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Carl R. Thornber

Publications and source records attributed to Carl R. Thornber.

At least 19 recordsLinked to original sources

Kilauea's 5-9 March 2011 Kamoamoa fissure eruption and its relation to 30+ years of activity from Pu'u 'Ō'ō

Lava output from Kīlauea's long-lived East Rift Zone eruption, ongoing since 1983, began waning in 2010 and was coupled with uplift, increased seismicity, and rising lava levels at the volcano's summit and Pu‘u ‘Ō‘ō vent. These changes culminated in the four-day-long Kamoamoa fissure eruption on the East Rift Zone starting on 5 March 2011. About 2.7 × 10 6 m 3 of lava erupted, accompanied by ˜15 cm of summit subsidence, draining of Kīlauea's summit lava lake, a 113 m drop of Pu‘u ‘Ō‘ō's crater floor, ˜3 m of East Rift Zone widening, and eruptive SO 2 emissions averaging 8500 tonnes/day. Lava effusion resumed at Pu‘u ‘Ō‘ō shortly after the Kamoamoa eruption ended, marking the onset of a new period of East Rift Zone activity. Multiparameter monitoring before and during the Kamoamoa eruption suggests that it was driven by an imbalance between magma supplied to and erupted from Kīlauea's East Rift Zone and that eruptive output is affected by changes in the geometry of the rift zone plumbing system. These results imply that intrusions and eruptive changes during ongoing activity at Kīlauea may be anticipated from the geophysical, geological, and geochemical manifestations of magma supply and magma plumbing system geometry.

Hawaii

Petrologic testament to changes in shallow magma storage and transport during 30+ years of recharge and eruption at Kīlauea Volcano, Hawai‘i

Petrologic monitoring of Kīlauea Volcano from January 1983 to October 2013 has yielded an extensive record of glass, phenocryst, melt inclusion, and bulk-lava chemistry from well-quenched lava. When correlated with 30+ years of geophysical and geologic monitoring, petrologic details testify to physical maturation of summit-to-rift magma plumbing associated with sporadic intrusion and prolonged magmatic overpressurization. Changes through time in bulk-lava major- and trace-element compositions, along with glass thermometry, record shifts in the dynamic balance of fractionation, mixing, and assimilation processes inherent to magma storage and transport during near-continuous recharge and eruption. Phenocryst composition, morphology, and texture, along with the sulfur content of melt inclusions, constrain coupled changes in eruption behavior and geochemistry to processes occurring in the shallow magmatic system. For the first 17 years of eruption, magma was steadily tapped from a summit reservoir at 1–4 km depth and circulating between 1180 and 1200°C. Furthermore, magma cooled another 30°C while flowing through the 18 km long rift conduit, before erupting olivine-spinel-phyric lava at temperatures of 1150–1170°C in a pattern linked with edifice deformation, vent formation, eruptive vigor, and presumably the flux of magma into and out of the summit reservoir. During 2000–2001, a fundamental change in steady state eruption petrology to that of relatively low-temperature, low-MgO, olivine(-spinel)-clinopyroxene-plagioclase-phryic lava points to a physical transformation of the shallow volcano plumbing uprift of the vent. Preeruptive comagmatic mixing between hotter and cooler magma is documented by resorption, overgrowth, and compositional zonation in a mixed population of phenocrysts grown at higher and lower temperatures. Large variations of sulfur (50 to >1000 ppm) in melt inclusions within individual phenocrysts and among phenocrysts in most samples provide an unequivocal glimpse of rapid crystal growth amid sulfur degassing at <30 MPa in a turbulent preeruptive environment. We speculate that, during the last decade, one or more shallow open-system reservoirs developed along the conduit between the summit and Pu‘u ‘Ō‘ō and now serve to buffer the magmatic throughput associated with ongoing recharge and eruption. Lava with identical trace-element signatures erupted simultaneously at the summit and at Pu‘u ‘Ō‘ō from 2008 to 2013 confirms magmatic continuity between the vents. Complementary changes in compositions of matrix glasses, phenocrysts, and melt inclusions of summit tephra are mirrored by similar changes in contemporaneous rift lava at eruption temperatures 20–35°C lower than those at the summit. Petrologic parameters measured at opposite ends of the shallow magmatic plumbing system are both correlated with summit deformation, demonstrating that effects of summit magma chamber pressurization are translated throughout interconnected magma pathways in the shallow edifice.

