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Carl M. Wentworth

Publications and source records attributed to Carl M. Wentworth.

At least 19 recordsLinked to original sources
USGS2023

Geologic and geophysical maps of the Stockton 30’ × 60’ quadrangle, California

This pamphlet and accompanying geologic and geophysical maps are the products of cooperative efforts by the California Geological Survey (CGS) and United States Geological Survey (USGS) to compile a comprehensive, digital representation of the bedrock geology, Quaternary surficial deposits, and potential-field anomalies within the boundaries of the Stockton 30’ × 60’ quadrangle. The Stockton 30’ × 60’ quadrangle covers approximately 4,890 km 2 of Contra Costa, Alameda, San Joaquin, and Stanislaus Counties, California. From the rugged hillsides of the northern Diablo Range in the west to the San Joaquin Valley in the east, the map extends roughly 88 km across growing suburban communities of the eastern San Francisco Bay Area and Livermore Valley, grass-covered ranchlands along eastern slopes of the Diablo Range, and into the low farmlands of the San Joaquin Valley and Sacramento-San Joaquin River Delta (Figure 1). The elevation ranges from near sea level in the Delta to 1,173 meters on Mt. Diablo, the most prominent peak of the San Francisco Bay region.

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USGS2021

Comment on ‘New insights on Franciscan Complex geology, architecture, depositional age, and provenance for the western Mt. Tamalpais area, Marin County, California’ by Bero et al. (2020)

Serious errors and inconsistencies in the article undermine many of its interpretations to the point that principal conclusions are not valid. Much dependence is placed on the maximum depositional age (Dmax) of sandstone units based on zircon analysis of 10 samples, but calculation of those Dmax values is flawed, and their use confuses maximum with actual depositional ages and makes age distinctions finer than the resolution of the data. Conclusions that are compromised include the concept of a westward/downward-younging tectonostratigraphic stack of accretionary units, comparison of mapped sandstones with other California Coast Ranges sandstones, comparison of timing of events recorded in the map area with regional events, identification of mélange only in a narrow band in the study area, and detrital provenance of some of the sandstone units.

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USGS2016

Paleomagnetic record determined in cores from deep research wells in the Quaternary Santa Clara basin, California

Paleomagnetic study of cores from six deep wells provides an independent temporal framework for much of the alluvial stratigraphy of the Quaternary basin beneath the Santa Clara Valley. This stratigraphy consists of 8 upward-fining cycles in the upper 300 m of section and an underlying 150 m or more of largely fine-grained sediment. The eight cycles have been correlated with the marine oxygen isotope record, thus providing one means of dating the section. The section has also proved to contain a rich paleomagnetic record despite the intermittent sedimentation characteristic of alluvial environments. Each well was designed to reach a depth of ~300 m, although 2 were terminated at shallower depth where bedrock was encountered and one (GUAD) was deepened to bedrock at 407.2 m. Cores were taken at intermittent intervals in most of the wells, composing ~20%–25% of their depths. In GUAD an attempt was made to core the entire upper 300 m, with core recovery of 201.8 m (67%). The paleomagnetic framework ranges from the 32 ka Mono Lake excursion near the top of the second sedimentary cycle to below the 780 ka Brunhes-Matuyama geomagnetic reversal beneath the eighth cycle. These ages nicely fit those assigned to the section based on correlation with the marine oxygen isotope record. Several episodes of anomalous magnetic inclinations were also found within the cyclic section in some of the wells. Some of the episodes of anomalous magnetic inclinations are only separated by short normal intervals in a pattern similar to that described for some welldocumented excursions. We consider that a geomagnetic excursion was likely only if the anomalous inclinations were found at approximately the same stratigraphic position in more than one drill hole. A deeper time constraint is provided by the upper boundary (990 ka) of the Jaramillo Normal Polarity Subchron recognized at a depth of 302 m in one deeply penetrating well (GUAD). Approximately 100 m of normal Jaramillo section is evident below that in wells GUAD and EVGR. The reversal that we identify as the 780 ka Brunhes-Matuyama boundary, found at depths of 291–303 m in three wells, indicates an average rate of deposition in this upper section of ~37 cm/k.y. In GUAD, the top of the underlying normally polarized section, which we assign to the upper part of the Jaramillo Normal Polarity Subchron, was found between 301.8 and 304.5 m. The resultant 10 m of reversed polarity section above the Jaramillo seems anomalously short for this 210 k.y. part of the Matuyama Chron, during which several times that thickness of section probably should have accumulated. This observation indicates that a significant unconformity should be present in that short section between the Jaramillo Subchron and the Brunhes-Matuyama boundary. Deeper cores in two wells (GUAD and EVGR) all have normal polarity and seem to represent much of the Jaramillo Subchron, although no base for that subchron was found. The resultant minimum rate of sedimentation for this lower section beneath the unconformity is 170 cm/k.y. The Mono Lake (ca. 32 ka), Pringle Falls (ca. 210 ka), and Big Lost (ca. 565 ka) geomagnetic excursions all seem to be represented in the Santa Clara Valley wells. Possible correlations to the Laschamp (ca. 40 ka) and Blake (ca. 110 ka) excursions are also noted. Three additional excursions that have apparently not been previously reported from western North America occur within cycle 6 (between 536 and 433 ka), near the base of cycle 5 (after 433 ka), and near the middle of cycle 2 (before ca. 75 ka).

