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Geology topics

Elisabeth L. Rowan

Publications and source records attributed to Elisabeth L. Rowan.

At least 19 recordsLinked to original sources

Utica shale play oil and gas brines: Geochemistry and factors influencing wastewater management

The Utica and Marcellus Shale Plays in the Appalachian Basin are the fourth and first largest natural gas producing plays in the United States, respectively. Hydrocarbon production generates large volumes of brine (“produced water”) that must be disposed of, treated, or reused. Though Marcellus brines have been studied extensively, there are few studies from the Utica Shale Play. This study presents new brine chemical analyses from 16 Utica Shale Play wells in Ohio and Pennsylvania. Results from Na–Cl–Br systematics and stable and radiogenic isotopes suggest that the Utica Shale Play brines are likely residual pore water concentrated beyond halite saturation during the formation of the Ordovician Beekmantown evaporative sequence. The narrow range of chemistry for the Utica Shale Play produced waters (e.g., total dissolved solids = 214–283 g/L) over both time and space implies a consistent composition for disposal and reuse planning. The amount of salt produced annually from the Utica Shale Play is equivalent to 3.4% of the annual U.S. halite production. Utica Shale Play brines have radium activities 580 times the EPA maximum contaminant level and are supersaturated with respect to barite, indicating the potential for surface and aqueous radium hazards if not properly disposed of.

Kentucky, Maryland, New York, Ohio, Pennsylvania,

Organic and inorganic composition and microbiology of produced waters from Pennsylvania shale gas wells

Hydraulically fractured shales are becoming an increasingly important source of natural gas production in the United States. This process has been known to create up to 420 gallons of produced water (PW) per day, but the volume varies depending on the formation, and the characteristics of individual hydraulic fracture. PW from hydraulic fracturing of shales are comprised of injected fracturing fluids and natural formation waters in proportions that change over time. Across the state of Pennsylvania, shale gas production is booming; therefore, it is important to assess the variability in PW chemistry and microbiology across this geographical span. We quantified the inorganic and organic chemical composition and microbial communities in PW samples from 13 shale gas wells in north central Pennsylvania. Microbial abundance was generally low (66–9400 cells/mL). Non-volatile dissolved organic carbon (NVDOC) was high (7–31 mg/L) relative to typical shallow groundwater, and the presence of organic acid anions (e.g., acetate, formate, and pyruvate) indicated microbial activity. Volatile organic compounds (VOCs) were detected in four samples (∼1 to 11.7 μg/L): benzene and toluene in the Burket sample, toluene in two Marcellus samples, and tetrachloroethylene (PCE) in one Marcellus sample. VOCs can be either naturally occurring or from industrial activity, making the source of VOCs unclear. Despite the addition of biocides during hydraulic fracturing, H 2 S-producing, fermenting, and methanogenic bacteria were cultured from PW samples. The presence of culturable bacteria was not associated with salinity or location; although organic compound concentrations and time in production were correlated with microbial activity. Interestingly, we found that unlike the inorganic chemistry, PW organic chemistry and microbial viability were highly variable across the 13 wells sampled, which can have important implications for the reuse and handling of these fluids

Pennsylvania

Factors controlling Li concentration and isotopic composition in formation waters and host rocks of Marcellus Shale, Appalachian Basin

