Geology topics

Elizabeth A. Nystrom

Publications and source records attributed to Elizabeth A. Nystrom.

32 records · Page 2Linked to original sources

USGS2014

An empirical approach to modeling methylmercury concentrations in an Adirondack stream watershed

Inverse empirical models can inform and improve more complex process-based models by quantifying the principal factors that control water quality variation. Here we developed a multiple regression model that explains 81% of the variation in filtered methylmercury (FMeHg) concentrations in Fishing Brook, a fourth-order stream in the Adirondack Mountains, New York, a known “hot spot” of Hg bioaccumulation. This model builds on previous observations that wetland-dominated riparian areas are the principal source of MeHg to this stream and were based on 43 samples collected during a 33 month period in 2007–2009. Explanatory variables include those that represent the effects of water temperature, streamflow, and modeled riparian water table depth on seasonal and annual patterns of FMeHg concentrations. An additional variable represents the effects of an upstream pond on decreasing FMeHg concentrations. Model results suggest that temperature-driven effects on net Hg methylation rates are the principal control on annual FMeHg concentration patterns. Additionally, streamflow dilutes FMeHg concentrations during the cold dormant season. The model further indicates that depth and persistence of the riparian water table as simulated by TOPMODEL are dominant controls on FMeHg concentration patterns during the warm growing season, especially evident when concentrations during the dry summer of 2007 were less than half of those in the wetter summers of 2008 and 2009. This modeling approach may help identify the principal factors that control variation in surface water FMeHg concentrations in other settings, which can guide the appropriate application of process-based models.

New York↗

USGS2013

Groundwater quality in the Mohawk River Basin, New York, 2011

Water samples were collected from 21 production and domestic wells in the Mohawk River Basin in New York in July 2011 to characterize groundwater quality in the basin. The samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Mohawk River Basin covers 3,500 square miles in New York and is underlain by shale, sandstone, carbonate, and crystalline bedrock. The bedrock is overlain by till in much of the basin, but surficial deposits of saturated sand and gravel are present in some areas. Nine of the wells sampled in the Mohawk River Basin are completed in sand and gravel deposits, and 12 are completed in bedrock. Groundwater in the Mohawk River Basin was typically neutral or slightly basic; the water typically was very hard. Bicarbonate, chloride, calcium, and sodium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Methane was detected in 15 samples. Strontium, iron, barium, boron, and manganese were the trace elements with the highest median concentrations. Four pesticides, all herbicides or their degradates, were detected in four samples at trace levels; three VOCs, including chloroform and two solvents, were detected in four samples. The greatest radon-222 activity, 2,300 picocuries per liter, was measured in a sample from a bedrock well, but the median radon activity was higher in samples from sand and gravel wells than in samples from bedrock wells. Coliform bacteria were detected in five samples with a maximum of 92 colony-forming units per 100 milliliters. Water quality in the Mohawk River Basin is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards. The standards exceeded are color (1 sample), pH (1 sample), sodium (9 samples), chloride (1 sample), sulfate (2 samples), dissolved solids (7 samples), aluminum (3 samples), iron (8 samples), manganese (6 samples), radon-222 (10 samples), and bacteria (5 samples). Fecal coliform bacteria and Escherichia coli (E. coli) were each detected in one sample. Concentrations of fluoride, nitrate, nitrite, antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, and uranium, and gross alpha activities, did not exceed existing drinking-water standards in any of the samples collected. Methane concentrations in two samples were greater than 28 milligrams per liter, and the maximum measured concentration was 44.3 milligrams per liter.

