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D.M. Unruh

Publications and source records attributed to D.M. Unruh.

14 recordsLinked to original sources
USGS2012

Lu-Hf and Sm-Nd evolution in lunar mare basalts

Lu-Hf and Sm-Nd data for mare basalts combined with Rb-Sr and total REE data taken from the literature suggest that the mare basalts were derived by small (≤10%) degrees of partial melting of cumulate sources, but that the magma ocean from which these sources formed was light REE and Hf-enriched. Calculated source compositions range from lherzolite to olivine websterite. Nonmodal melting of small amounts of ilmenite (≤3%) in the sources seems to be required by the Lu/Hf data. A comparison of the Hf and Nd isotopic characteristics between the mare basalts and terrestrial oceanic basalts reveals that the εHf/εNd ratios in low-Ti mare basalts are much higher than in terrestrial oceanic basalts. The results are qualitatively consistent with the hypothesis that terrestrial basalt sources are partial melt residues whereas mare basalt sources are cumulates. Alternatively, the results may imply that the terrestrial mantle has evolved in two (or more) stages of evolution, and that the net effect was depletion of the mantle during the first ∼1–3 b.y. followed by enrichment during the last 1–2 b.y.; or simply that there is a difference in Lu-Hf crystal-liquid partitioning (relative to Sm-Nd between the lunar and terrestrial mantles.

Journal of Geophysical Research Solid Earth↗
USGS2009

SHRIMP U-Pb dating of recurrent Cryogenian and Late Cambrian-Early Ordovician alkalic magmatism in central Idaho: Implications for Rodinian rift tectonics

Composite alkalic plutonic suites and tuffaceous diamictite, although discontinuously exposed across central Idaho in roof pendants and inliers within the Idaho batholith and Challis volcanic-plutonic complex, define the >200-km-long northwest-aligned Big Creek-Beaverhead belt. Sensitive highresolution ion microprobe (SHRIMP) U-Pb zircon dates on these igneous rocks provide direct evidence for the orientation and location of the Neoproterozoic-Paleozoic western Laurentian rift margin in the northern U.S. Cordillera. Dating delimits two discrete magmatic pulses at ca. 665-650 Ma and 500-485 Ma at the western and eastern ends, respectively, of this belt. Together with the nearby 685 Ma volcanic rocks of the Edwardsburg Formation, there is a 200 Ma history of recurrent extensional magmatic pulses along the belt. A similar history of recurrent uplift is reflected in the stratigraphic record of the associated miogeoclinal and cratonal platform basins, suggesting that the Big Creek-Beaverhead belt originated as a border fault during continental rift events. The magmatic belt is paired with the recurrently emergent Lemhi Arch and narrow miogeoclinal facies belts and it lies inboard of a northwest-striking narrow zone of thinned continental crust. These features define a northeast-extending upper-plate extensional system between southeast Washington and southeast Idaho that formed a segment of the Neoproterozoic-Paleozoic miogeocline. This segment was flanked on the north by the St. Mary-Moyie transform zone (south of a narrow southern Canadian upper-plate margin) and on the south by the Snake River transfer zone (north of a broad Great Basin lower-plate margin). These are the central segments of a zigzagshaped Cordilleran rift system of alternating northwest-striking extensional zones offset by northeast-striking transfers and transforms. The data substantiate polyphase rift and continental separation events that included (1) pre-and syn-Windermere rifting, (2) Windermere margin subsidence, (3) late Ediacaran-Cambrain rifting, and (4) welldeveloped late Ediacaran-Devonian passive margin subsidence and deposition. Timing and geometries support synchronous but opposing divergence along Cordilleran and Atlantic rifts with a junction in Southern California-Sonora. ?? 2010 Geological Society of America.