Hawaii

Primative components, crustal assimilation, and magmatic degassing of the 2008 Kilauea summit eruption

Simultaneous summit and rift zone eruptions at Kīlauea starting in 2008 reflect a shallow eruptive plumbing system inundated by a bourgeoning supply of new magma from depth. Olivine-hosted melt inclusions, host glass, and bulk lava compositions of magma erupted at both the summit and east rift zone demonstrate chemical continuity at both ends of a well-worn summit-to-rift pipeline. Analysis of glass within dense-cored lapilli erupted from the summit in March &ndash; August 2008 show these are not samplings of compositionally distinct magmas stored in the shallow summit magma reservoir, but instead result from remelting and assimilation of fragments from conduit wall and vent blocks. Summit pyroclasts show the predominant and most primitive component erupted to be a homogenous, relatively trace-element-depleted melt that is a compositionally indistinguishable from east rift lava. Based on a &ldquo;top-down&rdquo; model for the geochemical variation in east rift zone lava over the past 30 years, we suggest that the apparent absence of a 1982 enriched component in melt inclusions, as well as the proposed summit-rift zone connectivity based on sulfur and mineral chemistry, indicate that the last of the pre-1983 magma has been flushed out of the summit reservoir during the surge of mantle-derived magma from 2003-2007.

Hawaii

A mantle-driven surge in magma supply to Kīlauea Volcano during 2003-2007

The eruptive activity of a volcano is fundamentally controlled by the rate of magma supply. At Kīlauea Volcano, Hawai‘i, the rate of magma rising from a source within Earth’s mantle, through the Hawaiian hotspot, was thought to have been relatively steady in recent decades. Here we show that the magma supply to Kīlauea at least doubled during 2003–2007, resulting in dramatic changes in eruptive activity and the formation of new eruptive vents. An initial indication of the surge in supply was an increase in CO 2 emissions during 2003–2004, combined with the onset of inflation of Kīlauea’s summit, measured using the Global Positioning System and interferometric synthetic aperture radar. Inflation was not limited to the summit magma reservoirs, but was recorded as far as 50 km from the summit, implying the existence of a connected magma system over that distance. We also record increases in SO 2 emissions, heightened seismicity, and compositional and temperature variations in erupted lavas. The increase in the volume of magma passing through and stored within Kīlauea, coupled with increased CO 2 emissions, indicate a mantle source for the magma surge. We suggest that magma supply from the Hawaiian hotspot can vary over timescales of years, and that CO 2 emissions could be a valuable aid for assessing variations in magma supply at Kīlauea and other volcanoes.

Nature Geoscience

Catalog of Tephra samples from Kilauea's summit eruption, March-December 2008

The opening of a new vent within Halema'uma'u Crater in March 2008 ended a 26-year period of no eruptive activity at the summit of Kilauea Volcano. It also heralded the first explosive activity at Kilauea's summit since 1924 and the first of eight discrete explosive events in 2008. At the onset of the eruption, the Hawaiian Volcano Observatory (HVO) initiated a rigorous program of sample collection to provide a temporally constrained suite of tephra samples for petrographic, geochemical, and isotopic studies. Petrologic studies help us understand conditions of magma generation at depth; processes related to transport, storage, and mixing of magma within the shallow summit region; and specific circumstances leading to explosive eruptions. This report provides a catalog of tephra samples erupted at Kilauea's summit from March 19, 2008, through the end of 2008. The Kilauea 2008 Summit Sample Catalog is tabulated in the accompanying Microsoft Excel file, of2009-1134.xls (four file types linked on right). The worksheet in this file provides sampling information and sample descriptions. Contextual information for this catalog is provided below and includes (1) a narrative of 2008 summit eruptive activity, (2) a description of sample collection methods, (3) a scheme for characterizing a diverse range in tephra lithology, and (4) an explanation of each category of sample information (column headers) in the Microsoft Excel worksheet.

Hawaii

Catalog of Mount St. Helens 2004-2007 dome samples with major- and trace-element chemistry

