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Ed DeWitt

Publications and source records attributed to Ed DeWitt.

At least 19 recordsLinked to original sources

Geochemical, modal, and geochronologic data for 1.4 Ga A-type granitoid intrusions of the conterminous United States

Introduction The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K 2 O and K 2 O/Na 2 O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2–10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson’s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall’Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

Data Series

Basement domain map of the conterminous United States and Alaska

The basement-domain map is a compilation of basement domains in the conterminous United States and Alaska designed to be used at 1:5,000,000-scale, particularly as a base layer for national-scale mineral resource assessments. Seventy-seven basement domains are represented as eighty-three polygons on the map. The domains are based on interpretations of basement composition, origin, and architecture and developed from a variety of sources. Analysis of previously published basement, lithotectonic, and terrane maps as well as models of planetary development were used to formulate the concept of basement and the methodology of defining domains that spanned the ages of Archean to present but formed through different processes. The preliminary compilations for the study areas utilized these maps, national-scale gravity and aeromagnetic data, published and limited new age and isotopic data, limited new field investigations, and conventional geologic maps. Citation of the relevant source data for compilations and the source and types of original interpretation, as derived from different types of data, are provided in supporting descriptive text and tables. The tectonic settings for crustal types represented in the basement domains are subdivided into constituent geologic environments and the types of primary metals endowments and deposits in them are documented. The compositions, architecture, and original metals endowments are potentially important to assessments of primary mineral deposits and to the residence and recycling of metals in the crust of the United States portion of the North American continent. The databases can be configured to demonstrate the construction of the United States through time, to identify specific types of crust, or to identify domains potentially containing metal endowments of specific genetic types or endowed with specific metals. The databases can also be configured to illustrate other purposes chosen by users.

Data Series

Geochemical results from stream-water and stream-sediment samples collected in Colorado and New Mexico

Scientists from the U.S. Geological Survey are studying the relationship between watershed lithology and stream-water chemistry. As part of this effort, 60 stream-water samples and 43 corresponding stream-sediment samples were collected in 2010 and 2011 from locations in Colorado and New Mexico. Sample sites were selected from small to midsize watersheds composed of a high percentage of one rock type or geologic unit. Stream-water and stream-sediment samples were collected, processed, preserved, and analyzed in a consistent manner. This report releases geochemical data for this phase of the study.

Colorado;New Mexico

Using geochemistry to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: Part 2

Montezuma Well is a unique natural spring located in a sinkhole surrounded by travertine. Montezuma Well is managed by the National Park Service, and groundwater development in the area is a potential threat to the water source for Montezuma Well. This research was undertaken to better understand the sources of groundwater to Montezuma Well. Strontium isotopes ( 87 Sr/ 86 Sr) indicate that groundwater in the recharge area has flowed through surficial basalts with subsequent contact with the underlying Permian aged sandstones and the deeper, karstic, Mississippian Redwall Limestone. The distinctive geochemistry in Montezuma Well and nearby Soda Springs (higher concentrations of alkalinity, As, B, Cl, and Li) is coincident with added carbon dioxide and mantle-sourced He. The geochemistry and isotopic data from Montezuma Well and Soda Springs allow for the separation of groundwater samples into four categories: (1) upgradient, (2) deep groundwater with carbon dioxide, (3) shallow Verde Formation, and (4) mixing zone. δ 18 O and δD values, along with noble gas recharge elevation data, indicate that the higher elevation areas to the north and east of Montezuma Well are the groundwater recharge zones for Montezuma Well and most of the groundwater in this portion of the Verde Valley. Adjusted groundwater age dating using likely 14 C and δ 13 C sources indicate an age for Montezuma Well and Soda Springs groundwaters at 5,400–13,300 years, while shallow groundwater in the Verde Formation appears to be older (18,900). Based on water chemistry and isotopic evidence, groundwater flow to Montezuma Well is consistent with a hydrogeologic framework that indicates groundwater flow by (1) recharge in higher elevation basalts to the north and east of Montezuma Well, (2) movement through the upgradient Permian and Mississippian units, especially the Redwall Limestone, and (3) contact with a basalt dike/fracture system that provides a mechanism for groundwater to flow to the surface. While the exact nature of the groundwater flow connections is still uncertain, the available data indicate that flow to Montezuma Well may be more susceptible to future groundwater development in the Redwall Limestone than from any other geologic unit. Overall, the shallow groundwater in the surrounding Verde Formation appears to be largely disconnected from deeper groundwater flowing to Montezuma Well.