In this study, water and whole rock samples from hydraulically fractured wells in the Marcellus Shale (Middle Devonian), and water from conventional wells producing from Upper Devonian sandstones were analyzed for lithium concentrations and isotope ratios (&delta; 7 Li). The distribution of lithium concentrations in different mineral groups was determined using sequential extraction. Structurally bound Li, predominantly in clays, accounted for 75-91 wt. % of total Li, whereas exchangeable sites and carbonate cement contain negligible Li (< 3%). Up to 20% of the Li is present in the oxidizable fraction (organic matter and sulfides). The &delta; 7 Li values for whole rock shale in Greene Co., Pennsylvania, and Tioga Co., New York, ranged from -2.3 to + 4.3&permil;, similar to values reported for other shales in the literature. The &delta; 7 Li values in shale rocks with stratigraphic depth record progressive weathering of the source region; the most weathered and clay-rich strata with isotopically light Li are found closest to the top of the stratigraphic section. Diagenetic illite-smectite transition could also have partially affected the bulk Li content and isotope ratios of the Marcellus Shale. In Greene Co., southwest Pennsylvania, the Upper Devonian sandstone formation waters have &delta; 7 Li values of + 14.6 &plusmn; 1.2 (2SD, n = 25), and are distinct from Marcellus Shale formation waters which have &delta; 7 Li of + 10.0 &plusmn; 0.8 (2SD, n = 12). These two formation waters also maintain distinctive 87 Sr/ 86 Sr ratios suggesting hydrologic separation between these units. Applying temperature-dependent illitilization model to Marcellus Shale, we found that Li concentration in clay minerals increased with Li concentration in pore fluid during diagenetic illite-smectite transition. Samples from north central PA show a much smaller range in both &delta; 7 Li and 87 Sr/ 86 Sr than in southwest Pennsylvania. Spatial variations in Li and &delta; 7 Li values show that Marcellus formation waters are not homogeneous across the Appalachian Basin. Marcellus formation waters in the northeastern Pennsylvania portion of the basin show a much smaller range in both &delta; 7 Li and 87 Sr/ 86 Sr, suggesting long term, cross-formational fluid migration in this region. Assessing the impact of potential mixing of fresh water with deep formation water requires establishment of a geochemical and isotopic baseline in the shallow, fresh water aquifers, and site specific characterization of formation water, followed by long-term monitoring, particularly in regions of future shale gas development.

New York, Pennsylvania

Surface disposal of produced waters in western and southwestern Pennsylvania: potential for accumulation of alkali-earth elements in sediments

Waters co-produced with hydrocarbons in the Appalachian Basin are of notably poor quality (concentrations of total dissolved solids (TDS) and total radium up to and exceeding 300,000 mg/L and 10,000 pCi/L, respectively). Since 2008, a rapid increase in Marcellus Shale gas production has led to a commensurate rise in associated wastewater while generation of produced water from conventional oil and gas activities has continued. In this study, we assess whether disposal practices from treatment of produced waters from both shale gas and conventional operations in Pennsylvania could result in the accumulation of associated alkali earth elements. The results from our 5 study sites indicate that there was no increase in concentrations of total Ra (Ra-226) and extractable Ba, Ca, Na, or Sr in fluvial sediments downstream of the discharge outfalls (p > 0.05) of publicly owned treatment works (POTWs) and centralized waste treatment facilities (CWTs). However, the use of road spreading of brines from conventional oil and gas wells for deicing resulted in accumulation of Ra-226 (1.2 ×), and extractable Sr (3.0 ×), Ca (5.3 ×), and Na (6.2 ×) in soil and sediment proximal to roads (p < 0.05). Although this study is an important initial assessment of the impacts of these disposal practices, more work is needed to consider the environmental consequences of produced waters management.

Pennsylvania

Geologic cross section D-D' through the Appalachian basin from the Findlay arch, Sandusky County, Ohio, to the Valley and Ridge province, Hardy County, West Virginia

This chapter is a re-release of U.S. Geological Survey Scientific Investigations Map 3067, of the same title, by Ryder and others (2009). For this chapter, two appendixes have been added that do not appear with the original version. Appendix A provides Log ASCII Standard (LAS) files for each drill hole along cross-section D-D' ; they are text files which encode gamma-ray, neutron, density, and other logs that can be used by most well-logging software. Appendix B provides graphic well-log traces and lithologic descriptions with formation tops from each drill hole.

