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Geology topics

Chen Liu

Publications and source records attributed to Chen Liu.

2 recordsLinked to original sources

Paleosol stable isotope evidence for early hominid occupation of East Asian temperate environments

Hominids left Africa and occupied mainland Asia by 1.8 myr ago. About 1.15 myr ago Homo erectus and an associated Stegodon-Ailuropoda fauna migrated from subtropical China across the Qinling Mountains into the temperate Loess Plateau. This migration may be an evolutionary milestone in human adaptability because it may represent the first occupation of a nontropical environment. Loess-paleosol stable isotope ratios from the last interglacial-glacial cycle provide comparative data for reconstructing the hominid paleoenvironments. The climate during Gongwangling hominid occupation about 1.15 myr ago was influenced by both Siberian-Mongolian winter and Indian summer monsoon systems characterized as a cold/cool, dry winter and warm/mild, semihumid summer and fall. The Gongwangling hominids preyed mainly on warm-climate-adapted animals such as Stegodon-Ailuropoda fauna, suggesting a warm season occupation. The stable isotope ratios also indicate that the Chenjiawo hominids occupied an environment similar to that of the Gongwangling about 650,000 yr ago. The associated fauna, with a mixture of forest and steppe, warm-and cold/cool-climate-adapted animal assemblage's, suggests a permanent occupation by this time. Thus, the reliable earliest and permanent occupation of temperate environments may have occurred 150,000 yr earlier in eastern Asia rather than in Europe. ?? 1997 University of Washington.

Quaternary Research

Pathways of coupled arsenic and iron cycling in high arsenic groundwater of the Hetao basin, Inner Mongolia, China: an iron isotope approach

High As groundwater is widely distributed all over the world, which has posed a significant health impact on millions of people. Iron isotopes have recently been used to characterize Fe cycling in aqueous environments, but there is no information on Fe isotope characteristics in the groundwater. Since groundwater As behavior is closely associated with Fe cycling in the aquifers, Fe isotope signatures may help to characterize geochemical processes controlling As concentrations of shallow groundwaters. This study provides the first observation of Fe isotope fractionation in high As groundwater and evaluation of Fe cycling and As behaviors in shallow aquifers in terms of Fe isotope signatures. Thirty groundwater samples were taken for chemical and isotopic analysis in the Hetao basin, Inner Mongolia. Thirty-two sediments were sampled as well from shallow aquifers for Fe isotope analysis. Results showed that groundwater was normally enriched in isotopically light Fe with δ 56 Fe values between −3.40‰ and 0.58‰ and median of −1.14‰, while heavier δ 56 Fe values were observed in the sediments (between −1.10‰ and 0.75‰, median +0.36‰). In reducing conditions, groundwaters generally had higher δ 56 Fe values, in comparison with oxic conditions. High As groundwaters, generally occurring in reducing conditions, had high δ 56 Fe values, while low As groundwaters normally had low δ 56 Fe values. Although sediment δ 56 Fe values were generally independent of lithological conditions, a large variation in sediment δ 56 Fe values was observed in the oxidation–reduction transition zone. Three pathways were identified for Fe cycling in shallow groundwater, including dissimilatory reduction of Fe(III) oxides, re-adsorption of Fe(II), and precipitation of pyrite and siderite. Dissimilatory reduction of Fe(III) oxides resulted in light δ 56 Fe values (around −1.0‰) and high As concentration (>50 μg/L) in groundwater in anoxic conditions. Re-adsorption of isotopically heavy Fe(II) produced by microbially mediated reduction of Fe(III) oxides led to further enrichment of isotopically light Fe in groundwater (up to −3.4‰ of δ 56 Fe) in anoxic–suboxic conditions. Arsenic re-adsorption was expected to occur along with Fe(II) re-adsorption, decreasing groundwater As concentrations. In strongly reducing conditions, precipitation of isotopically light Fe-pyrite and/or siderite increased groundwater δ 56 Fe values, reaching +0.58‰ δ 56 Fe, with a subsequent decrease in As concentrations via co-precipitation. The mixed effect of those pathways would regulate As and Fe cycling in most groundwaters.

Inner Mongolia