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Geology topics

Edward A. du Bray

Publications and source records attributed to Edward A. du Bray.

At least 19 recordsLinked to original sources

Petrology and geochronology of 1.48 to 1.45 Ga igneous rocks in the St. Francois Mountains terrane, southeast Missouri

The igneous geology of the St. Francois Mountains terrane in southeast Missouri is dominated by the products of 1.48 to 1.45 billion year old volcanic and plutonic magmatism but also includes volumetrically minor, compositionally bimodal contributions added during plutonism between 1.34 and 1.27 billion years ago. The 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane are bimodally distributed between volumetrically dominant felsic rocks and volumetrically minor rocks with mafic to intermediate compositions. All of these rocks are ferroan, which like most of their trace element abundances, suggests a genesis associated with farfield intraplate extensional tectonism and decompression-related magmatism. The diversity of compositions among 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane probably reflects mixtures of mantle-derived mafic inputs and low-degree partial melting of more evolved crustal protoliths. Newly determined ages define essentially continuous magmatism during the 30-million-year period between 1.48 and 1.45 billion years ago. The products of this magmatism are essentially coeval, whether intrusive or extrusive or having mafic, intermediate, or felsic compositions. In addition, the iron oxide-apatite (for example, Pea Ridge) and likely the iron oxide-copper gold (Boss) deposits in the St. Francois Mountains terrane have ages coincident with this magmatic episode. Spatial and temporal relations between 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane and the mineral deposits they host suggest the associated magmatic and mineralization processes are also genetically related. Geochemical, petrographic, geochronologic, and terrane-wide physical characteristics of the 1.48 to 1.45 billion year old igneous rocks in the St. Francois Mountains terrane are consistent with an origin involving extension well inboard from the margin of the Laurentian craton, associated mantle upwelling, lower crustal melting in response to mantle-derived thermal inputs, and mixing of mantle- and juvenile lower crustal-derived melts. Significant major and trace element compositional dispersion characteristics of these rocks likely reflect midcrustal magma reservoir fractionation of their principal rock-forming minerals. The resultant magmas constitute a series of variably hybridized reservoirs, emplaced at upper levels in the crust, that form a series of plutonic and associated eruptive products.

Missouri

Petrology of volcanic rocks associated with silver-gold (Ag-Au) epithermal deposits in the Tonopah, Divide, and Goldfield Mining Districts, Nevada

