry. By these methods, we distinguished the Ibex Hollow Tuff from overlying and underlying tephra layers near its source and at distal sites. Fluvially reworked Ibex Hollow Tuff ash was transported by the ancestral Mississippi River drainage from the interior of the North American continent to the Gulf of Mexico, where it is present within an ~50-m-thick deposit in marine sediments in the subsurface. The minimum fallout area covered by the ash is ~2.7 million km 2 , with a minimum volume of ~800 km 3 , and potential dispersal farther to the north and northeast. The areal distribution for the Ibex Hollow Tuff is similar to that of the Lava Creek B (0.63 Ma) supereruption. The Ibex Hollow Tuff represents a unique chronostratigraphic marker allowing a synoptic view of paleoenvironments at a virtual moment in time across a large terrestrial and marine region. The Ibex Hollow Tuff is also an important marker bed for North American Land Mammal Ages, and it coincides with climatic cooling in the middle to late Miocene documented in marine cores.

Gulf of Mexico, Pacific Ocean

Quantification of a greenhouse hydrologic cycle from equatorial to polar latitudes: The mid-Cretaceous water bearer revisited

This study aims to investigate the global hydrologic cycle during the mid-Cretaceous greenhouse by utilizing the oxygen isotopic composition of pedogenic carbonates (calcite and siderite) as proxies for the oxygen isotopic composition of precipitation. The data set builds on the Aptian–Albian sphaerosiderite δ 18 O data set presented by Ufnar et al. (2002) by incorporating additional low latitude data including pedogenic and early meteoric diagenetic calcite δ 18 O. Ufnar et al. (2002) used the proxy data derived from the North American Cretaceous Western Interior Basin (KWIB) in a mass balance model to estimate precipitation–evaporation fluxes. We have revised this mass balance model to handle sphaerosiderite and calcite proxies, and to account for longitudinal travel by tropical air masses. We use empirical and general circulation model (GCM) temperature gradients for the mid-Cretaceous, and the empirically derived δ 18 O composition of groundwater as constraints in our mass balance model. Precipitation flux, evaporation flux, relative humidity, seawater composition, and continental feedback are adjusted to generate model calculated groundwater δ 18 O compositions (proxy for precipitation δ 18 O) that match the empirically-derived groundwater δ 18 O compositions to within ± 0.5‰. The model is calibrated against modern precipitation data sets. Four different Cretaceous temperature estimates were used: the leaf physiognomy estimates of Wolfe and Upchurch (1987) and Spicer and Corfield (1992), the coolest and warmest Cretaceous estimates compiled by Barron (1983) and model outputs from the GENESIS-MOM GCM by Zhou et al. (2008). Precipitation and evaporation fluxes for all the Cretaceous temperature gradients utilized in the model are greater than modern precipitation and evaporation fluxes. Balancing the model also requires relative humidity in the subtropical dry belt to be significantly reduced. As expected calculated precipitation rates are all greater than modern precipitation rates. Calculated global average precipitation rates range from 371 mm/year to 1196 mm/year greater than modern precipitation rates. Model results support the hypothesis that increased rainout produces δ 18 O-depleted precipitation. Sensitivity testing of the model indicates that the amount of water vapor in the air mass, and its origin and pathway, significantly affect the oxygen isotopic composition of precipitation. Precipitation δ 18 O is also sensitive to seawater δ 18 O and enriched tropical seawater was necessary to simulate proxy data (consistent with fossil and geologic evidence for a warmer and evaporatively enriched Tethys). Improved constraints in variables such as seawater δ 18 O can help improve boundary conditions for mid-Cretaceous climate simulations.

Palaeogeography, Palaeoclimatology, Palaeoecology

Ant-nest ichnofossils in honeycomb calcretes, Neogene Ogallala Formation, High Plains region of western Kansas, U.S.A.