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USGS2015

A summary of the late Cenozoic stratigraphic and tectonic history of the Santa Clara Valley, California

The late Cenozoic stratigraphic and tectonic history of the Santa Clara Valley illustrates the dynamic nature of the North American–Pacific plate boundary and its effect on basin and landscape development. Prior to early Miocene time, the area that became Santa Clara Valley consisted of eroding Franciscan complex basement structurally interleaved in places with Coast Range ophiolite and Mesozoic Great Valley sequence, and locally overlapped by Paleogene strata. During early to middle Miocene time, this landscape was flooded by the sea and was deformed locally into deeper depressions such as the Cupertino Basin in the southwestern part of the valley. Marine deposition during the middle and late Miocene laid down thin deposits in shallow water and thick deeper-water deposits in the Cupertino Basin. During this sedimentation, the San Andreas fault system encroached into the valley, with most offset partitioned onto the San Andreas fault southwest of the valley and the southern Calaveras–Silver Creek–Hayward fault system in the northeastern part of the valley. A 6-km-wide right step between the Hayward and Silver Creek faults formed the 40-km-long Evergreen pull-apart basin along the northeastern margin of the valley, leaving a basement ridge between it and the Cupertino Basin. The Silver Creek fault was largely abandoned ca. 2.5 Ma in favor of a compressional left step between the Calaveras and Hayward fault, although some slip continued to at least mid-Quaternary time. Gravity, seismic, stratigraphic, and interferometric synthetic aperture radar (InSAR) data indicate no other major San Andreas system faults within the central block between the present-day range-front faults bounding the valley and the Silver Creek fault. Sometime between 9 and 4 Ma (9 and 1 Ma for the central block), the area rose above sea level, and a regional surface of erosion was carved into the Mesozoic and Tertiary rocks. Alluvial gravels were deposited on this surface along the margins of the valley beginning ca. 4 Ma, but they may not have prograded onto the central block until ca. 1 Ma, because no older equivalents of the Pliocene–Quaternary Santa Clara gravels have been found there. Thus, either the central block was high enough relative to the surrounding areas that Santa Clara gravels were never deposited on it, or any Santa Clara gravels deposited there were stripped away before ca. 1 Ma. Analysis of alluvium on the central block implies a remarkably uniform, piston-like, subsidence of the valley of ∼0.4 mm/yr since ca. 0.8 Ma, possibly extending north to northern San Francisco Bay. Today, the central block continues to subside, the range-front reverse faults are active, and the major active faults of the San Andreas system are mostly outside the valley.

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USGS2015

Structural superposition in fault systems bounding Santa Clara Valley, California

Santa Clara Valley is bounded on the southwest and northeast by active strike-slip and reverse-oblique faults of the San Andreas fault system. On both sides of the valley, these faults are superposed on older normal and/or right-lateral normal oblique faults. The older faults comprised early components of the San Andreas fault system as it formed in the wake of the northward passage of the Mendocino Triple Junction. On the east side of the valley, the great majority of fault displacement was accommodated by the older faults, which were almost entirely abandoned when the presently active faults became active after ca. 2.5 Ma. On the west side of the valley, the older faults were abandoned earlier, before ca. 8 Ma and probably accumulated only a small amount, if any, of the total right-lateral offset accommodated by the fault zone as a whole. Apparent contradictions in observations of fault offset and the relation of the gravity field to the distribution of dense rocks at the surface are explained by recognition of superposed structures in the Santa Clara Valley region.

