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Geology topics

D. H. Schoellhamer

Publications and source records attributed to D. H. Schoellhamer.

At least 19 recordsLinked to original sources

Methyl mercury dynamics in a tidal wetland quantified using in situ optical measurements

We assessed monomethylmercury (MeHg) dynamics in a tidal wetland over three seasons using a novel method that employs a combination of in situ optical measurements as concentration proxies. MeHg concentrations measured over a single spring tide were extended to a concentration time series using in situ optical measurements. Tidal fluxes were calculated using modeled concentrations and bi-directional velocities obtained acoustically. The magnitude of the flux was the result of complex interactions of tides, geomorphic features, particle sorption, and random episodic events such as wind storms and precipitation. Correlation of dissolved organic matter quality measurements with timing of MeHg release suggests that MeHg is produced in areas of fluctuating redox and not limited by buildup of sulfide. The wetland was a net source of MeHg to the estuary in all seasons, with particulate flux being much higher than dissolved flux, even though dissolved concentrations were commonly higher. Estimated total MeHg yields out of the wetland were approximately 2.5 μg m −2 yr −1 —4–40 times previously published yields—representing a potential loading to the estuary of 80 g yr −1 , equivalent to 3% of the river loading. Thus, export from tidal wetlands should be included in mass balance estimates for MeHg loading to estuaries. Also, adequate estimation of loads and the interactions between physical and biogeochemical processes in tidal wetlands might not be possible without long-term, high-frequency in situ measurements.

Limnology and Oceanography

Mercury concentrations and loads in a large river system tributary to San Francisco Bay, California, USA

In order to estimate total mercury (Hg T ) loads entering San Francisco Bay, USA, via the Sacramento-San Joaquin River system, unfiltered water samples were collected between January 2002 and January 2006 during high flow events and analyzed for Hg T . Unfiltered Hg T concentrations ranged from 3.2 to 75 ng/L and showed a strong correlation (r 2 = 0.8, p < 0.001, n = 78) to suspended sediment concentrations (SSC). During infrequent large floods, Hg T concentrations relative to SSC were approximately twice as high as observed during smaller floods. This difference indicates the transport of more Hg-contaminated particles during high discharge events. Daily Hg T loads in the Sacramento-San Joaquin River at Mallard Island ranged from below the limit of detection to 35 kg. Annual Hg T loads varied from 61 ?? 22 kg (n = 5) in water year (WY) 2002 to 470 ?? 170 kg (n = 25) in WY 2006. The data collected will assist in understanding the long-term recovery of San Francisco Bay from Hg contamination and in implementing the Hg total maximum daily load, the long-term cleanup plan for Hg in the Bay. ?? 2009 SETAC.

Environmental Toxicology and Chemistry

Dietary flexibility in three representative waterbirds across salinity and depth gradients in salt ponds of San Francisco Bay

Salt evaporation ponds have existed in San Francisco Bay, California, for more than a century. In the past decade, most of the salt ponds have been retired from production and purchased for resource conservation with a focus on tidal marsh restoration. However, large numbers of waterbirds are found in salt ponds, especially during migration and wintering periods. The value of these hypersaline wetlands for waterbirds is not well understood, including how different avian foraging guilds use invertebrate prey resources at different salinities and depths. The aim of this study was to investigate the dietary flexibility of waterbirds by examining the population number and diet of three feeding guilds across a salinity and depth gradient in former salt ponds of the Napa-Sonoma Marshes. Although total invertebrate biomass and species richness were greater in low than high salinity salt ponds, waterbirds fed in ponds that ranged from low (20 g l −1 ) to very high salinities (250 g l −1 ). American avocets (surface sweeper) foraged in shallow areas at pond edges and consumed a wide range of prey types (8) including seeds at low salinity, but preferred brine flies at mid salinity (40–80 g l −1 ). Western sandpipers (prober) focused on exposed edges and shoal habitats and consumed only a few prey types (2–4) at both low and mid salinities. Suitable depths for foraging were greatest for ruddy ducks (diving benthivore) that consumed a wide variety of invertebrate taxa (5) at low salinity, but focused on fewer prey (3) at mid salinity. We found few brine shrimp, common in higher salinity waters, in the digestive tracts of any of these species. Dietary flexibility allows different guilds to use ponds across a range of salinities, but their foraging extent is limited by available water depths.