Miocene calc-alkaline volcanic rocks, part of the southern segment of the ancestral Cascades magmatic arc, are spatially, temporally, and likely genetically associated with precious metal epithermal deposits in the Tonopah, Divide, and Goldfield Districts of west-central Nevada. In the Tonopah mining district, volcanic rocks include the Mizpah Trachyte, Fraction Tuff, and Oddie Rhyolite; in the Divide mining district, they include the Heller Tuff, Brougher Rhyolite, trachyandesite of Red Mountain, Divide Andesite, and volcanics of Donovan Peak (which includes rhyolite, dacite, and rhyodacite units); in the Goldfield mining district they include the Milltown Andesite, an unnamed porphyritic andesite, and latite. All these rocks are porphyritic and contain phenocryst assemblages that include plagioclase, pyroxene, hornblende, biotite, quartz, alkali feldspar, and olivine. These mostly subalkaline, metaluminous, calc-alkalic, and magnesian rocks range from basaltic trachyandesite to rhyolite and contain 54 to 78 weight percent silicon dioxide. In the Divide mining district, the Divide Andesite and the volcanics of Donovan Peak are compositionally distinct from volcanic rocks in the other two mining districts. These rocks define a somewhat more restricted range of silicon dioxide content; are more alkalic; have greater titanium dioxide, sodium oxide, barium, hafnium, lanthanum, niobium, tantalum, yttrium, ytterbium, and zirconium abundances; and lower magnesium oxide, strontium, and vanadium abundances. Elevated zirconium contents are particularly characteristic of these rocks, which are also distinctly younger than most of the rocks in the other two mining districts. The alkalic character (principally higher sodium oxide abundances) and elevated zirconium contents characteristic of the Divide Andesite and the volcanics of Donovan Peak suggest that distinctive sources and (or) processes contributed to the petrogenesis of these rocks. In the Tonopah, Divide, and Goldfield mining districts the geochemistry of Oligocene and Miocene volcanic rocks constrain the processes that contributed to the petrogenesis of these rocks. Specifically, major oxide compositional variation among these rocks is consistent with crystallization and fractionation of the observed phenocryst minerals. In addition, these rocks have negatively sloping rare-earth element patterns consistent with partial melting in a high-pressure, garnet stable regime. Elevated strontium concentrations and small negative europium anomalies are consistent with partial melting in a plagioclase-unstable setting. However, larger negative europium anomalies among the more silica-rich volcanic rocks indicates a progressively greater role for plagioclase fractionation among these rocks. The importance of hornblende in the petrogenesis of these rocks is reflected in subtly U-shaped middle rare-earth element pattern segments. Increasing lead/cerium and decreasing phosphorus pentoxide/potassium oxide with increasing silicon dioxide are characteristic of these volcanic rocks. These characteristics and their distinctive pre-Cenozoic xenolith content suggest a significant role for crustal contamination in their petrogenesis. Diagnostic textural features preserved by phenocrysts, especially plagioclase, constitute additional evidence that open-system behavior, including reservoir-scale mixing, recharge, and assimilation, was critical to the petrogenesis of volcanic rocks in the Tonopah, Divide, and Goldfield mining districts.

Nevada

Petrographic, geochemical, and geochronologic data for cenozoic volcanic rocks of the Tonopah, Divide, and Goldfield Mining Districts, Nevada

The purpose of this report is to summarize geochemical, petrographic, and geochronologic data for samples, principally those of unmineralized Tertiary volcanic rocks, from the Tonopah, Divide, and Goldfield mining districts of west-central Nevada (fig. 1). Much of the data presented here for the Tonopah and Divide districts are for samples collected by Bonham and Garside (1979) during geologic mapping in and around those districts, whereas much of that for samples from the Goldfield district were obtained by Ashley (1974; 1979; 1990a). Additional data were derived from samples collected between 2012–2015, as part of the Mineral Resources Program funded project titled: “Magmatic-tectonic history and component sources of major precious metal deposits in the southern Walker Lane”. A small amount of additional geochemical data for samples from each of the districts were compiled from other sources. Individual sample collectors are identified by appropriate entries in the “Collector” field (appendix 1) and published sources of geochemical data are defined by entries in the “Chem_Src” data field (appendix 1).

California, Nevada

Characterization of the rhyolite of Bodie Hills and 40Ar/39Ar intercalibration with Ar mineral standards

The rhyolite of Bodie Hills (California) is characterized compositionally and the geochronology of selected phases is studied. Sanidine (BHs) from the rhyolite is well suited as a 40 Ar/ 39 Ar reference material with high K/Ca and radiogenic yield. Intercalibration with GA1550 biotite from the Dromedary igneous complex (New South Wales, Australia) yields an age of 9.7946 ± 0.0031 Ma for BHs relative to an age of 98.79 ± 0.54 Ma for GA1550 and a calibration factor ( R BHs/GA1550 ) of 0.096719 ± 0.000032. BHs is also intercalibrated with sanidines of the Taylor Creek Rhyolite (TCs; R TCs/BHs of 2.90874 ± 0.00067), Fish Canyon Tuff (FCs; R FCs/BHs of 2.88339 ± 0.00088), and rhyolite of Alder Creek (ACs; R ACs/BHs of 0.12028 ± 0.00024). These calibration factors yield ages of 28.344 ± 0.011 Ma, 28.099 ± 0.013 Ma, and 1.1809 ± 0.0024 Ma for TCs, FCs, and ACs, respectively, relative to GA1550. Full propagation of errors increases these uncertainties and that of BHs to ±0.9% of their ages. Calibration of BHs using the astronomically tuned age of FCs determined by Kuiper et al. (2008) yields an age of 9.8295 ± 0.0036 Ma. Stepwise heating of BHs reveals the same small, progressive increase in age across the age spectrum reported for FCs, ACs, and other potassium feldspars (e.g., Foland and Xu, 1990; Phillips et al., 2017). This increase is consistent with mass fractionation of argon during step heating and favors use of single-step fusion ages of all sanidines for monitor and calibration purposes.

