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Frances D. Hostettler

Publications and source records attributed to Frances D. Hostettler.

28 records · Page 2Linked to original sources
USGS1997

Reclamation of Bay wetlands and disposal of dredge spoils: meeting two goals simultaneously

San Francisco Bay is one of the world's largest urbanized estuarine systems with a watershed that drains about 40 percent of the State of California. Its freshwater and saltwater marshes comprise approximately 125 square kilometers (48 square miles), compared to 2,200 square kilometers (850 square miles) before California began rapid development in 1850. This staggering reduction in tidal wetlands of approximately 95 percent has resulted in significant loss . of habitat for many species of fish and wildlife. The need for wetlands is well documented- healthy and adequate wetlands are critical to the proper functioning of an estuarine ecosystem like San Francisco Bay.

California↗
USGS1994

Laboratory simulation of hydrothermal petroleum formation from sediment in Escanaba Trough, offshore from northern California

Petroleum associated with sulfide-rich sediment is present in Escanaba Trough at the southern end of the Gorda Ridge spreading axis offshore from northern California within the Exclusive Economic Zone (EEZ) of the U.S. This location and occurrence are important for evaluation of the mineral and energy resource potential of the seafloor under U.S. jurisdiction. In Escanaba Trough, petroleum is believed to be formed by hydrothermal processes acting on mainly terrigenous organic material in Quaternary, river-derived sediment. To attempt to simulate these processes in the laboratory, portions of a Pleistocene gray-green mud, obtained from ∼ 1.5 m below the seafloor at a water depth of ∼ 3250 m in Escanaba Trough, were heated in the presence of water in four hydrous-pyrolysis experiments conducted at temperatures ranging from 250 to 350°C and at a pressure of 350 bar for 1.0–4.5 days. Distributions of n -alkanes, isoprenoid hydrocarbons, triterpanes, and steranes in the heated samples were compared with those in a sample of hydrothermal petroleum from the same area. Mud samples heated for less than 4.5 days at less than 350°C show changes in some, but not all, molecular marker ratios of organic compounds that are consistent with those expected during hydrothermal petroleum formation. Our results suggest that the organic matter in this type of sediment serves as one possible source for some of the compounds found in the hydrothermal petroleum.

California↗
USGS1994

Geochemical changes in crude oil spilled from the Exxon Valdez supertanker into Prince William Sound, Alaska

North Slope crude oil spilled from the T/V Exxon Valdez in March 1989 and contaminated about 500 km of Prince William Sound shoreline. Aliphatic and aromatic hydrocarbons in oil samples collected in August 1990 and June 1992 from beaches on six islands impacted by the spill have been compared with the hydrocarbons from North Slope crude oil taken from the stricken tanker. Degradation processes have changed the physical appearance of this residual spilled oil; the beached oil as collected ranged from a light brown color, to a heavy black viscous oil, to a black, powder-like residue. In these physically different samples, terpane, sterane, and aromatic sterane distributions, as well as carbon isotope values, are similar and correlate with the original Exxon Valdez oil. On the other hand, n -alkanes, isoprenoids, and many of the polycyclic aromatic hydrocarbons which are present in the original crude oil are dramatically altered in the oil samples collected from the beaches.

Alaska↗
USGS1994

A survey of molecular marker compounds in sediments of San Francisco Bay, California

An areal survey of surficial sediments in San Francisco Bay has been conducted to evaluate the presence of extractable organic compounds. Molecular marker compounds studied include hydrocarbons (PAH's), chlorinated pesticides, and other organic compounds that provide information on sources of organic input into the Bay. Fairly uniform source profiles are seen throughout the Bay. Biomarker profiles contain mature constituents indicating anthropogenic influences and extensive sediment reworking. The dominant input signatures in San Francisco Bay sediment are those of anthropogenic PAH's from combustion and other sources, and long chain n-alkanes and n-aldehydes from terrigenous vascular plants. A comparison of the sums of the combustion PAH's and the terrigenous n-alkanes shows that an anthropogenic influence is dominant in the most urban parts of the Bay close to shore, and in mid-Bay channel areas, and a terrigenous signature is dominant nearshore in San Pablo Bay and at the southernmost station in South Bay.

California↗
USGS1992

Bioaccumulation of hydrocarbons derived from terrestrial and anthropogenic sources in the Asian clam, Potamocorbula amurensis , in San Francisco Bay estuary

An assessment was made in Suisun Bay, California, of the distributions of hydrocarbons in estuarine bed and suspended sediments and in the recently introduced asian clam, Potamocorbula amurensis . Sediments and clams were contaminated with hydrocarbons derived from petrogenic and pyrogenic sources. Distributions of alkanes and of hopane and sterane biomarkers in sediments and clams were similar, indicating that petroleum hydrocarbons associated with sediments are bioavailable to Potamocorbula amurensis . Polycyclic aromatic hydrocarbons in the sediments and clams were derived mainly from combustion sources. Potamocorbula amurensis is therefore a useful bioindicator of hydrocarbon contamination, and may be used as a biomonitor of hydrocarbon pollution in San Francisco Bay.