Hydrobiologia

Calibration of an estuarine sediment transport model to sediment fluxes as an intermediate step for simulation of geomorphic evolution

Modeling geomorphic evolution in estuaries is necessary to model the fate of legacy contaminants in the bed sediment and the effect of climate change, watershed alterations, sea level rise, construction projects, and restoration efforts. Coupled hydrodynamic and sediment transport models used for this purpose typically are calibrated to water level, currents, and/or suspended-sediment concentrations. However, small errors in these tidal-timescale models can accumulate to cause major errors in geomorphic evolution, which may not be obvious. Here we present an intermediate step towards simulating decadal-timescale geomorphic change: calibration to estimated sediment fluxes (mass/time) at two cross-sections within an estuary. Accurate representation of sediment fluxes gives confidence in representation of sediment supply to and from the estuary during those periods. Several years of sediment flux data are available for the landward and seaward boundaries of Suisun Bay, California, the landward-most embayment of San Francisco Bay. Sediment flux observations suggest that episodic freshwater flows export sediment from Suisun Bay, while gravitational circulation during the dry season imports sediment from seaward sources. The Regional Oceanic Modeling System (ROMS), a three-dimensional coupled hydrodynamic/sediment transport model, was adapted for Suisun Bay, for the purposes of hindcasting 19th and 20th century bathymetric change, and simulating geomorphic response to sea level rise and climatic variability in the 21st century. The sediment transport parameters were calibrated using the sediment flux data from 1997 (a relatively wet year) and 2004 (a relatively dry year). The remaining years of data (1998, 2002, 2003) were used for validation. The model represents the inter-annual and annual sediment flux variability, while net sediment import/export is accurately modeled for three of the five years. The use of sediment flux data for calibrating an estuarine geomorphic model guarantees that modeled geomorphic evolution will not exceed the actual supply of sediment from the watershed and seaward sources during the calibration period. Decadal trends in sediment supply (and therefore fluxes) can accumulate to alter decadal geomorphic change. Therefore, simulations of future geomorphic evolution are bolstered by this intermediate calibration step.

Continental Shelf Research

Temporal downscaling of decadal sediment load estimates to a daily interval for use in hindcast simulations

In this study we used hydrologic proxies to develop a daily sediment load time-series, which agrees with decadal sediment load estimates, when integrated. Hindcast simulations of bathymetric change in estuaries require daily sediment loads from major tributary rivers, to capture the episodic delivery of sediment during multi-day freshwater flow pulses. Two independent decadal sediment load estimates are available for the Sacramento/San Joaquin River Delta, California prior to 1959, but they must be downscaled to a daily interval for use in hindcast models. Daily flow and sediment load data to the Delta are available after 1930 and 1959, respectively, but bathymetric change simulations for San Francisco Bay prior to this require a method to generate daily sediment load estimates into the Delta. We used two historical proxies, monthly rainfall and unimpaired flow magnitudes, to generate monthly unimpaired flows to the Sacramento/San Joaquin Delta for the 1851-1929 period. This step generated the shape of the monthly hydrograph. These historical monthly flows were compared to unimpaired monthly flows from the modern era (1967-1987), and a least-squares metric selected a modern water year analogue for each historical water year. The daily hydrograph for the modern analogue was then assigned to the historical year and scaled to match the flow volume estimated by dendrochronology methods, providing the correct total flow for the year. We applied a sediment rating curve to this time-series of daily flows, to generate daily sediment loads for 1851-1958. The rating curve was calibrated with the two independent decadal sediment load estimates, over two distinct periods. This novel technique retained the timing and magnitude of freshwater flows and sediment loads, without damping variability or net sediment loads to San Francisco Bay. The time-series represents the hydraulic mining period with sustained periods of increased sediment loads, and a dramatic decrease after 1910, corresponding to a reduction in available mining debris. The analogue selection procedure also permits exploration of the morphological hydrograph concept, where a limited set of hydrographs is used to simulate the same bathymetric change as the actual set of hydrographs. The final daily sediment load time-series and morphological hydrograph concept will be applied as landward boundary conditions for hindcasting simulations of bathymetric change in San Francisco Bay.