Chemical Geology

Descriptive models for epithermal gold-silver deposits

Epithermal gold-silver deposits are vein, stockwork, disseminated, and replacement deposits that are mined primarily for their gold and silver contents; some deposits also contain substantial resources of lead, zinc, copper, and (or) mercury. These deposits form in the uppermost parts of the crust, at depths less than about 1,500 meters below the water table, and at temperatures below about 300 °C. Most epithermal gold-silver deposits are genetically related to hydrothermal systems associated with subaerial volcanism and intrusion of calc-alkaline magmas along convergent plate margins. These deposits formed throughout most of geologic time, although most known deposits are Cenozoic, which reflects preferential preservation of these shallowly formed deposits in tectonically unstable regions. Epithermal gold-silver deposits range in size from tens of thousands to greater than 1 billion metric tons of ore and have gold contents of 0.1 to greater than 30 grams per metric ton and silver contents of less than 1 to several thousand grams per metric ton. Historically, these deposits have been an important source of gold and silver and are estimated to contain about 8 percent of global gold. The wide range of tonnage-grade characteristics makes epithermal gold-silver deposits an attractive target for small and large exploration and mining companies. This report constitutes a new descriptive model for epithermal gold-silver deposits. It summarizes characteristics of known deposits, including their geological, geophysical, geochemical, and geoenvironmental aspects. Models concerning the genesis of epithermal gold-silver deposits are discussed. The application of descriptive and genetic aspects of the model to mineral exploration and resource assessment of undiscovered deposits is described. Finally, areas where additional research is needed to better understand the genesis of these deposits are identified. An extensive summary table outlining the characteristics of about 100 epithermal gold-silver deposits is included as an appendix; this summary table includes most of the world’s largest epithermal gold-silver deposits, and many smaller, well-studied deposits.

Scientific Investigations Report

Compilation of new and previously published geochemical and modal data for Mesoproterozoic igneous rocks of the St. Francois Mountains, southeast Missouri

The purpose of this report is to present recently acquired as well as previously published geochemical and modal petrographic data for igneous rocks in the St. Francois Mountains, southeast Missouri, as part of an ongoing effort to understand the regional geology and ore deposits of the Mesoproterozoic basement rocks of southeast Missouri, USA. The report includes geochemical data that is (1) newly acquired by the U.S. Geological Survey and (2) compiled from numerous sources published during the last fifty-five years. These data are required for ongoing petrogenetic investigations of these rocks. Voluminous Mesoproterozoic igneous rocks in the St. Francois Mountains of southeast Missouri constitute the basement buried beneath Paleozoic sedimentary rock that is over 600 meters thick in places. The Mesoproterozoic rocks of southeast Missouri represent a significant component of approximately 1.4 billion-year-old (Ga) igneous rocks that crop out extensively in North America along the southeast margin of Laurentia and subsequent researchers suggested that iron oxide-copper deposits in the St. Francois Mountains are genetically associated with ca. 1.4 Ga magmatism in this region. The geochemical and modal data sets described herein were compiled to support investigations concerning the tectonic setting and petrologic processes responsible for the associated magmatism.