Sampling and analysis of eruptive products at Mount St. Helens is an integral part of volcano monitoring efforts conducted by the U.S. Geological Survey?s Cascades Volcano Observatory (CVO). The objective of our eruption sampling program is to enable petrological assessments of pre-eruptive magmatic conditions, critical for ascertaining mechanisms for eruption triggering and forecasting potential changes in eruption behavior. This report provides a catalog of near-vent lithic debris and new dome-lava collected during 34 intra-crater sampling forays throughout the October 2004 to October 2007 (2004-7) eruptive interval at Mount St. Helens. In addition, we present comprehensive bulk-rock geochemistry for a time-series of representative (2004-7) eruption products. This data, along with that in a companion report on Mount St. Helens 2004 to 2006 tephra by Rowe and others (2008), are presented in support of the contents of the U.S. Geological Survey Professional Paper 1750 (Sherrod and others, eds., 2008). Readers are referred to appropriate chapters in USGS Professional Paper 1750 for detailed narratives of eruptive activity during this time period and for interpretations of sample characteristics and geochemical data. The suite of rock samples related to the 2004-7 eruption of Mount St. Helens and presented in this catalog are archived at the David A. Johnson Cascades Volcano Observatory, Vancouver, Wash. The Mount St. Helens 2004-7 Dome Sample Catalogue with major- and trace-element geochemistry is tabulated in 3 worksheets of the accompanying Microsoft Excel file, of2008-1130.xls. Table 1 provides location and sampling information. Table 2 presents sample descriptions. In table 3, bulk-rock major and trace-element geochemistry is listed for 44 eruption-related samples with intra-laboratory replicate analyses of 19 dacite lava samples. A brief overview of the collection methods and lithology of dome samples is given below as an aid to deciphering the dome sample catalog. This is followed by an explanation of the categories of sample information (column headers) in Tables 1 and 2. A summary of the analytical methods used to obtain the geochemical data in this report introduces the presentation of major- and trace-element geochemistry of 2004-7 Mount St. Helens dome samples in table 3. Intra-laboratory results for the USGS AGV-2 standard are presented (tables 4 and 5), which demonstrate the compatibility of chemical data from different sources.

Open-File Report

Catalog of Mount St. Helens 2004 - 2005 tephra samples with major- and trace-element geochemistry

This open-file report presents a catalog of information about 135 ash samples along with geochemical analyses of bulk ash, glass and individual mineral grains from tephra deposited as a result of volcanic activity at Mount St. Helens, Washington, from October 1, 2004 until August 15, 2005. This data, in conjunction with that in a companion report on 2004-2007 Mount St. Helens dome samples by Thornber and others (2008a) are presented in support of the contents of the U.S. Geological Survey Professional Paper 1750 (Sherrod and others, ed., 2008). Readers are referred to appropriate chapters in USGS Professional Paper 1750 for detailed narratives of eruptive activity during this time period and for interpretations of sample characteristics and geochemical data presented here. All ash samples reported herein are currently archived at the David A. Johnston Cascades Volcano Observatory in Vancouver, Washington. The Mount St. Helens 2004?2005 Tephra Sample Catalogue along with bulk, glass and mineral geochemistry are tabulated in 6 worksheets of the accompanying Microsoft Excel file, of2008-1131.xls. Samples in all tables are organized by collection date. Table 1 is a detailed catalog of sample information for tephra deposited downwind of Mount St. Helens between October 1, 2004 and August 18, 2005. Table 2 provides major- and trace-element analyses of 8 bulk tephra samples collected throughout that interval. Major-element compositions of 82 groundmass glass fragments, 420 feldspar grains, and 213 mafic (clinopyroxene, amphibole, hypersthene, and olivine) mineral grains from 12 ash samples collected between October 1, 2004 and March 8, 2005 are presented in tables 3 through 5. In addition, trace-element abundances of 198 feldspars from 11 ash samples (same samples as major-element analyses) are provided in table 6. Additional mineral and bulk ash analyses from 2004 and 2005 ash samples are published in chapters 30 (oxide thermometry; Pallister and others, 2008), 32 (amphibole major elements; Thornber and others, 2008b) and 37 (210Pb; 210Pb/226Pa; Reagan and others, 2008) of U.S. Geological Survey Professional Paper 1750 (Sherrod and others, 2008). A brief overview of sample collection methods is given below as an aid to deciphering the tephra sample catalog. This is followed by an explanation of the categories of sample information (column headers) in table 1. A summary of the analytical methods used to obtain the geochemical data in this report introduces the presentation of major- and trace-element geochemistry of Mount St. Helens 2004-2005 tephra samples in tables 2-6. Rhyolite glass standard analyses are reported (Appendix 1) to demonstrate the accuracy and precision of similar glass analyses presented herein.

