Geology topics

D.A. Clague

Publications and source records attributed to D.A. Clague.

At least 19 recordsLinked to original sources

USGS2012

Minor and trace element geochemistry of volcanic rocks dredged from the Galapagos spreading center: Role of crystal fractionation and mantle heterogeneity

A wide range of rock types (abyssal tholeiite, Fe-Ti-rich basalt, andesite, and rhyodacite) were dredged from near 95°W and 85°W on the Galapagos spreading center. Computer modeling of major element compositions has shown that these rocks could be derived from common parental magmas by successive degrees of fractional crystallization. However, the P 2 O 5 /K 2 O ratio averages 0.83 at 95°W and 1.66 at 85°W and implies distinct mantle source compositions for the two areas. These source regions also have different rare earth element (REE) abundance patterns, with [La/Sm] EF = 0.67 at 95°W and 0.46 at 85°W. The sequence of fractionated lavas differs for the two areas and indicates earlier fractionation of apatite and titanomagnetite in the lavas from 95°W. The mantle source regions for these two areas are interpreted to be depleted in incompatible (and volatile?) elements, although the source region beneath 95°W is less severely depleted in La and K. Incompatible trace element abundances in 26 samples are used to infer that the range of Fe-Ti-rich basalt from 85°W represents 19 to 35% residual liquid following crystal fractionation of a mineral assemblage of plagioclase, clinopyroxene, and lesser olivine. The most highly differentiated samples have also had less than 1% titanomagnetite removed. Most samples from 85°W can be related to a common parental magma that contained approximately 9 wt % FeO*, 1 wt % TiO 2 , and had an Mg number (Mg# = 100 Mg/(Mg + Fe 2+ )) of about 65. Although the samples from 95°W cannot all be derived from a common parental magma, the inferred parental magmas may have been derived by varying degrees of partial melting of a common source. The fractionation sequence consists of two parts: an initial iron enrichment trend followed by a silica enrichment trend. We interpret the trace element data to indicate that the most iron rich lavas represent about 32% residual liquid derived by crystal fractionation of plagioclase, clinopyroxene, and lesser olivine from a parental magma with an Mg number of about 66. The silica enrichment trend results from crystallization of titanomagnetite and some apatite. Fractionation of pigeonite, which is a minor phase in the major element models, cannot be distinguished from clinopyroxene fractionation by using trace elements.

Journal of Geophysical Research Solid Earth↗

USGS2012

Sr isotopic variations along the Juan de Fuca Ridge

Sr isotopic ratios of 39 glass and microcrystalline basalt samples along the Juan de Fuca Ridge and 1 glass sample from Brown Bear Seamount are at the lower end of the range for normal mid-oceanic ridge basalt (MORB); the average 87 Sr/ 86 Sr ratio is 0.70249±0.00014 (2-σ). Although subtle variations exist along strike of the ridge, the Sr isotope data do not show systematic variation relative to the proposed Cobb Hotspot. The isotopic data are inconsistent with an enriched mantle-plume origin for the Cobb-Eickelberg Seamount chain, as has been proposed for Iceland, the Azores, and the Galapagos spreading center. Sr isotopic ratios of samples collected north and south of the Cobb offset are identical, although minor element ratios indicate that these regions have chemically distinct mantle sources. These distinct mantle sources may not have been separated long enough to develop isotopic differences.

