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D.L. Bish

Publications and source records attributed to D.L. Bish.

3 recordsLinked to original sources

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale crater, Mars

H 2 O, CO 2 , SO 2 , O 2 , H 2 , H 2 S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H 2 O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO 2 . Concurrent evolution of O 2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

Science

Soil diversity and hydration as observed by ChemCam at Gale crater, Mars

The ChemCam instrument, which provides insight into martian soil chemistry at the submillimeter scale, identified two principal soil types along the Curiosity rover traverse: a fine-grained mafic type and a locally derived, coarse-grained felsic type. The mafic soil component is representative of widespread martian soils and is similar in composition to the martian dust. It possesses a ubiquitous hydrogen signature in ChemCam spectra, corresponding to the hydration of the amorphous phases found in the soil by the CheMin instrument. This hydration likely accounts for an important fraction of the global hydration of the surface seen by previous orbital measurements. ChemCam analyses did not reveal any significant exchange of water vapor between the regolith and the atmosphere. These observations provide constraints on the nature of the amorphous phases and their hydration.

Science

Hydrated states of MgSO4 at equatorial latiudes on Mars

The stability of water ice, epsomite, and hexahydrite to loss of H 2O molecules to the atmosphere at equatorial latitudes of Mars was studied to determine their potential contributions to the measured abundance of water-equivalent hydrogen (WEH). Calculation of the relative humidity based on estimates of yearly averages of water-vapor pressures and temperatures at the Martian surface was used for this purpose. Water ice was found to be sufficiently unstable everywhere within 45?? of the equator that if the observed WEH is due to water ice, it requires a low-permeability cover layer near the surface to isolate the water ice below from the atmosphere above. In contrast, epsomite or hexahydrite may be stable in many near-equatorial locations where significant amounts of WEH are observed. Copyright 2004 by the American Geophysical Union.

Geophysical Research Letters