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D. W. Hall

Publications and source records attributed to D. W. Hall.

8 recordsLinked to original sources

Relationships between land uses and rainwater quality in a southcentral Pennsylvania watershed

ABSTRACT: Spatial and temporal variability in rainfall concentrations of nutrients, major ions, and herbicides was monitored at 7 locations in or near the Conodoguinet Creek watershed in south-central Pennsylvania from 1991.1993. Results were used to (1) compare precipitation quality in forested, agricultural and urban areas, and (2) assess the practicality of using volunteer citizen monitoring in such a study.

Journal of the American Water Resources Associatio

Aircraft and runway deicers at General Mitchell International Airport, Milwaukee, Wisconsin, USA. 1. Biochemical oxygen demand and dissolved oxygen in receiving streams

Aircraft and runway deicers are used during cold weather at many of the world's airports to facilitate safe air travel. Propylene glycol-, ethylene glycol-, and urea-based deicers are known to have very high biochemical oxygen demand. At General Mitchell International Airport (GMIA) in Milwaukee, Wisconsin, USA, deicer application, water chemistry, and dissolved oxygen (DO) data were collected for two deicing seasons in order to evaluate and define premanagement water quality parameters prior to the implementation of a glycol management program. Calculations using stream-monitoring data during a controlled release of deicer provided an estimate of 0.8/d for the first-order decay rate constant, substantially higher than published laboratory test results. For eight precipitation events with deicing activities, between 2.4 and 99% of propylene and ethylene glycol applied to aircraft was delivered directly to receiving streams. The percentage of glycol runoff during an event increased with increasing storm-flow volume. Elevated concentrations of glycol and biochemical oxygen demand were measured downstream from the airport. However, the frequency of low DO concentrations in the receiving streams is comparable with that at an upstream reference site. This is possibly due to slowed bacteria metabolism at low water temperatures, short travel times, and dilution from downstream tributaries.

Wisconsin

Offshore-onshore correlation of upper Pleistocene strata, New Jersey Coastal Plain to continental shelf and slope

High-resolution seismic reflection profiles (~ 1-5 m resolution), including Geopulse(TM), Uniboom(TM), minisparker, small air gun, and water gun sources, are used to trace the ?? 18O stage 5 portion of the outcropping Cape May Formation across the shelf to the continental slope. The ?? 18O stage 5/6 boundary identified at Ocean Drilling Project (ODP) Site 903 on the continental slope anchors the onshore-offshore seismic correlations. Above the ?? 18O stage 5 sequence, there are distinguishable lowstand systems tracts (LST), transgressive systems tracts (TST) and highstand systems tracts (HST) that correlate with ?? 18O stages 4 through 1. Atlantic Margin Coring Project (AMCOR) holes 6009, 6010, 6011, 6020, and 6021C provide age and paleoenvironmental indicators that agree with these correlations. The sub-arctic paleoenvironmental indicators in sequences of ?? 18O stage 3 agree with the cooler temperatures and lower sea-level highstands of that time. Thicker ?? 18O stage 3 and 4 sequences are preserved in the Paleo-Hudson River incised valley across the shelf. The expanded ice sheets during stage ?? 18O 3 compared to ?? 18O stages 1 and 5 probably increased sediment discharge in the Hudson River drainage system. (C) 2000 Elsevier Science B.V. All rights reserved.

Conference Paper

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Hydrology of a small carbonate site near Ephrata, Pennsylvania, prior to implementation of nutrient management