Two new ant-nest trace fossils are described from calcic sandy paleosols of the Neogene Ogallala Formation in western Kansas. The ichnofossils are preserved within and below calcrete beds weathering in positive relief as carbonate-filled casts or as cavities in negative relief. Daimoniobarax ichnogenus nov. is established for burrow systems composed of vertically tiered, horizontally oriented pancake-shaped chambers connected by predominantly vertical and cylindrical shafts ~ 0.8 cm in diameter. Ichnospecies of Daimoniobarax are differentiated based on differences in the plan view outline of chambers, shaft orientation, and junctions between chambers and shafts. Daimoniobarax nephroides ichnospecies nov. is composed of an ~ 24–76 cm long vertical sequence of distinctly lobed chambers (~ 2–20 cm wide and ~ 1 cm high) arranged along sinuous to helical shafts. Chamber shape in plan view ranges from small teardrops to larger kidney- and U-shaped forms. Shafts intersect at chamber edges such that chambers appear to bud from the central shafts. Daimoniobarax nephroides is most similar to the nests of extant seed-harvester ants of the New World genus Pogonomyrmex . Such ants are specialized granivores and prefer sandy soils in arid to semi-arid grassland and desert regions. Daimoniobarax tschinkeli ichnospecies nov. is ~ 30–80 cm in vertical extent. Chambers (~ 2–30 cm wide and ~ 1 cm high) are circular to elongate or pseudopodial in plan view. Vertical shafts are straight to slightly sinuous and intersect most often toward the center of the chambers. The generalized architecture of D. tschinkeli is similar to that of the nests or nest portions of several extant ant genera, though it does not closely resemble any known modern nest. Ant ichnofossils provide valuable information on hidden biodiversity, paleohydrologic regimes, paleopedogenic processes, and paleoclimate during the time of nest occupation. Depth-related changes in chamber size and vertical spacing may also help interpret paleosurfaces and paleodepths, and serve as geopetal features.

Kansas

Correlation of aptian-albian carbon isotope excursions in continental strata of the cretaceous Foreland Basin, Eastern Utah, U.S.A.

Nodular carbonates ("calcretes") in continental foreland-basin strata of the Early Cretaceous Cedar Mountain Formation (CMF) in eastern Utah yield ??13C and ??O records of changes in the exogenic carbon cycle related to oceanic anoxic events (OAEs), and terrestrial paleoclimate. Chemostratigraphic profiles of both forebulge and foredeep sections show two prominent positive ??13C excursions, each with a peak value of -3% VPDB, and having background ??13C values of about -6% VPDB. These excursions correlate with the global early Aptian (Ap7) and late Aptian-early Albian (Apl2-All) carbon isotope excursions. Aptian-Albian positive ??13C excursions in the CMF also correspond to 3-4 per mil increases in carbonate ??18O. These phenomena record local aridification events. The chemostratigraphic profile on the thinner forebulge section of the CMF is calibrated, for the first time, by a radiogenic U-Pb date of 119.4 ?? 2.6 Ma on a carbonate bed, and by detrital zircon U-Pb dates on two bounding sandstone units (maximum depositional ages of 146 Ma and 112 Ma). P??trographie observations and diagenetic analyses of micritic to microsparitic carbonates from nodules indicate palustrine origins and demonstrate that they crystallized in shallow early meteoric phreatic environments. Meteoric calcite lines derived from CMF carbonates have ??18O values ranging between -8.1 to -7.5%o VPDB, supporting an estimate of zonal mean groundwater ??18O of -6% VSMOW for an Aptian-Albian paleolatitude of 34?? N. Furthermore, our two chemostratigraphic profiles exhibit a generally proportionate thinning of correlative strata from the foredeep on to the forebulge, suggesting that there were consistently lower rates of accumulation on the forebulge during the Aptian-Albian. Identification of the global Aptian-Albian ??13C excursions in purely continental strata, as demonstrated in this paper, opens a new avenue of research by identifying specific stratigraphie intervals that record the terrestrial paleoclimatic impacts of perturbations of the global carbon cycle. Copyright ?? 2010, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research