Geological Society of America Bulletin↗
USGS2008

Coolwater culmination: Sensitive high-resolution ion microprobe (SHRIMP) U-Pb and isotopic evidence for continental delamination in the Syringa Embayment, Salmon River suture, Idaho

During dextral oblique translation along Laurentia in western Idaho, the Blue Mountains superterrane underwent clockwise rotation and impinged into the Syringa embayment at the northern end of the Salmon River suture. Along the suture, the superterrane is juxtaposed directly against western Laurentia, making this central Cordilleran accretionary-margin segment unusually attenuated. In the embayment, limited orthogonal contraction produced a crustal wedge of oceanic rocks that delaminated Laurentian crust. The wedge is exposed through Laurentian crust in the Coolwater culmination as documented by mapping and by sensitive high-resolution ion microprobe U-Pb, Sri, and ??Nd data for gneisses that lie inboard of the suture. The predominant country rock is Mesoproterozoic paragneiss overlying Laurentian basement. An overlying Neoproterozoic (or younger) paragneiss belt in the Syringa embayment establishes the form of the Cordilleran miogeocline and that the embayment is a relict of Rodinia rifting. An underlying Cretaceous paragneiss was derived from arc terranes and suture-zone orogenic welt but also from Laurentia. The Cretaceous paragneiss and an 86-Ma orthogneiss that intruded it formed the wedge of oceanic rocks that were inserted into the Laurentian margin between 98 and 73 Ma, splitting supracrustal Laurentian rocks from their basement. Crustal thickening, melting and intrusion within the wedge, and folding to form the Coolwater culmination continued until 61 Ma. The embayment formed a restraining bend at the end of the dextral transpressional suture. Clockwise rotation of the impinging superterrane and overthrusting of Laurentia that produced the crustal wedge in the Coolwater culmination are predicted by oblique collision into the Syringa embayment. Copyright 2008 by the American Geophysical Union.

Tectonics↗
USGS2008

The persistence of lead from past gasoline emissions and mining drainage in a large riparian system: Evidence from lead isotopes in the Sacramento River, California

Lead concentrations and isotope ratios measured in river water colloids and streambed sediment samples along 426 km of the Sacramento River, California reveal that the influence of lead from the historical mining of massive sulfide deposits in the West Shasta Cu-mining district (at the headwaters of the Sacramento River) is confined to a 60 km stretch of river immediately downstream of that mining region, whereas inputs from past leaded gasoline emissions and historical hydraulic Au-mining in the Sierra Nevadan foothills are the dominant lead sources in the remaining 370 km of the river. Binary mixing calculations suggest that more than 50% of the lead in the Sacramento River outside of the region of influence of the West Shasta Cu-mining district is derived from past depositions of leaded gasoline emissions. This predominance is the first direct documentation of the geographic extent of gasoline lead persistence throughout a large riparian system (>160,000 km 2 ) and corroborates previous observations based on samples taken at the mouth of the Sacramento River. In addition, new analyses of sediment samples from the hydraulic gold mines of the Sierra Nevada foothills confirm the present-day fluxes into the Sacramento River of contaminant metals derived from historical hydraulic Au-mining that occurred during the latter half of the 19th and early part of the 20th centuries. These fluxes occur predominantly during periods of elevated river discharge associated with heavy winter precipitation in northern California. In the broadest context, the study demonstrates the potential for altered precipitation patterns resulting from climate change to affect the mobility and transport of soil-bound contaminants in the surface environment.

Geochimica et Cosmochimica Acta↗
USGS2002

Lead isotopic analyses of selected soil samples from the USEPA Vasquez Blvd.-I-70 study area, Denver, CO