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USGS2015

Physical subdivision and description of the water-bearing sediments of the Santa Clara Valley, California

A thick Quaternary alluvial section fills a sedimentary basin beneath the Santa Clara Valley, California, located within the San Andreas Fault system at the south end of San Francisco Bay. This section consists of an upper sequence about 1,000 feet thick containing eight sedimentary cycles and a lower fine-grained unit as thick as several hundred feet. Together these constitute the Quaternary Santa Clara Basin. The section overlies an irregular unconformity with more than 1,200 feet of relief cut into the underlying bedrock. This stratigraphy is determined through study of new wells and seismic reflection profiles, together with a sample of the many thousands of water wells in the valley. It represents a major change and improvement in understanding of the basin, particularly with regard to the upper cyclic sequence, which forms a large groundwater system that is an important resource in the San Francisco Bay region. Each of the eight sedimentary cycles consists of a coarse-grained bottom interval overlain by a fine-grained top, with the coarse bottom forming a permeable sheet that is more or less continuous around the basin and the fine top forming a similarly extensive, relatively impermeable confining layer. This stratigraphic organization contrasts with most previous views, which have considered the coarse sediment in the basin to occur as scattered, discrete lenses and (or) sinuous channel sands, all embedded in a predominantly fine-grained section. Temperature logs in several wells demonstrate that the fine cycle tops do limit vertical movement of groundwater, although this may not be the case where those tops are thin to perhaps locally absent around parts of the basin margin. Age control has been obtained from previous work, in which the sedimentary cycles were correlated with the marine oxygen isotope record and the ages of two deeper Quaternary unconformities were estimated, and from detailed paleomagnetic study of cores from the new wells by E.A. Mankinen. Despite careful search of the cores, very few fossils were found, and none that are helpful in subdividing the section. No tephra (volcanic ash) was recovered, and the few carbon samples found and dated radiometrically are limited to the upper 120 feet of the section. The upper cyclic section ranges in age from 0 to somewhat older than 718 thousand years (ka), and the lower fine-grained section lies between unconformities with estimated ages of 950 and 1500 ka. Reflections in the seismic profiles indicate that layering in the basin is subparallel to the ground surface, and this fact, together with the continuous stratigraphic detail provided by geophysical logs of the new wells, allows the confident interwell correlation required to delineate the sedimentary cycles. The sequence of layers within any one cycle tends to persist laterally between the wells in the dataset, which are spaced 1 to 3 km apart, with most changes occurring gradually. The eight cycles, in contrast, tend to differ from each other in the details of their internal organization. Maps and cross sections show the elevations of cycle boundaries and the underlying bedrock surface, the varying thicknesses of the cycles and of their fine tops and coarse bottoms, and the aggregate thickness of coarse layers in those bottom intervals. Coarse sediment is more abundant toward some parts of the basin margin and in the southern part of the basin. Cycle boundary surfaces are relatively smooth, and their shapes are consistent with having been intercycle topographic surfaces. The underlying bedrock surface has a relief of more than 1,200 feet and deepens toward the center of the basin and the west edge of the fault-bounded Evergreen Basin, which is concealed beneath the east side of the Quaternary basin. The absence of consistent abrupt changes in thicknesses or boundary elevations across the basin or in cross section indicates that the interior of the basin is largely unfaulted, with the Silver Creek strand of the San Andreas system at the west edge of the Evergreen Basin being the sole exception. The east and west margins of the Santa Clara Basin, in contrast, are marked by reverse and thrust fault systems.

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USGS2013

Previously unrecognized regional structure of the Coastal Belt of the Franciscan Complex, northern California, revealed by magnetic data

