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Geology topics

F. J. Pearson

Publications and source records attributed to F. J. Pearson.

13 recordsLinked to original sources
USGS1981

The origin and isotopic composition of dissolved sulfide in groundwater from carbonate aquifers in Florida and Texas

The δ 34 S values of dissolved sulfide and the sulfur isotope fractionations between dissolved sulfide and sulfate species in Floridan ground water generally correlate with dissolved sulfate concentrations which are related to flow patterns and residence time within the aquifer. The dissolved sulfide derives from the slow in situ biogenic reduction of sulfate dissolved from sedimentary gypsum in the aquifer. In areas where the water is oldest, the dissolved sulfide has apparently attained isotopic equilibrium with the dissolved sulfate ( Δ 34 S = 65 per mil) at the temperature (28°C) of the system. This approach to equilibrium reflects an extremely slow reduction rate of the dissolved sulfate by bacteria; this slow rate probably results from very low concentrations of organic matter in the aquifer. In the reducing part of the Edwards aquifer, Texas, there is a general down-gradient increase in both dissolved sulfide and sulfate concentrations, but neither the δ 34 S values of sulfide nor the sulfide-sulfate isotope fractionation correlates with the ground-water flow pattern. The dissolved sulfide species appear to be derived primarily from biogenic reduction of sulfate ions whose source is gypsum dissolution although upgradient diffusion of H 2 S gas from deeper oil field brines may be important in places. The sulfur isotope fractionation for sulfide-sulfate (about 38 per mil) is similar to that observed for modern oceanic sediments and probably reflects moderate sulfate reduction in the reducing part of the aquifer owing to the higher temperature and significant amount of organic matter present; contributions of isotopically heavy H 2 S from oil field brines are also possible.

Florida, Texas↗
USGS1979

Preliminary isotopic studies of fluids from the Cerro Prieto geothermal field

Preliminary isotopic studies of Cerro Prieto geothermal fluids and earlier studies of Mexicali Valley ground waters suggest local recharge of the geothermal system from the area immediately to the west. Oxygen isotope exchange of water with reservoir rock minerals at temperatures increasing with depth has produced fluids with oxygen-18 contents increasing with depth, and pressure drawdown in the southeastern part of the field has allowed lower oxygen-18 fluids to invade the production aquifer from above. The contents of tritium and carbon-14 in the fluid suggest only that the age of the fluid is between 50 and 10,000 years. The isotopic compositions of carbon and sulfur are consistent with a magmatic origin of these elements but a mixed sedimentary-organic origin appears more likely for carbon and is also possible for sulfur. Investigations of the isotopic compositions of geothermal and cold ground waters continue and are being expanded as fluids become available and as separation and analysis methods are improved. ?? 1979.

Geothermics↗
USGS1978

Mass transfer and carbon isotope evolution in natural water systems

This paper presents a theoretical treatment of the evolution of the carbon isotopes C13 and C14 in natural waters and in precipitates which derive from such waters. The effects of an arbitrary number of sources (such as dissolution of carbonate minerals and oxidation of organic material) and sinks (such as mineral precipitation, CO2 degassing and production of methane), and of equilibrium fractionation between solid, gas and aqueous phases are considered. The results are expressed as equations relating changes in isotopic composition to changes in conventional carbonate chemistry. One implication of the equations is that the isotopic composition of an aqueous phase may approach a limiting value whenever there are simultaneous inputs and outputs of carbonate. In order to unambiguously interpret isotopic data from carbonate precipitates and identify reactants and products in reacting natural waters, it is essential that isotopic changes are determined chiefly by reactant and product stoichiometry, independent of reaction path. We demonstrate that this is so by means of quantitative examples. The evolution equations are applied to: 1. (1) carbon-14 dating of groundwaters; 2. (2) interpretation of the isotopic composition of carbonate precipitates, carbonate cements and diagenetically altered carbonates; and 3. (3) the identification of chemical reaction stoichiometry. These applications are illustrated by examples which show the variation of ??C13 in solutions and in precipitates formed under a variety of conditions involving incongruent dissolution, CO2 degassing, methane production and mineral precipitation. ?? 1978.

Geochimica et Cosmochimica Acta↗
USGS1978

Correction of ground-water chemistry and carbon isotopic composition for effects of CO2 outgassing

Direct P co 2 "> P co2 measurements on water samples from several CO 2 -charged warm springs are significantly higher than P co 2 "> P co2 values calculated from field pH and alkalinity (and other constituents). In addition, calcite saturation indices calculated from field pH and solution composition indicated supersaturation in samples which, on the basis of hydrogeologic concepts, should be near saturation or undersaturated. We attribute these discrepancies to uncertainties in field pH, resulting from CO 2 outgassing during pH measurement. Because samples for direct P co 2 "> P co2 measurement can be taken with minimal disturbance to the water chemistry, we have used the measured P co 2 "> P co2 to back calculate an estimate of the field pH and the carbon isotopic composition of the water before outgassing. By reconstructing water chemistry in this way, we find generally consistent grouping of δ 13 C "> δ 13 C , pH, and degree of calcite saturation in samples taken from the same source at different times, an observation which we expect based on our understanding of the hydrogeology and geochemistry of the ground-water systems. This suggests that for very careful geochemical work, particularly on ground-waters much above ambient temperature, P co 2 "> P co2 measurements may provide more information on the system and a better estimate of its state of saturation with respect to carbonate minerals than can field measurements of pH.

