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D.B. Grove

Publications and source records attributed to D.B. Grove.

7 recordsLinked to original sources
USGS2008

Modeling the rate-controlled sorption of hexavalent chromium

Sorption of chromium VI on the iron-oxide- and hydroxide-coated surface of alluvial material was numerically simulated with rate-controlled reactions. Reaction kinetics and diffusional processes, in the form of film, pore, and particle diffusion, were simulated and compared with experimental results. The use of empirically calculated rate coefficients for diffusion through the reacting surface was found to simulate experimental data; pore or particle diffusion is believed to be a possible rate-controlling mechanism. The use of rate equations to predict conservative transport and rate- and local-equilibrium-controlled reactions was shown to be feasible.

Water Resources Research↗
USGS1985

Adsorption and desorption of hexavalent chromium in an alluvial aquifer near Telluride, Colorado

A laboratory investigation of reactions between hexavalent chromium [Cr(VI)] and alluvium was conducted to evaluate reactions of Cr(VI) contaminating an alluvial aquifer near Telluride, CO and to determine the mechanisms responsible for these reactions. Uncontaminated alluvium and groundwater (spiked with CrO 4 2− ) from the study site were used in batch and column experiments. Results of these experiments show that Cr(VI) was adsorbed by the alluvium. Distribution coefficients from batch experiments ranged from 52 L/kg at an equilibrium CrO 4 2− concentration of 0.4 µ mol/L to 1.7 L/kg at an equilibrium concentration of 1400 µ mol/L. The zero point of charge for the alluvium was approximately 8.3, and the alluvium had a positive net charge at the groundwater pH of 6.8. Visual and chemical evidence indicated that Fe oxide and hydroxide coatings on the alluvial particles principally were responsible for the adsorption of Cr(VI). During column experiments, Cr(VI) initially was desorbed easily from the alluvium by Cr‐free groundwater; however, the rate of desorption decreased rapidly, and > 60 pore volumes of groundwater were required to decrease the effluent concentration of Cr(VI) to 3 µ mol/L [drinking water standard for Cr(VI) = 1 µ mol/L]. The quantity of Cr(VI) adsorbed varied with the type and concentration of other anions in solution.

Colorado↗
USGS1985

Reduction of hexavalent chromium in water samples acidified for preservation

Reduction of hexavalent chromium, Cr(VI), in water samples, preserved by standard techniques, was investigated. The standard preservation technique for water samples that are to be analyzed for Cr(VI) consists of filtration through a 0.45‐ µ m membrane, acidification to a pH < 2, and storage in plastic bottles. Batch experiments were conducted to evaluate the effect of H + concentration, NO 2 , temperature, and dissolved organic carbon (DOC) on the reduction of Cr(VI) to Cr(III). The rate of reduction of Cr(VI) to Cr(III) increased with increasing NO 2 , DOC, H + , and temperature. Reduction of Cr(VI) by organic matter occurred in some samples even though the samples were unacidified. Reduction of Cr(VI) is inhibited to an extent by storing the sample at 4°C. Stability of Cr(VI) in water is variable and depends on the other constituents present in the sample. Water samples collected for the determination of Cr(VI) should be filtered (0.45‐ µ m membrane), refrigerated, and analyzed as quickly as possible. Water samples should not be acidified. Measurement of total Cr in addition to Cr(VI) can serve as a check for Cr(VI) reduction. If total Cr is greater than Cr(VI), the possibility that Cr(VI) reduction has occurred needs to be considered.

Journal of Environmental Quality↗
USGS1984

Application of the conjugate-gradient method to ground-water models

The conjugate-gradient method can solve efficiently and accurately finite-difference approximations to the ground-water flow equation. An aquifer-simulation model using the conjugate-gradient method was applied to a problem of ground-water flow in an alluvial aquifer at the Rocky Mountain Arsenal, Denver, Colorado. For this application, the accuracy and efficiency of the conjugate-gradient method compared favorably with other available methods for steady-state flow. However, its efficiency relative to other available methods depends on the nature of the specific problem. The main advantage of the conjugate-gradient method is that it does not require the use of iteration parameters, thereby eliminating this partly subjective procedure. (USGS)

Water-Resources Investigations Report↗
USGS1984

Computer model of one-dimensional equilibrium controlled sorption processes

A numerical solution to the one-dimensional solute-transport equation with equilibrium-controlled sorption and a first-order irreversible-rate reaction is presented. The computer code is written in FORTRAN language, with a variety of options for input and output for user ease. Sorption reactions include Langmuir, Freundlich, and ion-exchange, with or without equal valance. General equations describing transport and reaction processes are solved by finite-difference methods, with nonlinearities accounted for by iteration. Complete documentation of the code, with examples, is included. (USGS)

Water-Resources Investigations Report↗
USGS1977

Derivation of equations describing solute transport in ground water

A general equation describing the three-dimensional transport and dispersion of a reacting solute in flowing ground water is derived from the principle of conservation of mass. The derivation presented is more detailed but less rigorous than derivations published previously. The general solute-transport equation relates concentration changes to hydrodynamic dispersion, convective transport, fluid sources and sinks, and chemical reactions. Because both dispersion and convective transport depend on the velocity of ground-water flow, the solute-transport equation must be solved in conjunction with the ground-water flow equation. (Woodard-USGS)

Water-Resources Investigations Report↗