Appalachian basin

Assessment of undiscovered oil and gas resources of the East Coast Mesozoic basins of the Piedmont, Blue Ridge Thrust Belt, Atlantic Coastal Plain, and New England Provinces, 2011

During the early opening of the Atlantic Ocean in the Mesozoic Era, numerous extensional basins formed along the eastern margin of the North American continent from Florida northward to New England and parts of adjacent Canada. The basins extend generally from the offshore Atlantic continental margin westward beneath the Atlantic Coastal Plain to the Appalachian Mountains. Using a geology-based assessment method, the U.S. Geological Survey estimated a mean undiscovered natural gas resource of 3,860 billion cubic feet and a mean undiscovered natural gas liquids resource of 135 million barrels in continuous accumulations within five of the East Coast Mesozoic basins: the Deep River, Dan River-Danville, and Richmond basins, which are within the Piedmont Province of North Carolina and Virginia; the Taylorsville basin, which is almost entirely within the Atlantic Coastal Plain Province of Virginia and Maryland; and the southern part of the Newark basin (herein referred to as the South Newark basin), which is within the Blue Ridge Thrust Belt Province of New Jersey. The provinces, which contain these extensional basins, extend across parts of Georgia, South Carolina, North Carolina, Virginia, Maryland, Delaware, Pennsylvania, New Jersey, New York, Connecticut, and Massachusetts.

East Coast Mesozoic Basins

Temperature and petroleum generation history of the Wilcox Formation, Louisiana

A one-dimensional petroleum system modeling study of Paleogene source rocks in Louisiana was undertaken in order to characterize their thermal history and to establish the timing and extent of petroleum generation. The focus of the modeling study was the Paleocene and Eocene Wilcox Formation, which contains the youngest source rock interval in the Gulf Coast Province. Stratigraphic input to the models included thicknesses and ages of deposition, lithologies, amounts and ages of erosion, and ages for periods of nondeposition. Oil-generation potential of the Wilcox Formation was modeled using an initial total organic carbon of 2 weight percent and an initial hydrogen index of 261 milligrams of hydrocarbon per grams of total organic carbon. Isothermal, hydrous-pyrolysis kinetics determined experimentally was used to simulate oil generation from coal, which is the primary source of oil in Eocene rocks. Model simulations indicate that generation of oil commenced in the Wilcox Formation during a fairly wide age range, from 37 million years ago to the present day. Differences in maturity with respect to oil generation occur across the Lower Cretaceous shelf edge. Source rocks that are thermally immature and have not generated oil (depths less than about 5,000 feet) lie updip and north of the shelf edge; source rocks that have generated all of their oil and are overmature (depths greater than about 13,000 feet) are present downdip and south of the shelf edge. High rates of sediment deposition coupled with increased accommodation space at the Cretaceous shelf margin led to deep burial of Cretaceous and Tertiary source rocks and, in turn, rapid generation of petroleum and, ultimately, cracking of oil to gas.

Louisiana

Geologic cross section C-C' through the Appalachian basin from Erie County, north-central Ohio, to the Valley and Ridge province, Bedford County, south-central Pennsylvania

Geologic cross section C-C' is the third in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section C-C' provides a regional view of the structural and stratigraphic framework of the Appalachian basin from north-central Ohio to the Valley and Ridge province in south-central Pennsylvania, a distance of approximately 260 miles (mi). This cross section is a companion to cross sections E-E' and D-D' that are located about 50 to 125 mi and 25 to 50 mi, respectively, to the southwest. Cross section C-C' contains much information that is useful for evaluating energy resources in the Appalachian basin. Although specific petroleum systems are not identified on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and preferred migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on what is shown on the cross section. Cross section C-C' also provides a general framework (stratigraphic units and general rock types) for the coal-bearing section, although the cross section lacks the detail to illustrate key elements of coal systems (such as paleoclimate, coal quality, and coal rank). In addition, cross section C-C' may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Kentucky;Maryl;Ohio;Pennsylvania;Tennessee;Virgini

