USGS ScienceSearch

Geology topics

Carl E. Zipper

Publications and source records attributed to Carl E. Zipper.

7 recordsLinked to original sources

Trace elements and consequent ecological risks in mining- influenced streams of Appalachia

Appalachian coal surface mines fracture geologic materials, causing release of both major ions and trace elements to water via accelerated weathering. When elevated above natural background, trace elements in streams may produce adverse effects to biota via direct exposure from water and sediment and via dietary exposure in food sources. Other studies have found elevated water concentrations of multiple trace elements in Appalachia's mining-influenced streams. Excepting Se, trace-element concentrations in abiotic and biotic media of Appalachian mining-influenced streams are less well-known. We analyzed environmental media of headwater streams receiving alkaline waters from Appalachian coal mines for eight trace elements (Al, As, Cd, Cu, Ni, Sr, V, and Zn) and assessed potential consequent ecological risks. Streamwater, particulate media (sediment, biofilm, leaf detritus) and benthic macroinvertebrates (primary consumers, secondary consumers, crayfish) were sampled from six mining-influenced and three reference streams during low-flow conditions in two seasons. Dissolved Cu, Ni, and Sr were higher in mining-influenced streams than in reference streams; whereas Ni, Sr, and Zn in fine sediments and Ni in macroinvertebrates were also elevated relative to reference-stream levels in samples from mining-influenced streams. Seasonal ratios of mining-influenced stream concentrations to maximum concentrations in reference streams also demonstrated mining-influenced increases for several elements in multiple media. In most media, concentrations of several elements including Ni were correlated positively. All water-column dissolved concentrations were below protective levels, but fine-sediment concentrations of Ni approached or exceeded threshold-effect concentrations in several streams. Further study is warranted for several elements (Cd, Ni, and Zn in biofilms, and V in macroinvertebrates), which approached or exceeded previously established dietary-risk levels.

Virginia, West Virginia

Global review reveals how disparate study motivations, analytical designs, and focal ions limit understanding of salinization effects on freshwater animals

Global salinization of freshwaters is adversely affecting biotic communities and ecosystem processes. We reviewed six decades (1960–2020) of literature published on animal responses to increased salinities across different taxonomic and ecological contexts and identified knowledge gaps. From 585 journal articles, we characterized 5924 responses of mollusks, crustaceans, zooplankton, non-arthropod invertebrates (NAI), insects, fishes, and amphibians to salinization. Insects and fishes were the most studied taxa; Na + and Cl − were the most studied ions − . Collectively, concentrations of the ions examined typically spanned five orders of magnitude. Species' invasiveness was a key motivation for studying mollusks, crustaceans, and fishes; threats of urbanization and road salts were key motivations for studying NAI, zooplankton, and amphibians. Laboratory studies were more common than field studies for most taxa. Focal life stages in laboratory studies varied widely but juveniles and adults were represented similarly in field studies. Studies of mollusks, NAI, and crustacean focused on adults; studies of zooplankton, insects, fishes, and amphibians focused on juveniles. Organismal- and population-level responses measuring solute uptake, internal chemistry, body condition, or ion concentrations predominated laboratory studies; population- and assemblage-level responses measuring abundance, spatial distribution, or assemblage composition predominated field studies. Negative responses to salinization predominated but positive and unimodal responses were apparent across all taxa and organizational levels. Key topics for further research include a) salinity responses by more taxa, b) responses to especially toxic ions (i.e., potassium, bicarbonate, sulfate, magnesium), c) mechanisms causing positive and unimodal responses, d) traits underpinning responses, e) effects transcending organizational levels, f) ion-specific response thresholds, and g) interactions between salinity and other stressors. Our review suggests inter-taxa variation in sensitivity to salinization reflects occurrence of certain biological traits, including gill-breathing, semi-permeable skin, multiple life stages, and limited mobility. We propose a traits-based framework to predict salinization sensitivity from shared traits. This evolutionary approach could inform management aimed at preventing or reducing adverse impacts of freshwater salinization.

Science of the Total Environment

Autumn olive ( Elaeagnus umbellata ) presence and proliferation on former surface coal mines in Eastern USA

Invasive plants threaten native plant communities. Surface coal mines in the Appalachian Mountains are among the most disturbed landscapes in North America, but information about land cover characteristics of Appalachian mined lands is lacking. The invasive shrub autumn olive ( Elaeagnus umbellata ) occurs on these sites and interferes with ecosystem recovery by outcompeting native trees, thus inhibiting re-establishment of the native woody-plant community. We analyzed Landsat 8 satellite imagery to describe autumn olive’s distribution on post-mined lands in southwestern Virginia within the Appalachian coalfield. Eight images from April 2013 through January 2015 served as input data. Calibration and validation data obtained from high-resolution aerial imagery were used to develop a land cover classification model that identified areas where autumn olive was a primary component of land cover. Results indicate that autumn olive cover was sufficiently dense to enable detection on approximately 12.6 % of post-mined lands within the study area. The classified map had user’s and producer’s accuracies of 85.3 and 78.6 %, respectively, for the autumn olive coverage class. Overall accuracy was assessed in reference to an independent validation dataset at 96.8 %. Autumn olive was detected more frequently on mines disturbed prior to 2003, the last year of known plantings, than on lands disturbed by more recent mining. These results indicate that autumn olive growing on reclaimed coal mines in Virginia and elsewhere in eastern USA can be mapped using Landsat 8 Operational Land Imager imagery; and that autumn olive occurrence is a significant landscape vegetation feature on former surface coal mines in the southwestern Virginia segment of the Appalachian coalfield.