New York↗

USGS2013

Flood-inundation maps for the White River at Spencer, Indiana

Digital flood-inundation maps for a 5.3-mile reach of the White River at Spencer, Indiana, were created by the U.S. Geological Survey (USGS) in cooperation with the Indiana Office of Community and Rural Affairs. The inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation/, depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage White River at Spencer, Indiana (sta. no. 03357000). Current conditions for estimating near-real-time areas of inundation using USGS streamgage information may be obtained on the Internet at http://waterdata.usgs.gov/. National Weather Service (NWS)-forecasted peak-stage inforamation may be used in conjunction with the maps developed in this study to show predicted areas of flood inundation. In this study, flood profiles were computed for the stream reach by means of a one-dimensional step-backwater model. The model was calibrated by using the most current stage-discharge relation at the White River at Spencer, Indiana, streamgage and documented high-water marks from the flood of June 8, 2008. The hydraulic model was then used to compute 20 water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datum and ranging from the NWS action stage (9 feet) to the highest rated stage (28 feet) at the streamgage. The simulated water-surface profiles were then combined with a geographic information system digital elevation model (derived from Light Detection and Ranging (LiDAR) data) in order to delineate the area flooded at each water level. The availability of these maps along with Internet information regarding the current stage from the Spencer USGS streamgage and forecasted stream stages from the NWS will provide emergency management personnel and residents with information that is critical for flood response activities, such as evacuations and road closures, as well as for post-flood recovery efforts.

Indiana↗

USGS2012

Groundwater quality in the Delaware and St. Lawrence River Basins, New York, 2010

Water samples were collected from 10 production and domestic wells in the Delaware River Basin in New York and from 20 production and domestic wells in the St. Lawrence River Basin in New York from August through November 2010 to characterize groundwater quality in the basins. The samples were collected and processed by standard U.S. Geological Survey procedures and were analyzed for 147 physiochemical properties and constituents, including major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Delaware River Basin covers 2,360 square miles in New York, and is underlain mainly by shale and sandstone bedrock with other types of bedrock present locally. The bedrock is overlain by till in much of the basin, but surficial deposits of saturated sand and gravel are present in some areas. Five of the wells sampled in the Delaware study area are completed in sand and gravel deposits, and five are completed in bedrock. Groundwater in the Delaware study area was typically neutral or slightly acidic; the water typically was soft. Bicarbonate, chloride, and calcium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Strontium, barium, iron, and boron were the trace elements with the highest median concentrations. Radon was detected in all samples with activities greater than 300 picocuries per liter; the greatest radon activities were in samples from bedrock wells. Four pesticides, all herbicides or their degradates, were detected in four samples at trace levels; five VOCs, including four trihalomethanes and tetrachloromethane, were detected in two samples. Coliform bacteria were detected in five samples, but fecal coliform bacteria and Escherichia coli ( E. coli ) were not detected in any samples from the Delaware study area. The St. Lawrence River Basin covers 5,650 square miles in New York. The St. Lawrence River Basin in New York is underlain by crystalline, carbonate, and sandstone bedrock. The bedrock is overlain by till or lacustrine and marine deposits in much of the basin. Surficial deposits of saturated sand and gravel are present locally, but most wells in the basin are completed in bedrock. Five of the wells sampled in the St. Lawrence study area are completed in sand and gravel deposits, and 15 are completed in bedrock. Groundwater in the St. Lawrence study area was typically neutral or slightly basic; the water typically was hard. Bicarbonate, sulfate, and calcium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Strontium, iron, barium, and boron were the trace elements with the highest median concentrations. Radon was detected in two-thirds of samples with activities greater than 300 picocuries per liter; the greatest radon activities were in samples from bedrock wells. Seven pesticides, including 5 herbicides, an herbicide degradate, and an insecticide, were detected in 11 samples at trace levels; 3 VOCs (tetrachloroethene, toluene, and trichloromethane, or chloroform) were detected in 2 samples. Coliform bacteria were detected in 7 samples, and E. coli were detected in two samples in the St. Lawrence study area. Water quality in both study areas is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards. The standards exceeded are color (one sample in the St. Lawrence study area), pH (three samples in the Delaware study area), sodium (one sample in the St. Lawrence study area), total dissolved solids (one sample in the St. Lawrence study area), aluminum (one sample in the Delaware study area and one sample in the St. Lawrence study area), iron (seven samples in the St. Lawrence study area), manganese (one sample in the Delaware study area and five samples in the St. Lawrence study area), gross alpha radioactivity (one sample in the St. Lawrence study area), radon-222 (10 samples in the Delaware study area and 14 samples in the St. Lawrence study area), and bacteria (5 samples in the Delaware study area and 10 samples in the St. Lawrence study area). E. coli bacteria were detected in samples from two wells in the St. Lawrence study area. Concentrations of chloride, fluoride, sulfate, nitrate, nitrite, antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, and uranium did not exceed existing drinking-water standards in any of the samples collected.