Journal of Geophysical Research Solid Earth↗

USGS2012

Geochemistry, mineralogy, and petrogenesis of basalt from the Gorda Ridge

Basalt pillow lava with glassy rims was dredged from 17 sites along the Gorda Ridge between latitudes 43°N and 40.8°N. All samples are low-K 2 O mid-ocean ridge tholeiitic basalt having a narrow compositional range with Mg numbers clustered around 60–62; more primitive and evolved compositions are present but rare. None of the more fractionated samples is as evolved as ferrobasalt from the Juan de Fuca Ridge. Incompatible trace element ratios are typical of normal mid-ocean ridge basalt but show considerable scatter. The 87 Sr/ 86 Sr ratios, ranging from 0.70233 to 0.70267, are near the low end of the range for normal mid-ocean ridge basalt. The phenocrysts present are abundant plagioclase, less abundant olivine ± spinel, and traces of sulfide. Clinopyroxene is absent in the glasses. The mineral chemistry is typical of ocean floor basalt. However, unusually anorthitic plagioclase in some highly plagioclasephyric samples, complex zoning in plagioclase and olivine, and other disequilibrium features indicate complex petrogenetic processes involving magma mixing. Glass inclusions in olivine and plagioclase indicate primitive trapped melts. The chemical diversity of Gorda Ridge lava appears to have been primarily caused by variable degrees of partial melting, but crystal fractionation and magma mixing were also important processes. Compositional variations along the strike of the ridge indicate that lava from the segment south of the offset at latitude 41.6°N was generated by the smallest percentage of partial melting of a source less depleted than that of the two northern segments. Lava from the central and northern segments was generated by variable percentages of partial melting of a uniformly depleted source. Lava from the northern segment shows the greatest diversity with a large range in percentage of melting and both relatively primitive and evolved compositions in spatially and temporally closely associated lava. The diversity of lava from the northern segment may result from thermal perturbations caused by proximity to the Blanco Fracture Zone. Gorda Ridge lava is more similar to that from the Mid-Atlantic Ridge at 22°–25°N than to that from other spreading centers in the Pacific Ocean. Magma chambers under the Gorda Ridge appear to be small, discontinuous in time and space and possibly at greater depth than those beneath other Pacific spreading centers.

Journal of Geophysical Research Solid Earth↗

USGS2012

Petrology and age of alkalic lava from the Ratak Chain of the Marshall Islands

Volcanic rock dredged from the flanks of four volcanic edifices in the Ratak chain of the Marshall Islands consist of alkalic lava that erupted above sea level or in shallow water. Compositions of recovered samples are predominantly differentiated alkalic basalt and hawaiite but include strongly alkalic melilitite. Whole rock 40 Ar/ 39 Ar total fusion and incremental heating ages of 87.3±0.6 Ma and 82.2±1.6 Ma determined for samples from Erikub Seamount and Ratak Guyot, respectively, are within the range predicted by plate rotation models but show no age progression consistent with a simple hot spot model. Whole rock major element, and mineral chemistry are similar to those of alkalic lavas from other oceanic islands, but isotopic and certain trace element ratios reveal distinctive mantle source characteristics. Zr/Nb ratios of ∼3.0±0.2 for Bikar and Ratak Guyot, compared to 5.2±0.3 for Majuro Atoll and Erikub Seamount, at comparable degree of differentiation, suggest a more alkalic trend for the northern sites. The 143 Nd/ 144 Nd isotopic ratios range from 0.51283 to 0.51289 and 206 Pb/ 204 Pb, 207 Pb/ 204 Pb, and 208 Pb/ 204 Pb ratios range from 20.55 to 21.11, 15.71 to 15.77, and 39.93 to 40.75, for samples from Erikub and Ratak. Variations in isotopic and some incompatible element ratios suggest interisland heterogeneity. Similar highly radiogenic lead isotopes, coupled with distinct incompatible element ratios, especially with low Ba/Nb ratios (∼6), are observed for St. Helena in the South Atlantic and for Tubuai and Mangaia in the South Pacific. The similar mantle signature shown by lavas from Tubuai and Mangaia in the Austral-Cook chain, which are located at approximately the position where the Ratak edifices formed during the Late Cretaceous, indicates that this mantle anomaly is not of recent origin but has erupted distinctive lava compositions for at least 87 m.y.