Magnetic anomalies provide surprising structural detail within the previously undivided Coastal Belt, the westernmost, youngest, and least-metamorphosed part of the Franciscan Complex of northern California. Although the Coastal Belt consists almost entirely of arkosic graywacke and shale of mainly Eocene age, new detailed aeromagnetic data show that it is pervasively marked by long, narrow, and regularly spaced anomalies. These anomalies arise from relatively simple tabular bodies composed principally of magnetic basalt or graywacke confi ned mainly to the top couple of kilometers, even though metamorphic grade indicates that these rocks have been more deeply buried, at depths of 5–8 km. If true, this implies surprisingly uniform uplift of these rocks. The basalt (and associated Cretaceous limestone) occurs largely in the northern part of the Coastal Belt; the graywacke is recognized only in the southern Coastal Belt and is magnetic because it contains andesitic grains. The magnetic grains were not derived from the basalt, and thus require a separate source. The anomalies defi ne simple patterns that can be related to folding and faulting within the Coastal Belt. This apparent simplicity belies complex structure mapped at outcrop scale, which can be explained if the relatively simple tabular bodies are internally deformed, fault-bounded slabs. One mechanism that can explain the widespread lateral extent of the thin layers of basalt is peeling up of the uppermost part of the oceanic crust into the accretionary prism, controlled by porosity and permeability contrasts caused by alteration in the upper part of the subducting slab. It is not clear, however, how this mechanism might generate fault-bounded layers containing magnetic graywacke. We propose that structural domains defined by anomaly trend, wavelength, and source reflect imbrication and folding during the accretion process and local plate interactions as the Mendocino triple junction migrated north, a hypothesis that should be tested by more detailed structural studies.

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USGS2012

The Cedars ultramafic mass, Sonoma County, California

The Cedars ultramafic mass is a mantle fragment that consists of partially serpentinized spinel harzburgite and dunite. Compositional layering and a chromite lineation define a penetrative metamorphic foliation that almost certainly formed in the upper mantle. Although detailed petrofabric and mineral chemistry are presently lacking, it seems reasonable that the Cedars peridotite represents a slice of mantle tectonite that once formed the base of the Coast Range ophiolite, and not an abyssal peridotite tectonically emplaced within the Franciscan accretionary prism.

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USGS2012

Digital geologic map of the Redding 1° x 2° quadrangle, Shasta, Tehama, Humboldt, and Trinity Counties, California

The Redding 1° x 2° quadrangle in northwestern California transects the Franciscan Complex and southern Klamath Mountains province as well as parts of the Great Valley Complex, northern Great Valley, and southernmost Cascades volcanic province. The tectonostratigraphic terranes of the Klamath province represent slices of oceanic crust, island arcs, and overlying sediment that range largely from Paleozoic to Jurassic in age. The Eastern Klamath terrane forms the nucleus to which the other terranes were added westward, primarily during Jurassic time, and that package was probably accreted to North America during earliest Cretaceous time. The younger Franciscan Complex consists of a sequence of westward younging tectonostratigraphic terranes of late Jurassic to Miocene age that were accreted to North America from mid-Cretaceous through Miocene time, with the easternmost being the most strongly metamorphosed. The marine Great Valley sequence, of late Jurassic and Cretaceous age, was deposited unconformably across the southernmost Klamath rocks, but in turn was underthrust at its western margin by Eastern belt Franciscan rocks. Pliocene and Quaternary volcanic rocks and sediment of the Cascades province extend into the southeastern part of the quadrangle, abutting the northernmost part of the great central valley of California. This map and database represent a digital rendition of Open-File Report 87-257, 1987, by L.A. Fraticelli, J.P. Albers, W.P. Irwin, and M.C. Blake, Jr., with various improvements and additions.

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USGS2010

The style of late Cenozoic deformation at the eastern front of the California Coast Ranges

The 1983 Coalinga earthquake occurred at the eastern boundary of the California Coast Ranges in response to northeast directed thrusting. Such movements over the past 2 Ma have produced Coalinga anticline by folding above the blind eastern tip of the Coalinga thrust zone. The 600-km length of the Coast Ranges boundary shares a common structural setting that involves westward upturn of Cenozoic and Cretaceous strata at the eastern front of the Coast Ranges and a major, southwest facing step in the basement surface beneath the western Great Valley. Like Coalinga anticline, Pliocene and Quaternary folding and faulting along the rest of the boundary also result from northeast–southwest compression acting nearly perpendicular to the strike of the San Andreas fault. We suggest that much of this deformation is related to active thrusts beneath the eastern Coast Ranges. The step in the basement surface beneath the Great Valley seems to have controlled the distribution of this deformation and the shape of the Coast Ranges boundary.