Micromorphology and stable-isotope geochemistry of historical pedogenic siderite formed in PAH-contaminated alluvial clay soils, Tennessee, U.S.A

Alluvial clay soil samples from six boreholes advanced to depths of 400-450 cm (top of limestone bedrock) from the Chattanooga Coke Plant (CCP) site were examined micromorphologically and geochemically in order to determine if pedogenic siderite (FeCO3) was present and whether siderite occurrence was related to organic contaminant distribution. Samples from shallow depths were generally more heavily contaminated with polycyclic aromatic hydrocarbons (PAHs) than those at greater depth. The upper 1 m in most boreholes consisted of mixtures of anthropogenically remolded clay soil fill containing coal clinker, cinder grains, and limestone gravel; most layers of coarse fill were impregnated with creosote and coal tar. Most undisturbed soil (below 1 m depth) consisted of highly structured clays exhibiting fine subangular blocky ped structures, as well as redox-related features. Pedogenic siderite was abundant in the upper 2 m of most cores and in demonstrably historical (< 100 years old) soil matrices. Two morphologies were identified: (1) sphaerosiderite crystal spherulites ranging from 10 to 200 um in diameter, and (2) coccoid siderite comprising grape-like "clusters" of crystals 5-20 ??n in diameter. The siderite, formed in both macropores and within fine-grained clay matrices, indicates development of localized anaerobic, low-Eh conditions, possibly due to microbial degradation of organic contaminants. Stable-isotope compositions of the siderite have ??13C values spanning over 25%o (+7 to - 18%o VPDB) indicating fractionation of DIC by multiple microbial metabolic pathways, but with relatively constant ??18O values from (-4.8 ?? 0.66%o VPDB) defining a meteoric sphaerosiderite line (MSL). Calculated isotope equilibrium water ??18O values from pedogenic siderites at the CCP site are from 1 to 5 per mil lighter than the groundwater ??18O values that we estimate for the site. If confirmed by field studies in progress, this observation might call for a reevaluation of low-temperature siderite-water 18O fractionations. Investigations at the CCP site thus provide valuable information on the geochemical conditions under which siderite can form in modern soils, and thus insight on controls on siderite formation in ancient soils. Copyright ?? 2010, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research

Isotopic composition of low-latitude paleoprecipitation during the Early Cretaceous

The response of the hydrologic cycle in global greenhouse conditions is important to our understanding of future climate change and to the calibration of global climate models. Past greenhouse conditions, such as those of the Cretaceous, can be used to provide empirical data with which to evaluate climate models. Recent empirical studies have utilized pedogenic carbonates to estimate the isotopic composition of meteoric waters and calculate precipitation rates for the AptianAlbian. These studies were limited to data from mid(35??N) to high (75??N) paleolatitudes, and thus future improvements in accuracy will require more estimates of meteoric water compositions from numerous localities around the globe. This study provides data for tropical latitudes (18.5??N paleolatitude) from the Tlayua Formation, Puebla, Mexico. In addition, the study confirms a shallow nearshore depositional environment for the Tlayua Formation. Petrographic observations of fenestral fabrics, gypsum crystal molds, stromatolitic structures, and pedogenic matrix birefringence fabric support the interpretation that the strata represent deposition in a tidal flat environment. Carbonate isotopic data from limestones of the Tlayua Formation provide evidence of early meteoric diagenesis in the form of meteoric calcite lines. These trends in ?? 18 O versus ?? 13 C were used to calculate the mean ?? 18 O value of meteoric water, which is estimated at -5.46 ?? 0.56??? (Vienna Standard Mean Ocean Water [VSMOW]). Positive linear covariant trends in oxygen and carbon isotopic values from some horizons were used to estimate evaporative losses of vadose groundwater from tropical exposure surfaces during the Albian, and the resulting values range from 8% to 12%. However, the presence of evaporative mineral molds indicates more extensive evaporation. The added tropical data improve latitudinal coverage of paleoprecipitation ??18O estimates. The data presented here imply that earlier isotope mass balance models most likely underestimated tropical to subtropical precipitation and evaporation fluxes. The limited latitudinal constraints for earlier isotope mass balance modeling of the Albian hydrologic cycle of the Northern Hemisphere Americas resulted in extrapolated low-latitude precipitation ?? 18 O values that were much heavier (up to 3???) than the values observed in this study. The lighter values identified in this study indicate a more pronounced rainout effect for tropical regions and quite possibly a more vigorous evaporation effect. These and additional low-latitude data are required to better constrain changes in the hydrologic cycle during the Cretaceous greenhouse period, and to reduce the uncertainties resulting from limited geographic coverage of proxy data. ?? 2009 Geological Society of America.