New York↗

USGS2012

Dissolved methane in New York groundwater, 1999-2011

New York State is underlain by numerous bedrock formations of Cambrian to Devonian age that produce natural gas and to a lesser extent oil. The first commercial gas well in the United States was dug in the early 1820s in Fredonia, south of Buffalo, New York, and produced methane from Devonian-age black shale. Methane naturally discharges to the land surface at some locations in New York. At Chestnut Ridge County Park in Erie County, just south of Buffalo, N.Y., several surface seeps of natural gas occur from Devonian black shale, including one behind a waterfall. Methane occurs locally in the groundwater of New York; as a result, it may be present in drinking-water wells, in the water produced from those wells, and in the associated water-supply systems (Eltschlager and others, 2001). The natural gas in low-permeability bedrock formations has not been accessible by traditional extraction techniques, which have been used to tap more permeable sandstone and carbonate bedrock reservoirs. However, newly developed techniques involving horizontal drilling and high-volume hydraulic fracturing have made it possible to extract previously inaccessible natural gas from low-permeability bedrock such as the Marcellus and Utica Shales. The use of hydraulic fracturing to release natural gas from these shale formations has raised concerns with water-well owners and water-resource managers across the Marcellus and Utica Shale region (West Virginia, Pennsylvania, New York and parts of several other adjoining States). Molofsky and others (2011) documented the widespread natural occurrence of methane in drinking-water wells in Susquehanna County, Pennsylvania. In the same county, Osborn and others (2011) identified elevated methane concentrations in selected drinking-water wells in the vicinity of Marcellus gas-development activities, although pre-development samples were not available for comparison. In order to manage water resources in areas of gas-well drilling and hydraulic fracturing in New York, the natural occurrence of methane in the State's aquifers needs to be documented. This brief report presents a compilation of data on dissolved methane concentrations in the groundwater of New York available from the U.S. Geological Survey (USGS) National Water Information System (NWIS) (http://waterdata.usgs.gov/nwis).

New York↗

USGS2011

Groundwater quality in the Lake Champlain Basin, New York, 2009

Water was sampled from 20 production and domestic wells from August through November 2009 to characterize groundwater quality in the Lake Champlain Basin in New York. Of the 20 wells sampled, 8 were completed in sand and gravel, and 12 were completed in bedrock. The samples were collected and processed by standard U.S. Geological Survey procedures and were analyzed for 147 physiochemical properties and constituents, including major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. Water quality in the study area is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards; these were color (1 sample), pH (3 samples), sodium (3 samples), total dissolved solids (4 samples), iron (4 samples), manganese (3 samples), gross alpha radioactivity (1 sample), radon-222 (10 samples), and bacteria (5 samples). The pH of all samples was typically neutral or slightly basic (median 7.1); the median water temperature was 9.7°C. The ions with the highest median concentrations were bicarbonate [median 158 milligrams per liter (mg/L)] and calcium (median 45.5 mg/L). Groundwater in the study area is soft to very hard, but more samples were hard or very hard (121 mg/L or more as CaCO 3 ) than were moderately hard or soft (120 mg/L or less as CaCO 3 ); the median hardness was 180 mg/L as CaCO 3 . The maximum concentration of nitrate plus nitrite was 3.79 mg/L as nitrogen, which did not exceed established drinking-water standards for nitrate plus nitrite (10 mg/L as nitrogen). The trace elements with the highest median concentrations were strontium (median 202 micrograms per liter [μg/L]), and iron (median 55 μg/L in unfiltered water). Six pesticides and pesticide degradates, including atrazine, fipronil, disulfoton, prometon, and two pesticide degradates, CIAT and desulfinylfipronil, were detected among five samples at concentrations of 0.02 μg/L or less; they included herbicides, herbicide degradates, insecticides, and insecticide degradates. Six VOCs were detected among six samples; these included a solvent, the gasoline additive methyl tert-butyl ether (MTBE), and four trihalomethanes. The highest radon-222 activities were in samples from crystalline bedrock wells (maximum 4,100 picocuries per liter [pCi/L]); half of all samples exceeded a proposed U.S. Environmental Protection Agency (USEPA) drinking-water standard of 300 pCi/L. Total coliform bacteria were detected in five samples, fecal coliform bacteria were detected in one sample, and Escherichia coli (E. coli) were not detected in any sample.

