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Daniel E. Kile

Publications and source records attributed to Daniel E. Kile.

7 recordsLinked to original sources

Celestine-bearing geodes from Wayne and Emery counties, southeastern Utah: Genesis and mineralogy

Geodes containing celestine with associated quartz, calcite, chlorite, and other minerals occur in the Jurassic Curtis Formation of Emery and Wayne counties off the east and south flanks of the San Rafael Swell in southeastern Utah. The two areas discussed in this article produce geodes to 25 cm wide containing bladed to tabular celestine crystals that are as much as 4.5 cm in length. An evaporative littoral system resulting in the formation of anhydrite nodules is proposed as the initial environment for this deposit. Subsequent silicification of the nodules and, in some cases, the formation of hollow spaces within the silicified nodules, provided a geode structure for the eventual crystallization of celestine and associated minerals.

Utah↗

Mineralogy and provenance of clays in miarolitic cavities of the Pikes Peak batholith, Colorado

Clay samples from 105 cavities within miarolitic granitic pegmatites throughout the Pikes Peak batholith, in Colorado, were analyzed by powder X-ray diffraction (XRD). Smectite (beidellite), illite, and kaolinite were found within the cavities. Calculation of crystallite-thickness distribution (CTD), mean thickness of the crystallites, and variance in crystallite thickness, as deduced from XRD patterns, allowed a determination of provenance and mode of formation for illite and smectite. Authigenic miarolitic-cavity illite and smectite show lognormal CTDs and larger mean thicknesses of crystallites than do their soil-derived counterparts; non-lognormal illite in a cavity results from mixing of cavity and soil illite. Analysis of mean thickness and thickness variance shows that crystal growth of illite is initiated by a nucleation event of short duration, followed by surface-controlled kinetics. Crystallization of the miarolitic cavity clays is presumed to occur by neoformation from hydrothermal fluids. The assessment of provenance allows a determination of regional and local distributions of clay minerals in miarolitic cavities within the Pikes Peak batholith.

Colorado↗

Partition of nonpolar organic pollutants from water to soil and sediment organic matters

The partition coefficients (Koc) of carbon tetrachloride and 1,2-dichlorobenzene between normal soil/sediment organic matter and water have been determined for a large set of soils, bed sediments, and suspended solids from the United States and the People's Republic of China. The Koc values for both solutes are quite invariant either for the soils or for the bed sediments; the values on bed sediments are about twice those on soils. The similarity of Koc values between normal soils and between normal bed sediments suggests that natural organic matters in soils (or sediments) of different geographic origins exhibit comparable polarities and possibly comparable compositions. The results also suggest that the process that converts eroded soils into bed sediments brings about a change in the organic matter property. The difference between soil and sediment Koc values provides a basis for identifying the source of suspended solids in river waters. The very high Koc values observed for some special soils and sediments are diagnostic of severe anthropogenic contamination.

Environmental Science & Technology↗