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D. A. John

Publications and source records attributed to D. A. John.

At least 19 recordsLinked to original sources
USGS2011

Oligocene and Miocene arc volcanism in northeastern California: evidence for post-Eocene segmentation of the subducting Farallon plate

The Warner Range in northeastern California exposes a section of Tertiary rocks over 3 km thick, offering a unique opportunity to study the long-term history of Cascade arc volcanism in an area otherwise covered by younger volcanic rocks. The oldest locally sourced volcanic rocks in the Warner Range are Oligocene (28–24 Ma) and include a sequence of basalt and basaltic andesite lava flows overlain by hornblende and pyroxene andesite pyroclastic flows and minor lava flows. Both sequences vary in thickness (0–2 km) along strike and are inferred to be the erosional remnants of one or more large, partly overlapping composite volcanoes. No volcanic rocks were erupted in the Warner Range between ca. 24 and 16 Ma, although minor distally sourced silicic tuffs were deposited during this time. Arc volcanism resumed ca. 16 Ma with eruption of basalt and basaltic andesite lavas sourced from eruptive centers 5–10 km south of the relict Oligocene centers. Post–16 Ma arc volcanism continued until ca. 8 Ma, forming numerous eroded but well-preserved shield volcanoes to the south of the Warner Range. Oligocene to Late Miocene volcanic rocks in and around the Warner Range are calc-alkaline basalts to andesites (48%–61% SiO 2 ) that display negative Ti, Nb, and Ta anomalies in trace element spider diagrams, consistent with an arc setting. Middle Miocene lavas in the Warner Range are distinctly different in age, composition, and eruptive style from the nearby Steens Basalt, with which they were previously correlated. Middle to Late Miocene shield volcanoes south of the Warner Range consist of homogeneous basaltic andesites (53%–57% SiO 2 ) that are compositionally similar to Oligocene rocks in the Warner Range. They are distinctly different from younger (Late Miocene to Pliocene) high-Al, low-K olivine tholeiites, which are more mafic (46%–49% SiO 2 ), did not build large edifices, and are thought to be related to backarc extension. The Warner Range is ∼100 km east of the axis of the modern arc in northeastern California, suggesting that the Cascade arc south of modern Mount Shasta migrated west during the Late Miocene and Pliocene, while the arc north of Mount Shasta remained in essentially the same position. We interpret these patterns as evidence for an Eocene to Miocene tear in the subducting slab, with a more steeply dipping plate segment to the north, and an initially more gently dipping segment to the south that gradually steepened from the Middle Miocene to the present.

California↗
USGS2008

Characteristics, extent and origin of hydrothermal alteration at Mount Rainier Volcano, Cascades Arc, USA: Implications for debris-flow hazards and mineral deposits