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USGS2010

The Quaternary Silver Creek Fault Beneath the Santa Clara Valley, California

The northwest-trending Silver Creek Fault is a 40-km-long strike-slip fault in the eastern Santa Clara Valley, California, that has exhibited different behaviors within a changing San Andreas Fault system over the past 10-15 Ma. Quaternary alluvium several hundred meters thick that buries the northern half of the Silver Creek Fault, and that has been sampled by drilling and imaged in a detailed seismic reflection profile, provides a record of the Quaternary history of the fault. We assemble evidence from areal geology, stratigraphy, paleomagnetics, ground-water hydrology, potential-field geophysics, and reflection and earthquake seismology to determine the long history of the fault in order to evaluate its current behavior. The fault formed in the Miocene more than 100 km to the southeast, as the southwestern fault in a 5-km-wide right step to the Hayward Fault, within which the 40-km-long Evergreen pull-apart basin formed. Later, this basin was obliquely cut by the newly recognized Mt. Misery Fault to form a more direct connection to the Hayward Fault, although continued growth of the basin was sufficient to accommodate at least some late Pliocene alluvium. Large offset along the San Andreas-Calaveras-Mt Misery-Hayward Faults carried the basin northwestward almost to its present position when, about 2 Ma, the fault system was reorganized. This led to near abandonment of the faults bounding the pull-apart basin in favor of right slip extending the Calaveras Fault farther north before stepping west to the Hayward Fault, as it does today. Despite these changes, the Silver Creek Fault experienced a further 200 m of dip slip in the early Quaternary, from which we infer an associated 1.6 km or so of right slip, based on the ratio of the 40-km length of the strike-slip fault to a 5-km depth of the Evergreen Basin. This dip slip ends at a mid-Quaternary unconformity, above which the upper 300 m of alluvial cover exhibits a structural sag at the fault that we interpret as a negative flower structure. This structure implies some continuing strike slip on the Silver Creek Fault in the late Quaternary as well, with a transtensional component but no dip slip. Our only basis for estimating the rate of this later Quaternary strike slip on the Silver Creek Fault is to assume continuation of the inferred early Quaternary rate of less than 2 mm/yr. Faulting evident in a detailed seismic reflection profile across the Silver Creek Fault extends up to the limit of data at a depth of 50 m and age of about 140 ka, and the course of Coyote Creek suggests Holocene capture in a structural depression along the fault. No surface trace is evident on the alluvial plain, however, and convincing evidence of Holocene offset is lacking. Few instrumentally recorded earthquakes are located near the fault, and those that are near its southern end represent cross-fault shortening, not strike slip. The fault might have been responsible, however, for two poorly located moderate earthquakes that occurred in the area in 1903. Its southeastern end does mark an abrupt change in the pattern of abundant instrumentally recorded earthquakes along the Calaveras Fault-in both its strike and in the depth distribution of hypocenters-that could indicate continuing influence by the Silver Creek Fault. In the absence of convincing evidence to the contrary, and as a conservative estimate, we presume that the Silver Creek Fault has continued its strike-slip movement through the Holocene, but at a very slow rate. Such a slow rate would, at most, yield very infrequent damaging earthquakes. If the 1903 earthquakes did, in fact, occur on the Silver Creek Fault, they would have greatly reduced the short-term future potential for large earthquakes on the fault.

Open-File Report↗
USGS2006

Maps of quaternary deposits and liquefaction susceptibility in the Central San Francisco Bay Region, California

This report presents a map and database of Quaternary deposits and liquefaction susceptibility for the urban core of the San Francisco Bay region. It supercedes the equivalent area of U.S. Geological Survey Open-File Report 00-444 (Knudsen and others, 2000), which covers the larger 9-county San Francisco Bay region. The report consists of (1) a spatial database, (2) two small-scale colored maps (Quaternary deposits and liquefaction susceptibility), (3) a text describing the Quaternary map and liquefaction interpretation (part 3), and (4) a text introducing the report and describing the database (part 1). All parts of the report are digital; part 1 describes the database and digital files and how to obtain them by downloading across the internet. The nine counties surrounding San Francisco Bay straddle the San Andreas fault system, which exposes the region to serious earthquake hazard (Working Group on California Earthquake Probabilities, 1999). Much of the land adjacent to the Bay and the major rivers and streams is underlain by unconsolidated deposits that are particularly vulnerable to earthquake shaking and liquefaction of water-saturated granular sediment. This new map provides a consistent detailed treatment of the central part of the 9-county region in which much of the mapping of Open-File Report 00-444 was either at smaller (less detailed) scale or represented only preliminary revision of earlier work. Like Open-File Report 00-444, the current mapping uses geomorphic expression, pedogenic soils, inferred depositional environments, and geologic age to define and distinguish the map units. Further scrutiny of the factors controlling liquefaction susceptibility has led to some changes relative to Open-File Report 00-444: particularly the reclassification of San Francisco Bay mud (Qhbm) to have only MODERATE susceptibility and the rating of artificial fills according to the Quaternary map units inferred to underlie them (other than dams - adf). The two colored maps provide a regional summary of the new mapping at a scale of 1:200,000, a scale that is sufficient to show the general distribution and relationships of the map units but not to distinguish the more detailed elements that are present in the database. The report is the product of cooperative work by the National Earthquake Hazards Reduction Program (NEHRP) and National Cooperative Geologic Mapping Program of the U.S. Geological Survey, William Lettis and & Associates, Inc. (WLA), and the California Geological Survey. An earlier version was submitted to the U.S. Geological Survey by WLA as a final report for a NEHRP grant (Witter and others, 2005). The mapping has been carried out by WLA geologists under contract to the NEHRP Earthquake Program (Grant 99-HQ-GR-0095) and by the California Geological Survey.

