Geology topics

Carol J. Morel

Publications and source records attributed to Carol J. Morel.

3 recordsLinked to original sources

USGS2023

Geology, hydrology, and groundwater contamination in the vicinity of Central Chemical facility, Hagerstown, Maryland

The soil and groundwater at the Central Chemical facility, Hagerstown, Maryland, are contaminated due to the blending and production of pesticides and fertilizers during much of the 20th century. Remedial investigations focus on two operable units (OU) consisting of the surface soils and waste disposal lagoon (OU-1) and the groundwater (OU-2). The contaminants of concern (COC) for groundwater include 41 compounds categorized within the subgroups of volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), pesticides, and metals. The purpose of this report is to provide a conceptual site model of the hydrogeology and groundwater contaminant transport at and near the Central Chemical facility. The conceptual model was developed through review, synthesis, and interpretation of the results of hydrogeologic, soil, and other environmental investigations conducted at and in the vicinity of the facility in recent decades and is intended to support plans for environmental remediation of the groundwater in OU-2. The extent and nature of the groundwater contaminant plume associated with the bedrock was characterized for OU-2 of the site. Lithologic and structural comparisons between shallow soil, weathered rock, and epikarst and deeper competent but bedded, dipping, fractured, and karstic limestones illustrate two connected flow systems—a surficial flow system consisting of the unconsolidated overburden and epikarst and a structurally dominant bedrock flow system below the epikarst. Uncertainties exist regarding the nature and transport of contaminants within the epikarst system particularly within voids and perched epikarst water tables. Karst dissolution features are observed within the site including sinkholes and dissolution voids within wells at the site. Of interest, one well in the northern part of the study area (MW-J-71) appears to have a dissolution void connected to an offsite well (OW-2-115) farther to the north. This connection is supported by groundwater level data and elevated concentrations of total suspended solids (TSS) and chlorobenzene in both wells. The high level of TSS supports the possibility of offsite transport of particle-bound contaminants within the conduit system. Episodically elevated concentrations of COC from different groups also were observed within select wells in the epikarst near the waste disposal lagoon (particularly MW-A-51). The variability observed between different COC within the same well may be the result of additional contaminated source materials unrelated to the disposal lagoon. Storage and episodic transport of contaminated material within the epikarst system has the potential to hinder remediation efforts if not considered in the remedial action.

Maryland↗

USGS2020

Making ‘chemical cocktails’ – Evolution of urban geochemical processes across the periodic table of elements

Urbanization contributes to the formation of novel elemental combinations and signatures in terrestrial and aquatic watersheds, also known as ‘chemical cocktails.’ The composition of chemical cocktails evolves across space and time due to: (1) elevated concentrations from anthropogenic sources, (2) accelerated weathering and corrosion of the built environment, (3) increased drainage density and intensification of urban water conveyance systems, and (4) enhanced rates of geochemical transformations due to changes in temperature, ionic strength, pH, and redox potentials. Characterizing chemical cocktails and underlying geochemical processes is necessary for: (1) tracking pollution sources using complex chemical mixtures instead of individual elements or compounds; (2) developing new strategies for co-managing groups of contaminants; (3) identifying proxies for predicting transport of chemical mixtures using continuous sensor data; and (4) determining whether interactive effects of chemical cocktails produce ecosystem-scale impacts greater than the sum of individual chemical stressors. First, we discuss some unique urban geochemical processes which form chemical cocktails, such as urban soil formation, human-accelerated weathering, urban acidification-alkalinization, and Freshwater Salinization Syndrome. Second, we review and synthesize global patterns in concentrations of major ions, carbon and nutrients, and trace elements in urban streams across different world regions and make comparisons with reference conditions. In addition to our global analysis, we highlight examples from watersheds in the Baltimore-Washington DC area, USA, which show increased transport of major ions, trace metals, and nutrients across streams draining a well-defined land-use gradient. Urbanization increased the concentrations of multiple major and trace elements in streams draining human-dominated watersheds compared to reference conditions. Chemical cocktails of major and trace elements were formed over diurnal cycles coinciding with changes in streamflow, dissolved oxygen, pH, and other variables measured by high-frequency sensors. Some chemical cocktails of major and trace elements were also significantly related to specific conductance (p < 0.05), which can be measured by sensors. Concentrations of major and trace elements increased, peaked, or decreased longitudinally along streams as watershed urbanization increased, which is consistent with distinct shifts in chemical mixtures upstream and downstream of other major cities in the world. Our global analysis of urban streams shows that concentrations of multiple elements along the periodic table significantly increase when compared with reference conditions. Furthermore, similar biogeochemical patterns and processes can be grouped among distinct mixtures of elements of major ions, dissolved organic matter, nutrients, and trace elements as chemical cocktails. Chemical cocktails form in urban waters over diurnal cycles, decades, and throughout drainage basins. We conclude our global review and synthesis by proposing strategies for monitoring and managing chemical cocktails using source control, ecosystem restoration, and green infrastructure. We discuss future research directions applying the watershed chemical cocktail approach to diagnose and manage environmental problems. Ultimately, a chemical cocktail approach targeting sources, transport, and transformations of different and distinct elemental combinations is beneficial to more holistically monitor and manage the emerging impacts of chemical mixtures in the world's fresh waters.

Applied Geochemistry↗

USGS2019

Effective solubility assessment for organic analytes in liquid samples, BKK class I landfill, West Covina, California, 2014–16

Executive Summary The U.S. Geological Survey assessed the effective solubilities of organic analytes at the BKK Class Ⅰ Landfill site, West Covina, California, in cooperation with the California Department of Toxic Substances Control, using available data for liquid samples collected within (in-waste) and below (sub-waste) the landfill in 2014–16. The primary purpose of the effective solubility calculations was to determine the likely presence or absence of dense non-aqueous phase liquids (DNAPLs), which is important for understanding the sources, persistence, and movement of the leachate contaminants. Percent effective solubility (a measure of the degree of deviation of a measured liquid concentration of a compound from the aqueous effective solubility) greater than 1 percent is the threshold that commonly has been used to infer the presence of DNAPLs or mixed DNAPLs in aqueous monitoring results. In the present study, however, thresholds higher than 1 percent were used because of elevated temperatures and concentrations of cosolvents in the liquid samples—thresholds of 10 percent or 100 percent, respectively, were used for liquid and solid (at 25 degrees Celsius) organic compounds for potential non-aqueous phase liquid presence. Overall, the effective solubility calculations indicate the likely presence of DNAPLs or mixed DNAPLs in some samples for a range of compounds, including tetrachloroethene, trichloroethene, 1,1-dichloroethene, vinyl chloride, 1,2,4-trichlorobenzene, 1,4-dichlorobenzene, 1,2-dichlorobenzene, naphthalene, toluene, ethylbenzene, and xylenes. Samples with the highest calculated percent effective solubilities for chlorinated ethenes, ethanes, and benzenes were from a location where liquid in the waste prism is known to be in contact with the groundwater beneath the landfill. Trends in the effective solubilities for the chlorinated ethenes and ethanes were generally consistent between the in-waste and sub-waste samples, supporting a similar source composition for these liquids. Percent effective solubilities were less than 10 for the chlorinated ethanes in all the in-waste and sub-waste samples, indicating that DNAPL of these compounds is not present. Percent effective solubilities of chlorinated benzenes, ethylbenzene, and xylenes exceeded the 10-percent effective solubility threshold in more of the sub-waste samples than the in-waste liquid samples. Volatilization also may influence the patterns in the calculated effective solubilities but were not included in this study.

California↗