D.N. Edgington | USGS Science

USGS1997

Sedimentary phosphorus cycling and a phosphorus mass balance for the Green Bay (Lake Michigan) ecosystem

The tributaries of Green Bay have long been recognized as major sources of phosphorus in the Lake Michigan basin. The status of Green Bay as a sink or source of phosphorus for Lake Michigan proper has been less well defined. The bay receives nearly 70% of its annual load of phosphorus (700 metric tons (t)??year-1) from a single source: the Fox River. Most of this phosphorus is deposited in sediments accumulating at rates that reach 160 mg??cm-2??year-1 with an average of 20 mg??cm-2 year-1. The phosphorus content of these sediments varies from <5 to >70 ??mol??g-1. Deposition is highly focused, with ???0% of the total sediment accumulation and at least 80% of the phosphorus burial occurring within 20% of the surface area of the bay. Diagenetic and stoichiometric models of phosphorus cycling imply that >80% of the phosphorus deposited is permanently buried. External phosphorus loading to the bay is combined with sediment fluxes of phophorus to arrive at a simple phosphorus budget. Green Bay acts as an efficient nutrient trap, with the sediments retaining an estimated 70-90% of the external phosphorus inputs before flowing into Lake Michigan.

Canadian Journal of Fisheries and Aquatic Sciences↗

USGS1996

Uranium-series disequilibrium, sedimentation, diatom frustules, and paleoclimate change in Lake Baikal

The large volume of water, approximately one-fifth of the total surface fresh water on the planet, contained in Lake Baikal in southeastern Siberia is distinguished by having a relatively high concentration of uranium (ca. 2 n M ), and, together with the surface sediments, an unusually high 234 U 238 U alpha activity ratio of 1.95. About 80% of the input of uranium to the lake, with a 234 U 238 U ratio of 2.0, comes from the Selenga River. Profiles of uranium, as well as the extent of isotopic disequilibrium in a 9 m sediment core collected on Academic Ridge, generally show high values during interglacial periods corresponding to high diatom frustule numbers (DiFr) and biogenic silica (BSi) data that have been reported elsewhere. During glacial periods (low DiFr and BSi), uranium progeny ( 234 U and 230 Th) were in secular equilibrium with low concentrations of their parent 238 U. Radionuclide distributions were interpreted in terms of a quantitative model allowing for adsorption of riverine inputs of uranium onto two classes of sedimenting particles with differing 238 U 232 Th ratios and uranium progeny in secular equilibrium. If the 234 U 238 U activity ratio of adsorbed uranium has remained constant, mean sedimentation rates can be independently estimated as 3.6 ± 0.6 and 3.7 ± 0.9 cm · kyr −1 for the decay of 234 U and in-growth of 230 Th, respectively. These rates are consistent with a mean rate of 3.76 cm · kyr −1 , calculated by optimization of the correspondence between adsorbed 238 U and δ 18 O in dated oceanic sediments. The adsorbed uranium apparently tracks variable river flow during interglacials and is drastically reduced during periods of glaciation. Evidently, uranium has not been significantly redistributed within Baikal sediments over at least the past 250 kyr and is a unique, biologically non-essential, tracer for climate-sensitive processes, which provide their own internal geochronometers, potentially useful for ages up to 1 Myr BP.

Earth and Planetary Science Letters↗