Hydrothermal alteration at Mount Rainier waxed and waned over the 500,000-year episodic growth of the edifice. Hydrothermal minerals and their stable-isotope compositions in samples collected from outcrop and as clasts from Holocene debris-flow deposits identify three distinct hypogene argillic/advanced argillic hydrothermal environments: magmatic-hydrothermal, steam-heated, and magmatic steam (fumarolic), with minor superimposed supergene alteration. The 3.8 km 3 Osceola Mudflow (5600 y BP) and coeval phreatomagmatic F tephra contain the highest temperature and most deeply formed hydrothermal minerals. Relatively deeply formed magmatic-hydrothermal alteration minerals and associations in clasts include quartz (residual silica), quartz–alunite, quartz–topaz, quartz–pyrophyllite, quartz–dickite/kaolinite, and quartz–illite (all with pyrite). Clasts of smectite–pyrite and steam-heated opal–alunite–kaolinite are also common in the Osceola Mudflow. In contrast, the Paradise lahar, formed by collapse of the summit or near-summit of the edifice at about the same time, contains only smectite–pyrite and near-surface steam-heated and fumarolic alteration minerals. Younger debris-flow deposits on the west side of the volcano (Round Pass and distal Electron Mudflows) contain only low-temperature smectite–pyrite assemblages, whereas the proximal Electron Mudflow and a < 100 y BP rock avalanche on Tahoma Glacier also contain magmatic-hydrothermal alteration minerals that are exposed in the avalanche headwall of Sunset Amphitheater, reflecting progressive incision into deeper near-conduit alteration products that formed at higher temperatures. The pre-Osceola Mudflow alteration geometry is inferred to have consisted of a narrow feeder zone of intense magmatic-hydrothermal alteration limited to near the conduit of the volcano, which graded outward to more widely distributed, but weak, smectite–pyrite alteration within 1 km of the edifice axis, developed chiefly in porous breccias. The edifice was capped by a steam-heated alteration zone, most of which resulted from condensation of fumarolic vapor and oxidation of H 2 S in the unsaturated zone above the water table. Weakly developed smectite–pyrite alteration extended into the west and east flanks of the edifice, spatially associated with dikes that are localized in those sectors; other edifice flanks lack dikes and associated alteration. The Osceola collapse removed most of the altered core and upper east flank of the volcano, but intensely altered rocks remain on the uppermost west flank. Major conclusions of this study are that: (1) Hydrothermal–mineral assemblages and distributions at Mount Rainier can be understood in the framework of hydrothermal processes and environments developed from studies of ore deposits formed in analogous settings. (2) Frequent eruptions supplied sufficient hot magmatic fluid to alter the upper interior of the volcano hydrothermally, despite the consistently deep (≥ 8 km) magma reservoir which may have precluded formation of economic mineral deposits within or at shallow depths beneath Mount Rainier. The absence of indicator equilibrium alteration-mineral assemblages in the debris flows that effectively expose the volcano to a depth of 1–1.5 km also suggests a low potential for significant high-sulfidation epithermal or porphyry-type mineral deposits at depth. (3) Despite the long and complex history of the volcano, intensely altered collapse-prone rocks were spatially restricted to near the volcano's conduit system and summit, and short distances onto the upper east and west flanks, due to the necessary supply of reactive components carried by ascending magmatic fluids. (4) Intensely altered rocks were removed from the summit, east flank, and edifice interior by the Osceola collapse, but remain on the upper west flank in the Sunset Amphitheater area and present a continuing collapse hazard. (5) Visually conspicuous rocks on the lower east and mid-to-lower west flanks are not intensely altered and probably have not significantly weakened the rock, and thus do not present significant collapse hazards. (6) Alteration developed most intensely within breccia units, because of their high permeability and porosity. Volcanoes with abundant near-conduit upper-edifice breccias are prone to alteration increasing the possibility of collapse, whereas those that are breccia-poor (e.g., massive domes) are less prone to alteration.

Journal of Volcanology and Geothermal Research↗
USGS2007

Three-dimensional geophysical mapping of rock alteration and water content at Mount Adams, Washington: Implications for lahar hazards

[1] Hydrothermally altered rocks, particularly if water saturated, can weaken stratovolcanoes, thereby increasing the potential for catastrophic sector collapses that can lead to far-traveled, destructive debris flows. Evaluating the hazards associated with such alteration is difficult because alteration has been mapped on few active volcanoes and the distribution and intensity of subsurface alteration are largely unknown on any active volcano. At Mount Adams, some Holocene debris flows contain abundant hydrothermal minerals derived from collapse of the altered edifice. Intense hydrothermal alteration significantly reduces the resistivity and magnetization of volcanic rock, and therefore hydrothermally altered rocks can be identified with helicopter electromagnetic and magnetic measurements. Electromagnetic and magnetic data, combined with geological mapping and rock property measurements, indicate the presence of appreciable thicknesses of hydrothermally altered rock in the central core of Mount Adams north of the summit. We identify steep cliffs at the western edge of this zone as the likely source for future large debris flows. In addition, the electromagnetic data identified water in the brecciated core of the upper 100–200 m of the volcano. Water helps alter the rocks, reduces the effective stress, thereby increasing the potential for slope failure, and acts, with entrained melting ice, as a lubricant to transform debris avalanches into lahars. Therefore knowing the distribution of water is also important for hazard assessments. Our results demonstrate that high-resolution geophysical and geological observations can yield unprecedented views of the three-dimensional distribution of altered rock and shallow pore water aiding evaluation of the debris avalanche hazard.