Geological Society of America Bulletin

Precipitation rates and atmospheric heat transport during the Cenomanian greenhouse warming in North America: Estimates from a stable isotope mass-balance model

Stable isotope mass-balance modeling results of meteoric ??18O values from the Cenomanian Stage of the Cretaceous Western Interior Basin (KWIB) suggest that precipitation and evaporation fluxes were greater than that of the present and significantly different from simulations of Albian KWIB paleohydrology. Sphaerosiderite meteoric ??18O values have been compiled from the Lower Tuscaloosa Formation of southwestern Mississippi (25??N paleolatitude), The Dakota Formation Rose Creek Pit, Fairbury Nebraska (35??N) and the Dunvegan Formation of eastern British Columbia (55??N paleolatitude). These paleosol siderite ??18O values define a paleolatitudinal gradient ranging from - 4.2??? VPDB at 25??N to - 12.5??? VPDB at 55??N. This trend is significantly steeper and more depleted than a modern theoretical siderite gradient (25??N: - 1.7???; 65??N: - 5.6??? VPDB ), and a Holocene meteoric calcite trend (27??N: - 3.6???; 67??N: - 7.4??? VPDB). The Cenomanian gradient is also comparatively steeper than the Albian trend determined for the KWIB in the mid- to high latitudes. The steep latitudinal trend in meteoric ??18O values may be the result of increased precipitation and evaporation fluxes (amount effects) under a more vigorous greenhouse-world hydrologic cycle. A stable-isotope mass-balance model has been used to generate estimates of precipitation and evaporation fluxes and precipitation rates. Estimates of Cenomanian precipitation rates based upon the mass-balance modeling of the KWIB range from 1400??mm/yr at 25??N paleolatitude to 3600??mm/yr at 45??N paleolatitude. The precipitation-evaporation (P-E) flux values were used to delineate zones of moisture surplus and moisture deficit. Comparisons between Cenomanian P-E and modern theoretical siderite, and Holocene calcite latitudinal trends shows an amplification of low-latitude moisture deficits between 5-25??N paleolatitude and moisture surpluses between 40-60??N paleolatitude. The low-latitude moisture deficits correlate with a mean annual average heat loss of 48??W/m2 at 10??N paleolatitude (present, 8??W/m2 at 15??N). The increased precipitation flux and moisture surplus in the mid-latitudes corresponds to a mean average annual heat gain of 180??W/m2 at 50??N paleolatitude (present, 17??W/m2 at 50??N). The Cenomanian low-latitude moisture deficit is similar to that of the Albian, however the mid-latitude (40-60??N) precipitation flux values and precipitation rates are significantly higher (Albian: 2200??mm/yr at 45??N; Cenomanian: 3600??mm/yr at 45??N). Furthermore, the heat transferred to the atmosphere via latent heat of condensation was approximately 10.6?? that of the present at 50??N. The intensified hydrologic cycle of the mid-Cretaceous greenhouse warming may have played a significant role in the poleward transfer of heat and more equable global conditions. Paleoclimatological reconstructions from multiple time periods during the mid-Cretaceous will aid in a better understanding of the dynamics of the hydrologic cycle and latent heat flux during greenhouse world conditions.