New York↗

USGS2011

TOPMODEL simulations of streamflow and depth to water table in Fishing Brook Watershed, New York, 2007-09

TOPMODEL, a physically based, variable-source area rainfall-runoff model, was used to simulate streamflow and depth to water table for the period January 2007-September 2009 in the 65.6 square kilometers of Fishing Brook Watershed in northern New York. The Fishing Brook Watershed is located in the headwaters of the Hudson River and is predominantly forested with a humid, cool continental climate. The motivation for applying this model at Fishing Brook was to provide a simulation that would be effective later at this site in modeling the interaction of hydrologic processes with mercury dynamics. TOPMODEL uses a topographic wetness index computed from surface-elevation data to simulate streamflow and subsurface-saturation state, represented by the saturation deficit. Depth to water table was computed from simulated saturation-deficit values using computed soil properties. In the Fishing Brook Watershed, TOPMODEL was calibrated to the natural logarithm of streamflow at the study area outlet and depth to water table at Sixmile Wetland using a combined multiple-objective function. Runoff and depth to water table responded differently to some of the model parameters, and the combined multiple-objective function balanced the goodness-of-fit of the model realizations with respect to these parameters. Results show that TOPMODEL reasonably simulated runoff and depth to water table during the study period. The simulated runoff had a Nash-Sutcliffe efficiency of 0.738, but the model underpredicted total runoff by 14 percent. Depth to water table computed from simulated saturation-deficit values matched observed water-table depth moderately well; the root mean squared error of absolute depth to water table was 91 millimeters (mm), compared to the mean observed depth to water table of 205 mm. The correlation coefficient for temporal depth-to-water-table fluctuations was 0.624. The variability of the TOPMODEL simulations was assessed using prediction intervals grouped using the combined multiple-objective function. The calibrated TOPMODEL results for the entire study area were applied to several subwatersheds within the study area using computed hydrogeomorphic properties of the subwatersheds.

Scientific Investigations Report↗

USGS2010

Groundwater quality in the Lower Hudson River Basin, New York, 2008

Water samples were collected from 32 production and domestic wells in the study area from August through November 2008 to characterize the groundwater quality. The study area, which covers 5,607 square miles, encompasses the part of the Lower Hudson River Basin that lies within New York plus the parts of the Housatonic, Hackensack, Bronx, and Saugatuck River Basins that are in New York. The study area is underlain by mainly clastic bedrock, predominantly shale, with carbonate and crystalline rock present locally. The bedrock is generally overlain by till, but surficial deposits of saturated sand and gravel are present in some areas. Of the 32 wells sampled, 16 were finished in sand and gravel deposits and 16 were finished in bedrock. The samples were collected and processed by standard U.S. Geological Survey procedures and were analyzed for 225 physiochemical properties and constituents, including major ions, nutrients, trace elements, radon-222, pesticides, and volatile organic compounds (VOCs); indicator bacteria were collected and analyzed by New York State Department of Health procedures. Water quality in the study area is generally good, but concentrations of some constituents exceeded current or proposed Federal or New York State primary or secondary drinking-water standards; the standards exceeded were color (2 samples), pH (6 samples), sodium (8 samples), fluoride (1 sample), aluminum (3 samples), arsenic (1 sample), iron (7 samples), manganese (14 samples), radon-222 (17 samples), tetrachloroethene (1 sample), and bacteria (7 samples). The pH of all samples was typically neutral or slightly basic (median 7.2); the median water temperature was 11.8 degrees C. The ions with the highest concentrations were bicarbonate [median 167 milligrams per liter (mg/L)] and calcium (median 38.2 mg/L). Groundwater in the study area ranged from very soft to very hard, but more samples were classified as very hard (181 mg/L as CaCO3 or more) than soft (60 mg/L as CaCO3 or less); the median hardness was 140 mg/L as CaCO3. The maximum concentration of nitrate plus nitrite was 2.38 mg/L as nitrogen, which did not exceed established drinking-water standards for nitrate plus nitrite (10 mg/L as nitrogen). The trace elements with the highest concentrations were strontium [median 189 micrograms per liter ((u or mu)g/L)] and barium (median 50.6 (u or mu)g/L). The highest radon-222 activities were in samples from crystalline bedrock wells [maximum 13,800 picocuries per liter (pCi/L)]. Seventeen samples had radon-222 activities that exceeded a proposed U.S. Environmental Protection Agency (USEPA) drinking-water standard of 300 pCi/L; activities in two samples exceeded a proposed alternative drinking-water standard of 4,000 pCi/L. Ten pesticides and pesticide degradates were detected among 14 samples at concentrations of 0.183 (u or mu)g/L or less; most were herbicides or their degradates. Eight VOCs were detected among six samples; these included solvents, gasoline components, and a trihalomethane. Total coliform bacteria were detected in seven samples; fecal coliform bacteria, including Escherichia coli, were detected in one sample.