Journal of Geophysical Research B: Solid Earth↗
USGS2007

Crustal controls on magmatic-hydrothermal systems: A geophysical comparison of White River, Washington, with Goldfield, Nevada

The White River altered area, Washington, and the Goldfield mining district, Nevada, are nearly contemporaneous Tertiary (ca. 20 Ma) calc-alkaline igneous centers with large exposures of shallow (<1 km depth) magmatic-hydrothermal, acid-sulfate alteration. Goldfield is the largest known high-sulfidation gold deposit in North America. At White River, silica is the only commodity exploited to date, but, based on its similarities with Goldfield, White River may have potential for concealed precious and/or base metal deposits at shallow depth. Both areas are products of the ancestral Cascade arc. Goldfield lies within the Great Basin physiographic province in an area of middle Miocene and younger Basin and Range and Walker Lane faulting, whereas White River is largely unaffected by young faults. However, west-northwest–striking magnetic anomalies at White River do correspond with mapped faults synchronous with magmatism, and other linear anomalies may reflect contemporaneous concealed faults. The White River altered area lies immediately south of the west-northwest–striking White River fault zone and north of a postulated fault with similar orientation. Structural data from the White River altered area indicate that alteration developed synchronously with an anomalous stress field conducive to left-lateral, strike-slip displacement on west-northwest–striking faults. Thus, the White River alteration may have developed in a transient transtensional region between the two strike-slip faults, analogous to models proposed for Goldfield and other mineral deposits in transverse deformational zones. Gravity and magnetic anomalies provide evidence for a pluton beneath the White River altered area that may have provided heat and fluids to overlying volcanic rocks. East– to east-northeast–striking extensional faults and/or fracture zones in the step-over region, also expressed in magnetic anomalies, may have tapped this intrusion and provided vertical and lateral transport of fluids to now silicified areas. By analogy to Goldfield, geophysical anomalies at the White River altered area may serve as proxies for geologic mapping in identifying faults, fractures, and intrusions relevant to hydrothermal alteration and ore formation in areas of poor exposure.

Nevada, Washington↗
USGS2003

Geologic setting and genesis of the Mule Canyon low-sulfidation epithermal gold-silver deposit, north-central Nevada

The Mule Canyon mine exploited shallow, low - sulfidation , epithermal Au-Ag deposits that lie near the west side of the Northern Nevada rift in northern Lander County, Nevada . Mule Canyon consists of six small deposits that contained premining reserves of about 8.2 Mt at an average grade of 3.81 g Au/tonne. It is an uncommon mafic end member of low - sulfidation Au-Ag deposits associated with tholeiitic bimodal basalt-rhyolite magmatism. The ore is hosted by a basalt-andesite eruptive center that formed between about 16.4 to 15.8 Ma during early mafic eruptions related to regionally extensive bimodal magmatism. Hydrothermal alteration and Au-Ag ores formed at about 15.6 Ma and were tightly controlled by north -northwest- to north -striking high-angle fault and breccia zones developed during rifting, emplacement of mafic dikes, and eruption of mafic lava flows. Hydrothermal alteration assemblages are zoned outward from fluid conduits in the sequence silica-adularia, adularia-smectite, smectite (intermediate argillic), and smectite-carbonate (propylitic). All alteration types contain abundant pyrite and/or marcasite ± arsenopyrite. Field relations indicate that silica-adularia alteration is superimposed on argillic and propylitic alteration. Little or no steam-heated acid-sulfate alteration is present, probably the result of a near-surface water table during hydrothermal alteration and ore deposition. Two distinct ore types are present at Mule Canyon : early replacement and later open-space filling. Replacement ores consist of disseminated and vesicle-filling pyrite, marcasite, and arsenopyrite in argillically altered or weakly silicified rocks. Ore minerals consist of Au-bearing arsenopyrite and arsenian pyrite overgrowths on earlier-formed pyrite and marcasite. Open-space filling ores include narrow stockwork quartz-adularia veins, banded and crustiform opaline and chalcedonic silica-adularia veins, silica-adularia cemented breccias, and sparse carbonate-pyrite and/or marcasite veins. Ore minerals consist mostly of electrum and Ag sulfide and selenide minerals, with minor to major amounts of pyrite, marcasite, and arsenopyrite, and local stibnite. Both types of ores have similar geochemical signatures, characterized by high Au, Ag, As, Sb, and Se contents, locally high Hg, Mo, Tl, and W contents, and low Cu, Pb, and Zn contents. Stable isotope data indicate that ore fluids consisted dominantly of meteoric water that evolved by deep circulation through Paleozoic sedimentary rocks at low water/rock ratios (about 1) and high temperatures (>200°C). Calculated isotopic compositions of ore fluids are δ 18 O H2O = -3 to -7 per mil, δD H2O = -107 to -124 per mil, δ 13 C CO2 = 0 to -6 per mil, and δ 34 S H2S = -3 to +8 per mil. The ore fluids obtained much of their H 2 S and CO 2 and probably scavenged ore metals and trace elements from the Paleozoic sedimentary rocks. Some H 2 S and CO 2 may have been derived from degassing Miocene magmas. Mule Canyon formed at shallow depths, probably about 100 m below the paleosurface. Ore fluids were dilute, nearly neutral in pH, reduced, H 2 S-rich, and CO 2 -bearing. Peak temperatures in ore zones reached 230° to 265°C at nearly lithostatic pressures when some crystalline quartz ± adularia precipitated, but most ore formed at temperatures <200°C at near hydrostatic pressures and was accompanied by precipitation of opaline and chalcedonic silica ± adularia ± calcite and dolomite. Deposition of gold in As-rich overgrowths on pyrite and/or marcasite in disseminated ores occurred owing to decreasing H 2 S in the ore fluids resulting from sulfidation reactions. Later electrum and Ag selenide precipitation in open spaces occurred owing to boiling, loss of H 2 S to the vapor phase, and cooling. Mule Canyon is similar to most other low - sulfidation Au-Ag deposits associated with Miocene tholeiitic bimodal basalt-rhyolite magmatism in the Great Basin, such as Sleeper, Midas, and Buckhorn. Major differences at Mule Canyon are the high Fe sulfide contents of some ores and altered wall rocks, the paucity of silicification, and the presence of only narrow and discontinuous gold -bearing siliceous veins. These differences primarily are due to the mafic composition of the host rocks. Mule Canyon differs from low - sulfidation deposits associated with subduction-related calc-alkaline porphyry intrusions, such as the Comstock lode, in that a much smaller proportion of water, salts, and metals was derived from crystallizing magmas.