Washington

From dome to dust: shallow crystallization and fragmentation of conduit magma during the 2004-2006 dome extrusion of Mount St. Helens, Washington

An unusual feature of the 2004-6 eruptive activity of Mount St. Helens has been the continuous growth of successive spines that are mantled by thick fault gouge. Fault gouge formation requires, first, solidification of ascending magma within the conduit, then brittle fragmentation and cataclastic flow. We document these processes through field relations, hand samples, and thin-section textures. Field observations show that the gouge zone is typically 1-3 m thick and that it includes cataclasite and, locally, breccia in addition to unconsolidated (true) gouge. The gouge contains multiple slickenside sets oriented subparallel to each other and to the striation direction, as well as surface striations parallel to extrusion direction. Hand specimens show the cataclasite and gouge to be composed of a wide size range of broken dome and wallrock fragments. This grain-size heterogeneity is even more pronounced in thin section, where individual samples contain fragments that span more than four orders of magnitude in size (from more than 10 to less than 10 -3 mm). Textures preserved within the gouge zone provide evidence of different processes operating in time and space. Most individual fragments are holocrystalline, suggesting that crystallization of the ascending magma preceded gouge formation. Cataclasite samples preserve a wide range of clast sizes; pronounced rounding of many clasts indicates extensive abrasion during transport. Within the gouge, crystals and lava fragments adjacent to finely comminuted shear zones (slickensides) are shattered into small, angular fragments that are either preserved in place, with little disruption, or incorporated into shear trains, creating a well-developed foliation. Together, evidence of initial grain shattering, followed by shear, grinding, and wear, suggests extensive transport distances (large strains). Textural transitions are often abrupt, indicating extreme shear localization during transport. Comparison of groundmass textures from dome lavas and fault gouge further suggests that brittle fracture was confined to the upper 400-500 m of the conduit. Observed magma extrusion (ascent) rates of ~7 m/d (8×10 -5 m/s) permit several weeks for magma ascent from ~1,000 m (where groundmass crystallization becomes important) to ~500 m (where solidification nears completion). Brittle fracture, cataclastic flow, and shear localization (slickenside formation) probably dominated in the upper 500 m of the conduit. Comparison of eruptive conditions during the 2004-6 activity at Mount St. Helens with those of other spine-forming eruptions suggests that magma ascent rates of about 10 -4 m/s or less allow sufficient degassing and crystallization within the conduit to form large volcanic spines of intermediate composition (andesite to dacite). Solidification deep within the conduit, in turn, requires transport of the solid plug over long distances (hundreds of meters); resultant large strains are responsible for extensive brittle breakage and development of thick gouge zones. Moreover, similarities between gouge textures and those of ash emitted by explosions from spine margins indicate that fault gouge is the origin for the ash. As the comminution and generation of ash-sized particles was clearly a multistep process, this observation suggests that fragmentation preceded, rather than accompanied, these explosions.

Washington

Identification and evolution of the juvenile component in 2004-2005 Mount St. Helens ash

Petrologic studies of volcanic ash are commonly used to identify juvenile volcanic material and observe changes in the composition and style of volcanic eruptions. During the 2004-5 eruption of Mount St. Helens, recognition of the juvenile component in ash produced by early phreatic explosions was complicated by the presence of a substantial proportion of 1980-86 lava-dome fragments and glassy tephra, in addition to older volcanic fragments possibly derived from crater debris. In this report, we correlate groundmass textures and compositions of glass, mafic phases, and feldspar from 2004-5 ash in an attempt to identify juvenile material in early phreatic explosions and to distinguish among the various processes that generate and distribute ash. We conclude that clean glass in the ash is derived mostly from nonjuvenile sources and is not particularly useful for identifying the proportion of juvenile material in ash samples. High Li contents (>30 &mu;g/g) in feldspars provide a useful tracer for juvenile material and suggest an increase in the proportion of the juvenile component between October 1 and October 4, 2004, before the emergence of hot dacite on the surface of the crater on October 11, 2004. The presence of Li-rich feldspar out of equilibrium (based on Liplagioclase/melt partitioning) with groundmass and bulk dacite early in the eruption also suggests vapor enrichment in the initially erupted dacite. If an excess vapor phase was, indeed, present, it may have provided a catalyst to initiate the eruption. Textural and compositional comparisons between dome fault gouge and the ash produced by rockfalls, rock avalanches, and vent explosions indicate that the fault gouge is a likely source of ash particles for both types of events. Comparison of the ash from vent explosions and rockfalls suggests that the fault gouge and new dome were initially heterogeneous, containing a mixture of conduit and crater debris and juvenile material, but became increasingly homogeneous, dominated by juvenile material, by early January 2005.