California

Chapter 24 Lateral variability of the estuarine turbidity maximum in a tidal strait

The behavior of the estuarine turbidity maximum (ETM) in response to freshwater flow, tidal forcing, and bed dynamics has been studied extensively by many researchers. However, the majority of investigations focus on the longitudinal position and strength of the ETM, which can vary over tidal, spring-neap, and seasonal timescales. ETMs may become longitudinally fixed due to bathymetric constraints, and thus the lateral position may vary significantly on differing timescales. Lateral dynamics of the ETM may affect contaminant uptake in biologically active regions, while local deposition patterns may be affected by the dominant lateral position. A longitudinally fixed ETM in Carquinez Strait, California, was studied to specifically investigate the dynamics of lateral ETM variability during April 2004. an abrupt topographical control on the north side restricts gravitational circulation resulting in convergence and particle trapping, creating the ETM. The cross-section was continuously monitored with two upward-looking velocity profilers and four optical backscatterance sensors. In addition, cross-sectional measurements over one tidal cycle were performed during a spring tide with boat-mounted velocity and water quality profilers. The lateral and vertical positions of the ETM center of mass varied by a maximum of 250 and 5 m, respectively (20% of width and 17% of depth) over the tidal timescale, while tidally averaged lateral and vertical positions varied substantially less (50 and 1 m, respectively). ETM position responded to tidal energy (Urms), with higher vertical position and a laterally centered position resulting from increased mixing during spring tides, and a northerly lateral position from decreased mixing during neap tides. Hydrodynamic and sediment transport modeling of this period reproduces the lateral and vertical movements of the ETM center of mass. Modeling results indicate increased gravitational circulation in the strait and enhanced particle trapping on the north side during neap tides, thus displacing the ETM center of mass to the north. The south side has no topographical control, and therefore no particle trapping mechanism exists on the south side. Secondary circulation is strengthened on spring tides, distributing near-bed sediment toward the south. The field and modeling results are in agreement with previous work in Carquinez Strait and further elucidate the strong lateral variation of the ETM, even in narrow, energetic tidal straits. ?? 2008 Elsevier B.V. All rights reserved.

Proceedings in Marine Science

Chapter 31 Sensitivity and spin-up times of cohesive sediment transport models used to simulate bathymetric change

