Christopher S. Kochiss | USGS Science

USGS2007

Borehole geophysical monitoring of amendment emplacement and geochemical changes during vegetable oil biostimulation, Anoka County Riverfront Park, Fridley, Minnesota

The U.S. Geological Survey ( USGS ) conducted a series of geophysical investigations to monitor a field-scale biostimulation pilot project at the Anoka County Riverfront Park ( ACP ), downgradient from the Naval Industrial Reserve Ordnance Plant, in Fridley, Minnesota. The pilot project was undertaken by the U.S. Naval Facilities Engineering Command, Southern Division, for the purpose of evaluating biostimulation using emulsified vegetable oil to treat ground water contaminated with chlorinated hydrocarbons. Vegetable oil was introduced to the subsurface to serve as substrate for naturally occurring microbes, which ultimately break down chlorinated hydrocarbons into chloride, carbon dioxide, and water through oxidation-reduction reactions. In support of this effort, the USGS collected cross-borehole radar data and conventional borehole geophysical data in five site visits over 1.5 years to evaluate the effectiveness of geophysical methods for monitoring emplacement of the vegetable oil emulsion and for tracking changes in water chemistry. Radar zero-offset profile ( ZOP ) data, radar traveltime tomograms, electromagnetic ( EM ) induction logs, natural gamma logs, neutron porosity logs, and magnetic susceptibility logs were collected and analyzed. In order to facilitate data interpretation and to test the effectiveness of radar for monitoring oil-emulsion placement and movement, three injection mixtures with different radar signatures were used: (1) vegetable oil emulsion, (2) vegetable oil emulsion with a colloidal iron tracer, and (3) vegetable oil emulsion with a magnetite tracer. Based on petrophysical modeling, mixture (1) was expected to increase radar velocity and decrease radar attenuation relative to background—a water-saturated porous medium; mixtures (2) and (3) were expected to increase radar velocity and increase radar attenuation because of their greater electrical conductivity compared to background ground water. Radar ZOP data and tomograms show increased EM velocity in the vicinity of injection wells. Comparison of pre- and post-injection datasets shows that velocity anomalies are observed only in planes connected to injection wells, indicating that the emulsified vegetable oil does not migrate far after injection. In contrast to the localization of velocity anomalies, radar attenuation anomalies are observed in all zero-offset profiles, particularly those downgradient from the injection wells. Despite the expected signatures of different tracers, increases in attenuation are observed downgradient from all three injection wells; thus, we infer that the attenuation changes do not result from the iron tracers alone. Over the period of data collection, the slowness (reciprocal velocity) anomalies are relatively stable, whereas the attenuation anomalies generally increase in magnitude and extent. One explanation for the attenuation changes is that products of vegetable oil-enhanced biodegradation (for example, chloride) increase the specific conductance of ground water and thus bulk electrical conductivity and radar attenuation. This interpretation is supported by the results of EM-induction and magnetic susceptibility logs, which indicate increases in electrical conductivity in the absence of magnetic anomalies that might result from the iron and magnetite. Based on the geophysical data, conceptual models of the distributions of emulsified vegetable oil and ground water with altered chemistry were developed. The field data indicate that, in several cases, the plume of ground water with altered chemistry would not be detected by direct chemical sampling given the construction of monitoring wells; hence the geophysical data provide valuable site-specific insights for the interpretation of water samples and monitoring of biostimulation projects. Application of geophysical methods to data from the ACP demonstrated the utility of radar for monitoring biostimulation injections.

Minnesota↗

USGS2005

Use of discrete-zone monitoring systems for hydraulic characterization of a fractured-rock aquifer at the University of Connecticut Landfill, Storrs, Connecticut, 1999 to 2002

The U.S. Geological Survey, in cooperation with the University of Connecticut, used a suite of hydraulic methods to characterize the hydrogeology of a fractured-rock aquifer near the former landfill and chemical-waste disposal pits at the University of Connecticut, Storrs, Connecticut. Multiple methods were used to determine head, driving potential, and transmissivity, including manual open-hole water-level and discretezone water-level measurements from 11 boreholes; continuous discrete-zone water-level measurements from 6 of the boreholes; estimated head and transmissivity for 11 boreholes using heat-pulse flowmeter profiles and pumping records; and differential head testing using a straddle-packer apparatus from 4 boreholes. These data were analyzed to identify and characterize relations between long-term water-level patterns and precipitation, topographic setting, contaminant distribution at the site, and a conceptual ground-water flow model. Data collected using the heat-pulse flowmeter, the straddle-packer apparatus, and discrete-zone monitoring (DZM) systems helped to establish, refine, and verify a conceptual model of ground-water flow in the study area. Monitoring of DZM systems installed in 11 boreholes provided a method for longterm monitoring of hydraulic head and water quality of the aquifer at fracture zones of different depths. These data were used to help define the conceptual site model for ground-water flow and to determine and explain the distribution of contamination. Hydrographs constructed for discretely isolated zones in the boreholes showed the magnitude of seasonal changes of water levels and driving potential in response to precipitation and drought. Heads in discrete zones and in different boreholes varied both in magnitude of response and in timing of response to precipitation. Water levels in open boreholes and in DZM systems showed a semi-diurnal pattern that coincides with gravimetric tidal plots generated for this area. No fluctuations that might indicate pumping were identified in the continuous water-level records. Lack of hydraulic response between boreholes during cross-hole testing in the area of the former chemical-waste disposal pits indicates poor hydraulic connection between the boreholes that were tested. In general, data indicated the presence of downward driving potentials in the recharge areas and in the area of the ground-water divide, and upward driving potentials in discharge areas north and south of the landfill. The results of this study illustrate the importance of discrete-zone isolation and monitoring in fractured-rock aquifers to prevent cross contamination while permitting head measurements and water-quality sampling that can be used to identify and characterize contamination or pathways for contaminant migration in a fractured-rock aquifer. Without DZM systems installed in the boreholes, only open-hole heads can be measured. The open-hole heads may be misleading when determining potential flow directions at contamination sites, because they are a composite of the heads associated with each of the fractures intersecting the borehole. The flowmeter tool and straddle-packer apparatus are effective screening tools for generating a snapshot of the hydraulic conditions, including vertical flow, transmissivity, and heads; however, they cannot prevent flow and potential cross-contamination and cannot easily be used to monitor long-term conditions. This work was conducted as part of a larger multidisciplinary investigation to characterize the nature and extent of contamination in the soil, surface water, and ground water in the overburden and fractured bedrock in the area of the landfill and former chemical-waste disposal pits near the University of Connecticut. The methods and hydraulic data presented in this report were used along with surface- and borehole-geophysical data and geochemical data to understand and characterize the ground-water flow in overburden and fractured bedrock; to assess possible chemical migration; to develop a site conceptual ground-water flow model; and to assess remediation alternatives.

Connecticut↗