Large amounts of arsenic contamination, in excess of 2000 ppm, have been found in some residential surface soils in northern Denver, Colorado (USEPA, 1999). Associated with the arsenic are elevated levels of metals such as lead, cadmium and mercury. Potential sources of this contamination include waste from smelters in the area and commercial herbicide containing arsenic trioxide and lead arsenate (USEPA, 1999). As a part of the U.S. Environmental Protection Agency’s Vasquez Boulevard-I-70 Project (VBI70 project; USEPA, 1999), lead isotopic analyses of selected soil samples, smelter waste, and a commercial herbicide and a commercial lead arsenate pesticide have been performed in order to constrain the possible sources of elevated lead, and by proxy arsenic, found in these residential soils. The isotopes of lead can be used as a natural tracer in determining sources of contaminants in soils and stream sediments (e.g. Church and others, 1997; Fey and others, 1999; Unruh and others, 2000). The element lead (Pb) consists of four naturally occurring and stable isotopes, 204Pb, 206Pb, 207Pb, and 208Pb. Three of these, 206Pb, 207Pb, and 208Pb are radiogenic decay products of naturally occurring 238U, 235U, and 232Th, respectively. Owing to variations among the U/Pb and Th/Pb elemental abundance ratios among different types of geologic materials, variations in the relative abundances of the Pb isotopes are produced among different materials during geologic time. In order for the Pb isotope method to be useful for determining possible contaminant sources, two important criteria must be met (e.g. Church and others 1997): (1) It must be possible to obtain and measure the Pb isotopic compositions in all potential contaminant sources and in uncontaminated material and (2) the Pb isotopic compositions of the potential contaminant sources must be distinctly different from one another and from uncontaminated background. Variations among the Pb isotopic ratios in selected samples can be correlated with potential sources of Pb with known isotopic compositions in order to determine the relative contribution of Pb from a specific source to the sample. The purpose of this study is to use Pb isotopic data obtained from a selected subset of samples to determine the Pb isotopic signatures of uncontaminated soils as well as those of potential sources of contamination. The data will eventually be used in conjunction with other geochemical data to help determine which source or sources of contamination are most likely responsible for the elevated arsenic levels in the residential soils.

Colorado↗
USGS2002

Water and sediment study of the Snake River watershed, Colorado, Oct. 9-12, 2001

The Snake River watershed, located upstream from Dillon Reservoir in the central mountains of Colorado, has been affected by historical base-metal mining. Trout stocked in the Snake River for recreational purposes do not survive through the winter. Sediment cores analyzed by previous investigators from the reservoir revealed elevated concentrations of base metals and mercury. We collected 36 surface water samples (filtered and unfiltered) and 38 streambed-sediment samples from streams in the Snake River watershed. Analyses of the sediment and water samples show that concentrations of several metals exceed aquatic life standards in one or both media. Ribbon maps showing dissolved concentrations of zinc, cadmium, copper, and manganese in water (0.45-micron filtered and corrected for the ameliorating effect of hardness), and copper, cadmium, and zinc in sediment indicate reaches where toxic effects on trout would be expected and stream reaches where toxicity standards for rainbow, brown, and brook trout are exceeded. Instantaneous loads for sulfate, strontium, iron, cadmium, copper, and zinc were calculated from 0.45-micron-filtered water concentrations and discharge measurements were made at each site. Sulfate and strontium behave conservatively, whereas copper, cadmium, and zinc are reactive. The dissolved copper load entering the reservoir is less than 20 percent of the value calculated from some upper reaches; copper is transferred to suspended and or streambed sediment by sorption to iron oxyhydroxides. Higher percentages of zinc and cadmium reach the reservoir in dissolved form; however, load calculations indicate that some of these metals are also precipitated out of solution. The most effective remediation activities should be concentrated on reducing the dissolved loads of zinc, cadmium, and copper in two reaches of lower Peru Creek between the confluence with the Snake River and Cinnamon Gulch. We analyzed all streambed sediment for mercury and selected streambed-sediment and reservoir core samples for lead isotope signatures. Results indicate that the mercury anomaly in the reservoir sediment was not from any known source in the Snake River, Blue River, or Tenmile Creek watersheds. Its source remains an enigma.

Colorado↗
USGS1993

Actualistic models of mantle metasomatism documented in a composite xenolith from Dish Hill, California

