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G.E. Michael

Publications and source records attributed to G.E. Michael.

4 recordsLinked to original sources
USGS2002

Controls on porphyrin concentrations of Pennsylvanian organic-rich shales, Western U.S.A.

Organic-rich black shales of Middle Pennsylvanian (Desmoinesian) age occur over much of the central U.S. and as far west as the northern Denver and southeastern Powder River basins. Total organic carbon contents (Corg) are commonly greater than 10 wt %. Porphyrin concentrations (vanadyl + nickel) are as high as 40000 ppm relative to extractable bitumen. In bulk, the organic matter contained in the shales is mostly type II and III (Rock-Eval hydrogen indexes 200-400 mg of hydrocarbons/g of Corg). The finding of high porphyrin concentrations in type III organic matter is unusual but can be explained by a depositional model wherein high preservation of primary organic production (water column photosynthesis) is combined with substantial input of allochthonous organic matter. The allochthonous organic matter (low porphyrin concentration) may come from erosion during advance of the sea across the area or from fluvial transport from shore.

Energy & Fuels↗
USGS1993

Geochemical evaluation of upper cretaceous fruitland formation coals, San Juan Basin, New Mexico and Colorado

Geochemical analyses of coal samples from the Upper Cretaceous Fruitland Formation in the San Juan Basin of New Mexico and Colorado were used to determine thermal maturity, type of kerogen, and hydrocarbon generation potential. Mean random vitrinite reflectance (% R m ) of the Fruitland coal ranges from 0.42 to 1.54%. Rock-Eval pyrolysis data and saturated to aromatic hydrocarbon ratio indicate that the onset of thermal hydrocarbon generation begins at about 0.60% R m and peak generation occurs at about 0.85% R m . Several samples have hydrogen index values between 200 and 400, indicating some potential for liquid hydrocarbon generation and a mixed Type III and II kerogen. Pentacyclic and tricyclic terpanes, steranes, aromatic steroids and methylphenanthrene maturity parameters were observed through the complete range of thermal maturity in the Fruitland coals. Aromatic pentacyclic terpanes, similar to those found in brown coals of Australia, were observed in low maturity samples, but not found above 0.80% R m . N -alkane depleted coal samples, which occur at a thermal maturity of approx. 0.90% R m , paralleling peak hydrocarbon generation, are fairly widespread throughout the basin. Depletion of n -alkanes in these samples may be due to gas solution stripping and migration fromthe coal seams coincident with the development of pressure induced fracturing due to hydrocarbon generation; however, biodegradation may also effect these samples.

Colorado, New Mexico↗
USGS1991

Oil-generating coals of the San Juan Basin, New Mexico and Colorado, U.S.A.

Coal beds of the Upper Cretaceous Fruitland Formation in the San Juan Basin of northwestern New Mexico and southwestern Colorado have significant liquid hydrocarbon generation potential as indicated by typical Rock-Eval Hydrogen Indexes in the range of 200–400 mg hydrocarbon/g organic carbon (type II and III organic matter). Small, non-commercial quantities of oil have been produced from the coal beds at several locations. The oils are characterized by high pristane/phytane ( ca 4) and pristane/ n -C 17 ratios ( ca 1.2), abundant C 21+ alkanes in the C 10+ fraction with a slight predominance of odd carbon-numbered n -alkanes, abundant branched-chain alkanes in the C 15+ region, and a predominance of methylcyclohexane in the C 4 -C 10 fraction. The oils are indigenous to the Fruitland Formation coals and probably migrated at thermal maturities corresponding to vitrinite reflectance values in the range 0.7–0.8%. Although the oils found to date are not present in commercial amounts, these findings illustrate the potential of some coals to generate and expel oil under conditions of moderate thermal heating.

Colorado, New Mexico↗