Missouri

Review of the geochemistry and metallogeny of approximately 1.4 Ga granitoid intrusions of the conterminous United States

The conterminous United States hosts numerous volumetrically significant and geographically dispersed granitoid intrusions that range in age from 1.50 to 1.32 billion years before present (Ga). Although previously referred to as A-type granites, most are better described as ferroan granites. These granitoid intrusions are distributed in the northern and central Rocky Mountains, the Southwest, the northern midcontinent, and a swath largely buried beneath Phanerozoic cover across the Great Plains and into the southern midcontinent. These intrusions, with ages that are bimodally distributed between about 1.455–1.405 Ga and 1.405–1.320 Ga, are dispersed nonsystematically with respect to age across their spatial extents. Globally, although A-type or ferroan granites are genetically associated with rare-metal deposits, most U.S. 1.4 Ga granitoid intrusions do not contain significant deposits. Exceptions are the light rare-earth element deposit at Mountain Pass, California, and the iron oxide-apatite and iron oxide-copper-gold deposits in southeast Missouri. Most of the U.S. 1.4 Ga granitoid intrusions are composed of hornblende ± biotite or biotite ± muscovite monzogranite, commonly with prominent alkali feldspar megacrysts; however, modal compositions vary widely. These intrusions include six of the eight commonly identified subtypes of ferroan granite: alkali-calcic and calc-alkalic peraluminous subtypes; alkalic, alkali-calcic, and calc-alkalic metaluminous subtypes; and the alkalic peralkaline subtype. The U.S. 1.4 Ga granitoid intrusions also include variants of these subtypes that have weakly magnesian compositions. Extreme large-ion lithophile element enrichments typical of ferroan granites elsewhere are absent among these intrusions. Chondrite-normalized rare-earth element patterns for these intrusions have modest negative slopes and moderately developed negative europium anomalies. Their radiogenic isotopic compositions are consistent with mixing involving primitive, mantle-derived components and evolved, crust-derived components. Each compositional subtype can be ascribed to a relatively unique petrogenetic history. The numerically dominant ferroan, peraluminous granites probably represent low-degree, relatively high-pressure partial melting of preexisting, crust-derived, intermediate-composition granitoids. The moderately numerous, weakly magnesian, peraluminous granites probably reflect similar partial melting but at a higher degree and in a lower pressure environment. In contrast, the ferroan but metaluminous granites may be the result of extensive differentiation of tholeiitic basalt. Finally, the peralkaline igneous rocks at Mountain Pass have compositions potentially derived by differentiation of alkali basalt. The varying alkalic character of each subtype probably reflects polybaric petrogenesis and the corresponding effect of diverse mineral stabilities on ultimate melt compositions. Mantle-derived mafic magma and variably assimilated partial melts of mainly juvenile Paleoproterozoic crustal components are required to generate the relatively low initial strontium (87Sr/86Sr) and distinctive neodymium isotope compositions characteristic of the U.S. 1.4 Ga granitoid intrusions. The characteristics of these intrusions are consistent with crustal melting in an extensional/decompressional, intracratonic setting that was triggered by mantle upwelling and emplacement of tholeiitic basaltic magma at or near the base of the crust. Composite magmas, formed by mingling and mixing mantle components with partial melts of Paleoproterozoic crust, produced variably homogenized storage reservoirs that continued polybaric evolution as intrusions lodged at various crustal depths.

Scientific Investigations Report

Isotopic data for Late Cretaceous intrusions and associated altered and mineralized rocks in the Big Belt Mountains, Montana

