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Daniel J Bain

Publications and source records attributed to Daniel J Bain.

3 recordsLinked to original sources

Seasonal drivers of chemical and hydrological patterns in roadside infiltration-based green infrastructure

Infiltration-based green infrastructure has become a popular means of reducing stormwater hazards in urban areas. However, the long-term effects of green infrastructure on the geochemistry of roadside environments are poorly defined, particularly given the considerable roadside legacy metal contamination from historic industrial activity and vehicle emissions (e.g., Pb). Most current research on green infrastructure geochemistry is restricted to time periods of less than a year or limited sets of chemical species. This further limits our understanding of systems that evolve over time and are subject to seasonal variability. Between 2016 and 2018, two infiltration trenches in Pittsburgh, PA, were monitored to determine infiltration rates and dissolved nutrient and metal content. The trench water was analyzed to characterize seasonal patterns in both trench function and chemistry. Shifting patterns in infiltration rate and geochemical activity show trends corresponding with seasonal changes. Trench function is dependent on the local water table, with the highest infiltration rates occurring when evapotranspiration is active and groundwater elevation is low. Two seasonal chemical patterns were identified. The first is driven by road salt application in the winter and interaction of the salt pulse increase Pb and Cu concentrations. The second is driven by the formation of summer reducing environments that increase dissolved Fe and Mn. These findings suggest that chemical and hydrological activity in infiltration-based green infrastructure varies seasonally and may remobilize legacy contamination.

Pennsylvania↗

Nitrogen isotopes as indicators of NOx source contributions to atmospheric nitrate deposition across the midwestern and northeastern United States

Global inputs of NO x are dominated by fossil fuel combustion from both stationary and vehicular sources and far exceed natural NO x sources. However, elucidating NO x sources to any given location remains a difficult challenge, despite the need for this information to develop sound regulatory and mitigation strategies. We present results from a regional-scale study of nitrogen isotopes (δ 15 N) in wet nitrate deposition across 33 sites in the midwestern and northeastern U.S. We demonstrate that spatial variations in δ 15 N are strongly correlated with NO x emissions from surrounding stationary sources and additionally that δ 15 N is more strongly correlated with surrounding stationary source NO x emissions than pH, SO 4 2- , or NO 3 - concentrations. Although emission inventories indicate that vehicle emissions are the dominant NO x source in the eastern U.S., our results suggest that wet NO 3 - deposition at sites in this study is strongly associated with NO x emissions from stationary sources. This suggests that large areas of the landscape potentially receive atmospheric NO y deposition inputs in excess of what one would infer from existing monitoring data alone. Moreover, we determined that spatial patterns in δ 15 N values are a robust indicator of stationary NO x contributions to wet NO 3 - deposition and hence a valuable complement to existing tools for assessing relationships between NO 3 - deposition, regional emission inventories, and for evaluating progress toward NO x reduction goals.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

Placing the pieces: Reconstructing the original property mosaic in a warrant and patent watershed

Recent research shows that land use history is an important determinant of current ecosystem function. In the United States, characterization of land use change following European settlement requires reconstruction of the original property mosaic. However, this task is difficult in unsystematically surveyed areas east of the Appalachian Mountains. The Gwynns Falls watershed (Baltimore, MD) was originally surveyed in the 1600-1700s under a system of warrants and patents (commonly known as ‘metes and bounds’). A method for the reconstruction and mapping of warrant and patent properties is presented and used to map the original property mosaic in the Gwynns Falls watershed. Using the mapped mosaic, the persistence of properties and property lines in the current Gwynns Falls landscape is considered. The results of this research indicate that as in agricultural areas, the original property lines in the Gwynns Falls watershed are persistent. At the same time, the results suggest that the property mosaic in heavily urbanized/suburbanized areas is generally ‘reset.’ Further, trends in surveying technique, parcel size, and settlement patterns cause property line density and property shape complexity to increase in the less urbanized upper watershed. The persistence of original patterns may be damping expression of heterogeneity gradients in this urban landscape. This spatial pattern of complexity in the original mosaic is directly opposite of hypothesized patterns of landscape heterogeneity arising from urbanization. The technique reported here and the resulting observations are important for landscape pattern studies in areas settled under unsystematic survey systems, especially the heavily urbanized areas of the eastern United States.

Landscape Ecology↗