Bathymetric change in tidal environments is modulated by watershed sediment yield, hydrodynamic processes, benthic composition, and anthropogenic activities. These multiple forcings combine to complicate simple prediction of bathymetric change; therefore, numerical models are necessary to simulate sediment transport. Errors arise from these simulations, due to inaccurate initial conditions and model parameters. We investigated the response of bathymetric change to initial conditions and model parameters with a simplified zero-dimensional cohesive sediment transport model, a two-dimensional hydrodynamic/sediment transport model, and a tidally averaged box model. The zero-dimensional model consists of a well-mixed control volume subjected to a semidiurnal tide, with a cohesive sediment bed. Typical cohesive sediment parameters were utilized for both the bed and suspended sediment. The model was run until equilibrium in terms of bathymetric change was reached, where equilibrium is defined as less than the rate of sea level rise in San Francisco Bay (2.17 mm/year). Using this state as the initial condition, model parameters were perturbed 10% to favor deposition, and the model was resumed. Perturbed parameters included, but were not limited to, maximum tidal current, erosion rate constant, and critical shear stress for erosion. Bathymetric change was most sensitive to maximum tidal current, with a 10% perturbation resulting in an additional 1.4 m of deposition over 10 years. Re-establishing equilibrium in this model required 14 years. The next most sensitive parameter was the critical shear stress for erosion; when increased 10%, an additional 0.56 m of sediment was deposited and 13 years were required to re-establish equilibrium. The two-dimensional hydrodynamic/sediment transport model was calibrated to suspended-sediment concentration, and despite robust solution of hydrodynamic conditions it was unable to accurately hindcast bathymetric change. The tidally averaged box model was calibrated to bathymetric change data and shows rapidly evolving bathymetry in the first 10-20 years, though sediment supply and hydrodynamic forcing did not vary greatly. This initial burst of bathymetric change is believed to be model adjustment to initial conditions, and suggests a spin-up time of greater than 10 years. These three diverse modeling approaches reinforce the sensitivity of cohesive sediment transport models to initial conditions and model parameters, and highlight the importance of appropriate calibration data. Adequate spin-up time of the order of years is required to initialize models, otherwise the solution will contain bathymetric change that is not due to environmental forcings, but rather improper specification of initial conditions and model parameters. Temporally intensive bathymetric change data can assist in determining initial conditions and parameters, provided they are available. Computational effort may be reduced by selectively updating hydrodynamics and bathymetry, thereby allowing time for spin-up periods. reserved.

Proceedings in Marine Science

Suspended sediment and sediment-associated contaminants in San Francisco Bay

Water-quality managers desire information on the temporal and spatial variability of contaminant concentrations and the magnitudes of watershed and bed-sediment loads in San Francisco Bay. To help provide this information, the Regional Monitoring Program for Trace Substances in the San Francisco Estuary (RMP) takes advantage of the association of many contaminants with sediment particles by continuously measuring suspended-sediment concentration (SSC), which is an accurate, less costly, and more easily measured surrogate for several trace metals and organic contaminants. Continuous time series of SSC are collected at several sites in the Bay. Although semidiurnal and diurnal tidal fluctuations are present, most of the variability of SSC occurs at fortnightly, monthly, and semiannual tidal time scales. A seasonal cycle of sediment inflow, wind-wave resuspension, and winnowing of fine sediment also is observed. SSC and, thus, sediment-associated contaminants tend to be greater in shallower water, at the landward ends of the Bay, and in several localized estuarine turbidity maxima. Although understanding of sediment transporthas improved in the first 10 years of the RMP, determining a simple mass budget of sediment or associated contaminants is confounded by uncertainties regarding sediment flux at boundaries, change in bed-sediment storage, and appropriate modeling techniques. Nevertheless, management of sediment-associated contaminants has improved greatly. Better understanding of sediment and sediment-associated contaminants in the Bay is of great interest to evaluate the value of control actions taken and the need for additional controls.

Environmental Research

Constancy of the relation between floc size and density in San Francisco Bay

The size and density of fine-sediment aggregates, or flocs, govern their transport and depositional properties. While the mass and volume concentrations of flocs can be measured directly or by optical methods, they must be determined simultaneously to gain an accurate density measurement. Results are presented from a tidal cycle study in San Francisco Bay, where mass concentration was determined directly, and volume concentration was measured in 32 logarithmically spaced size bins by laser-diffraction methods. The relation between floc size and density is investigated assuming a constant primary particle size and fractal floc dimension. This relation is validated with measurements from several sites throughout San Francisco Bay. The constancy of this relation implies a uniform primary particle size throughout the Bay, as well as uniform aggregation/disaggregation mechanisms (which modify fractal dimension). The exception to the relation is identified during near-bed measurements, when adverted flocs mix with recently resuspended flocs from the bed, which typically have a higher fractal dimension than suspended flocs. The constant relation for suspended flocs simplifies monitoring and numerical modeling of suspended sediment in San Francisco Bay.