The quartz monzodiorite of Mount Edith and the concentrically zoned intrusive suite of Boulder Baldy constitute the principal Late Cretaceous igneous intrusions hosted by Mesoproterozoic sedimentary rocks of the Newland Formation in the Big Belt Mountains, Montana. These calc-alkaline plutonic masses are manifestations of subduction-related magmatism that prevailed along the western edge of North America during the Cretaceous. Radiogenic isotope data for neodymium, strontium, and lead indicate that the petrogenesis of the associated magmas involved a combination of (1) sources that were compositionally heterogeneous at the scale of the geographically restricted intrusive rocks in the Big Belt Mountains and (2) variable contamination by crustal assimilants also having diverse isotopic compositions. Altered and mineralized rocks temporally, spatially, and genetically related to these intrusions manifest at least two isotopically distinct mineralizing events, both of which involve major inputs from spatially associated Late Cretaceous igneous rocks. Alteration and mineralization of rock associated with the intrusive suite of Boulder Baldy requires a component characterized by significantly more radiogenic strontium than that characteristic of the associated igneous rocks. However, the source of such a component was not identified in the Big Belt Mountains. Similarly, altered and mineralized rocks associated with the quartz monzodiorite of Mount Edith include a component characterized by significantly more radiogenic strontium and lead, particularly as defined by 207 Pb/ 204 Pb values. The source of this component appears to be fluids that equilibrated with proximal Newland Formation rocks. Oxygen isotope data for rocks of the intrusive suite of Boulder Baldy are similar to those of subduction-related magmatism that include mantle-derived components; oxygen isotope data for altered and mineralized equivalents are slightly lighter.

Montana

Geochemical characteristics of igneous rocks associated with epithermal mineral deposits—A review

Newly synthesized data indicate that the geochemistry of igneous rocks associated with epithermal mineral deposits varies extensively and continuously from subalkaline basaltic to rhyolitic compositions. Trace element and isotopic data for these rocks are consistent with subduction-related magmatism and suggest that the primary source magmas were generated by partial melting of the mantle-wedge above subducting oceanic slabs. Broad geochemical and petrographic diversity of individual igneous rock units associated with epithermal deposits indicate that the associated magmas evolved by open-system processes. Following migration to shallow crustal reservoirs, these magmas evolved by assimilation, recharge, and partial homogenization; these processes contribute to arc magmatism worldwide. Although epithermal deposits with the largest Au and Ag production are associated with felsic to intermediate composition igneous rocks, demonstrable relationships between magmas having any particular composition and epithermal deposit genesis are completely absent because the composition of igneous rock units associated with epithermal deposits ranges from basalt to rhyolite. Consequently, igneous rock compositions do not constitute effective exploration criteria with respect to identification of terranes prospective for epithermal deposit formation. However, the close spatial and temporal association of igneous rocks and epithermal deposits does suggest a mutual genetic relationship. Igneous systems likely contribute heat and some of the fluids and metals involved in epithermal deposit formation. Accordingly, deposit formation requires optimization of source metal contents, appropriate fluid compositions and characteristics, structural features conducive to hydrothermal fluid flow and confinement, and receptive host rocks, but not magmas with special compositional characteristics.

Ore Geology Reviews

Geology and mineral resources of the Sheldon-Hart Mountain National Wildlife Refuge Complex (Oregon and Nevada), the Southeastern Oregon and North-Central Nevada, and the Southern Idaho and Northern Nevada (and Utah) Sagebrush Focal Areas: Chapter B in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming

Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of selected locatable minerals in lands proposed for withdrawal that span the Nevada, Oregon, Idaho, and Utah borders. In this report, the four study areas evaluated were (1) the Sheldon-Hart Mountain National Wildlife Refuge Complex SFA in Washoe County, Nevada, and Harney and Lake Counties, Oregon; (2) the Southeastern Oregon and North-Central Nevada SFA in Humboldt County, Nevada, and Harney and Malheur Counties, Oregon; (3) the Southern Idaho and Northern Nevada SFA in Cassia, Owyhee, and Twin Falls Counties, Idaho, Elko County, Nevada, and Box Elder County, Utah; and (4) the Nevada additions in Humboldt and Elko Counties, Nevada.