Major and trace-element whole rock and mineral variations in composite hornblendite-peridotite xenolith Ba-2-1, from Dish Hill, CA, are due to a single event of metasomatism in the mantle. The hornblendite is the crystallized selvage of a dike conduit charged with incompatible-element-enriched hydrous mafic magma. The magma infiltrated the refractory peridotite wallrock, reacted with its constituent minerals, and simultaneously deposited amphibole. The systematic data from this study show considerable variation in isotopic values and trace elements. These data provide insight into a mantle process that was defined previously from samples without context, lacking evidence about the number or source of metasomatic events. In the contact zone of Ba-2-1, peridotite is enriched in Fe, Ti, CO 2 ) and H 2 O; clinopyroxene and amphibole also are enriched in Fe and Ti, but clinopyroxene appears slightly depleted in CaO. Compared to chondrites, peridotite, clinopyroxene, and probably amphibole are enriched in light rare earth (LREE cn ) and other incompatible trace elements. Values of 87 Sr 86 Sr "> 87 Sr 86 Sr and 143 Nd 144 Nd "> 143 Nd 144 Nd in the contact zone are close to isotopic equilibrium with the dike. Whole rock and constituent clinopyroxene compositions change to those of refractory peridotite with distance from the contact. These compositional variations were modelled using Gresens' equation for whole-rock major and minor elements, and calculations for isotopic ratios and REEs, which emulate the effects of Chromatographic fractionation. The choice of endmembers was restricted to compositions actually present in mantle samples from Dish Hill. Model results indicate that: 1. the variations can be explained as the result of a single metasomatic event, probably a single pulse of previously fractionated liquid; 2. the ratio of total interacting liquid to peridotite was at least 1:3 by weight in the contact zone; and 3. the composition of the metasomatic liquid changed progressively as it infiltrated beyond that zone. The small distance over which variations occur is due to the small amount of liquid that infiltrated. Only in the contact zone was peridotite wallrock saturated by a liquid composition similar to the dike. Comparison of the Ba-2-1 data with those of another xenolith from Dish Hill suggests that the compositional variations of mantle metasomatism result from both the compositional contrast between the metasomatizing liquid and wallrock and the relative abundances of each. Compositional and volumetric variations of mantle partial melts and their fractionates, and repeated events of melting and reaction in contiguous mantle, can create broad ranges of metasomatic “signatures” from the same process.

California↗
USGS1983

40Ar/39Ar and U-Th-Pb dating of separated clasts from the Abee E4 chondrite

Determinations of 40 Ar/ 39 Ar and U-Th-Pb are reported for three clasts from the Abee (E4) enstatite chondrite, which has been the object of extensive consortium investigations. The clasts give 40 Ar/ 39 Ar plateau ages and/or maximum ages of 4.5 Gy, whereas two of the clasts give average ages of 4.4 Gy. Within the range of 4.4–4.5 Gy these data do not resolve any possible age differences among the three clasts. 206 Pb measured in these clasts is only ∼1.5–2.5% radiogenic, which leads to relatively large uncertainties in the Pb isochron age and in the 207 Pb/ 206 Pb model ages. The Pb data indicate that the initial 207 Pb/ 206 Pb was no more than 0.08±0.07% higher than this ratio in Can˜on Diablo troilite. The U-Th-Pb data are consistent with the interpretation that initial formation of these clasts occurred 4.58 Gy ago and that the clasts have since remained closed systems, but are contaminated with terrestrial Pb. The 40 Ar/ 39 Ar ages could be gas retention ages after clast formation or impact degassing ages. The thermal history of Abee deduced from Ar data appears consistent with that deduced from magnetic data, and suggests that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, and experienced no appreciable subsequent heating.

Earth and Planetary Science Letters↗
USGS1977

History of the Pasamonte achondrite: Relative susceptibility of the SmNd, RbSr, and UPb systems to metamorphic events

The Rb Sr, Sm Nd, and U Pb systematics of the eucrite Pasamonte have been studied in order to investigate the relative susceptibility of the different systems to post-crystallization events and to determine the age and history of the meteorite. The Rb Sr and 238 U- 206 Pb data of mineral separates do not define an isochron but the Sm Nd data define an internal isochron which corresponds to the formation age of 4.58 ± 0.12b.y. (10 9 years). The 207 Pb- 206 Pb data of mineral separates define an apparent age of 4.53 ± 0.03b.y. , however we conclude that this age, while in agreement with the Sm Nd age, is not strictly valid since the U Pb data indicate at least three stages of evolution. The U Pb data indicate that the parent body of the meteorite experienced brecciation shortly after the formation of the parent body surface ( ∼4.2–4.45b.y. ago) and a recent disturbance (collision?) 6 ± 30m.y. ago. The latter age is within the range of cosmic ray exposure ages for achondrites.