Open-File Report↗
USGS2004

Mono Lake excursion recorded in sediment of the Santa Clara Valley, California

Two intervals recording anomalous paleomagnetic inclinations were encountered in the top 40 meters of research drill hole CCOC in the Santa Clara Valley, California. The younger of these two intervals has an age of 28,090 ± 330 radiocarbon years B.P. (calibrated age ∼32.8 ka). This age is in excellent agreement with the latest estimate for the Mono Lake excursion at the type locality and confirms that the excursion has been recorded by sediment in the San Francisco Bay region. The age of an anomalous inclination change below the Mono Lake excursion was not directly determined, but estimates of sedimentation rates indicate that the geomagnetic behavior it represents most likely occurred during the Mono Lake/Laschamp time interval (∼45–28 ka). If true, it may represent one of several recurring fluctuations of magnetic inclination during an interval of a weak geomagnetic dipole, behavior noted in other studies in the region.

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USGS2004

Cross-sections and maps showing double-difference relocated earthquakes from 1984-2000 along the Hayward and Calaveras faults, California

We present cross-section and map views of earthquakes that occurred from 1984 to 2000 in the vicinity of the Hayward and Calaveras faults in the San Francisco Bay region, California. These earthquakes came from a catalog of events relocated using the double-difference technique, which provides superior relative locations of nearby events. As a result, structures such as fault surfaces and alignments of events along these surfaces are more sharply defined than in previous catalogs.

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USGS2003

Preliminary paleomagnetic results from the Coyote Creek Outdoor Classroom drill hole, Santa Clara Valley, California

Paleomagnetic samples were obtained from cores taken during the drilling of a research well along Coyote Creek in San Jose, California, in order to use the geomagnetic field behavior recorded in those samples to provide age constraints for the sediment encountered. The well reached a depth of 308 meters and material apparently was deposited largely (entirely?) during the Brunhes Normal Polarity Chron, which lasted from 780 ka to the present time. Three episodes of anomalous magnetic inclinations were recorded in parts of the sedimentary sequence; the uppermost two we correlate to the Mono Lake (~30 ka) geomagnetic excursion and 6 cm lower, tentatively to the Laschamp (~45 ka) excursion. The lowermost anomalous interval occurs at 305 m and consists of less than 10 cm of fully reversed inclinations underlain by 1.5 m of normal polarity sediment. This lower anomalous interval may represent either the Big Lost excursion (~565 ka) or the polarity transition at the end of the Matuyama Reversed Polarity Chron (780 ka). The average rates of deposition for the Pleistocene section in this well, based on these two alternatives, are approximately 52 or 37 cm/kyr, respectively.

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USGS2003

Chromium geochemistry of serpentinous sediment in the Willow core, Santa Clara County, California

A preliminary investigation of Cr geochemistry in serpentinous sediment completed for a multiple-aquifer ground-water monitoring well (Willow core of Santa Clara County, CA) determined sediment at depths >225 meters contains Cr concentrations ranging from 195 to 1155 mg/kg. Serpentinous sediment from this site is a potential source of non-anthropogenic Cr contamination. Chromium-bearing minerals such as Cr-spinel appear to be the main source of Cr in the sediment; however, Cr-bearing silicates and clay minerals are additional Cr sources. Aqueous Cr concentrations in the sediment are <4.6 mg/L; however, the valence of Cr was not identified in the solutions or in the sediment. Although there is no indication of Cr(VI) contamination derived from the serpentinous sediment, elevated Cr concentrations in the sediment, the observed ‘dissolution’ textures of the Cr-bearing minerals, the estimated redox environment, and water chemistry indicate the formation of Cr(VI) is potentially favorable.

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