Washington

Petrology of the 2004-2006 Mount St. Helens lava dome -- implications for magmatic plumbing and eruption triggering

Eighteen years after dome-forming eruptions ended in 1986, and with little warning, Mount St. Helens began to erupt again in October 2004. During the ensuing two years, the volcano extruded more than 80×10 6 m 3 of gas-poor, crystal-rich dacite lava. The 2004-6 dacite is remarkably uniform in bulk-rock composition and, at 65 percent SiO 2 , among the richest in silica and most depleted in incompatible elements of the magmas erupted at Mount St. Helens during the past 500 years. Since shortly after the first spine of lava appeared, samples have been collected using a steel box dredge (“Jaws”) suspended 20-35 m below a helicopter and, occasionally, by hand sampling. As of the spring of 2006, 25 age-controlled samples have been collected from the seven spines of the new lava dome. Samples were obtained from both the interiors of spines and from their carapaces, which are composed of fault gouge and cataclasite 1-2 m thick. The dacite lava is crystal rich, with 40-50 percent phenocrysts. The groundmass is extensively crystallized to a cotectic assemblage of quartz, tridymite, and Na- and K-rich feldspar microlites, raising the total crystal content to more than 80 percent on a vesicle-free basis in all but the earliest erupted samples. Early samples and those collected from near the spine margin are more glassy and vesicular that those collected later and from the interior of the spines. Oxide thermobarometer determinations for the earliest erupted samples we collected cluster at temperatures of approximately 850&deg;C and at an oxygen fugacity one log unit above the nickel-nickel oxide (NNO) buffer curve. In contrast, samples from relatively glass-poor samples erupted in late 2004 and early 2005 have zoned oxides with apparent temperatures that range to greater than 950&deg;C. The higher temperatures in these microlite-rich rocks are attributed to latent heat evolved during extensive and rapid groundmass crystallization. Low volatile contents of matrix glasses and presence of tridymite and quartz in the high-silica rhyolite matrix glass indicate extensive shallow (<1 km) crystallization of the matrix, driven by degassing of water and solidifying the magma below the level of the vent. The mode of eruption of the dacite as a series of fault-gouge-mantled spines is explained by this process of extensive subvent degassing and solidification. Although the dacite from this eruption is more silica rich than 1980-86 dome rocks, most major and trace element concentrations of the 1980-86 and 2004-6 magma batches are similar, and magmatic gas emissions have been low and have had similar ratios to those of the 1980s, raising the possibility that the magma might be residual from the 1980–86 reservoir. However, titanium and chromium are enriched slightly relative to the most recent 1980-86 and Goat Rocks (A.D. 1800-1857) eruptive cycles, and heavy rare-earth-element abundances are slightly depleted relative to those erupted during the past 500 years at Mount St. Helens. These data suggest either addition of new gas-poor dacite magma or tapping of a region of the preexisting reservoir that was not erupted previously. A relatively low pressure of last phenocryst growth suggests that the magma was derived from near the apex of the Mount St. Helens magma reservoir at a depth of about 5 km. Viewed in the context of seismic, deformation, and gas-emission data, the petrologic and geochemical data can be explained by ascent of a geochemically distinct batch of magma into the apex of the reservoir during the period 1987-97, followed by upward movement of magma into a new conduit beginning in late September 2004. The question of new versus residual magma has implications for the long-term eruptive behavior of Mount St. Helens, because arrival of a new batch of dacitic magma from the deep crust could herald the beginning of a new long-term cycle of eruptive activity. It is also important to our understanding of what triggered the eruption and its future course. Two hypotheses for triggering are considered: (1) top-down fracturing related to the shallow groundwater system and (2) an increase in reservoir pressure brought about by recent magmatic replenishment. With respect to the future course of the eruption, similarities between textures and character of eruption of the 2004-6 dome and the long-duration (greater than 100 years) pre-1980 summit dome, along with the low eruptive rate of the current eruption, suggest that the eruption could continue sluggishly or intermittently for years to come.

Washington

Chemistry, mineralogy, and petrology of amphibole in Mount St. Helens 2004-2006 dacite