Nevada↗
USGS2001

Miocene and early Pliocene epithermal gold-silver deposits in the northern Great Basin, western United States: Characteristics, distribution, and relationship to Magmatism

Numerous important Miocene and early Pliocene epithermal Au-Ag deposits are present in the northern Great Basin. Most deposits are spatially and temporally related to two magmatic assemblages: bimodal basalt-rhyolite and western andesite. These magmatic assemblages are petrogenetic suites that reflect variations in tectonic environment of magma generation. The bimodal assemblage is a K-rich tholeiitic series formed during continental rifting. Rocks in the bimodal assemblage consist mostly of basalt to andesite and rhyolite compositions that generally contain anhydrous and reduced mineral assemblages (e.g., quartz + fayalite rhyolites). Eruptive forms include mafic lava flows, dikes, cinder and/or spatter cones, shield volcanoes, silicic flows, domes, and ash-flow calderas. Fe-Ti oxide barometry indicates oxygen fugacities between the magnetite-wustite and fayalite-magnetite-quartz oxygen buffers for this magmatic assemblage. The western andesite assemblage is a high K calc-alkaline series that formed a continental-margin are related to subduction of oceanic crust beneath the western coast of North America. In the northern Great Basin, most of the western andesite assemblage was erupted in the Walker Lane belt, a zone of transtension and strike-slip faulting. The western andesite assemblage consists of stratovolcanoes, dome fields, and subvolcanic plutons, mostly of andesite and dacite composition. Biotite and hornblende phenocrysts are abundant in these rocks. Oxygen fugacities of the western andesite assemblage magmas were between the nickel-nickel oxide and hematite-magnetite buffers, about two to four orders of magnitude greater than magmas of the bimodal assemblage. Numerous low-sulfidation Au-Ag deposits in the bimodal assemblage include deposits in the Midas (Ken Snyder), Sleeper, DeLamar, Mule Canyon, Buckhorn, National, Hog Ranch, Ivanhoe, and Jarbidge districts; high-sulfidation gold and porphyry copper-gold deposits are absent. Both high- and low-sulfidation gold-silver and porphyry copper-gold deposits are affiliated with the western andesite assemblage and include the Comstock Lode, Tonopah, Goldfield, Aurora, Bodie, Paradise Peak, and Rawhide deposits. Low-sulfidation Au-Ag deposits in the bimodal assemblage formed under relatively low oxygen and sulfur fugacities and have generally low total base metal (Cu + Pb + Zn) contents, low Ag/Au ratios, and notably high selenide mineral contents compared to temporally equivalent low-sulfidation deposits in the western andesite assemblage. Petrologic studies suggest that these differences may reflect variations in the magmatic-tectonic settings of the associated magmatic assemblages-deposits in the western andesite assemblage formed from oxidized, water-rich, subduction-related calc-alkaline magmas, whereas deposits in the bimodal assemblage were associated with reduced, water-poor tholeiitic magmas derived from the lithospheric mantle during continental extension. The contrasting types and characteristics of epithermal deposits and their affinities with associated igneous rocks suggest that a genetic relationship is present between these Au-Ag deposits and their temporally associated magmatism, although available data do not prove this relationship for most low-sulfidation deposits.