Journal of Geophysical Research Solid Earth↗

USGS2012

Gabbroic xenoliths from the northern Gorda Ridge: Implications for magma chamber processes under slow spreading centers

Abundant gabbroic xenoliths in porphyritic pillow basalt were dredged from the northern Gorda Ridge. The host lava is a moderately fractionated, normal mid-ocean ridge basalt with a heterogeneous glass rind (Mg numbers 56-60). Other lavas in the vicinity range from near primary (Mg number 69) to fractionated (Mg number 56). On the basis of textures and mineral compositions, the xenoliths are divided into five types. The xenoliths are not cognate to the host lava, but they are genetically related. Chemistry of mineral phases in conjunction with textural features suggests that the xenoliths formed in different parts of a convecting magma chamber that underwent a period of closed system fractionation. The chamber was filled with a large proportion of crystalline mush when new, more primitive, and less dense magma was injected and mixed incompletely with the contents in the chamber, forming the hybrid host lava. -from Authors

Journal of Geophysical Research Solid Earth↗

USGS2010

Variations in the fine-scale composition of a central Pacific ferromanganese crust: Paleoceanographic implications

A 47- to 60-mm-thick Fe-Mn crust from Horizon Guyot (water depth 1800–1780 m), central Pacific, was used to evaluate the potential of crusts as recorders of Neogene paleoceanographic and paleoclimatic conditions. The chemical composition was determined by microprobe for 16 elements from a polished thin section. Three analyses were made per millimeter and averaged to give the composition of each millimeter. The age of the crust was determined by measuring the strontium isotope composition of the crust and comparing it with the Tertiary seawater curve. The crust represents 18.5 m.y. of growth of Fe and Mn oxyhydroxides. The crust is composed of alternating botryoidal and laminated layers. The botryoidal layers formed during the same time intervals that widespread Neogene deep-sea hiatuses were forming in bottom sediments. The botryoidal layers represent growth during times of intensified deepwater flow, whereas the laminated intervals represent more quiescent conditions. The correspondence between the botryoidal layers and the Neogene hiatuses is so strong that we were able to choose a variable growth rate model over a constant growth rate model for the crust. Chemical changes in the crust take two forms. The first is represented by broad changes in the composition defined chiefly by fourth-order polynomial fits to the chemical profiles of each element with depth in the crust. The second is high-frequency changes in composition. The broader changes occurred primarily at about 15, 11.5, 7.4, 6.4, 5.2, and 4.6 Ma, which may correlate with major changes in paleoceanographic circulation and development of ice caps at the poles. The periods of the high-frequency changes may reflect climatic changes that resulted from orbital forcing. These high-frequency changes may correspond to the high-order eccentricity periods of 3.47, 2.04, and 1.31 m.y.

Paleoceanography and Paleoclimatology↗

USGS2009

Coral reef evolution on rapidly subsiding margins

A series of well-developed submerged coral reefs are preserved in the Huon Gulf (Papua New Guinea) and around Hawaii. Despite different tectonics settings, both regions have experienced rapid subsidence (2-6??m/ka) over the last 500??ka. Rapid subsidence, combined with eustatic sea-level changes, is responsible for repeated drowning and backstepping of coral reefs over this period. Because we can place quantitative constraints on these systems (i.e., reef drowning age, eustatic sea-level changes, subsidence rates, accretion rates, basement substrates, and paleobathymetry), these areas represent unique natural laboratories for exploring the roles of tectonics, reef accretion, and eustatic sea-level changes in controlling the evolution of individual reefs, as well as backstepping of the entire system. A review of new and existing bathymetric, radiometric, sedimentary facies and numerical modeling data indicate that these reefs have had long, complex growth histories and that they are highly sensitive, recording drowning not only during major deglaciations, but also during high-frequency, small-amplitude interstadial and deglacial meltwater pulse events. Analysis of five generalized sedimentary facies shows that reef drowning is characterized by a distinct biological and sedimentary sequence. Observational and numerical modeling data indicate that on precessional (20??ka) and sub-orbital timescales, the rate and amplitude of eustatic sea-level changes are critical in controlling initiation, growth, drowning or sub-aerial exposure, subsequent re-initiation, and final drowning. However, over longer timescales (> 100-500??ka) continued tectonic subsidence and basement substrate morphology influence broad scale reef morphology and backstepping geometries. Drilling of these reefs will yield greatly expanded stratigraphic sections compared with similar reefs on slowly subsiding, stable and uplifting margins, and thus they represent a unique archive of sea-level and climate changes, as well as a record of the response of coral reefs to these changes over the last six glacial cycles. ?? 2008 Elsevier B.V. All rights reserved.

