Geology topics

F. Von Blanckenburg

Publications and source records attributed to F. Von Blanckenburg.

3 recordsLinked to original sources

USGS1997

Evolution of Nd and Pb isotopes in Central Pacific seawater from ferromanganese crusts

Hydrogenetic ferromanganese crusts incorporate elements from ambient seawater during their growth on seamounts. By analysing Nd, Pb and Be isotope profiles within crusts it is possible to reconstruct seawater tracer histories. Depth profiles of 10 Be/ 9 Be ratios in three Pacific ferromanganese crusts have been used to obtain growth rates which are between 1.4 and 3.8 mm/Ma. Nd and Pb isotopes provide intact records of isotopic variations in Pacific seawater over the last 20 Ma or more. There were only small changes in Pb isotope composition in the last 20 Ma. This indicates a constant Pb composition for the erosional sources and suggests further that erosional Nd inputs may have been uniform too. ε Nd values vary considerably with time and most probably reflect changes in ocean circulation. The ε Nd values of the crusts not only vary as a function of age but also as a function of water depth. From 25 to 0 Ma, crust VA13/2 from 4.8 km water depth has a similar pattern of ε Nd variation to the two shallower crusts from 1.8 and 2.3 km, but about 1.0 to 1.5 units more negative. This suggests that ε Nd stratification in Pacific seawater, as demonstrated for the present day, has been maintained for at least 20 Ma. Each crust shows a decrease in ε Nd from 3–5 Ma to the present, which is interpreted in terms of an increase in the NADW component present in the Pacific. From 10 to 3–5 Ma ago the crusts show an increase in ε Nd . This suggests a decreasing role for a deep water source with ε Nd less than circum-Pacific sources. In this regard the Panamanian gateway restriction from ∼ 10 Ma with final closure at 3–5 Ma may have played an important role in reducing access of Atlantic-derived Nd to the Pacific.

Earth and Planetary Science Letters↗

USGS1996

Global distribution of beryllium isotopes in deep ocean water as derived from Fe-Mn crusts

The direct measurement of the ratio of cosmogenic 10 Be ( T 1 2 = 1.5 Ma "> T12= 1.5 Ma ) to stable terrigenously sourced 9 Be in deep seawater or marine deposits can be used to trace water mass movements and to quantify the incorporation of trace metals into the deep sea. In this study a SIMS-based technique has been used to determine the 10 Be 9 Be "> 10Be9Be ratios of the outermost millimetre of hydrogenetic ferromanganese crusts from the worlds oceans. 10 Be 9 Be "> 10Be9Be ratios, time-corrected for radioactive decay of cosmogenic 10 Be using 234 U 238 U "> 234U238U , are in good agreement with AMS measurements of modern deep seawater. Ratios are relatively low in the North and equatorial Atlantic samples (0.4–0.5 × 10 −7 ). In the Southwest Atlantic ratios increase up to 1 × 10 −7 , they vary between 0.7 and 1.0 × 10 −7 in Indian Ocean samples, and have a near constant value of 1.1 ± 0.2 × 10 −7 for all Pacific samples. If the residence time of 10 Be ( τ 10 Be ) in deep water is constant globally, then the observed variations in 10 Be 9 Be "> 10Be9Be ratios could be caused by accumulation of 10 Be in deep water as it flows and ages along the conveyor, following a transient depletion upon its formation in the Northern Atlantic. In this view both 10 Be and 9 Be reach local steady-state concentration in Pacific deep water and the global τ10 Be ≌ 600 a ">≌ τ10Be≌ 600a . An alternative possibility is that the Be isotope abundances are controlled by local scavenging. For this scenario τ 10 Be would vary according to local particle concentration and would ≌ 600 a in the central Pacific, but τ10 Be ≌ 230 a ">≌ τ10Be≌ 230a in the Atlantic. Mass balance considerations indicate that hydrothermal additions of 9 Be to the oceans are negligible and that the dissolved riverine source is also small. Furthermore, aeolian dust input of 9 Be appears insufficient to provide the dissolved 9 Be inventory. The dissolution of only a small proportion (2%) of river-derived particulates could in principle supply the observed seawater 9 Be content. If true, ocean margins would be the sites for 9 Be addition. Due to the particle-reactive nature of Be, these would also be the primary sites of Be removal. A possible net result of horizontal water masses passing through these marginal areas might be a decrease in seawater 10 Be 9 Be "> 10Be9Be , and establishment of a relatively constant 9 Be concentration. As τ 10 Be (∼ 600 a) is less than the apparent age of deep water in the Pacific (∼ 1500 a), the Pacific record of 10 Be 9 Be "> 10Be9Be is not expected to show secular variations due to changes in deep-water flow, despite the large variations in 10 Be 9 Be "> 10Be9Be between different water masses. Because of this insensitivity to deep-water flow, however, it is suggested that the 10 Be 9 Be "> 10Be9Be ratio, determined in the authigenic phase of marine sediments or hydrogenetic precipitates, should be a suitable tool for monitoring changes in continental input or cosmic ray intensity on longer time scales.

Earth and Planetary Science Letters↗

USGS1996

Distribution and sources of pre-anthropogenic lead isotopes in deep ocean water from Fe-Mn crusts

The lead isotope composition of ocean water is not well constrained due to contamination by anthropogenic lead. Here the global distribution of lead isotopes in deep ocean water is presented as derived from dated (ca. 100 ka) surface layers of hydrogenetic Fe-Mn crusts. The results indicate that the radiogenic lead in North Atlantic deep water is probably supplied from the continents by river particulates, and that lead in Pacific deep water is similar to that characteristic of island and continental volcanic arcs. Despite a short residence time in deep water (80-100 a), the isotopes of lead appear to be exceedingly well mixed in the Pacific basin. There is no evidence for the import of North Atlantic deep water-derived lead into the Pacific ocean, nor into the North Indian Ocean. This implies that the short residence time of lead in deep water prohibits advection over such long distances. Consequently, any climate-induced changes in deep-water flow are not expected to result in major changes in the seawater Pb-isotope record of the Pacific Ocean.

Geochimica et Cosmochimica Acta↗