Palaeogeography, Palaeoclimatology, Palaeoecology

Clarification and changes in Permian stratigraphic nomenclature in Kansas

This paper outlines Permian nomenclature changes to Zeller (1968) that have been adopted by the Kansas Geological Survey. The Permian System/ Period, Cisuralian Series/Epoch, and Asselian Stage/Age are established at the base of the Bennett Shale Member of the Red Eagle Limestone. Series/epoch names Wolfcampian, Leonardian, and Guadalupian are retained and usage of Gearyan, Cimarronian, and Custerian is abandoned. The repositioned Carboniferous-Permian boundary divides the Council Grove Group into Carboniferous (Upper Pennsylvanian Series/Epoch; Virgilian Stage/Age) and Permian (Wolfcampian Series Epoch) segments.

Current Research in Earth Sciences

Recognizing the Albian-Cenomanian (OAE1d) sequence boundary using plant carbon isotopes: Dakota Formation, Western Interior Basin, USA

Analysis of bulk sedimentary organic matter and charcoal from an Albian-Cenomanian fluvial-estuarine succession (Dakota Formation) at Rose Creek Pit (RCP), Nebraska, reveals a negative excursion of ???3???, in late Albian strata. Overlying Cenomanian strata have ??13C values of -24???, to -23???, that are similar to pre-excursion values. The absence of an intervening positive excursion (as exists in marine records of the Albian-Cenomanian boundary) likely results from a depositional hiatus. The corresponding positive ??13C event and proposed depositional hiatus are concordant with a regionally identified sequence boundary in the Dakota Formation (D2), as well as a major regressive phase throughout the globe at the Albian-Cenomanian boundary. Data from RCP confirm suggestions that some positive carbon-isotope excursions in the geologic record are coincident with regressive sea-level phases. We estimate using isotopic correlation that the D2 sequence boundary at RCP was on the order of 0.5 m.y. in duration. Therefore, interpretations of isotopic events and associated environmental phenomena, such as oceanic anoxic events, in the shallow-marine and terrestrial record may be influenced by stratigraphic incompleteness. Further investigation of terrestrial ??13C records may be useful in recognizing and constraining sea-level changes in the geologic record. ?? 2006 Geological Society of America.

Geology

Late Ordovician (Turinian-Chatfieldian) carbon isotope excursions and their stratigraphic and paleoceanographic significance

Five positive carbon isotope excursions are reported from Platteville-Decorah strata in the Upper Mississippi Valley. All occur in subtidal carbonate strata, and are recognized in the Mifflin, Grand Detour, Quimbys Mill, Spechts Ferry, and Guttenberg intervals. The positive carbon isotope excursions are developed in a Platteville-Decorah succession in which background ??13C values increase upward from about -2??? at the base to about 0??? Vienna Pee Dee belemnite (VPDB) at the top. A regional north-south ??13C gradient, with lighter values to the north and heavier values to the south is also noted. Peak excursion ??13C values of up to +2.75 are reported from the Quimbys Mill excursion, and up to +2.6 from the Guttenberg excursion, although there are considerable local changes in the magnitudes of these events. The Quimbys Mill, Spechts Ferry, and Guttenberg carbon isotope excursions occur in units that are bounded by submarine disconformities, and completely starve out in deeper, more offshore areas. Closely spaced chemostratigraphic profiles of these sculpted, pyrite-impregnated hardground surfaces show that they are associated with very abrupt centimeter-scale negative ??13C shifts of up to several per mil, possibly resulting from the local diagenetic effects of incursions of euxinic bottom waters during marine flooding events. ?? 2004 Elsevier B.V. All rights reserved.

