Geology topics

D.J. Blunt

Publications and source records attributed to D.J. Blunt.

4 recordsLinked to original sources

USGS2017

Amino acid geochemistry of fossil bones from the Rancho La Brea asphalt deposit, California

Low aspartic acid d:l ratios and modern collagenlike concentration values indicate that amino acids in bones from the Rancho La Brea asphalt deposit, Los Angeles, California are better preserved than amino acids in bones of equivalent age that have not been preserved in asphalt. Amino acids were recovered from 10 Rancho La Brea bone samples which range in age from less than 200 to greater than 36,000 yr. The calibrated rates of aspartic acid racemization range from 2.1 to 5.0 × 10 −6 yr −1 . Although this wide range of rate constants decreases the level of confidence for age estimates, use of the larger rate constant of 5.0 × 10 −6 yr −1 provides minimum age estimates which fit the known stratigraphic and chronologic records of the Rancho La Brea deposits.

California↗

USGS1988

Amino-acid diagenesis and its implication for late Pleistocene lacustrine sediment, Clear Lake, California

The diagenesis of amino acids in sediments from Clear Lake core CL-80-1 is indicated by changes in amino acid concentrations, compositions, and stereochemistry. Concentrations of total amino acids decrease with depth, but the decrease is not systematic, possibly reflecting a nonuniformity in sedimentary and postdepositional processes affecting the amino acids. Ratios of neutral/acidic amino acids may indicate that the pH of interstitial water is slightly alkaline to slightly acidic and that the organic matter is well humified. Ratios of nonprotein/protein amino acids suggest that some changes in amino acids with depth result from microbial degradations. The extent of racemization of alanine increases with depth; the trends of these data may be explained, in part, by rapid sedimentation within the lake. Agreement between extents of alanine racemization for sediments from equivalent depths in two cores from the lake suggests that diagenetic temperatures are uniform within the sediments of the northern basin of Clear Lake.

California↗

USGS1980

Geochemistry of amino acids in shells of the clam Saxidomus

Concentrations of amino acids and their corresponding d l "> dl enantiomeric ratios have been measured in shells of the bivalve mollusk Saxidomus from eleven localities, ranging in age from modern to probably more than 500,000 yr, along the Pacific coast of North America. Natural logarithms of amino acid concentrations correlate well with d l "> dl ratios, and the relationship provides a possible guide to the selection of fossils for use in amino acid dating. The relative order of the extents of racemization of amino acids at any given time appears to change with increasing sample age. Application of the amino acid dating method to shells from Whidbey Island, Washington, yields an age of about 80,000 yr, in contrast to the previously determined radiocarbon age of 36,000 yr which was measured on some shell carbonate and considered a minimum age. The amino acid age is compatible with the geologic record in the area.

Alaska, Washington↗

USGS1979

Amino-acid racemizarion in Quaternary shell deposits at Willapa Bay, Washington

Extents of racemization ( d l "> dl ratios) of amino acids in fossil Saxidomus giganteus (Deshayes) and Ostrea lurida Carpenter were measured on shell deposits exposed at 21 sites on the east side of Willapa Bay, Washington. Amino acids from Saxidomus show less variability in d Spl "> dSpl ratios and, therefore, are of greater use in correlation and age estimation than are amino acids from Ostrea . Shells of two different ages, about 120,000 ± 40,000 yr old and about 190,000 ± 40,000 yr old, are present. These ages correspond to Stages 5 and 7 of the marine isotope record defined by Shackleton and Opdyke in 1973 and hence the shell deposits likely formed during two different high stands of sea level. The stratigraphic record at Willapa Bay is consistent with this interpretation.

Geochimica et Cosmochimica Acta↗