California↗
USGS1990

Hydrocarbons in sediment of the Weddell Sea, Antarctica

Heavy hydrocarbons (about C15+) are ubiquitous but minor components in sediment from three sites (692, 693, and 694) drilled during Ocean Drilling Program (ODP) Leg 113. This preliminary report is the first to describe the distribution of some of these hydrocarbons in sediment of the Weddell Sea. Samples from Sites 692 and 693, located on a mid-slope bench along the margin of Queen Maud Land, span a time interval from Early Cretaceous to Pleistocene. In samples from the Tertiary portion of the record, having an average organic-carbon content of about 0.2%, n-alkanes are common and are characterized by populations that indicate both marine and terrigenous sources. In contrast, samples from the Cretaceous portion of the record, having an average organic carbon content of about 4%, contain mixtures of hydrocarbons in which n-alkanes are secondary in abundance to the isoprenoid hydrocarbons, pristane and phytane. Diasterenes, sterenes, and hopenes are present in anomalously high concentrations and indicate immaturity. The Cretaceous hydrocarbons appear to be mainly primary, whereas the Tertiary hydrocarbons contain compounds which indicate that the sediment, along with its organic content, has been recycled. Samples from Site 694, located in the Weddell Sea on the abyssal plain, range in age from late Miocene to early Pliocene.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1988

Organic geothermometry of petroleum from Escanaba Trough, offshore northern California

We have measured the extent of hopane and sterane isomerization and of monoaromatic-steroid-hydrocarbon aromatization in a sample of hydrothermally derived petroleum from the Escanaba Trough, a sediment-covered, volcanically active ridge axis. The results, along with kinetic parameters, predict the possible time-temperature history of the petrolum-forming process for this sample. The extent of these reactions is consistent with petroleum formation by intense heating (about 300–350°C) if the time period of this heating was as short as about 100 yr. Such a time scale is reasonable for hydrothermal-discharge events associated with ridge-crest volcanism.

California↗
USGS1988

Aliphatic hydrocarbons in sediments from Prydz Bay, Antarctica

High molecular weight aliphatic hydrocarbons were extracted from sediments at two sites (741 and 742) drilled during ODP Leg 119 in Prydz Bay. The distributions of n-alkanes and triterpenoid and steroid hydrocarbons suggest that the n- alkanes and steranes are mainly of terrestrial origin and that the hydrocarbons are immature to slightly mature in the Lower Cretaceous sediments and immature to mature in the Tertiary sediments. At Site 741, the Lower Cretaceous depositional sequence, which is generally characterized by immature hydrocarbons, is interrupted by sediment having more mature components, suggesting a change of source during part of Early Cretaceous time. At Site 742, the mature geochemical parameters of a Pliocene sample correlate with results reported elsewhere for Site 739. In all but one of the other Tertiary samples, the geochemical parameters indicate intermediate maturity. The Lower Cretaceous and Pliocene sediments average about 1.9% organic carbon, a value of interest from the point of view of potential sources of petroleum offshore of Antarctica.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1987

Multiple sources of alkanes in Quaternary oceanic sediment of Antarctica

Normal alkanes ( n -C 13 n -C 36 ), isoprenoid hydrocarbons ( i -C 15 , i -C 16 , i -C 18 , i -C 19 , and i -C 20 ) triterpanes (C 27 C 32 ), and (C 27 C 29 ) are present in low concentrations offshore Antarctica in near-surface, Quaternary sediment of the Wilkes Land continental margin and of the western Ross Sea. The distributions of these hydrocarbons are interpreted relative to possible sources and processes. The hydrocarbons appear to be mixtures of primary and recycled material from marine and terrigenous sources. The n -alkanes are most abundant and are characterized by two distinct populations, one of probable marine origin and the other likely from terrigenous, vascular plant sources. Because the continent of Antarctica today is devoid of higher plants, the plant-derived hydrocarbons in these offshore sediments probably came from wind-blown material and recycled Antarctic sediment that contains land-plant remains from an earlier period of time. Isoprenoid hydrocarbons are partially recycled and mainly of marine origin; the dominance of pristane over phytane suggests oxic paleoenvironmental conditions. Both modern and ancient triterpanes and steranes are present, and the distribution of these indicates a mixture of primary and recycled bacterial, algal, and possible higher-plant materials. Although the sampled sediments were deposited during the Quaternary, they apparently contain a significant component of hydrocarbons of pre-Quaternary age.

Organic Geochemistry↗