Global and Planetary Change↗

USGS2008

Postshield stage transitional volcanism on Mahukona Volcano, Hawaii

Age spectra from 40Ar/39Ar incremental heating experiments yield ages of 298 ± 25ka and 310 ± 31ka for transitional composition lavas from two cones on submarine Mahukona Volcano, Hawaii. These ages are younger than the inferred end of the tholeiitic shield stage and indicate that the volcano had entered the postshield alkalic stage before going extinct. Previously reported elevated helium isotopic ratios of lavas from one of these cones were incorrectly interpreted to indicate eruption during a preshield alkalic stage. Consequently, high helium isotopic ratios are a poor indicator of eruptive stage, as they occur in preshield, shield, and postshield stage lavas. Loihi Seamount and Kilauea are the only known Hawaiian volcanoes where the volume of preshield alkalic stage lavas can be estimated. Springer-Verlag 2008.

Hawaii↗

USGS2008

Metalliferous sediment and a silica-hematite deposit within the Blanco fracture zone, Northeast Pacific

A Tiburon ROV dive within the East Blanco Depression (EBD) increased the mapped extent of a known hydrothermal field by an order of magnitude. In addition, a unique opal-CT (cristobalite-tridymite)-hematite mound was discovered, and mineralized sediments and rock were collected and analyzed. Silica-hematite mounds have not previously been found on the deep ocean floor. The light-weight rock of the porous mound consists predominantly of opal-CT and hematite filaments, rods, and strands, and averages 77.8% SiO2 and 11.8% Fe2O3. The hematite and opal-CT precipitated from a low-temperature (???115?? C), strongly oxidized, silica- and iron-rich, sulfur-poor hydrothermal fluid; a bacterial mat provided the framework for precipitation. Samples collected from a volcaniclastic rock outcrop consist primarily of quartz with lesser plagioclase, smectite, pyroxene, and sulfides; SiO2 content averages 72.5%. Formation of these quartz-rich samples is best explained by cooling in an up-flow zone of silica-rich hydrothermal fluids within a low permeability system. Opal-A, opal-CT, and quartz mineralization found in different places within the EBD hydrothermal field likely reflects decreasing silica saturation and increasing temperature of the mineralizing fluid with increasing silica crystallinity. Six push cores recovered gravel, coarse sand, and mud mineralized variously by Fe or Mn oxides, silica, and sulfides. Total rare-earth element concentrations are low for both the rock and push core samples. Ce and Eu anomalies reflect high and low temperature hydrothermal components and detrital phases. A remarkable variety of types of mineralization occur within the EBD field, yet a consistent suite of elements is enriched (relative to basalt and unmineralized cores) in all samples analyzed: Ag, Au, S, Mo, Hg, As, Sb, Sr, and U; most samples are also enriched in Cu, Pb, Cd, and Zn. On the basis of these element enrichments, the EBD hydrothermal field might best be described as a base- and precious-metal-bearing, silica-Fe-oxide-barite deposit. Such deposits are commonly spatially and temporally associated with volcanogenic massive sulfide (VMS) ores. A plot of data for pathfinder elements shows a large hot spot at the northwestern margin of the field, which may mark a region where moderate to high temperature sulfide deposits are forming at depth; further exploration of the hydrothermal field to the northwest is warranted.