The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture and Pennsylvania Department of Environmental Protection, investigated the effects of agricultural best-management practices on water quality in the Conestoga River headwaters watershed. This report describes environmental factors and the surface-water and ground-water quality of one 47.5-acre field site, Field-Site 2, from October 1984 through September 1986, prior to implementation of nutrient management. The site is partially terraced agricultural cropland underlain by carbonate rock. Twenty-seven acres are terraced, pipe-drained, and are under no-till cultivation. The remaining acreage is under minimum-till cultivation. Corn is the primary crop. The average annual rate of fertilization at the site was 480 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. An unconfined limestone and dolomitic aquifer underlies the site, Depth to bedrock ranges from 5 to 30 feet below land surface. Estimated specific yields range from 0.05 to 0.10, specific capacities of wells range from less than 1 to about 20 gallons per minute per foot of drawdown, and estimates of transmissivities range from 10 to 10,000 square feet per day. Average ground-water recharge was estimated to be about 23 inches per year. The specific capacity and transmissivity data indicate that two aquifer regimes are present at the site. Wells drilled into dolomites in the eastern part of the site have larger specific capacities (averaging 20 gallons per minute per foot of drawdown) relative to specific capacities (averaging less than 1 gallon per minute per foot of drawdown) of wells drilled into limestones in the western part of the site. Median concentrations of soil-soluble nitrate and soluble phosphorus in the top 4 feet of silt- or silty-clay-loam soil ranged from 177 to 329 and 8.5 to 35 pounds per acre, respectively. Measured runoff from the pipe-drained terraces ranged from 10 to 48,000 cubic feet and was 1.7 and 0.8 percent, respectively, of the 1985 and 1986 annual precipitation. An estimated 90,700 cubic feet of surface runoff carried 87 pounds to total nitrogen and 37 pounds of total phosphorus, or less that 0.65 percent of the amount of either nutrient applied during the study period. Rainfall on the snow-covered, frozen ground produced more that half of the runoff and nitrogen and phosphorus loads measured in pipe-drained runoff. Graphical and regression analyses of surface runoff suggest that (1) mean-storm concentrations of total nitrogen species and total phosphorus decreased with increasing time between a runoff event and the last previous nutrient application, and (2) mean total-phosphorus concentrations approached a baseline value (estimated at 2 to 5 milligrams per liter for total-phosphorus concentrations) after several months without nutrient applications. Dissolved nitrate concentrations in ground water in wells unaffected by an on-site ammonia spill ranged from 7.4 to 100 milligrams per liter. Average annual additions and removals of nitrogen were estimated. Nitrogen was added to the site by applications of manure and commercial fertilizer nitrogen, as well as by precipitation and ground water entering across the western site boundary. These sources of nitrogen accounted for 95, 3, 1, and 1 percent, respectively, of estimated additions. Nitrogen was removed from the site in harvested crops, by ground-water discharge, by volatilization, and in surface runoff, which accounted for 42, 28, 29, and less than 1 percent, respectively, of estimated removals.

Pennsylvania

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Effects of pipe-outlet terracing on quantity and quality of surface runoff and ground water in a small carbonate-rock basin near Churchtown, Pennsylvania, 1983-89

Terracing effects on surface-runoff and ground- water quantity and quality were investigated by the U.S. Geological Survey, in cooperation with Pennsylvania Department of Environmental Resources, during 1983-89 at a 23.1-acre agricultural site in Lancaster County, Pa., as part of the 1982 Rural Clean Water Program. The site, underlain by carbonate rock, was primarily corn and alfalfa fields; the median slope was 6 percent.Normal precipitation is about 42 inches per year. Average annual runoff was 11 percent and ground- water recharge was 37 percent of precipitation.Runoff quantity, suspended-sediment, and nutrient data, ground-water level and nutrient data, and precipitation-quantity data were collected for 21 months prior to, and 58 months after, pipe-outlet terrace construction. Data were analyzed by use of graphical, regression, covariate, cluster, Mann- Whitney Rank Sum test, and double-mass curvetechniques. Terracing changed runoff characteristics. Storm characteristics were similar throughout the study period. However, after terracing, storms producing less than 0.4 inch of precipitation rarely produced runoff. Total-storm discharge as a function of precipitation did not change significantly throughout the range of runoff-producing storms after terracing. Multiple-discharge peaks on hydrographs before terracing did not occur after terracing when hydrographs reflected the stepwisedraining of each terrace through the pipe outlet. After an initial 2-year period of terrace stabilization, suspended-sediment yield in runoff decreased significantly as a function of runoff. This result was expected because terracing decreased runoff energy, and because terrace ponding allowed time for sediment redeposition. Nitrate plus nitrite yields increased proportionally throughout the range of runoff during the post-terracing period relative to the pre- terracing period. After terracing, a combination of increased soil contact time and increased nitrification caused by wetter soils is believed to have increased nitrate concentrations in runoff. No significant change was found in yields of total nitrogen, ammonia plus organic nitrogen, or total phosphorus relative to runoff before and after terracing. Limited data suggest that fine-sediment particles (less than 0.62 micrometers in diameter), which continued to be discharged from the site, transported most of the phosphorus. Terracing did not significantly change the quantity of recharge to the carbonate aquifer. The mean annual water-table altitude did not change after terracing. Nitrate concentrations of ground water increased significantly at four of the site wells after terracing, probably because of increased contact time of the recharge with nutrient-rich soils in ponded terrace water. Qualitative evidence indicates that large decreases in nutrient requirements and nitrogen applications because of a crop change from corn to alfalfa upgradient of two site wells resulted in either no detectable change or a significant decrease in nitrate concentrations of ground water after terracing.