Idaho, Nevada, Oregon, Utah

Geochemistry, petrologic evolution, and ore deposits of the Miocene Bodie Hills Volcanic Field, California and Nevada

The southern segment of the ancestral Cascades magmatic arc includes numerous volcanic fields; among these, the Bodie Hills volcanic field (BHVF), astride the California-Nevada border north of Mono Lake, is one of the largest (>700 km2) and most well studied. Episodic magmatism in the BHVF spanned about 9 million years between about 15 and 6 Ma; magmatic output was greatest between ca. 15.0 to 12.6 Ma and ca. 9.9 to 8.0 Ma. About two dozen contiguous and coalescing eruptive centers above middle- to shallow-crustal-level reservoirs generated several trachyandesite stratovolcanoes and numerous silicic trachyandesite to rhyolite flow dome complexes whose compositional variations are consistent with fractionation of observed phenocryst phases. BHVF rocks have high-potassium calc-alkaline compositions consistent with generation of subduction-related continental margin arc magmas beneath thick continental crust. Radiogenic isotope ratios in BHVF rocks vary considerably but suggest somewhat enriched, crustal sources; isotopic ratios for some of the more primitive units are consistent with more depleted, mantle sources. Neither age nor whole-rock compositions of BHVF rocks are well correlated with isotopic variations. Textures and compositions of phenocrysts in BHVF rocks are in accord with the associated magma reservoirs evolving via open-system behavior. Reservoir recharge and subsequent incomplete homogenization are evidenced by the broad compositional diversity characteristic of many BHVF eruptive units. Significant compositional diversity among the products of coeval eruptive centers further suggests that centers responsible for BHVF magmatism were underlain by small, discrete, compositionally distinct, and closely spaced reservoirs. Volcanic rocks of the BHVF host quartz-adularia and quartz-alunite epithermal gold-silver deposits, from which about 3.4 Moz. of gold and 28 Moz. of silver have been produced. The volcanic rocks and contained deposits are broadly coeval, which suggests that the associated magmas are the sources of heat, fluids, and metals involved in deposit genesis. Characteristics of the quartz-adularia deposits are consistent with derivation from near-neutral pH fluids at ≤250 °C, whereas those of the quartz-alunite systems require more acidic, oxidized, and sulfur-rich fluids at temperatures <250 °C. Economically viable precious metal accumulations are in fault-hosted vein deposits in the Bodie and Aurora districts. Circulation of hydrothermal fluids through permeable pyroclastic deposits but lacking prominent structural conduits resulted in large areas of altered but unmineralized rock.

California, Nevada

Gold-silver mining districts, alteration zones, and paleolandforms in the Miocene Bodie Hills Volcanic Field, California and Nevada

The Bodie Hills is a ~40 by ~30 kilometer volcanic field that straddles the California-Nevada state boundary between Mono Lake and the East Walker River. Three precious metal mining districts and nine alteration zones are delineated in Tertiary-Quaternary volcanic and Mesozoic granitic and metamorphic rocks that comprise the volcanic field. Cumulative production from the mining districts, Bodie, Aurora, and Masonic, is 3.4 million ounces of gold and 28 million ounces of silver. Small amounts of mercury were produced from the Potato Peak, Paramount-Bald Peak, and Cinnabar Canyon-US 395 alteration zones; a native sulfur resource in the Cinnabar Canyon-US 395 alteration zone has been identified by drilling. There are no known mineral resources in the other six alteration zones, Red Wash-East Walker River, East Brawley Peak, Sawtooth Ridge, Aurora Canyon, Four Corners, and Spring Peak. The mining districts and alteration zones formed between 13.4 and 8.1 Ma in predominantly ~15&ndash;9 Ma volcanic rocks of the Bodie Hills volcanic field. Ages of hydrothermal minerals in the districts and zones are the same as, or somewhat younger than, the ages of volcanic host rocks. Based on volcanic stratigraphy, geochronology, remnant paleosurfaces, and paleopotentiometric surfaces in mining districts and alteration zones, present landforms in the Bodie Hills volcanic field reflect incremental construction of stratovolcanoes and large- to small-volume flow-domes, magmatic inflation, and fault displacements. Landform evolution began with construction of the 15&ndash;13 Ma Masonic and 13&ndash;12 Ma Aurora volcanic centers in the northwestern and northeastern parts of the field, respectively. Smaller volcanoes erupted at ~11&ndash;10 Ma in, between, and south of these centers as erosional detritus accumulated north of the field in Fletcher Valley. Distally sourced, 9.7&ndash;9.3 Ma Eureka Valley Tuff filled drainages and depressions among older volcanoes and was partly covered by nearly synchronous eruptives during construction of four large 10&ndash;8 Ma volcanoes, in the southern part of the field. The lack of significant internal fault displacement, distribution of Eureka Valley Tuff, and elevation estimates derived from floras, suggest that the Bodie Hills volcanic field attained present elevations mostly through volcano construction and magmatic inflation, and that maximum paleoelevations (>8,500 ft) at the end of large volume eruptions at ~8 Ma are similar to present elevations.

