Christine E. Jilly-Rehak

USGS2024

Zircon constraints on the eruptive sequence and magma evolution of rhyolites at South Sister volcano, Oregon

We present 230 Th- 238 U crystallization ages and trace element compositions for zircons spanning the late Pleistocene to Holocene rhyolite eruptive record at South Sister volcano in the central Oregon Cascade Range. Most zircon ages are between 100 and 20 ka, with very few in secular equilibrium (>350 ka). The weighted mean of zircon ages for the two oldest South Sister rhyolites, 31.5 ± 2.1 and 39.1 ± 2.4 ka, are significantly younger than the associated 40 Ar/ 39 Ar ages, 47.4 ± 9.7 and 51.4 ± 9.7 ka. We propose that these 40 Ar/ 39 Ar dates, performed on plagioclase separates, are compromised by a subtle amount of excess Ar and therefore the younger weighted mean zircon ages yield more reliable eruption ages. These results imply that the interval of rhyolite eruption at South Sister during the late Pleistocene was both shorter and more productive than previously thought and that eruption at South Sister initiated after Middle Sister. Compositionally, zircons from the Pleistocene rhyolites are broadly similar and show down-temperature zircon and plagioclase crystallization trends. However, we argue that destabilized amphibole and titanite in a common mush also exert leverage on the Pleistocene zircon trace element compositions. Divergence in the Eu/Eu* ratio between the Pleistocene and Holocene lavas implies chemically distinct magma reservoirs originating from the Pleistocene rhyolite eruptive sequence and the Holocene eruptive sequence. This work suggests a higher flux of rhyolite volcanism than previously thought and characterizes magmatic storage distinctions between the Pleistocene and Holocene rhyolites, aiding in the assessment of future eruptive hazards at South Sister volcano.

Oregon↗

USGS2024

A Bayesian age from dispersed plagioclase and zircon dates in the Los Chocoyos ash, Central America

The eruption that produced the modern Atitlán caldera in Guatemala has a Volcanic Explosivity Index (VEI) greater than 8, making it the largest of the Quaternary in the Central American Volcanic Arc (CAVA). It generated ∼1220 km 3 (730 km 3 dense rock equivalent) of dispersed rhyolitic ash and unwelded pyroclastic flow deposits known as the Los Chocoyos ash. Despite its scale, the age of the Los Chocoyos ash has been difficult to constrain. Its inferred position in marine sediment off the coast of Ecuador suggests an oxygen isotope-based age of 84 ± 5 thousand years (ka) that has been used for decades. A recent effort to determine the eruption age of the Los Chocoyos ash used U-Th/He and U/Th disequilibrium methods that both yield overdispersed sets of dates from zircon. Using U/Th disequilibrium corrected U-Th/He dates, which include some that are up to 19 ± 8 kyr younger than the youngest U/Th disequilibrium dates, an eruption age of 75 ± 4 ka has been proposed, which overlaps the eruption age of the Youngest Toba Tuff, 40 Ar/ 39 Ar dated at 73.9 ± 0.6 ka. Critically, the above findings have led to the hypothesis that this pair of sulfate-rich supereruptions may be responsible for a global cooling event ∼74 ka. To further test this supereruption doublet hypothesis we present new 40 Ar/ 39 Ar and U-Th disequilibrium data from plagioclase and zircon rim surfaces, respectively, to quantify the timing of the Los Chocoyos eruption. We apply Bayesian estimation to the overdispersed sets of 40 Ar/ 39 Ar plagioclase and U-Th disequilibrium zircon dates. This approach accounts for retention of radiogenic 40 Ar in plagioclase in a subset of crystals and for crystallization of zircon that may precede the time of eruption and yields remarkably consistent ages from two independent chronometers. The Bayesian estimate of 98 ± 6 ka calculated from 308 individual dates identifies the population nearest to the time of the Los Chocoyos eruption. Interpreted as an eruption age, this finding precludes a link between the Los Chocoyos eruption and global cooling ∼74 ka and rules out the supereruption doublet trigger.

Earth and Planetary Science Letters↗