Earth and Planetary Science Letters↗
USGS1976

U-Th-Pb and Rb-Sr systematics of Allende and U-Th-Pb systematics of Orgueil

U-Th-Pb systematics study of Allende inclusions showed that U, Th and Sr concentrations in Ca, Al (pyroxene)-rich chondrules and white and pinkish-white aggregate separates of Allende are five to ten times higher than those of the matrix, whereas Mg (olivine)-rich chondrules have U and Th concentrations about twice as high as the matrix. Th concentrations are extremely high in white aggregates and in pinkish-white (spinel-rich) aggregates while U and Sr concentrations in white aggregates are more than twice as high as those in pinkish-white aggregates. Large enrichment of these refractory elements in the white aggregates indicates that they contain high-temperature condensates from the solar nebula. The Pb concentrations in the inclusions are less than half of those in the whole rock and matrix, indicating that the matrix is a lower-temperature condensate. The isotopic composition of lead in the matrix is less radiogenic than that of the whole meteorite, whereas lead in Ca- and Al-rich chondrules and aggregates is extremely radiogenic. The 206 Pb/ 204 Pb ratio reaches as high as 55.9 in a white aggregate separate. The lead of Mg-rich chondrules is moderately radiogenic and the 206 Pb/ 204 Pb ratio ranges from 18 to 26. A striking linear relationship exists among leads in the chondrules, aggregates and matrix on the 207 Pb/ 204 Pb vs 204 Pb/ 204 Pb plot. The slope of the best fit line is 0.6188 ± 0.0016, yielding an isochron age of 4553 ± 4 m.y. The regression line passes through primordial lead values obtained from Canyon Diablo troilite. The data, when corrected for Canyon Diablo troilite Pb and plotted on a U-Pb concordia diagram, show that the pink and white aggregates and the Ca-Al-rich and Mg-rich inclusions have excess Pb and define a chord which intersects the concordia curve at 4548 ± 25 m.y. and 107 ± 70 m.y. The intercepts might correspond to the agglomeration age of the meteorite and a time of probably later disturbance, respectively. The matrix and some chondrules which contain less radiogenic lead did, however, not fit on the chord. The Rb-Sr data of Allende did not define an isochron suggesting that the Rb-Sr system was also disturbed by a later event, as suggested by the U-Pb concordia data. The lowest observed 87 Sr/ 86 Sr ratio in Allende inclusions is similar to the initial ratio of the Angra dos Reis achondrite (Papanastassiou, Thesis, 1970). The initial Pb isotopic composition of Orgueil calculated by a single-stage evolution model is more radiogenic than that of Canyon Diablo troilite. To reconcile the U-Pb data of Orgueil and Allende, we propose that the initial lead isotopic composition of the carbonaceous chondrites was slightly different from that of Canyon Diablo troilite Pb.

Geochimica et Cosmochimica Acta↗
USGS1974

U-Th-Pb and Rb-Sr systematics of Apollo 17 boulder 7 from the North Massif of the Taurus-Littrow Valley

Portions of highland breccia boulder 7 collected during the Apollo 17 mission were studied using U Th Pb and Rb Sr systematics. A Rb Sr internal isochron age of 3.89 ± 0.08b.y. with an initial 87 Sr/ 86 Sr of0.69926 ± 0.00008 was obtained for clast 1 (77135,57) (a troctolitic microbreccia). A troctolitic portion of microbreccia clast 77215,37 yielded a U Pb internal isochron of 3.8 ± 0.2b.y. and an initial 206 Pb/ 207 Pb of 0.69. These internal isochron age are interpreted as reflecting metamorphic events, probably related to impacts, which reset Rb Sr and U Pb mineral systems of older rocks. Six portions of boulder 7 were analyzed for U, Th, and Pb as whole rocks. Two chemical groups appear to be defined by the U, Th, and Pb concentration data. Chemical group A is characterized by U, Th, and Pb concentrations and 238 U/ 204 Pb values which are higher than those of group B. Group A rocks have typical 232 Th/ 238 U ratios of ∼ 3.85, whereas-group B rocks have unusually high Th/U values of ∼ 4.1. Whole-rock U Pb and Pb Pb ages are nearly concordant. Two events appear to be reflected in these data — one at ∼ 4.4 b.y. and one at ∼ 4.5 b.y. The chemical groupings show no correlation with documented ages. The old ages of ∼ 4.4 b.y. and ∼ 4.5 b.y. may, like the younger ∼ 4.0 b.y. ages, be related to basin excavation events.

Earth and Planetary Science Letters↗