California, Nevada

Book review: Large igneous provinces

This book presents a comprehensive compilation of all aspects of large igneous provinces (LIPs). Published in 2014, the book is now the definitive source of information on the petrogenesis of this type of globally important, voluminous magmatic activity. In the first few pages, LIPs are characterized as magmatic provinces with areal extents >0.1 Mkm 2 that are dominated by mafic magmas emplaced or erupted in intraplate settings during relatively short (1&ndash;5 m.y.) time intervals. Given these parameters, particularly areal extent, LIPs clearly represent significant contributions to global geologic evolution through time. This point is underscored, also in the introductory chapter, by a series of figures that aptly characterize the global time-space distribution of LIPs; an accompanying, particularly useful table identifies individual LIPs, quantifies their basic characteristics, and enumerates pertinent references. Accordingly, this compilation is a welcome addition to the geologic literature. Review info: Large Igneous Provinces . By Richard E. Ernst . 2014 . ISBN 978-0-521-87177-8. 653 pp.

Economic Geology

Geochemical, modal, and geochronologic data for 1.4 Ga A-type granitoid intrusions of the conterminous United States

Introduction The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K 2 O and K 2 O/Na 2 O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2&ndash;10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson&rsquo;s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall&rsquo;Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

Data Series

Rare earth elements in sedimentary phosphate deposits: Solution to the global REE crisis?

The critical role of rare earth elements (REEs), particularly heavy REEs (HREEs), in high-tech industries has created a surge in demand that is quickly outstripping known global supply and has triggered a worldwide scramble to discover new sources. The chemical analysis of 23 sedimentary phosphate deposits (phosphorites) in the United States demonstrates that they are significantly enriched in REEs. Leaching experiments using dilute H 2 SO 4 and HCl, extracted nearly 100% of their total REE content and show that the extraction of REEs from phosphorites is not subject to the many technological and environmental challenges that vex the exploitation of many identified REE deposits. Our data suggest that phosphate rock currently mined in the United States has the potential to produce a significant proportion of the world's REE demand as a byproduct. Importantly, the size and concentration of HREEs in some unmined phosphorites dwarf the world's richest REE deposits. Secular variation in phosphate REE contents identifies geologic time periods favorable for the formation of currently unrecognized high-REE phosphates. The extraordinary endowment, combined with the ease of REE extraction, indicates that such phosphorites might be considered as a primary source of REEs with the potential to resolve the global REE (particularly for HREE) supply shortage.

Gondwana Research

Geochemical and petrographic data for intrusions peripheral to the Big Timber Stock, Crazy Mountains, Montana

The Paleocene Fort Union Formation hosts a compositionally diverse array of Eocene plugs, dikes, and sills arrayed around the Eocene Big Timber stock in the Crazy Mountains of south-central Montana. The geochemistry and petrography of the sills have not previously been characterized or interpreted. The purpose of this report is (1) to present available geochemical and petrographic data for several dozen samples of these rocks and (2) to provide a basic interpretive synthesis of these data.