Modeling the mesozoic-cenozoic structural evolution of east texas

The U.S. Geological Survey (USGS) recently assessed the undiscovered technically recoverable oil and gas resources within Jurassic and Cretaceous strata of the onshore coastal plain and State waters of the U.S. Gulf Coast. Regional 2D seismic lines for key parts of the Gulf Coast basin were interpreted in order to examine the evolution of structural traps and the burial history of petroleum source rocks. Interpretation and structural modeling of seismic lines from eastern Texas provide insights into the structural evolution of this part of the Gulf of Mexico basin. Since completing the assessment, the USGS has acquired additional regional seismic lines in east Texas; interpretation of these new lines, which extend from the Texas-Oklahoma state line to the Gulf Coast shoreline, show how some of the region's prominent structural elements (e.g., the Talco and Mount Enterprise fault zones, the East Texas salt basin, and the Houston diapir province) vary along strike. The interpretations also indicate that unexplored structures may lie beneath the current drilling floor. Structural restorations based upon interpretation of these lines illustrate the evolution of key structures and show the genetic relation between structural growth and movement of the Jurassic Louann Salt. 1D thermal models that integrate kinetics and burial histories were also created for the region's two primary petroleum source rocks, the Oxfordian Smackover Formation and the Cenomanian-Turonian Eagle Ford Shale. Integrating results from the thermal models with the structural restorations provides insights into the distribution and timing of petroleum expulsion from the Smackover Formation and Eagle Ford Shale in eastern Texas.

Texas

Geology and assessment of undiscovered oil and gas resources in Mesozoic (Jurassic and Cretaceous) rocks of the onshore and state waters of the Gulf of Mexico Region, U.S.A

The U.S. Geological Survey (USGS) is in the final phase of the most recent assessment of the undiscovered technically recoverable oil and gas resources of the U.S. Gulf of Mexico coastal plain and state waters. Ongoing geologic, geochemical, and petrophysical framework studies have defined the total petroleum systems and assessment units (AUs) in the Gulf Coast region. Current studies examine the Mesozoic (Jurassic and Cretaceous) source rocks and reservoir units, and recent studies have assessed the undiscovered resources in Tertiary and certain Jurassic and Cretaceous units. The Upper Jurassic and Lower Cretaceous Cotton Valley Group and Lower Cretaceous Hosston and Travis Peak formations, as well as the Upper Cretaceous Taylor and Navarro groups and the Tuscaloosa and Woodbine groups downdip shelf-margin deltas, were assessed in 2006. Tertiary strata were assessed in 2007. Jurassic strata presently under evaluation include the Upper Jurassic Norphlet, Smackover, Haynesville, and Bossier formations. Lower Cretaceous units to be assessed in the present study include the Knowles Limestone, Sligo Formation, Trinity Group, Fredericksburg Group, and lower part of the Washita Group. Upper Cretaceous rocks being assessed include the Buda Limestone of the Washita Group, Eagle Ford Group (Eagle Ford shale, and the updip Tuscaloosa and Woodbine groups), Austin Chalk (Group), and Tokio and Eutaw formations. For each AU, a geologic model is developed to define hydrocarbon source, charge, migration, trap, and reservoir, and to estimate technically recoverable undiscovered oil and gas resources. The USGS assessment is focused on evaluating conventional clastic and carbonate deposystems, as well as resource volumes in emerging unconventional gas, shale gas, and shale oil plays currently attracting global attention.

Texas, Louisiana, Alabama, Mississippi, Florida

Geologic Cross Section D-D' Through the Appalachian Basin from the Findlay Arch, Sandusky County, Ohio, to the Valley and Ridge Province, Hardy County, West Virginia

Geologic cross section D-D' is the second in a series of cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section D-D' provides a regional view of the structural and stratigraphic framework of the Appalachian basin from the Findlay arch in northwestern Ohio to the Valley and Ridge province in eastern West Virginia, a distance of approximately 290 miles. The information shown on the cross section is based on geological and geophysical data from 13 deep drill holes, several of which penetrate the Paleozoic sedimentary rocks of the basin and bottom in Mesoproterozoic (Grenville-age) crystalline basement rocks. This cross section is a companion to cross section E-E' (Ryder and others, 2008) that is located about 25 to 50 mi to the southwest. Although specific petroleum systems in the Appalachian basin are not identified on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and preferred migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on information shown on the cross section. Cross section D-D' lacks the detail to illustrate key elements of coal systems (such as paleoclimate, coal quality, and coal rank), but it does provide a general geologic framework (stratigraphic units and general rock types) for the coal-bearing section. Also, cross section D-D' may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Scientific Investigations Map

The Yukon Flats Cretaceous(?)-Tertiary extensional basin, east-central Alaska: Burial and thermal history modeling