California

Trophic structure and avian communities across a salinity gradient in evaporation ponds of the San Francisco Bay estuary

Commercial salt evaporation ponds comprise a large proportion of baylands adjacent to the San Francisco Bay, a highly urbanized estuary. In the past two centuries, more than 79% of the historic tidal wetlands in this estuary have been lost. Resource management agencies have acquired more than 10 000 ha of commercial salt ponds with plans to undertake one of the largest wetland restoration projects in North America. However, these plans have created debate about the ecological importance of salt ponds for migratory bird communities in western North America. Salt ponds are unique mesohaline (5–18 g l −1 ) to hyperhaline (> 40 g l −1 ) wetlands, but little is known of their ecological structure or value. Thus, we studied decommissioned salt ponds in the North Bay of the San Francisco Bay estuary from January 1999 through November 2001. We measured water quality parameters (salinity, DO, pH, temperature), nutrient concentrations, primary productivity, zooplankton, macroinvertebrates, fish, and birds across a range of salinities from 24 to 264 g l −1 . Our studies documented how unique limnological characteristics of salt ponds were related to nutrient levels, primary productivity rates, invertebrate biomass and taxa richness, prey fish, and avian predator numbers. Salt ponds were shown to have unique trophic and physical attributes that supported large numbers of migratory birds. Therefore, managers should carefully weigh the benefits of increasing habitat for native tidal marsh species with the costs of losing these unique hypersaline systems.

California

Annual sediment flux estimates in a tidal strait using surrogate measurements

Annual suspended-sediment flux estimates through Carquinez Strait (the seaward boundary of Suisun Bay, California) are provided based on surrogate measurements for advective, dispersive, and Stokes drift flux. The surrogates are landward watershed discharge, suspended-sediment concentration at one location in the Strait, and the longitudinal salinity gradient. The first two surrogates substitute for tidally averaged discharge and velocity-weighted suspended-sediment concentration in the Strait, thereby providing advective flux estimates, while Stokes drift is estimated with suspended-sediment concentration alone. Dispersive flux is estimated using the product of longitudinal salinity gradient and the root-mean-square value of velocity-weighted suspended-sediment concentration as an added surrogate variable. Cross-sectional measurements validated the use of surrogates during the monitoring period. During high freshwater flow advective and dispersive flux were in the seaward direction, while landward dispersive flux dominated and advective flux approached zero during low freshwater flow. Stokes drift flux was consistently in the landward direction. Wetter than average years led to net export from Suisun Bay, while dry years led to net sediment import. Relatively low watershed sediment fluxes to Suisun Bay contribute to net export during the wet season, while gravitational circulation in Carquinez Strait and higher suspended-sediment concentrations in San Pablo Bay (seaward end of Carquinez Strait) are responsible for the net import of sediment during the dry season. Annual predictions of suspended-sediment fluxes, using these methods, will allow for a sediment budget for Suisun Bay, which has implications for marsh restoration and nutrient/contaminant transport. These methods also provide a general framework for estimating sediment fluxes in estuarine environments, where temporal and spatial variability of transport are large. ?? 2006 Elsevier Ltd. All rights reserved.

Estuarine, Coastal and Shelf Science

Estimates of suspended sediment entering San Francisco Bay from the Sacramento and San Joaquin Delta, San Francisco Bay, California