Open-File Report↗

USGS2009

Ground-Water Quality in the Upper Hudson River Basin, New York, 2007

Water samples were collected from 25 production and domestic wells in the Upper Hudson River Basin (north of the Federal Dam at Troy, N.Y.) from August through November 2007 to characterize the ground-water quality. The Upper Hudson River Basin covers 4,600 square miles in upstate New York, Vermont, and Massachusetts; the study area encompasses the 4,000 square miles that lie within New York. The basin is underlain by crystalline and sedimentary bedrock, including gneiss, shale, and slate; some sandstone and carbonate rocks are present locally. The bedrock in some areas is overlain by surficial deposits of saturated sand and gravel. Of the 25 wells sampled, 13 were finished in sand and gravel deposits, and 12 were finished in bedrock. The samples were collected and processed by standard U.S. Geological Survey procedures and were analyzed for 225 physical properties and constituents, including major ions, nutrients, trace elements, radon-222, pesticides, volatile organic compounds (VOCs), and indicator bacteria. Water quality in the study area is generally good, but concentrations of some constituents exceeded current or proposed Federal or New York State drinking-water standards; these were: color (1 sample), pH (2 samples), sodium (5 samples), nitrate plus nitrite (2 samples), aluminum (3 samples), iron (1 sample), manganese (7 samples), radon-222 (11 samples), and bacteria (1 sample). Dissolved-oxygen concentrations in samples from wells finished in sand and gravel [median 5.4 milligrams per liter (mg/L)] were greater than those from wells finished in bedrock (median 0.4 mg/L). The pH of all samples was typically neutral or slightly basic (median 7.6); the median water temperature was 9.7 deg C. The ions with the highest concentrations were bicarbonate (median 123 mg/L) and calcium (median 33.9 mg/L). Ground water in the basin is generally soft to moderately hard (less than or equal to 120 mg/L as CaCO3) (median hardness 110 mg/L as CaCO3). Concentrations of nitrate plus nitrite in samples from sand and gravel wells (median concentration 0.47 mg/L as nitrogen) were generally higher than those in samples from bedrock wells (median estimated 0.05 mg/L as nitrogen), and concentrations in two samples exceeded established drinking-water standards for nitrate (10 mg/L as nitrogen). The trace elements with the highest concentrations were strontium [median 217 micrograms per liter (ug/L)] and iron (median 39 ug/L). The highest radon-222 activities were in samples from bedrock wells [maximum 2,930 picocuries per liter (pCi/L)] and 44 percent of all samples exceeded a proposed U.S. Environmental Protection Agency (USEPA) drinking-water standard of 300 pCi/L. Ten pesticides and pesticide degradates were detected among 11 samples at concentrations of 1.47 ug/L or less; most were herbicides or their degradates. Six VOCs were detected among 10 samples at concentrations of 4.2 ug/L or less; these included three trihalomethanes and methyl tert-butyl ether, tetrachloroethene, and toluene. Most detections were in samples from sand and gravel wells and none exceeded drinking-water standards. Total coliform bacteria were detected in only one sample, and fecal coliform bacteria, including Escherichia coli, were not detected in any sample.