Conference Paper

Aggradation of gravels in tidally influenced fluvial systems: Upper Albian (Lower Cretaceous) on the cratonic margin of the North American Western Interior foreland basin

Alluvial conglomerates were widely distributed around the margin of the Early Cretaceous North American Cretaceous Western Interior Seaway (KWIS). Conglomerates, sandstones, and lesser amounts of mudstones of the upper Albian Nishnabotna Member of the Dakota Formation were deposited as fill-in valleys that were incised up to 80 m into upper Paleozoic strata. These paleovalleys extended southwestward across present-day northwestern Iowa into eastern Nebraska. Conglomerate samples from four localities in western Iowa and eastern Nebraska consist mostly of polycrystalline quartz with lesser amounts of microcrystalline (mostly chert), and monocrystalline quartz. Previous studies discovered that some chert pebbles contain Ordovician-Pennsylvanian invertebrate fossils. The chert clasts analyzed in this study were consistent with these findings. In addition, we found that non-chert clasts consist of metaquartzite, strained monocrystalline quartz and 'vein' quartz from probable Proterozic sources, indicating that parts of the fluvial system's sediment load must have travelled distances of 400-1200 km. The relative tectonic stability of this subcontinent dictated that stream gradients were relatively low with estimates ranging from 0.3 to 0.6 m/km. Considering the complex sedimentologic relationships that must have been involved, the ability of low-gradient easterly-sourced rivers to entrain gravel clasts was primarily a function of paleodischarge rather than a function of steep gradients. Oxygen isotopic evidence from Albian sphaerosiderite-bearing paleosols in the Dakota Formation and correlative units from Kansas to Alaska suggest that mid-latitude continental rainfall in the Albian was perhaps twice that of the modern climate system. Hydrologic fluxes may have been related to wet-dry climatic cycles on decade or longer scales that could account for the required water supply flux. Regardless of temporal scale, gravels were transported during 'high-energy' pulses, under humid climatic conditions in large catchment areas. An overall rising sea level during the late Albian created accommodation space for the gravelly lithofacies equivalent to the Kiowa-Skull Creek rocks. As Western Interior sea level rose, regional stream gradients were reduced, resulting in regional fluvial aggradation. The conglomeratic lower parts of the Nishnabotna Member of the Dakota Formation formed the transgressive systems tract within an upper Albian sequence that is defined by two unconformities that can be traced from marine Kiowa strata in western Kansas northeastward into western Iowa (Brenner et al., 2000). Mud-draped cross-bedded sandstone bodies, laminated mudstone intervals, and vertical burrows in the lower strata of the Nishnabotna Member indicate that estuarine conditions existed at the mouths of the river system, and tidal effects were transmitted at least 200 km inland from the interpreted late Albian coast. These observations suggest that estuarine conditions stepped up the incised valleys as fluvial sediments aggraded in response to regional transgression that continued through the Late Albian. ?? 2003 Elsevier Ltd. All rights reserved.

Cretaceous Research

The mid-cretaceous water bearer: Isotope mass balance quantification of the Albian hydrologic cycle

A latitudinal gradient in meteoric ??18O compositions compiled from paleosol sphaerosiderites throughout the Cretaceous Western Interior Basin (KWIB) (34-75??N paleolatitude) exhibits a steeper, more depleted trend than modern (predicted) values (3.0??? [34??N latitude] to 9.7??? [75??N] lighter). Furthermore, the sphaerosiderite meteoric ??18O latitudinal gradient is significantly steeper and more depleted (5.8??? [34??N] to 13.8??? [75??N] lighter) than a predicted gradient for the warm mid-Cretaceous using modern empirical temperature-??18O precipitation relationships. We have suggested that the steeper and more depleted (relative to the modern theoretical gradient) meteoric sphaerosiderite ??18O latitudinal gradient resulted from increased air mass rainout effects in coastal areas of the KWIB during the mid-Cretaceous. The sphaerosiderite isotopic data have been used to constrain a mass balance model of the hydrologic cycle in the northern hemisphere and to quantify precipitation rates of the equable 'greenhouse' Albian Stage in the KWIB. The mass balance model tracks the evolving isotopic composition of an air mass and its precipitation, and is driven by latitudinal temperature gradients. Our simulations indicate that significant increases in Albian precipitation (34-52%) and evaporation fluxes (76-96%) are required to reproduce the difference between modern and Albian meteoric siderite ??18O latitudinal gradients. Calculations of precipitation rates from model outputs suggest mid-high latitude precipitation rates greatly exceeded modern rates (156-220% greater in mid latitudes [2600-3300 mm/yr], 99% greater at high latitudes [550 mm/yr]). The calculated precipitation rates are significantly different from the precipitation rates predicted by some recent general circulation models (GCMs) for the warm Cretaceous, particularly in the mid to high latitudes. Our mass balance model by no means replaces GCMs. However, it is a simple and effective means of obtaining quantitative data regarding the mid-Cretaceous hydrologic cycle in the KWIB. Our goal is to encourage the incorporation of isotopic tracers into GCM simulations of the mid-Cretaceous, and to show how our empirical data and mass balance model estimates help constrain the boundary conditions. ?? 2002 Elsevier Science B.V. All rights reserved.