Marine Georesources and Geotechnology↗

USGS2004

Hawaiian submarine manganese-iron oxide crusts - A dating tool?

Black manganese-iron oxide crusts form on most exposed rock on the ocean floor. Such crusts are well developed on the steep lava slopes of the Hawaiian Ridge and have been sampled during dredging and submersible dives. The crusts also occur on fragments detached from bedrock by mass wasting, on submerged coral reefs, and on poorly lithified sedimentary rocks. The thickness of the crusts was measured on samples collected since 1965 on the Hawaiian Ridge from 140 dive or dredge localities. Fifty-nine (42%) of the sites were collected in 2001 by remotely operated vehicles (ROVs). The thinner crusts on many samples apparently result from postdepositional breakage, landsliding, and intermittent burial of outcrops by sediment. The maximum crust thickness was selected from each dredge or dive site to best represent crusts on the original rock surface at that site. The measurements show an irregular progressive thickening of the crusts toward the northwest—i.e., progressive thickening toward the older volcanic features with increasing distance from the Hawaiian hotspot. Comparison of the maximum crust thickness with radiometric ages of related subaerial features supports previous studies that indicate a crust-growth rate of about 2.5 mm/m.y. The thickness information not only allows a comparison of the relative exposure ages of two or more features offshore from different volcanoes, but also provides specific age estimates of volcanic and landslide deposits. The data indicate that some of the landslide blocks within the south Kona landslide are the oldest exposed rock on Mauna Loa, Kilauea, or Loihi volcanoes. Crusts on the floors of submarine canyons off Kohala and East Molokai volcanoes indicate that these canyons are no longer serving as channelways for downslope, sediment-laden currents. Mahukona volcano was approximately synchronous with Hilo Ridge, both being younger than Hana Ridge. The Nuuanu landslide is considerably older than the Wailau landslide. The Waianae landslide southwest of Oahu has yielded samples with the greatest manganese-iron oxide crusts (9.5 mm thick) and therefore apparently represents the oldest submarine material yet found in the study area. The submarine volcanic field 100 km southwest of Oahu is apparently younger than the Waianae landslide.

Hawaii↗

USGS2004

Drowning of the - 150 m reef off Hawaii: A casualty of global meltwater pulse 1A?

We present evidence that the drowning of the - 150 m coral reef around Hawaii was caused by rapid sea-level rise associated with meltwater pulse 1A (MWP-1A) during the last deglaciation. New U/Th and 14C accelerator mass spectrometry dates, combined with reinterpretation of existing radiometric dates, constrain the age of the coral reef to 15.2-14.7 ka (U/Th age), indicating that reef growth persisted for 4.3 k.y. following the end of the Last Glacial Maximum at 19 ka. The drowning age of the reef is roughly synchronous with the onset of MWP-1A between 14.7 and 14.2 ka. Dates from coralline algal material range from 14 to 10 cal ka (calibrated radiocarbon age), 1-4 k.y. younger than the coral ages. A paleoenvironmental reconstruction incorporating all available radiometric dates, high-resolution bathymetry, dive observations, and coralgal paleobathymetry data indicates a dramatic rise in sea level around Hawaii ca. 14.7 ka. Paleowater depths over the reef crest increased rapidly above a critical depth (30-40 m), drowning the shallow reef-building Porites corals and causing a shift to deepwater coralline algal growth, preserved as a crust on the drowned reef crest. ?? 2004 Geological Society of America.