Open-File Report↗

USGS2008

Ground-Water Quality in the Mohawk River Basin, New York, 2006

Water samples were collected from 27 wells from August through November 2006 to characterize ground-water quality in the Mohawk River Basin. The Mohawk River Basin covers 3,500 square miles in central New York; most of the basin is underlain by sedimentary bedrock, including shale, sandstone, and carbonates. Sand and gravel form the most productive aquifers in the basin. Samples were collected from 13 sand and gravel wells and 14 bedrock wells, including production and domestic wells. The samples were collected and processed through standard U.S. Geological Survey procedures and were analyzed for 226 physical properties and constituents, including physical properties, major ions, nutrients, trace elements, radon-222, pesticides, volatile organic compounds, and bacteria. Many constituents were not detected in any sample, but concentrations of some constituents exceeded current or proposed Federal or New York State drinking-water quality standards, including color (1 sample), pH (2 samples), sodium (11 samples), chloride (2 samples), fluoride (1 sample), sulfate (1 sample), aluminum (2 samples), arsenic (2 samples), iron (10 samples), manganese (10 samples), radon-222 (12 samples), and bacteria (6 samples). Dissolved oxygen concentrations were greater in samples from sand and gravel wells (median 5.6 milligrams per liter [mg/L]) than from bedrock wells (median 0.2 mg/L). The pH was typically neutral or slightly basic (median 7.3); the median water temperature was 11?C. The ions with the highest concentrations were bicarbonate (median 276 mg/L), calcium (median 58.9 mg/L), and sodium (median 41.9 mg/L). Ground water in the basin is generally very hard (180 mg/L as CaCO3 or greater), especially in the Mohawk Valley and areas with carbonate bedrock. Nitrate-plus-nitrite concentrations were generally higher samples from sand and gravel wells (median concentration 0.28 mg/L as N) than in samples from bedrock wells (median < 0.06 mg/L as N), although no concentrations exceeded established State or Federal drinking-water standards of 10 mg/L as N for nitrate and 1 mg/L as N for nitrite. Ammonia concentrations were higher in samples from bedrock wells (median 0.349 mg/L as N) than in those from samples from sand and gravel wells (median 0.006 mg/L as N). The trace elements with the highest concentrations were strontium (median 549 micrograms per liter [?g/L]), iron (median 143 ?g/L), boron (median 35 ?g/L), and manganese (median 31.1 ?g/L). Concentrations of several trace elements, including boron, copper, iron, manganese, and strontium, were higher in samples from bedrock wells than those from sand and gravel wells. The highest radon-222 activities were in samples from bedrock wells (maximum 1,360 pCi/L); 44 percent of all samples exceeded a proposed U.S. Environmental Protection Agency drinking water standard of 300 pCi/L. Nine pesticides and pesticide degradates were detected in six samples at concentrations of 0.42 ?g/L or less; all were herbicides or their degradates, and most were degradates of alachlor, atrazine, and metolachlor. Six volatile organic compounds were detected in four samples at concentrations of 0.8 ?g/L or less, including four trihalomethanes, tetrachloroethene, and toluene; most detections were in sand and gravel wells and none of the concentrations exceeded drinking water standards. Coliform bacteria were detected in six samples but fecal coliform bacteria, including Escherichia coli, were not detected in any sample.