Palaeogeography, Palaeoclimatology, Palaeoecology

Meteoric sphaerosiderite lines and their use for paleohydrology and paleoclimatology

Sphaerosiderite, a morphologically distinct millimeter-scale spherulitic siderite (FeCO 3 ), forms predominantly in wetland soils and sediments, and is common in the geologic record. Ancient sphaerosiderites are found in paleosol horizons within coal-bearing stratigraphic intervals and, like their modern counterparts, are interpreted as having formed in water-saturated environments. Here we report on sphaerosiderites from four different stratigraphic units, each of which has highly variable 13 C and relatively stable 18 C compositions. The unique isotopic trends are analogous to well-documented meteoric calcite lines, which we define here as meteoric sphaerosiderite lines. Meteoric sphaerosiderite lines provide a new means of constraining ground-water δ 18 O and thus allow evaluation of paleohydrology and paleoclimate in humid continental settings.

Geology

Introduction: Paleozoic applications of sequence stratigraphy

Despite conceptual origins from studies of the Paleozoic strata of cratonic basins, sequence stratigraphy has largely been developed and applied to post-Paleozoic successions in extracratonic settings. The application of continental-margin sequence stratigraphic concepts to cratonic basinal successions is fraught with problems owing to slower rates of sediment accumulation, and consequently, a more coarsely defined temporal resolution. In addition, some important sequence stratigraphic components are rare or completely missing from cratonic areas. Common usage of genetic sequence stratigraphic terminology can coopt critical evaluation of depositional characters, and must be practiced with extreme caution in order to avoid 'model-driven' approaches to stratigraphic synthesis. The best available tests for evaluating current questions regarding the central role of eustasy in sequence stratigraphy may be through interregional and intercontinental comparisons of cratonic stratigraphic sequences.

Paleozoic sequence stratigraphy: views from the No

Epigenetic sulfide mineralization associated with Pennsylvanian paleokarst in eastern Iowa, U.S.A.

Paleokarst-associated, sulfide-bearing mineral deposits are wide-spread in the Paleozoic carbonate rocks of eastern Iowa. Minerals occur in nodules enclosed in karst-filling mudstones, as sandstone cements, and as surface coatings on, and fracture fillings in, foundered carbonate rock clasts. Mineralogy and paragenetic sequence vary among the occurrences. Sulfur isotopic compositions exhibit wide variations within and among deposits (??34S = -33.8 to + 35.1???). Oxygen isotopic compositions of fracture-filling calcite spars (??18O = -8.41 to + 3.60???) are similar to the isotopic compositions of their carbonate rock hosts. Calcite spars are somewhat depleted in ??13C relative to host rock [??13C (spars) = - 5.66 to + 0.24??? vs. -1.54 to + 1.21??? (host rock)]. Results of mineralogic, paragenetic and isotopic investigations suggest that: (1) minerals are products of multiple events operating on a local, rather than a regional scale; (2) spatially-disjunct fracture-filling mineral deposits exposed in the same quarries are probably not cogenetic with paleokarst-associated deposits; (3) paleokarst-filling calcite spars formed at near-surface temperatures; and (4) paleokarst-associated deposits are probably not cogenetic with Upper Mississippi Valley ZnPb pitch-flat deposits. ?? 1993.

Chemical Geology