Arizona

Water and rock geochemistry, geologic cross sections, geochemical modeling, and groundwater flow modeling for identifying the source of groundwater to Montezuma Well, a natural spring in central Arizona

The National Park Service (NPS) seeks additional information to better understand the source(s) of groundwater and associated groundwater flow paths to Montezuma Well in Montezuma Castle National Monument, central Arizona. The source of water to Montezuma Well, a flowing sinkhole in a desert setting, is poorly understood. Water emerges from the middle limestone facies of the lacustrine Verde Formation, but the precise origin of the water and its travel path are largely unknown. Some have proposed artesian flow to Montezuma Well through the Supai Formation, which is exposed along the eastern margin of the Verde Valley and underlies the Verde Formation. The groundwater recharge zone likely lies above the floor of the Verde Valley somewhere to the north or east of Montezuma Well, where precipitation is more abundant. Additional data from groundwater, surface water, and bedrock geology are required for Montezuma Well and the surrounding region to test the current conceptual ideas, to provide new details on the groundwater flow in the area, and to assist in future management decisions. The results of this research will provide information for long-term water resource management and the protection of water rights.

Arizona

Geochemical database for the Boulder batholith and its satellitic plutons, Southwest Montana

Geochemical data presented in this report pertain to Cretaceous igneous intrusions of the Boulder batholith and its satellitic plutons in southwest Montana. The geographic area addressed in this compilation is approximately bounded by lats 45.6 deg and 46.7 deg N. and longs 112.75 deg and 111.5 deg W. These data were compiled in order to establish the geologic framework for world-class mineral deposits of the Butte district. Although these deposits and their host rocks have been the subject of many investigations, the petrologic characteristics of associated intrusive rocks have not been systematically compiled, synthesized, or interpreted. Abundant late Mesozoic intrusions in the study area are probably byproducts of subduction-related processes, including back-arc magmatism that prevailed along the west edge of the North American plate during this interval. The ultimate goal of this effort will be an evaluation of the time-space-compositional evolution of Mesozoic magmatism associated with the Boulder batholith and identification of genetic associations between magmatic and mineralizing processes in this region.

Data Series

Maps showing geology, structure, and geophysics of the central Black Hills, South Dakota

This 1:100,000-scale digital geologic map details the complex Early Proterozoic granitic rocks, Early Proterozoic supracrustal metamorphic rocks, and Archean crystalline basement of the Black Hills. The granitic rocks host pegmatite deposits renowned for their feldspar, mica, spodumene, and beryl. The supracrustal rocks host the Homestake gold mine, which produced more than 40 million ounces of gold over a 125-year lifetime. The map documents the Laramide deformation of Paleozoic and Mesozoic cover rocks; and shows the distribution of Laramide plutonic rocks associated with precious-metals deposits. Four 1:300,000-scale maps summarize Laramide structures; Early Proterozoic structures; aeromagnetic anomalies; and gravity anomalies. Three 1:500,000-scale maps show geophysical interpretations of buried Early Proterozoic to Archean rocks in western South Dakota and eastern Wyoming.

South Dakota

Geologic map of the Prescott National Forest and the headwaters of the Verde River, Yavapai and Coconino Counties, Arizona

This 1:100,000-scale digital geologic map details the complex Early Proterozoic metavolcanic and plutonic basement of north-central Arizona; shows the mildly deformed cover of Paleozoic rocks; reveals where Laramide to mid-Tertiary plutonic rocks associated with base- and precious-metals deposits are exposed; subdivides the Tertiary volcanic rocks according to chemically named units; and maps the Pliocene to Miocene fill of major basins. Associated digital files include more than 1,300 geochemical analyses of all rock units; 1,750 logs of water wells deeper than 300 feet; and interpreted logs of 300 wells that define the depth to basement in major basins. Geophysically interpreted buried features include normal faults defining previous unknown basins, mid-Tertiary intrusive rocks, and half-grabens within shallow bains.

Arizona

Geologic and aeromagnetic maps of the Fossil Ridge area and vicinity, Gunnison County, Colorado

This data set includes a GIS geologic map database of an Early Proterozoic metavolcanic and metasedimentary terrane extensively intruded by Early and Middle Proterozoic granitic plutons. Laramide to Tertiary deformation and intrusion of felsic plutons have created numerous small mineral deposits that are described in the tables and are shown on the figures in the accompanying text pamphlet. Also included in the pamphlet are numerous chemical analyses of igneous and meta-igneous bodies of all ages in tables and in summary geochemical diagrams. The text pamphlet also contains a detailed description of map units and discussions of the aeromagnetic survey, igneous and metmorphic rocks, and mineral deposits. The printed map sheet and browse graphic pdf file include the aeromagnetic map of the study area, as well as figures and photographs. Purpose: This GIS geologic map database is provided to facilitate the presentation and analysis of earth-science data for this region of Colorado. This digital map database may be displayed at any scale or projection. However, the geologic data in this coverage are not intended for use at a scale other than 1:30,000. Supplemental useful data accompanying the database are extensive geochemical and mineral deposits data, as well as an aeromagnetic map.