Open-File Report↗

USGS2007

Ground-Water Quality in the St. Lawrence River Basin, New York, 2005-06

The Federal Clean Water Act requires that States monitor and report on the quality of ground water and surface water. To satisfy part of these requirements, the U.S. Geological Survey and New York State Department of Environmental Conservation have developed a program in which ground-water quality is assessed in 2 to 3 of New York State's 14 major river basins each year. To characterize the quality of ground water in the St. Lawrence River Basin in northern New York, water samples were collected from 14 domestic and 11 production wells between August 2005 and January 2006. Eight of the wells were finished in sand and gravel and 17 wells were finished in bedrock. Ground-water samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 229 constituents and physical properties, including inorganic constituents, nutrients, trace elements, radon-222, pesticides and pesticide degradates, volatile organic compounds, and bacteria. Sixty-six constituents were detected above laboratory reporting levels. Concentrations of most compounds at most sites were within drinking water standards established by the U.S. Environmental Protection Agency and New York State Department of Health, but a few compounds exceeded drinking water standards at some sites. Water in the basin is generally hard to very hard (hardness equal to 121 mg/L as CaCO3 or greater); hardness and alkalinity were generally higher in the St. Lawrence Valley than in the Adirondack Mountains. The cation with the highest median concentration was calcium; the anion with the highest median concentration was bicarbonate. The concentration of chloride in one sample exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard; the concentration of sulfate in one sample also exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard. Nitrate was the predominant nutrient detected but no sample exceeded the 10 mg/L U.S. Environmental Protection Agency Maximum Contaminant Level. The trace elements detected with the highest median concentrations were strontium, barium, and iron. Concentration of trace elements in several samples exceeded U.S. Environmental Protection Agency Secondary Drinking Water Standards, including aluminum (50 micrograms per liter, 4 samples), iron (300 micrograms per liter, 5 samples), and manganese (50 micrograms per liter, 4 samples). The concentration of uranium in one sample from a domestic well finished in crystalline bedrock was three times the U.S. Environmental Protection Agency Maximum Contaminant Level of 30 micrograms per liter. The median concentration of radon-222 was 600 picoCuries per liter, but concentrations as high as 18,800 picoCuries per liter were detected; two wells with high radon concentrations also had high uranium concentrations. Radon-222 is not currently regulated, but the U.S. Environmental Protection Agency has proposed a Maximum Contaminant Level of 300 picoCuries per liter along with an Alternative Maximum Contaminant Level of 4,000 picoCuries per liter, to be in effect in states that have programs to address radon in indoor air. Concentrations of radon-222 exceeded the proposed Maximum Contaminant Level in 60 percent of samples and exceeded the proposed Alternative Maximum Contaminant Level in 8 percent of samples. Six pesticides and pesticide degradates were detected; all were amide or triazine herbicides or degradates. Five volatile organic compounds were detected, including disinfection byproducts such as trichloromethane and gasoline components or additives such as methyl tert-butyl ether. No pesticides, pesticide degradates, or volatile organic compounds were detected above established limits. Coliform bacteria, including Escherichia coli, were detected in three wells finished in carbonate bedrock.