Montana

Geochronology of Cenozoic rocks in the Bodie Hills, California and Nevada

The purpose of this report is to present geochronologic data for unaltered volcanic rocks, hydrothermally altered volcanic rocks, and mineral deposits of the Miocene Bodie Hills and Pliocene to Pleistocene Aurora volcanic fields of east-central California and west-central Nevada. Most of the data presented here were derived from samples collected between 2000&ndash;13, but some of the geochronologic data, compiled from a variety of sources, pertain to samples collected during prior investigations. New data presented here (tables 1 and 2; Appendixes 1&ndash;3) were acquired in three U.S. Geological Survey (USGS) 40 Ar/ 39 Ar labs by three different geochronologists: Robert J. Fleck (Menlo Park, CA), Lawrence W. Snee (Denver, CO), and Michael A. Cosca (Denver, CO). Analytical methods and data derived from each of these labs are presented separately. The middle to late Miocene Bodie Hills volcanic field (BHVF) is a large (>700 km 2 ), long-lived (~9 million years [m.y.]), episodic eruptive complex (John and others, 2012) in the southern segment of the ancestral Cascades arc (du Bray and others, written commun., 2015) north of Mono Lake and east of Bridgeport, California (fig. 1). The field is near the west edge of the Walker Lane and the northwest edge of the Mina deflection where structures related to these shear zones may have localized magmatism. The Walker Lane (fig. 1) is a broad, northwest-striking zone of right-lateral shear that accommodates right-lateral motion between the Pacific and North America plates; the Mina deflection constitutes a 60-km-long right step in the Walker Lane (Faulds and Henry, 2008; Oldow, 1992, 2003; Stewart, 1988). The Bodie Hills volcanic field includes at least 31 volcanic rock units erupted from 21 significant volcanic eruptive centers. Four trachyandesite stratovolcanoes developed along the margins of the volcanic field and numerous silicic trachyandesite to rhyolite flow dome complexes erupted more centrally. Volcanism in the Bodie Hills volcanic field peaked at two periods, ~15.0 to 12.6 million years before present (Ma) and ~9.9 to 8.0 Ma, which were dominated by emplacement of large stratovolcanoes and large silicic trachyandesite-dacite lava domes, respectively. A final period of small-volume silicic dome emplacement began in the western part of the volcanic field at ~6 Ma and culminated at ~5.5 Ma (John and others, 2012).

California, Nevada

Geologic map of the Bodie Hills, California and Nevada

The Bodie Hills covers about 1,200 km 2 straddling the California-Nevada state boundary just north of Mono Lake in the western part of the Basin and Range Province, about 20 km east of the central Sierra Nevada. The area is mostly underlain by the partly overlapping, middle to late Miocene Bodie Hills volcanic field and Pliocene to late Pleistocene Aurora volcanic field (John and others, 2012). Upper Miocene to Pliocene sedimentary deposits, mostly basin-filling sediments, gravel deposits, and fanglomerates, lap onto the west, north, and east sides of the Bodie Hills, where they cover older Miocene volcanic rocks. Quaternary surficial deposits, including extensive colluvial, fluvial, glacial, and lacustrine deposits, locally cover all older rocks. Miocene and younger rocks are tilted &le;30&deg; in variable directions. These rocks are cut by several sets of high-angle faults that exhibit a temporal change from conjugate northeast-striking left-lateral and north-striking right-lateral oblique-slip faults in rocks older than about 9 Ma to north- and northwest-striking dip-slip faults in late Miocene rocks. The youngest faults are north-striking normal and northeast-striking left-lateral oblique-slip faults that cut Pliocene-Pleistocene rocks. Numerous hydrothermal systems were active during Miocene magmatism and formed extensive zones of hydrothermally altered rocks and several large mineral deposits, including gold- and silver-rich veins in the Bodie and Aurora mining districts (Vikre and others, in press).

California, Nevada