Textural, compositional, and mineralogical data are reported and interpreted for a large population of clinoamphibole phenocrysts in 22 samples from the seven successive dacite spines erupted at Mount St. Helens between October 2004 and January 2006. Despite the uniformity in bulk composition of magma erupted since 2004, there is striking textural and compositional diversity among amphibole phenocrysts and crystal fragments that have grown from, partly dissolved in, or been accidentally incorporated in the new dacite. This study demonstrates that magma erupted throughout the current dome-building episode is the end product of small-scale, thorough mixing of multiple generations of crystal-laden magma. The mixed amphibole population provides important clues to magma conditions within the dacite magma reservoir prior to ascent and, to some extent, the dynamics of mixing and ascent. The predominant amphibole in new dome rock ranges from moderate- to high-alumina tschermakite and magnesiohastingsite compositions. As substantiated by major- and trace-element geochemistry and barometry calculations, this compositional range of crystals, along with plagioclase, orthopyroxene, and iron-titanium oxide, is likely to have precipitated from dacite magma over a range of pressures and temperatures consistent with experimentally determined phase relations (~900&deg;C to ~800&deg;C between 100 MPa and ~350-400 MPa or ~4-km and 13.5-15-km depth). Along with traceelement characteristics, textural and compositional data help to distinguish some low-alumina magnesiohornblende crystals as xenocrysts. The diverse range in composition of amphibole in all samples of 2004-6 dacite, and the complex zonation observed in many phenocrysts, suggests a well-mixed source magma with components that are subjected to repeated heating and (or) pressurization within this pressure-temperature window. Amphibole textural and compositional diversity suggest dynamic conditions in the upper-reservoir zone, which has been tapped steadily during ~2 years of continuous and monotonous eruption. This well-mixed crystal mush is likely to have been subjected to repeated injection of hotter magma into cooler crystal-laden magma while simultaneously assimilating earlier generations of dacitic roof material and surrounding gabbroic rock. Decompression-related reaction rims around subhedral, rounded, resorbed, and fragmented amphibole phenocrysts, regardless of composition, indicate that this mixed-crystal assemblage was being broken, abraded, and dissolved in the magma as a result of mechanical mixing before and during early stages of ascent from conduit roots extending into a mushy cupola of the shallow reservoir. In the earliest lava samples (October 2004), amphiboles with <3-&mu;m rims associated with a glassier matrix than later samples suggest a slightly faster ascent rate consistent with the relatively high eruptive flux of the earliest phases of dome extrusion. Reaction rim widths of ~5 &mu;m on amphibole in all subsequently extruded lava result from a steady influx and upward transport of magma from 3.5-2.5-km to ~1-km depth at rates of ~600 to ~1,200 m/day, through a conduit less than 10 m in radius. Slower ascent rates inferred from volumetric-flux and matrixcrystallization parameters are explained by a widening of the conduit to greater than 60 m radius within 1 km of the surface.

Washington

Trace element and Pb isotope composition of plagioclase from dome samples from the 2004-2005 eruption of Mount St. Helens, Washington

We report the results of in-situ laser ablation ICP–MS analyses of anorthite content, trace-element (Li, Ti, Sr, Ba, La, Pr, Ce, Nd, Eu, Pb) concentrations, and Pb-isotope compositions in plagioclase from eight dome-dacite samples collected from the 2004-5 eruption of Mount St. Helens and, for comparison, from three dome samples from 1981-85. For 2004-5 samples, plagioclase phenocrysts range in composition from An 30 to An 80 , with the majority An 42 -An 65 . With the exception of Li, the range of trace-element abundances in plagioclase phenocrysts is largely constant in material erupted between October 2004 and April 2005 and is broadly consistent with the 1983-85 dome samples. Anomalously high Li contents in the early stage of the eruption are thought to reflect addition of Li to the upper part of the magma chamber immediately before eruption (within ~1 year) by transfer of an alkali-enriched, exsolved vapor from deep within the magma chamber. Other trace elements show significant correlations (at >99 percent confidence limits) with anorthite content in plagioclase phenocrysts--Ba, light rareearth elements (LREE), and Pb show positive correlations, whereas Ti and Sr correlate negatively. Variations in plagioclase-melt partitioning as a function of anorthite content cannot explain trace-element variations--in particular predicting trends for Ti and Sr opposite to those observed. A simple model involving closed-system fractional crystallization of plagioclase + hypersthene + amphibole + oxides largely reproduces the observed trends. The model requires no gain or loss of plagioclase and is consistent with the lack of europium anomalies in bulk dacite samples. Analytical traverses within individual plagioclase phenocrysts support this model but also point to a diversity of melt compositions present within the magma storage zone in which plagioclase crystallized. Plagioclase crystals from gabbronorite inclusions in three dacite samples have markedly different trace-element and Pbisotope compositions from those of plagioclase phenocrysts, despite having a similar range of anorthite contents. Inclusions show some systematic differences from each other but typically have higher Ti, Ba, LREE, and Pb and lower Sr and have lower 208 Pb/ 206 Pb and 207 Pb/ 206 Pb ratios than coexisting plagioclase phenocrysts. The compositions of plagioclase from inclusions cannot be related to phenocryst compositions by any reasonable petrologic model. From this we suggest that they are unlikely to represent magmatic cumulates or restite inclusions but instead are samples of mafic Tertiary basement from beneath the volcano.