Open-File Report↗

USGS2007

Ground-Water Quality in the Delaware River Basin, New York, 2001 and 2005-2006

The Federal Clean Water Act Amendments of 1977 require that States monitor and report on the quality of ground water and surface water. To satisfy part of these requirements, the U.S. Geological Survey and New York State Department of Environmental Conservation have developed a program in which ground-water quality is assessed in 2 to 3 of New York State's 14 major basins each year. To characterize the quality of ground water in the Delaware River Basin in New York, water samples were collected from December 2005 to February 2006 from 10 wells finished in bedrock. Data from 9 samples collected from wells finished in sand and gravel in July and August 2001 for the National Water Quality Assessment Program also are included. Ground-water samples were collected and processed using standard U.S. Geological Survey procedures. Samples were analyzed for more than 230 properties and compounds, including physical properties, major ions, nutrients, trace elements, radon-222, pesticides and pesticide degradates, volatile organic compounds, and bacteria. Concentrations of most compounds were less than drinking-water standards established by the U.S. Environmental Protection Agency and New York State Department of Health; many of the organic analytes were not detected in any sample. Drinking-water standards that were exceeded at some sites include those for color, turbidity, pH, aluminum, arsenic, iron, manganese, radon-222, and bacteria. pH ranged from 5.6 to 8.3; the pH of nine samples was less than the U.S. Environmental Protection Agency secondary drinking-water standard range of 6.5 to 8.5. Water in the basin is generally soft to moderately hard (hardness 120 milligrams per liter as CaCO3 or less). The cation with the highest median concentration was calcium; the anion with the highest median concentrations was bicarbonate. Nitrate was the predominant nutrient detected but no sample exceeded the 10 mg/L U.S. Environmental Protection Agency maximum contaminant level. The trace elements detected with the highest median concentrations were strontium and iron in unfiltered water and strontium and barium in filtered water. Concentrations of trace elements in several samples exceeded U.S. Environmental Protection Agency secondary drinking-water standards, including aluminum (50-200 micrograms per liter, three wells), arsenic (10 micrograms per liter, one well), iron (300 micrograms per liter, three wells), and manganese (50 micrograms per liter, four wells). The median concentration of radon-222 was 1,580 picoCuries per liter. Radon-222 is not currently regulated, but the U.S. Environmental Protection Agency has proposed a maximum contaminant level of 300 picoCuries per liter along with an alternative maximum contaminant level of 4,000 picoCuries per liter, to be in effect in states that have programs to address radon in indoor air. Concentrations of radon-222 exceeded the proposed maximum contaminant level in all 19 of the samples and exceeded the proposed alternative maximum contaminant level in 1 sample. Eleven pesticides and pesticide degradates were detected in samples from ten wells; all were herbicides or herbicide degradates. Three volatile organic compounds were detected, including disinfection byproducts such as trichloromethane and gasoline components or additives such as methyl tert-butyl ether. No pesticides, pesticide degradates, or volatile organic compounds were detected above established limits. Coliform bacteria were detected in samples from five wells, four of which were finished in sand and gravel; Escherichia coli was not detected in any sample.

Open-File Report↗

USGS2006

Use of an ADCP to compute suspended-sediment discharge in the tidal Hudson River, New York

Acoustic Doppler current profilers (ADCPs) can provide data needed for computation of suspended-sediment discharge in complex river systems, such as tidal rivers, in which conventional methods of collecting time-series data on suspended-sediment concentration (SSC) and water discharge are not feasible. Although ADCPs are not designed to measure SSC, ADCP data can be used as a surrogate under certain environmental conditions. However, the software for such computation is limited, and considerable post-processing is needed to correct and normalize ADCP data for this use. This report documents the sampling design and computational procedure used to calibrate ADCP measures of echo intensity to SSC and water velocity to discharge in the computation of suspended-sediment discharge at the study site on the Hudson River near Poughkeepsie, New York. The methods and procedures described may prove useful to others doing similar work in different locations; however, they are specific to this study site and may have limited applicability elsewhere.

Connecticut, New York↗

USGS2006

Ground-water quality in the Lake Champlain basin, New York, 2004

Water samples were collected from 11 public-supply wells and 11 private domestic wells in the Lake Champlain basin in New York during the fall of 2004 to characterize the chemical quality of ground water. Wells were selected for sampling based on location and focused on areas of greatest ground-water use. Samples were analyzed for 219 physical properties and constituents, including inorganic compounds, nutrients, metals, radionuclides, pesticides and pesticide degradates, volatile organic compounds, and bacteria. Sixty-eight constituents were detected at concentrations above laboratory reporting levels. The cation and anion with the highest median concentration were calcium (34.8 mg/L) bicarbonate (134 mg/L), respectively. The predominant nutrient was nitrate, which was detected in 14 (64 percent) of the 22 samples. The two metals with the highest median concentrations were iron (175 ?g/L) and strontium (124 ?g/L); concentrations of iron, manganese, aluminum, and zinc exceeded U.S. Environmental Protection Agency secondary drinking-water standards in one or more samples. Radon concentrations were less than 1,000 picocuries per liter (pCi/L) in most samples, but concentrations as high as 6,900 pCi/L were detected and, in eight samples, exceeded the U.S. Environmental Protection Agency proposed maximum contaminant level (300 pCi/L) for radon. The most frequently detected pesticides were degradates of the broadleaf herbicides metolachlor, alachlor, and atrazine. Volatile organic compounds were detected in only three samples; those that were detected typically were fuel oxygenates, such as methyl tert-butyl ether. Coliform bacteria were detected in four samples, two of which also tested positive for E. coli.

Open-File Report↗