Pennsylvania

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Effects of nutrient management on quality of surface runoff and ground water at a small carbonate-rock site near Ephrata, Pennsylvania, 1984-90

The U.S. Geological Survey and the Pennsylvania Department of Environmental Protection conducted a study from 1984 to 1990 to determine theeffects of the implementation and practice of nutrient management [an agricultural best-management practice (BMP)] on the quality of surface runoff and ground water at a 55-acre crop and livestock farm in carbonate terrain nearEphrata, Pa. Implementation of nutrient management at Field-Site 2 resulted in application decreases of 33 percent for nitrogen and 29 percent for phosphorus. There wereno significant changes in nitrogen or phosphorusloads for a given amount of runoff from the pre-BMP to the post-BMP periods. However, less than 2 percent of the applied nutrients weredischarged with runoff throughout the study period.After the implementation of nutrient management, statistically significant decreases in concentrations of nitrate in ground-water samples occurred at threeof the four wells monitored throughout the pre- and post-BMP periods. The largest decreases in nitrate concentrations occurred at wells where samples hadthe largest nitrate concentrations prior to nutrient management. Changes in nitrogen applications to the contributing areas of five wells were correlated with nitrate concentrations of the well water. The correlations between the timing and amount of applied nitrogen and changes in ground-water quality met the four conditions that are characteristic of a cause-effect relation: an association, consistency, responsiveness, and a mechanism. Changes in ground-water nitrate concentrations lagged behind changes in loading of nitrogen fertilizers (primarily manure) by approximately 4 to 19 months.

Pennsylvania

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Characterization of surface-runoff and ground-water quantity and quality in a small carbonate basin near Churchtown, Pennsylvania, prior to terracing and implementation of nutrient management: Water-quality study of the Conestoga River headwaters, Pennsylvania

The U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection1 , conducted a study as part of the U.S. Department of Agriculture's Rural Clean Water Program to determine the effects of agricultural best-management practices on surface-water and ground-water quality in the Conestoga River headwaters basin. This report describes Field-Site 1 and characterizes the surface-runoff and ground-water quantity and quality at the site from January 1983 through September 1984, before the implementation of terracing and nutrient-management best-management practices. The 22.1-acre site, part of two dairy farms, was cropland used primarily for the production of corn and alfalfa, and is underlain by carbonate rock. During the 21-month study period, 91.2 inches of precipitation fell, of which 66 percent occurred during the 1984 water year. Of the 169 storms of 0.10 inch or larger, 97 produced measurable runoff. The average annual application of nutrients to the 14.4 acres of cornfields was 410 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. About three times more nutrients were applied during 1984 water year than during the 1983 water year. The approximate soil-nitrate concentration as nitrogen for the study period was 8.2 milligrams per kilogram in the top 8 inches of soil. Runoff for the study period totalled 714,000 cubic feet, or 9.8 percent of total precipitation. Eighty-eight percent of the runoff occurred during the 1984 water year. Regression analyses indicate that total runoff was controlled primarily by total precipitation amounts during storms and by antecedent moisture conditions; mean event and maximum instantaneous discharges are controlled by precipitation intensity and by antecedent moisture conditions. Regression analyses also suggest that crop cover on the corn acreage affected runoff amounts and rates. Mean concentrations in runoff ranged from 24 to 73,000 milligrams per liter for suspended sediment, 0.45 to 24 milligrams per liter for total phosphorus, and 1.5 to 55 milligrams per liter for total nitrogen. Of the total nitrogen in instantaneous runoff samples, a median of 72 percent was total organic nitrogen. Results of multiple regression analyses suggest that mean nitrogen concentrations in runoff (1) increased with increased surface-nitrogen applications made prior to runoff, and (2) were diluted with increased precipitation duration. Runoff from storms on frozen ground produced the highest loads of nitrogen in runoff. Over the 21-month study period, an estimated 258 tons of suspended sediment, 314 pounds of nitrogen, and 176 pounds of phosphorus were transported with runoff from the site. Of this, 88 percent of the nitrogen and phosphorus loads and 94 percent of the suspended-sediment load were discharged during the wet 1984 water year. The loads for the study period represent 2.5 percent of the total nitrogen and 5.5 percent of the total phosphorus applied to the site as manure and commercial fertilizer. The ground-water basin at the site is slightly larger than the surface-water basin. Ground-water levels, except at one well, responded quickly to recharge; water levels peaked several hours to a day after precipitation. Surface-applied materials moved rapidly to the water table through macropores and slowly by transport through micropores in the unsaturated zone. Median concentrations of dissolved nitrate ranged from 9.2 to 13 milligrams per liter as nitrogen for ground-water samples collected monthly from five wells and a spring. Dissolved nitrate comprised 93 percent (median percentage) of the total nitrogen in ground-water samples. The effect of recharge on ground-water nitrate concentrations was affected by variations in nutrient availability at the land surface and in the unsaturated zone. A lag time of 1 to 3 months was observed between the time that nitrogen was applied to the land surface and local maximums in nitrate concentrations were detected in ground water unaffected by recharge events. Approximately 3,187,000 cubic feet of ground water and an associated 2,200 pounds of nitrate-nitrogen discharged from the site during the study period. For the study period, 42 percent of the precipitation recharged to ground water, 10 percent became runoff, and 48 percent evapotranspired. Inputs of nitrogen to the study area were estimated to be 93 percent from manure, 5 percent from commercial fertilizer, and 2 percent from precipitation. Nitrogen outputs from the system were estimated to be 38 percent to crop uptake, 39 percent to volatilization, 20 percent to ground-water discharge, and 3 percent to surface runoff.

Pennsylvania