Washington

Timing of degassing and plagioclase growth in lavas erupted from Mount St. Helens, 2004-2005, from 210Po-210Pb-226Ra disequilibria

Disequilibrium between 210 Po, 210 Pb, and 226 Ra was measured on rocks and plagioclase mineral separates erupted during the first year of the ongoing eruption of Mount St. Helens. The purpose of this study was to monitor the volatile fluxing and crystal growth that occurred in the weeks, years, and decades leading up to eruption. Whole-rock samples were leached in dilute HCl to remove 210 Po precipitated in open spaces. Before leaching, samples had variable initial ( 210 Po) values, whereas after leaching, the groundmasses of nearly all juvenile samples were found to have had ( 210 Po) &asymp; 0 when they erupted. Thus, most samples degassed 210 Po both before and after the magmas switched from open- to closed-system degassing. All juvenile samples have ( 210 Pb)/( 226 Ra) ratios within 2 &delta; of equilibrium, suggesting that the magmas involved in the ongoing eruption did not have strong, persistent fluxes of 222 Rn in or out of magmas during the decades and years leading to eruption. These equilibrium values also require a period of at least a century after magma generation and the last significant differentiation of the Mount St. Helens dacites. Despite this, the elevated ( 210 Pb)/( 226 Ra) value measured in a plagioclase mineral separate from lava erupted in 2004 suggests that a significant proportion of this plagioclase grew within a few decades of eruption. The combined dataset suggests that for most 2004-5 lavas, the last stage of open-system degassing of the dacite magmas at Mount St. Helens is confined to the period between 1-2 years and 1-2 weeks before eruption, whereas plagioclase large enough to be included in the mineral separate grew around the time of the 1980s eruption or earlier.

Washington

A compilation of whole-rock and glass major-element geochemistry of Kilauea Volcano, Hawai'i, near-vent eruptive products: January 1983 through September 2001

This report presents major-element geochemical data from 652 glasses (~6,520 analyses) and 795 whole-rock aliquots from 1,002 fresh samples of olivine-tholeiitic lava collected throughout the near-continuous eruption of Kïlauea Volcano, Hawai'i, from January 1983 through September 2001. The data presented herein provide a unique temporal compilation of lava geochemistry that best reflects variations of pre-eruptive magma compositions during prolonged rift-zone eruption. This document serves as a repository for geochemical data referred to in U.S. Geological Survey Professional Paper 1676 (Heliker, Swanson, and Takahashi, eds., 2003) which includes multidisciplinary research papers pertaining to the first twenty years of Puu Oo-Kupaianaha eruption activity. Details of eruption characteristics and nomenclature are provided in the introductory chapter of that volume (Heliker and Mattox, 2003). Geochemical relations among all or portions of this data set are depicted and interpreted by Thornber (2003), Thornber and others (2003) and Thornber (2001). Trace element compositions and Nd, Sr and Pb isotopic analyses of representative samples of this select eruption suite will be provided in a separate and complimentary open file report. From 1983 to October 2001, approximately 2,500 eruption samples were collected and archived by the U.S. Geological Survey’s Hawaiian Volcano Observatory (HVO). Geochemical data for 1,002 of these samples are included here. Previous reports present bulk-lava major- element chemistry for eruption samples collected from 1983 to 1986 and from 1990 to 1994 (Neal and others, 1988 and Mangan and others, 1995, respectively). Major element glass chemistry and thermometry data for samples collected from 1983 to 1994 is reported by Helz and Hearn (1998) and whole-rock and glass chemistry for samples collected from September 1994 to October 2001 is provided by Thornber and others (2002). This report is a compilation of previously published data along with unpublished whole-rock data for the 1986–1990 eruptive interval (episode 48, see Heliker and Mattox, 2003). The geochemical data in this report is mostly limited to well-quenched samples collected at or near their respective vents. The samples include tephra and spatter, in addition to lava dipped from lava lakes, lava tubes, and surface lava flows. The details of sample collection techniques as described by Thornber and others (2002) are generally applicable for this entire sampling interval. Specifically excluded from this database are samples of distal surface flows, many of which were collected for topical studies of emplacement dynamics (for example, Cashman and others, 1999). Samples of sluggish or crystal-laden tube flows collected during eruptive pauses were also excluded, because they bear visual, petrographic and geochemical evidence for crystal accumulation during surface-flow stagnation. In addition, the pre-1992 whole-rock major element data reported here has been corrected to compensate for minor analytical discrepancies between pre- and post-1991 XRF analyses. These discrepancies resulted from a change in instrumentation at the USGS Denver analytical laboratories. This select suite of time-constrained geochemical data is suitable for constructing petrologic models of pre-eruptive magmatic processes associated with prolong rift zone eruption of Hawaiian shield volcanoes.