Economic Geology↗
USGS1995

Tilted middle Tertiary ash-flow calderas and subjacent granitic plutons, southern Stillwater Range, Nevada: Cross sections of an Oligocene igneous center

Steeply tilted late Oligocene caldera systems in the Stillwater caldera complex record a number of unusual features including extreme thickness of caldera-related deposits (>4–5.5 km), lack of conclusive evidence for structural doming of the calderas despite intrusion of cogenetic plutonic rocks, and preservation of vertical compositional zoning in the plutonic rocks. The Stillwater caldera complex comprises three partly overlapping ash-flow calderas and subjacent plutonic rocks that were steeply tilted during early Miocene extension. The calderas and cogenetic plutonic rocks are exposed in cross section over an unusually large depth range of ∼10 km. The Job Canyon caldera, the oldest (ca. 29–28 Ma) caldera, consists of two structural blocks. The north block consists of 0–1500 m of precollapse intermediate composition lava flows and breccias overlain by 2000 m of intracaldera rhyolite ash-flow tuff locally interbedded with thick sequences of caldera-collapse breccia, overlain in turn by 2500 m of intermediate lava flows and minor lacustrine and fluvial sedimentary rocks. The south block consists of thinner sequences (total thickness ≤2500 m) of intermediate lava flows and ash-flow tuff with local interbedded collapse breccia. The north part of the caldera is intruded by the cogenetic IXL pluton, which is vertically zoned downward from granodiorite to quartz monzodiorite. The 25 to 23 Ma Poco Canyon and Elevenmile Canyon calderas and underlying Freeman Creek pluton overlap in time and space with each other. Caldera-related deposits in the Poco Canyon caldera comprise two cooling units of crystal-rich rhyolite and high-silica rhyolite tuff (tuff of Poco Canyon) separated by a unit of crystal-poor high-silica rhyolite tuff and caldera-collapse breccia (megabreccia of Government Trail Canyon) and by a thick unit of crystal-rich rhyolite and trachydacite ash-flow tuff related to the Elevenmile Canyon caldera (tuff of Elevenmile Canyon). Total thickness of caldera-related deposits is locally >4500 m in the Poco Canyon caldera. The Elevenmile Canyon caldera is filled by >3000 m of ash-flow tuff (tuff of Elevenmile Canyon), locally overlain by a unit of water-laid rhyolite tuff and sedimentary rocks and by a locally thick unit of rhyolite ash-flow tuff (tuff of Lee Canyon). Total thickness of caldera-related deposits in the Elevenmile Canyon caldera is >4000 m. The composite Freeman Creek pluton intrudes the central and north parts of these calderas and consists of an older granodiorite porphyry phase probably related to the Elevenmile Canyon caldera and a younger granite phase probably related to the Poco Canyon caldera. A 7-km-long, texturally zoned rhyolite-porphyry to granite-porphyry dike intruded the north edges of these calderas and is probably a ring-fracture dike related to the Poco Canyon caldera. Caldera collapse occurred mostly along subvertical ring-fracture faults that penetrated to depths of >5 km and were repeatedly active during eruption of ash-flow tuffs. Subsidiary growth faults with relatively minor displacement are present in caldera-related deposits in the interior of the Job Canyon caldera. A fault separating the two structural blocks of the Job Canyon caldera later served as the north walls of both the Poco Canyon and the Elevenmile Canyon calderas. A second, long-active fault formed the south margin of the Job Canyon caldera, separated the Poco Canyon and Elevenmile Canyon calderas into blocks with greatly different amounts of caldera-related deposits, and later was reactivated during early Miocene extension. The calderas collapsed as large piston-like blocks, and there is no evidence for chaotic collapse. Preserved parts of caldera floors are relatively flat surfaces several kilometers across.

Geological Society of America Bulletin↗