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D. McKnight

Publications and source records attributed to D. McKnight.

5 recordsLinked to original sources
USGS2001

Annual maxima in Zn concentrations during spring snowmelt in streams impacted by mine drainage

Long-term hydrochemical monitoring and 2 years of intensive sampling were used to identify annual patterns in Zn export from three neighboring catchments in Summit County, Colorado. These catchments are characterized by a snowmelt-dominated hydrologic cycle, but range in the level of mining impact from little to severe. Zn concentrations increased during snowmelt along stream reaches with a history of mining, but were diluted by snowmelt where metals originated in widely disseminated pyrite in the host rock of the catchment. Inter-site differences in the relationship between Zn and sulfate, together with inter-annual variability in the timing and magnitude of peak Zn concentrations suggest that a portion of the Zn flush is retarded, perhaps through interaction with cation exchange sites in soil. Although Dissolved Organic Carbon (DOC) concentrations also increase during snowmelt, there was no indication that the export of Zn was facilitated by the flush of organic carbon.

Environmental Geology↗
USGS1996

Geochemistry of aquatic humic substances in the Lake Fryxell basin, Antarctica

Dissolved organic carbon (DOC) in Lake Fryxell, 10 streams flowing into the lake, and the moat surrounding the lake was studied to determine the influence of sources and biogeochemical processes on its distribution and chemical nature. Lake Fryxell is an amictic, permanently ice-covered lake in the McMurdo Dry Valleys which contains benthic and planktonic microbial populations, but receives essentially no input of organic material from the ahumic soils of the watershed. Biological activity in the water column does not appear to influence the DOC depth profile, which is similar to the profiles for conservative inorganic constituents. DOC values for the streams varied with biomass in the stream channel, and ranged from 0.2 to 9.7 mg C/L. Fulvic acids in the streams were a lower percentage of the total DOC than in the lake. These samples contain recent carbon and appear to be simpler mixtures of compounds than the lake samples, indicating that they have undergone less humification. The fulvic acids from just above the sediments of the lake have a high sulfur content and are highly aliphatic. The main transformations occurring as these fractions diffuse upward in the water column are 1) loss of sulfur groups through the oxycline and 2) decrease in aliphatic carbon and increase in the heterogeneity of aliphatic moieties. The fraction of modem 14C content of the lake fulvic acids range from a minimum of 0.68 (approximately 3000 years old) at 15m depth to 0.997 (recent material) just under the ice. The major processes controlling the DOC in the lake appear to be: 1) The transport of organic matter by the inflow streams resulting in the addition of recent organic material to the moat and upper waters of the lake; 2) The diffusion of organic matter composed of relict organic material and organic carbon resulting from the degradation of algae and bacteria from the bottom waters or sediments of the lake into overlying glacial melt water; 3) The addition of recent organic matter to the bottom waters of the lake from the moat.

Biogeochemistry↗
USGS1994

McMurdo LTER: streamflow measurements in Taylor Valley

Has established a stream gaging network for the three major lake basins in Taylor Valley. These data are critical for determining nutrient budgets for the lake ecosystems and for understanding physical factors controlling microbial mats in the streams.

Antarctic Journal of the United States↗
USGS1988

Diel variations in iron chemistry in an acidic stream in the Colorado Rocky Mountains, USA

In the Snake River, an acidic mountain stream in the Colorado Rocky Mountains, the concentration of dissolved iron is apparently unrelated to seasonal changes in hydrologic regime, which strongly influence the concentrations of most other dissolved constituents. Hourly sampling indicated that short-term fluctuations in iron chemistry occur, whereas the concentrations of most other dissolved constituents, including other trace metals, remain stable. During the day, greater concentrations of dissolved total and ferrous iron generally occurred during periods of full sunlight. Photoreduction of hydrous iron oxides, which are abundant in the fine sediment and as coatings on the rocks, may be responsible for these observations. Iron chemistry also varied at night, decreasing in dissolved total and ferrous iron until about midnight and increasing until dawn. Oxidation of ferrous iron, and several microbial processes, may contribute to these nighttime changes. In an on-site batch experiment using rocks and streamwater, an increase in dissolved total and ferrous iron occurred on exposure to sunlight, and ferrous oxidation occurred on return to darkness. Short-term fluctuations in iron chemistry are consistent with the lack of correlation between iron and other constituents in the long-term data, and illustrate the potential importance of complex in-stream processes in such stream systems.

Colorado↗