Geochimica et Cosmochimica Acta↗
USGS1977

Geochemical and hydrologic data for wells and springs in thermal-spring areas of the Appalachians

Current interest in geothermal potential of thermal-spring areas in the Appalachians enhances the value of data on thermal springs and wells in these areas. This report presents maps showing locations of selected springs and wells and tables of physical and chemical data pertaining to these wells and springs. The chemical tables show compositions of gases (oxygen, nitrogen, argon, methane, carbon dioxide, and helium), isotope contents (tritium, carbon-13, and oxygen-18), trace and minor element chemical data, and concentrations of the major chemical constituents.

Water-Resources Investigations Report↗
USGS1976

Geochemical and hydrologic data for wells and springs in thermal-spring areas of the Appalachians

Current interest in geothermal potential of thermal-spring areas in the Appalachians makes all data on thermal springs and wells in these areas valuable. Presented here without interpretive comment are maps showing selected springs and wells and tables of physical and chemical data pertaining to these wells and springs. The chemical tables show compositions of gases (oxygen, nitrogen, argon, methane, carbon dioxide, and helium), isotope contents (tritium, carbon (13), and oxygen (18)), trace and minor element Chemical data, and the usual complete chemical data.

Open-File Report↗
USGS1973

A preliminary evaluation of regional ground-water flow in south-central Washington

The characteristics of regional ground-water flow were investigated in a 4,500-square-mile region of south-central Washington, centered on the U.S. Atomic Energy Commission Hanford Reservation. The investigation is part of the Commission's feasibility study on storing high-level radioactive waste in chambers mined in basaltic rocks at a. depth of about 3,000 feet or more below the surface. Ground-water flow., on a regional scale, occurs principally in the basalt and-in interbedded sediments of the Columbia River Group, and is controlled by topography, the structure of the basalt, and the large streams--the Columbia, Snake, and Yakima Rivers. The ground water beneath the main part of the Hanford Reservation, south and west of the Columbia River, inures southeastward from recharge areas in the uplands, including Cold Creek and Dry Creek valleys, and ultimately discharges to the Columbia River south of the reservation: East and southeast of the Columbia River, ground water flows generally southwestward and discharges to the River. The Yakima River valley contains a distinct flow system in which movement is toward the Yakima River from the topographic divides. A large southward-flowing ground-water system beneath the southern flank of the Horse Heaven Hills discharges to the Columbia River in the westward-trending reach downstream from Wallula Gap.

Open-File Report↗
USGS1972

Hydrochemistry of the Oneida Lake basin, New York

Oneida Lake, the largest lake within New York State, supports massive algae blooms that interfere with one of its major uses, recreation. As part of a study of the algae problem, a chemical balance for the lake and its drainage basin has been made. The quantities of major dissolved species entering the lake are determined for each of the hydrochemically homogeneous terrains comprising the basin. The largest terrain, the Tug Hill terrain to the north of the lake contributes more than half the total streamflow to the lake, but is underlain by chemically unreactive bedrock and glacial deposits and its mean annual dissolved-solids contribution is only 0.25 t per d per sq mi (tons per day per square mile). Adjacent to Oneida Lake and extensive to the south and west is the Lake Plain terrain, underlain by sediments from ancestral Oneida Lake and contributing dissolved solids to streams at the moderate rate of 0.57 t per d per sq mi. At the foot of the Appalachian Upland escarpment is the Salina Group terrain, underlain by gypsiferous shales and carbonate rocks, and contributing more dissolved solids than any other terrain--32 t per d per sq mi. Within the Appalachian Upland, in the extreme southern part of the basin are two terrains underlain by glacial sand and gravel and by glacial till and bedrock. Their contributions are 0.58 and 0.85 t per d per sq mi, respectively. Throughout the basin, the dissolved-solid contribution of precipitation is 0.06 t per d per sq mi. Lake input is balanced by lake output for all major species except sulfate and possibly calcium and magnesium, which are retained in the lake. Stream nitrogen loads are about 0.0016 t per d per sq mi throughout the basin, a value lower than that typical of undeveloped grassland and forest. In the southern part of the basin, this load is increased to 0.0020 t per d per sq mi by sewered wastes. Nitrogen loads leaving balance those entering the lake. Phosphate loads are consistent with the geology of the several terrains and range from 0.0006 to 0.0034 t per d per sq mi. Domestic and industrial wastes, lakeshore cottages, and boaters and recreationists probably contribute not more than 30 percent of the phosphate entering the lake. Phosphate is strongly retained in the lake.

New York↗