Hawai'i

Trace element and Nd, Sr, Pb isotope geochemistry of Kilauea Volcano, Hawai'i, near-vent eruptive products: 1983-2001

This open-file report serves as a repository for geochemical data referred to in U.S. Geological Survey Professional Paper 1676 (Heliker, Swanson, and Takahashi, eds., 2003), which includes multidisciplinary research papers pertaining to the first twenty years of Puu Oo Kupaianaha eruption activity. Details of eruption characteristics and nomenclature are provided in the introductory chapter of that volume (Heliker and Mattox, 2003). Geochemical relations of this data are depicted and interpreted by Thornber (2003), Thornber and others (2003a) and Thornber (2001). This report supplements Thornber and others (2003b) in which whole-rock and glass major-element data on ~1000 near-vent lava samples collected during the 1983 to 2001 eruptive interval of Kilauea Volcano, Hawai'i, are presented. Herein, we present whole-rock trace element compositions of 85 representative samples collected from January 1983 to May 2001; glass trace-element compositions of 39 Pele’s Tear (tephra) samples collected from September 1995 to September 1996, and whole-rock Nd, Sr and Pb isotopic analyses of 10 representative samples collected from September 1983 to September 1993. Thornber and others (2003b) provide a specific record of sample characteristics, location, etc., for each of the samples reported here. Spreadsheets of both reports may be integrated and sorted based upon time of formation or sample numbers. General information pertaining to the selectivity and petrologic significance of this sample suite is presented by Thornber and others (2003b). As justified in that report, this select suite of time-constrained geochemical data is suitable for constructing petrologic models of pre-eruptive magmatic processes associated with prolonged rift zone eruption of Hawaiian shield volcanoes.

Hawai'i

Whole-rock and glass major-element geochemistry of Kilauea Volcano, Hawaii, near-vent eruptive products: September 1994 through September 2001

This report presents major-element geochemical data for glasses and whole-rock aliquots among 523 lava samples collected near the vent on Kilauea's east rift zone between September 1994 and October 2001. Information on sample collection, analysis techniques and analytical standard reproducibility are presented as a PDF file, which also includes a detailed explantion of the categories of sample information presented in the database spreadsheet. The sample database is downloadable as a separate Microsoft Excel file.

Hawai'i

Olivine-liquid relations of lava erupted by Kilauea volcano from 1994 to 1998: Implications for shallow magmatic processes associated with the ongoing east-rift-zone eruption

From 1994 through 1998, the eruption of Kîlauea, in Hawai’i, was dominated by steady-state effusion at Pu‘u ‘Ô‘ô that was briefly disrupted by an eruption 4 km uprift at Nāpau Crater on January 30, 1997. In this paper, I describe the systematic relations of whole-rock, glass, olivine, and olivine-inclusion compositions of lava samples collected throughout this interval. This suite comprises vent samples and tube-contained flows collected at variable distances from the vent. The glass composition of tube lava varies systematically with distance and allows for the “vent-correction” of glass thermometry and olivine–liquid K D as a function of tube-transport distance. Combined olivine–liquid data for vent samples and “vent-corrected” lava-tube samples are used to document pre-eruptive magmatic conditions. K D values determined for matrix glasses and forsterite cores define three types of olivine phenocrysts: type A (in equilibrium with host glass), type B (Mg-rich relative to host glass) and type C (Mg-poor relative to host glass). All three types of olivine have a cognate association with melts that are present within the shallow magmatic plumbing system during this interval. During steady-state eruptive activity, the compositions of whole-rock, glass and most olivine phenocrysts (type A) all vary sympathetically over time and as influenced by changes of magmatic pressure within the summit-rift-zone plumbing system. Type-A olivine is interpreted as having grown during passage from the summit magma-chamber along the east-rift-zone conduit. Type-B olivine (high Fo) is consistent with equilibrium crystallization from bulk-rock compositions and is likely to have grown within the summit magma-chamber. Lower-temperature, fractionated lava was erupted during non-steady-state activity of the Nāpau Crater eruption. Type-A and type-B olivine–liquid relations indicate that this lava is a mixture of rift-stored and summit-derived magmas. Post- Nāpau lava (at Pu‘u ‘Ô‘ô) gradually increases in temperature and MgO content, and contains type-C olivine with complex zoning, indicating magma hybridization associated with the flushing of rift-stored components through the eruption conduit.

Hawaii