One-dimensional burial and thermal history modeling of the Yukon Flats basin, east-central Alaska, was conducted as part of an assessment of the region’s undiscovered oil and gas resources. No deep exploratory wells have been drilled in the Yukon Flats region, and the subsurface geology of the basin is inferred from seismic reflection, gravity and magnetic surveys, and studies of shallow core holes in the basin and outcrops in the surrounding region. A thick sequence of Upper Cretaceous(?) and Cenozoic nonmarine sedimentary rocks is believed to fill the basin; coal and organic-rich mudstone and shale within this sequence represent potential hydrocarbon source rocks. The burial and thermal history models presented here represent the sole source of information on the thermal maturity of these potential source rocks at depth. We present four alternative burial history scenarios for a hypothetical well through the deepest portion of Yukon Flats basin. They differ from each other in the thicknesses of Upper Cretaceous and Cenozoic strata, the timing of initial basin subsidence, and the timing of inferred unconformities. The burial modeling results suggest a present-day depth to the oil window of approximately 6,000 feet.

Alaska

Estimating the amount of eroded section in a partially exhumed basin from geophysical well logs: An example from the North Slope

The reconstruction of burial and thermal histories of partially exhumed basins requires an estimation of the amount of erosion that has occurred since the time of maximum burial. We have developed a method for estimating eroded thickness by using porosity-depth trends derived from borehole sonic logs of wells in the Colville Basin of northern Alaska. Porosity-depth functions defined from sonic-porosity logs in wells drilled in minimally eroded parts of the basin provide a baseline for comparison with the porosity-depth trends observed in other wells across the basin. Calculated porosities, based on porosity-depth functions, were fitted to the observed data in each well by varying the amount of section assumed to have been eroded from the top of the sedimentary column. The result is an estimate of denudation at the wellsite since the time of maximum sediment accumulation. Alternative methods of estimating exhumation include fission-track analysis and projection of trendlines through vitrinite-reflectance profiles. In the Colville Basin, the methodology described here provides results generally similar to those from fission-track analysis and vitrinite-reflectance profiles, but with greatly improved spatial resolution relative to the published fission-track data and with improved reliability relative to the vitrinite-reflectance data. In addition, the exhumation estimates derived from sonic-porosity logs are independent of the thermal evolution of the basin, allowing these estimates to be used as independent variables in thermal-history modeling.

Alaska

USGS assessment of undiscovered oil and gas resources in Paleogene strata of the U.S. Gulf of Mexico coastal plain and state waters

This report presents a review of the U.S. Geological Survey ( USGS ) 2007 assessment of the undiscovered oil and gas resources in Paleogene strata underlying the U.S. Gulf of Mexico Coastal Plain and state waters. Geochemical, geologic, geophysical, thermal maturation, burial history, and paleontologic studies have been combined with regional cross sections and data from previous USGS petroleum assessments have helped to define the major petroleum systems and assessment units. Accumulations of both conventional oil and gas and continuous coal-bed gas within these petroleum systems have been digitally mapped and evaluated, and undiscovered resources have been assessed following USGS methodology. The primary source intervals for oil and gas in Paleogene (and Cenozoic) reservoirs are coal and shale rich in organic matter within the Wilcox Group (Paleocene-Eocene) and Sparta Formation of the Claiborne Group (Eocene); in addition, Cretaceous and Jurassic source rocks probably have contributed substantial petroleum to Paleogene (and Cenozoic) reservoirs. For the purposes of the assessment, Paleogene strata have divided into the following four stratigraphic study intervals: (1) Wilcox Group (including the Midway Group and the basal Carrizo Sand of the Claiborne Group; Paleocene-Eocene); (2) Claiborne Group (Eocene); (3) Jackson and Vicksburg Groups (Eocene-Oligocene); and (4) the Frio-Anahuac Formations (Oligocene). Recent discoveries of coal-bed gas in Paleocene strata confirm a new petroleum system that was not recognized in previous USGS assessments. In total, 26 conventional Paleogene assessment units are defined. In addition, four Cretaceous-Paleogene continuous (coal-bed gas) assessment units are included in this report. Initial results of the assessment will be released as USGS Fact Sheets (not available at the time of this writing). Comprehensive reports for each assessment unit are planned to be released via the internet and distributed on CD-ROMs within the next year.