Geology↗

USGS2002

The proximal part of the giant submarine Wailau landslide, Molokai, Hawaii

The main break-in-slope on the northern submarine flank of Molokai at -1500 to -1250 m is a shoreline feature that has been only modestly modified by the Wailau landslide. Submarine canyons above the break-in-slope, including one meandering stream, were subaerially carved. Where such canyons cross the break-in-slope, plunge pools may form by erosion from bedload sediment carried down the canyons. West Molokai Volcano continued infrequent volcanic activity that formed a series of small coastal sea cliffs, now submerged, as the island subsided. Lavas exposed at the break-in-slope are subaerially erupted and emplaced tholeiitic shield lavas. Submarine rejuvenated-stage volcanic cones formed after the landslide took place and following at least 400-500 m of subsidence after the main break-in-slope had formed. The sea cliff on east Molokai is not the headwall of the landslide, nor did it form entirely by erosion. It may mark the location of a listric fault similar to the Hilina faults on present-day Kilauea Volcano. The Wailau landslide occurred about 1.5 Ma and the Kalaupapa Peninsula most likely formed 330??5 ka. Molokai is presently stable relative to sea level and has subsided no more than 30 m in the last 330 ka. At their peak, West and East Molokai stood 1.6 and 3 km above sea level. High rainfall causes high surface runoff and formation of canyons, and increases groundwater pressure that during dike intrusions may lead to flank failure. Active shield or postshield volcanism (with dikes injected along rift zones) and high rainfall appear to be two components needed to trigger the deep-seated giant Hawaiian landslides. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2000

Lava bubble-wall fragments formed by submarine hydrovolcanic explosions on Lō'ihi Seamount and Kīlauea Volcano

Glassy bubble-wall fragments, morphologically similar to littoral limu o Pele, have been found in volcanic sands erupted on Lō'ihi Seamount and along the submarine east rift zone of Kīlauea Volcano. The limu o Pele fragments are undegassed with respect to H 2 O and S and formed by mild steam explosions. Angular glass sand fragments apparently form at similar, and greater, depths by cooling-contraction granulation. The limu o Pele fragments from Lō'ihi Seamount are dominantly tholeiitic basalt containing 6.25–7.25% MgO. None of the limu o Pele samples from Lō'ihi Seamount contains less than 5.57% MgO, suggesting that higher viscosity magmas do not form lava bubbles. The dissolved CO 2 and H 2 O contents of 7 of the limu o Pele fragments indicate eruption at 1200±300 m depth (120±30 bar). These pressures exceed that generally thought to limit steam explosions. We conclude that hydrovolcanic eruptions are possible, with appropriate pre-mixing conditions, at pressures as great as 120 bar.

Hawai'i↗

USGS1999

Kilauea summit overflows: Their ages and distribution in the Puna District, Hawai'i

The tube-fed pahoehoe lava flows covering much of the northeast flank of Kilauea Volcano are named the 'Aila'au flows. Their eruption age, based on published and six new radiocarbon dates, is approximately AD 1445. The flows have distinctive paleomagnetic directions with steep inclinations (40??-50??) and easterly declinations (0??-10??E). The lava was transported ~40 km from the vent to the coast in long, large-diameter lava tubes; the longest tube (Kazumura Cave) reaches from near the summit to within several kilometers of the coast near Kaloli Point. The estimated volume of the 'Aila'au flow field is 5.2 ?? 0.8 km3, and the eruption that formed it probably lasted for approximately 50 years. Summit overflows from Kilauea may have been nearly continuous between approximately AD 1290 and 1470, during which time a series of shields formed at and around the summit. The 'Aila'au shield was either the youngest or the next to youngest in this series of shields. Site-mean paleomagnetic directions for lava flows underlying the 'Aila'au flows form only six groups. These older pahoehoe flows range in age from 2750 to <18,000 BP, and the region was inundated by lava flows only three times in the past 5000 years. The known intervals between eruptive events average ~1600 years and range from ~1250 years to >2200 years. Lava flows from most of these summit eruptions also reached the coast, but none appears as extensive as the 'Aila'au flow field. The chemistry of the melts erupted during each of these summit overflow events is remarkably similar, averaging approximately 6.3 wt.% MgO near the coast and 6.8 wt.% MgO near the summit. The present-day caldera probably formed more recently than the eruption that formed the 'Aila'au flows (estimated termination ca. AD 1470). The earliest explosive eruptions that formed the Keanakako'i Ash, which is stratigraphically above the 'Aila'au flows, cannot be older than this age.

