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D. Schmitt

Publications and source records attributed to D. Schmitt.

3 recordsLinked to original sources

Obliquity-paced Pliocene West Antarctic ice sheet oscillations

Thirty years after oxygen isotope records from microfossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth's orbital geometry control the ice ages 1 , fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles 2 . Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the 'warmer-than-present' early-Pliocene epoch ( 5–3 Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming 3 . Here we present a marine glacial record from the upper 600 m of the AND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, 40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth's axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to 3 °C warmer than today 4 and atmospheric CO 2 concentration was as high as 400 p.p.m.v. (refs 5 , 6 ). The evidence is consistent with a new ice-sheet/ice-shelf model 7 that simulates fluctuations in Antarctic ice volume of up to +7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the East Antarctic ice sheet, in response to ocean-induced melting paced by obliquity. During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and air temperatures above freezing, suggesting an additional influence of surface melt 8 under conditions of elevated CO 2 .

Nature↗

Influence of natural organic matter on the adsorption of metal ion onto clay particles

The influence of natural organic matter (NOM) on the adsorption of Al, Fe, Zn, and Pb onto clay minerals was investigated. Adsorption experiments were carried out at pH = 5 and pH = 7 in the presence and absence of NOM. In general, the presence of NOM decreased the adsorption of metal ions onto the clay particles. Al and Fe were strongly influenced by NOM, whereas Zn and Pb adsorption was only slightly altered. The interaction of the metal ions with the minerals and the influence of NOM on this interaction was investigated by coupling SdFFF with an inductively coupled plasma mass spectrometer (ICPMS) or an inductively coupled plasma atomic emission spectrometer (ICPAES). Quantitative atomization of the clay particles in the ICP was confirmed by comparing elemental content determined by direct injection of the clay into the ICPMS with values from acid digestion. Particle sizes of the clays were found to be between 0.1 and 1 μm by sedimentation field-flow fractionation (SdFFF) with UV detection. Aggregation of particles due to metal adsorption was observed using SdFFF-ICPMS measurements. This aggregation was dependent on the specific metal ion and decreased in the presence of NOM and at higher pH value.

Environmental Science & Technology↗

Analysis of borehole televiewer measurements in the Vorotilov drillhole, Russia - First results

In the Eurasian part of the World Stress Map almost the whole region east of the Tornquist-Teisseyre line is terra incognita. The closure of this information gap is of fundamental importance to the understanding of the geodynamics of the Eurasian continent. A detailed analysis of stress-induced wellbore breakouts has been performed over a 4.1-km-long depth interval in the Vorotilov drillhole (VGS). The borehole is located in the central part of the Russian platform, right in the center of the Vorotilov meteorite impact crater 60 km to the NNE of the city of Nizni Novgorod. An ultrasonic borehole televiewer (BHTV) was used to obtain high-resolution acoustical images from the borehole wall. With an interactive system for analyzing BHTV data the azimuth and shape of borehole breakouts occurring in the depth range of 1.3–4.8 km were analyzed. A statistical analysis of the resulting orientation profile of the breakout azimuths yields an overall direction of the maximum horizontal principal stress S H of N 137°E ± 15°. Variations of breakout orientation with depth ranging from a few degrees up to more than 90° are seen on various depth scales. The observed stress direction of N 137°E agrees very well with the average S H orientation of N 145°E in Central Europe. If this measurement is taken as representative for the Russian platform, the stress field in Russia is only slightly rotated in comparison to Central Europe. This can possibly be interpreted as indicative for the stress field to be governed by broad scale tectonic forces, such as a strong contribution from the forces exerted by the collision zone in the Alpine-Himalayan belt and by the Mid-Atlantic ridge.

Vorotilov drillhole↗