U.S. Gulf Coast

Burial and thermal history of the central Appalachian basin, based on three 2-D models of Ohio, Pennsylvania, and West Virginia

Introduction: Three regional-scale, cross sectional (2-D) burial and thermal history models are presented for the central Appalachian basin based on the detailed geologic cross sections of Ryder and others (2004), Crangle and others (2005), and Ryder, R.T., written communication. The models integrate the available thermal and geologic information to constrain the burial, uplift, and erosion history of the region. The models are restricted to the relatively undeformed part of the basin and extend from the Rome trough in West Virginia and Pennsylvania northwestward to the Findlay arch in Ohio. This study expands the scope of previous work by Rowan and others (2004) which presented a preliminary burial/thermal history model for a cross section (E-E') through West Virginia and Ohio. In the current study, the burial/thermal history model for E-E' is revised, and integrated with results of two additional cross sectional models (D-D' and C-C'). The burial/thermal history models provide calculated thermal maturity (Ro%) values for the entire stratigraphic sequence, including hydrocarbon source rocks, along each of the three cross sections. In contrast, the Ro and conodont CAI data available in the literature are sparse and limited to specific stratigraphic intervals. The burial/thermal history models also provide the regional temperature and pressure framework that is needed to model hydrocarbon migration.

Open-File Report

Sandstone and shale compaction curves derived from sonic and gamma ray logs in offshore wells, North Slope, Alaska– Parameters for basin modeling

Representative compaction curves for the principle lithologies are essential input for reliable models of basin history. Compaction curves influence estimates of maximum burial and erosion. Different compaction curves may produce significantly different thermal histories. Default compaction curves provided by basin modeling packages may or may not be a good proxy for the compaction properties in a given area. Compaction curves in the published literature span a wide range, even within one lithology, e.g., sandstone (see Panel 3). An abundance of geophysical well data for the North Slope, from both government and private sources, provides us with an unusually good opportunity to develop compaction curves for the Cretaceous-Tertiary Brookian sandstones, siltstones, and shales. We examined the sonic and gamma ray logs from 19 offshore wells (see map), where significant erosion is least likely to have occurred. Our data are primarily from the Cretaceous-Tertiary Brookian sequence and are less complete for older sequences. For each well, the fraction of shale (Vsh) at a given depth was estimated from the gamma ray log, and porosity was computed from sonic travel time. By compositing porosities for the near-pure sand (Vsh<1%) and shale (Vsh>99%)from many individual wells we obtained data over sufficient depth intervals to define sandstone and shale 'master' compaction curves. A siltstone curve was defined using the sonic-derived porosities for Vsh values of 50%. These compaction curves generally match most of the sonic porosities with an error of 5% or less. Onshore, the curves are used to estimate the depth of maximum burial at the end of Brookian sedimentation. The depth of sonic-derived porosity profiles is adjusted to give the best match with the 'master' compaction curves. The amount of the depth adjustment is the erosion estimate. Using our compaction curves, erosion estimates on the North Slope range from zero in much of the offshore, to as much as 1500 ft along the coast, and to more than 10,000 ft in the foothills (Panel 3). Compaction curves provide an alternative to vitrinite reflectance for estimating erosion. Vitrinite reflectance data are often very sparse in contrast to well log data and are subject to inconsistencies when measurements are made by different labs. The phenomenon of 'recycling' can also make the reflectance values of dispersed vitrinite problematic for quantifying erosion. Recycling is suspected in dispersed vitrinite in North Slope rocks, particularly in the younger, Cretaceous-Tertiary section. The compaction curves defined here are being integrated into our burial history and thermal models to determine the timing of source rock maturation. An example on Panel 3 shows the results of calculating the maturity of the Shublik Fm. at the Tulaga well using two different sets of shale and siltstone compaction curves. Finally, accurate compaction curves improve a model's ability to realistically simulate the pressure regime during burial, including overpressures.

Alaska