Bulletin of Volcanology↗

USGS1996

Coral ages and island subsidence, Hilo drill hole

A 25.8-m-thick sedimentary section containing coral fragments occurs directly below a surface lava flow (the ∼1340 year old Panaewa lava flow) at the Hilo drill hole. Ten coral samples from this section dated by accelerator mass spectrometry (AMS) radiocarbon and five by thermal infrared multispectral scanner (TIMS) 230 Th/U methods show good agreement. The calcareous unit is 9790 years old at the bottom and 1690 years old at the top and was deposited in a shallow lagoon behind an actively growing reef. This sedimentary unit is underlain by a 34-m-thick lava flow which in turn overlies a thin volcaniclastic silt with coral fragments that yield a single 14 C date of 10,340 years. The age-depth relations of the dated samples can be compared with proposed eustatic sea level curves after allowance for island subsidence is taken. Island subsidence averages 2.2 mm/yr for the last 47 years based on measurements from a tide gage near the drill hole or 2.5–2.6 mm/yr for the last 500,000 years based on the ages and depths of a series of drowned coral reefs offshore from west Hawaii. The age-depth measurements of coral fragments are more consistent with eustatic sea levels as determined by coral dating at Barbados and Albrolhos Islands than those based on oxygen isotopic data from deep sea cores. The Panaewa lava flow entered a lagoon underlain by coral debris and covered the drill site with 30.9 m of lava of which 11 m was above sea level. This surface has now subsided to 4.2 m above sea level, but it demonstrates how a modern lava flow entering Hilo Bay would not only change the coastline but could extensively modify the offshore shelf.

Journal of Geophysical Research B: Solid Earth↗

USGS1996

Origin and depositional environment of clastic deposits in the Hilo drill hole, Hawaii

Volcaniclastic units cored at depths of about 87, 164, 178, 226, and 246 m below sea level and carbonate units located between depths of 27 and 53 m below sea level in the Hilo drill core were found to be deposited at or near sea level. Four of these units are hydroclastic deposits, formed when subaerially erupted Mauna Loa lava flows entered the ocean and fragmented to produce quenched, glassy fragments during hydrovolcanic explosions. Ash units 24 and 26, at 178 m depth, accumulated at sea level in a freshwater bog. They contain pyroxenes crystallized from tholeiitic magma that we infer erupted explosively at the summit of Kilauea volcano. Two carbon‐rich layers from these ashes have a weighted average radiocarbon age of 38.6 ± 0.9 ka; the ashes probably correlate with the oldest and thickest part of the Pahala ash. Ash unit 44, at the transition from Mauna Kea to Mauna Loa lava flows, was probably nearly 3.2 m thick and is inferred to be equivalent to the lower thick part of the composite Homelani ash mapped in Hilo and on the flanks of Mauna Kea. The age of this part of Homelani ash is between 128 ± 33 and 200 ± 10 ka; it may have erupted subglacially during the Pohakuloa glacial maxima on Mauna Kea. Beach sand units 12 and 22 were derived from nearby Mauna Loa and Mauna Kea lava flows. The middle of beach sand unit 38 was derived mainly from lava erupted near the distal end of the subaerial east rift zone of Kilauea volcano; these sands were transported about 33 km northwest to Hilo Bay by prevailing longshore currents. Combined age, depth, and sea level markers in the core allow us to determine that lava flow recurrence intervals averaged one flow every 4 kyr during the past 86 kyr and one flow every 16 kyr between 86 and 200 ka at the drill site and that major explosive eruptions that deposit thick ash in Hilo have occurred only twice in the last 400 kyr. These recurrence intervals support the moderate lava flow hazard zonation (zone 3) for coastal Hilo previously determined from surficial mapping.