This study demonstrates the use of suspended-sediment concentration (SSC) data collected at Mallard Island as a means of determining suspended-sediment load entering San Francisco Bay from the Sacramento and San Joaquin River watersheds. Optical backscatter (OBS) data were collected every 15 min during water years (WYs) 1995-2003 and converted to SSC. Daily fluvial advective sediment load was estimated by combining estimated Delta outflow with daily averaged SSC. On days when no data were available, SSC was estimated using linear interpolation. A model was developed to estimate the landward dispersive load using velocity and SSC data collected during WYs 1994 and 1996. The advective and dispersive loads were summed to estimate the total load. Annual suspended-sediment load at Mallard Island averaged 1.2??0.4 Mt (million metric tonnes). Given that the average water discharge for the 1995-2003 period was greater than the long -term average discharge, it seems likely that the average suspended-sediment load may be less than 1.2??0.4 Mt. Average landward dispersive load was 0.24 Mt/yr, 20% of the total. On average during the wet season, 88% of the annual suspended-sediment load was discharged through the Delta and 43% occurred during the wettest 30-day period. The January 1997 flood transported 1.2 Mt of suspended sediment or about 11% of the total 9-year load (10.9 Mt). Previous estimates of sediment load at Mallard Island are about a factor of 3 greater because they lacked data downstream from riverine gages and sediment load has decreased. Decreasing suspended-sediment loads may increase erosion in the Bay, help to cause remobilization of buried contaminants, and reduce the supply of sediment for restoration projects. ?? 2005 Elsevier B.V. All rights reserved.

Journal of Hydrology

A tool for assessing mercury loadings from restored tidal systems

Accurately quantifying net loads in tidal systems is difficult owing to the high variability in constituent concentrations over the vastly different time scales present in these systems. Perhaps most difficult is the measurement of fluxed over the tidal time scale. On this scale, the net export of the constituent is orders of magnitude less than the bulk exchange in either direction because of the vast quantities of water that are exchanged. Therefore, numerous measurements are required in a brief amount of time to accurately quantify constituent fluxes between a tidal wetland and its surrounding waters. These complications with sampling are exacerbated for mercury species because of the difficulties is to develop surrogates that may be measured in situ and which may be used for interpolating and extrapolating from discrete measurements over a number of tidal cycles and a range of conditions.

Conference Paper

Suspended sediment fluxes in a tidal wetland: Measurement, controlling factors, and error analysis

Suspended sediment fluxes to and from tidal wetlands are of increasing concern because of habitat restoration efforts, wetland sustainability as sea level rises, and potential contaminant accumulation. We measured water and sediment fluxes through two channels on Browns Island, at the landward end of San Francisco Bay, United States, to determine the factors that control sediment fluxes on and off the island. In situ instrumentation was deployed between October 10 and November 13, 2003. Acoustic Doppler current profilers and the index velocity method were employed to calculate water fluxes. Suspended sediment concentrations (SSC) were determined with optical sensors and cross-sectional water sampling. All procedures were analyzed for their contribution to total error in the flux measurement. The inability to close the water balance and determination of constituent concentration were identified as the main sources of error; total error was 27% for net sediment flux. The water budget for the island was computed, with an unaccounted input of 0.20 m 3 s −1 (22% of mean inflow), after considering channel flow, change in water storage, evapotranspiration, and precipitation. The net imbalance may be a combination of groundwater seepage, overland flow, and flow through minor channels. Change of island water storage, caused by local variations in water surface elevation, dominated the tidally averaged water flux. These variations were mainly caused by wind and barometric pressure change, which alter regional water levels throughout the Sacramento-San Joaquin River Delta. Peak instantaneous ebb flow was 35% greater than peak flood flow, indicating an ebbdominant system, though dominance varied with the spring-neap cycle. SSC were controlled by wind-wave resuspension adjacent to the island and local tidal currents that mobilized sediment from the channel bed. During neap tides sediment was imported onto the island but during spring tides sediment was exported because the main channel became ebb dominant. Over the 34-d monitoring period 14,000 kg of suspended sediment were imported through the two channels. The water imbalance may affect the sediment balance if the unmeasured water transport pathways are capable of transporting large amounts of sediment. We estimate a maximum of 2,800 kg of sediment may have been exported through unmeasured pathways, giving a minimum ent import of 11,200 kg. Sediment flux measurements provide insight on tidal to fortnightly marsh sedimentation processes, especially in complex systems where sedimentation is spatially and temporally variable.

California