IMAP

Preliminary report on geophysical data in Yavapai County, Arizona

Recently acquired geophysical data provide information on the geologic framework and its effect of groundwater flow and on stream/aquifer interaction in Yavapai County, Arizona. High-resolution aeromagnetic data reflect diverse rock types at and below the topographic surface and have permitted a preliminary interpretation of faults and underlying rock types (in particular, volcanic) that will provide new insights on the geologic framework, critical input to future hydrologic investigations. Aeromagnetic data map the western end of the Bear Wallow Canyon fault into the sedimentary fill of Verde Valley. Regional gravity data indicate potentially significant accumulations of low-density basin fill in Big Chino, Verde, and Williamson Valleys. Electrical and seismic data were also collected and help evaluate the approximate depth and extent of recent alluvium overlying Tertiary and Paleozoic sediments. These data will be used to ascertain the potential contribution of shallow ground-water subflow that cannot be measured by gages or flow meters and whether stream flow in losing reaches is moving as subflow or is being lost to the subsurface. The geophysical data will help produce a more robust groundwater flow model of the region.

Arizona

Preliminary report on geophysics of the Verde River headwaters region, Arizona

This report summarizes the acquisition, data processing, and preliminary interpretation of a high-resolution aeromagnetic and radiometric survey near the confluence of the Big and Little Chino basins in the headwaters of the Verde River, Arizona. The goal of the aeromagnetic study is to improve understanding of the geologic framework as it affects groundwater flow, particularly in relation to the occurrence of springs in the upper Verde River headwaters region. Radiometric data were also collected to map surficial rocks and soils, thus aiding geologic mapping of the basin fill. Additional gravity data were collected to enhance existing coverage. Both aeromagnetic and gravity data indicate a large gradient along the Big Chino fault, a fault with Quaternary movement. Filtered aeromagnetic data show other possible faults within the basin fill and areas where volcanic rocks are shallowly buried. Gravity lows associated with Big Chino and Williamson Valleys indicate potentially significant accumulations of low-density basin fill. The absence of a gravity low associated with Little Chino Valley indicates that high-density rocks are shallow. The radiometric maps show higher radioactivity associated with the Tertiary latites and with the sediments derived from them. The surficial materials on the eastern side of the Big Chino Valley are significantly lower in radioactivity and reflect the materials derived from the limestone and basalt east of the valley. The dividing line between the low radioactivity materials to the east and the higher radioactiviy materials to the west coincides approximately with the major drainage system of the valley, locally known as Big Chino Wash. This feature is remarkably straight and is approximately parallel to the Big Chino Fault. The uranium map shows large areas with concentrations greater than 5 ppm eU, and we expect that these areas will have a significantly higher risk potential for indoor radon.

Arizona

Chronology of Late Cretaceous igneous and hydrothermal events at the Golden Sunlight gold-silver breccia pipe, southwestern Montana

Gold mineralization at the Golden Sunlight breccia pipe, southwestern Montana, is related to emplacement of Late Cretaceous alkali-calcic rhyolite and subsequent collapse of the Belt Supergroup wallrock and rhyolite in the pipe. The pipe is inferred to grade downward into an alkalic porphyry molybdenum system. The pipe is cut by alkalic to sub-alkalic lamprophyre dikes and sills, which locally contain high-grade gold where emplaced along late shear zones and vein systems. Determination of the emplacement age of the rhyolite is hampered by inherited lead or inherited Late Archean zircon from the source region of the rhyolite. An emplacement age of about 80 Ma for the rhyolite can be inferred if a basement age of 2,600 Ma is assumed. This Late Archean age is in agreement with basement ages determined in many parts of southwestern Montana. A 206 Pb- 238 U whole-rock date of 84 ? 18 Ma from altered and mineralized Belt Supergroup strata and rhyolite in the breccia pipe indicates hydrothermal alteration related to gold mineralization in Late Cretaceous time. Although sericite is a relatively widespread hydrothermal mineral, attempts to date the very fine grained material by the 40 Ar- 39 Ar method did not provide a spectra that could be interpreted unambiguously. A 40 Ar- 39 Ar plateau date of 76.9 ? 0.5 Ma from biotite phenocrysts in the lamprophyre indciates intrusion of mafic magma and attendant CO 2 metasomatism in the Late Cretaceous. Fission-track data from zircon in the rhyolite are permissive of slow uplift of the Belt Supergroup strata, 1U.S. Geological Survey, Box 25046, Denver Federal Center, Denver, CO 80225. 2Golden Sunlight Mines, Inc., 453 MT Highway 2 East, Whitehall, MT 59759. rhyolite, and lamprophyre between 55 and 50 Ma, but the data are not definitive. Rhyolitic welded tuff in the informally named units 7, 9, and 11 of the Elkhorn Mountains Volcanics is most similar in chemistry and age to the rhyolite at the Golden Sunlight mine. Trachybasalt in the Adel Mountains Volcanics and andesitic basalt in the informally named unit 8 of the Elkhorn Mountains Volcanics are the most analogous in chemistry and age to lamprophyres at the mine. The rhyolitic rocks appear to be derived from deep crustal sources, but data for the lamprophyres and mafic rocks in the Elkhorn Mountains Volcanics indicate that they were derived from the mantle.

Bulletin