Journal of Geophysical Research B: Solid Earth↗

USGS1996

Hydrothermal mineralization along submarine rift zones, Hawaii

This is the first article to describe mineralization of midplate submarine rift zones and hydrothermal manganese oxide mineralization of midplate volcanic edifices. Hydrothermal Mn oxides were recovered from submarine extensions of two Hawaiian rift zones, along Haleakala and Puna Ridges. These Mn oxides form two types of deposits, metallic stratiform layers in volcaniclastic rocks and cement for clastic rocks; both deposit types are composed of todorokite and bimessite. Thin Fe‐Mn crusts that coat some rocks formed by a combination of hydrogenetic and hydrothermal processes and are composed of δ‐MnO 2 . The stratiform layers have high Mn contents (mean 40%) and a large fractionation between Mn and Fe (Fe/Mn = 0.04). Unlike most other hydrothermal Mn oxide deposits, those from Hawaiian rift zones are enriched in the trace metals Zn, Co, Ba, Mo, Sr, V, and especially Ni (mean 0.16%). Metals are derived from three sources: mafic and ultramafic rocks leached by circulating hydrothermal fluids, clastic material (in Mn‐cemented sandstone), and seawater that mixed with the hydrothermal fluids. Mineralization on Haleakala Ridge occurred sometime during the past 200 to 400 ka, when the summit was at a water depth of more than 1,000 m. Hydrothermal circulation was probably driven by heat produced by intrusion of dikces, magma reservoirs, and flow of magma through axial and lateral conduits. The supply of seawater to ridge interiors must be extensive because of their high porosity and permeability. Precipitation of Mn oxide below the seafloor is indicated by its occurrence as cement, growth textures that show mineralizing fluids were introduced from below, and pervasive replacement of original matrix of clastic rocks.

Hawaii↗

USGS1994

Role of olivine cumulates in destabilizing the flanks of Hawaiian volcanoes

The south flank of Kilauea Volcano is unstable and has the structure of a huge landslide; it is one of at least 17 enormous catastrophic landslides shed from the Hawaiian Islands. Mechanisms previously proposed for movement of the south flank invoke slip of the volcanic pile over seafloor sediments. Slip on a low friction de??collement alone cannot explain why the thickest and widest sector of the flank moves more rapidly than the rest, or why this section contains a 300 km3 aseismic volume above the seismically defined de??collement. It is proposed that this aseismic volume, adjacent to the caldera in the direction of flank slip, consists of olivine cumulates that creep outward, pushing the south flank seawards. Average primary Kilauea tholeiitic magma contains about 16.5 wt.% MgO compared with an average 10 wt.% MgO for erupted subaerial and submarine basalts. This difference requires fractionation of 17 wt.% (14 vol.%) olivine phenocrysts that accumulate near the base of the magma reservoir where they form cumulates. Submarine-erupted Kilauea lavas contain abundant deformed olivine xenocrysts derived from these cumulates. Deformed dunite formed during the tholeiitic shield stage is also erupted as xenoliths in subsequent alkalic lavas. The deformation structures in olivine xenocrysts suggest that the cumulus olivine was densely packed, probably with as little as 5-10 vol.% intercumulus liquid, before entrainment of the xenocrysts. The olivine cumulates were at magmatic temperatures (>1100??C) when the xenocrysts were entrained. Olivine at 1100??C has a rheology similar to ice, and the olivine cumulates should flow down and away from the summit of the volcano. Flow of the olivine cumulates places constant pressure on the unbuttressed seaward flank, leading to an extensional region that localizes deep intrusions behind the flank; these intrusions add to the seaward push. This mechanism ties the source of gravitational instability to the caldera complex and deep rift systems and, therefore, limits catastrophic sector failure of Hawaiian volcanoes to their active growth phase, when the core of olivine cumulates is still hot enough to flow. ?? 1994 Springer-Verlag.

Bulletin of Volcanology↗