Biological Invasions

Statistical analysis of soil geochemical data to identify pathfinders associated with mineral deposits: An example from the Coles Hill uranium deposit, Virginia, USA

Soil geochemical anomalies can be used to identify pathfinders in exploration for ore deposits. In this study, compositional data analysis is used with multivariate statistical methods to analyse soil geochemical data collected from the Coles Hill uranium deposit, Virginia, USA, to identify pathfinders associated with this deposit. Elemental compositions and relationships were compared between the collected Coles Hill soil and reference soil samples extracted from a regional subset of a national-scale geochemical survey. Results show that pathfinders for the Coles Hill deposit include light rare earth elements (La and Ce), which, when normalised by their Al content, are correlated with U/Al, and elevated Th/Al values, which are not correlated with U/Al, supporting decoupling of U from Th during soil generation. These results can be used in genetic and weathering models of the Coles Hill deposit, and can also be applied to future prospecting for similar U deposits in the eastern United States, and in regions with similar geological/climatic conditions.

Virginia

Freshwater mussel population status and habitat quality in the Clinch River, Virginia and Tennessee, USA: a featured collection

The Clinch River of southwestern Virginia and northeastern Tennessee is arguably the most important river for freshwater mussel conservation in the United States. This featured collection presents investigations of mussel population status and habitat quality in the Clinch River. Analyses of historic water- and sediment-quality data suggest that water column ammonia and water column and sediment metals, including Cu and Zn, may have contributed historically to declining densities and extirpations of mussels in the river's Virginia sections. These studies also reveal increasing temporal trends for dissolved solids concentrations throughout much of the river's extent. Current mussel abundance patterns do not correspond spatially with physical habitat quality, but they do correspond with specific conductance, dissolved major ions, and water column metals, suggesting these and/or associated constituents as factors contributing to mussel declines. Mussels are sensitive to metals. Native mussels and hatchery-raised mussels held in cages in situ accumulated metals in their body tissues in river sections where mussels are declining. Organic compound and bed-sediment contaminant analyses did not reveal spatial correspondences with mussel status metrics, although potentially toxic levels were found. Collectively, these studies identify major ions and metals as water- and sediment-quality concerns for mussel conservation in the Clinch River.

Tennessee, Virginia

Reforestation to enhance Appalachian mined lands as habitat for terrestrial wildlife

Surface mining is widespread throughout the Appalachian coalfield, a region with extensive forests that are rich in wildlife. Game species for hunting, non-game wildlife species, and other organisms are important contributors to sustainable and productive ecosystems. Although small breaks in the forest canopy are important to wildlife diversity, most native Appalachian wildlife species require primarily forested habitats. This Forest Reclamation Advisory provides guidance on reforestation practices to provide high quality habitat for native forest wildlife on Appalachian coal mines.

Forest Reclamation Advisory

Increasing precision of turbidity-based suspended sediment concentration and load estimates

Turbidity is an effective tool for estimating and monitoring suspended sediments in aquatic systems. Turbidity can be measured in situ remotely and at fine temporal scales as a surrogate for suspended sediment concentration (SSC), providing opportunity for a more complete record of SSC than is possible with physical sampling approaches. However, there is variability in turbidity-based SSC estimates and in sediment loadings calculated from those estimates. This study investigated the potential to improve turbidity-based SSC, and by extension the resulting sediment loading estimates, by incorporating hydrologic variables that can be monitored remotely and continuously (typically 15-min intervals) into the SSC estimation procedure. On the Roanoke River in southwestern Virginia, hydrologic stage, turbidity, and other water-quality parameters were monitored with in situ instrumentation; suspended sediments were sampled manually during elevated turbidity events; samples were analyzed for SSC and physical properties including particle-size distribution and organic C content; and rainfall was quantified by geologic source area. The study identified physical properties of the suspended-sediment samples that contribute to SSC estimation variance and hydrologic variables that explained variability of those physical properties. Results indicated that the inclusion of any of the measured physical properties in turbidity-based SSC estimation models reduces unexplained variance. Further, the use of hydrologic variables to represent these physical properties, along with turbidity, resulted in a model, relying solely on data collected remotely and continuously, that estimated SSC with less variance than a conventional turbidity-based univariate model, allowing a more precise estimate of sediment loading. Modeling results are consistent with known mechanisms governing sediment transport in hydrologic systems.

Virginia