The distribution of silver and other metals in sediments from Massachusetts and Cape Cod Bays
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Geology topics
Publications and source records attributed to C.M. Parmenter.
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Of the 12 elements analyzed in bulk (undifferentiated) sediments collected adjacent to drilling rigs on Georges Bank, only barium was found to increase in concentration during the period when eight exploratory wells were drilled (July 1981 until September 1982). The maximum postdrilling concentration of barium (a major element in drilling mud) reached 172 ppm in bulk sediments near the drill site in block 410. This concentration is higher than the predrilling concentration at this location by a factor of 5.9. This maximum barium concentration is within the range of predrilling concentrations (28-300 ppm) measured in various sediment types from the regional stations of this program. No drilling-related changes in the concentrations of the 11 other metals have been observed in bulk sediments at any of the locations sampled in this program. We estimate that about 25 percent of the barite discharged at block 312 was present in the sediments within 6 km of the rig, 4 weeks after drilling was completed at this location (drilling period was December 8, 1981-June 27, 1982). For almost a year following completion of this well, the inventory of barite decreased rapidly, with a half-life of 0.34 year. During the next year, the inventory decreased at a slower rate (half-life of 3.4 years). The faster rate probably reflects resuspension and sediment transport of bariterich material residing at the sediment surface. Elevated barium concentrations in post-drilling sediment-trap samples from block 312 indicate that such resuspension can occur up to at least 25 m above the sea floor. As the remaining barite particles are reworked deeper into the sediments by currents and bioturbation, removal by sediment-transport processes is slower. The barite discharged during the exploratory phase of drilling is associated with the fine fraction of sediment and is widely distributed around the bank. We found evidence for barium transport to Great South Channel, 115 km west of the drilling, and to stations 2 and 3, 35 km east of the easternmost drilling site. Small increases in barium concentrations, present in the fine fraction of sediment only, were measured also at the heads of both Lydonia and Oceanographer Canyons, located 8 and 39 km, respectively, seaward of the nearest exploratory well.
From July 1981, when drilling began on Georges Bank, to May 1982, the concentration of barium, a major element in drilling mud, has increased by a factor of 3.5 in bulk sediments 200 m from the drill site in block 410 and by a factor of 2.3 at the drill site in block 312. The postdrilling barium concentrations are within the range of predriiling concentrations measured at other locations on Georges Bank. We estimate that no more than 21 percent of the barite (principal barium-bearing mineral) discharged during drilling remains within 6 km of the drill site in block 312. No drilling-related changes in the concentration of chromium or other metals have been observed in bulk sediments from blocks 410 or 312. The chemical signal of drilling mud in surficial sediments has been enhanced by separating and analyzing the sediment fraction finer than 60 ?m. Barium concentrations in the fine fraction have increased by factors of 36 and 22 at the drill sites in blocks 410 and 312, respectively. At the drill site in block 410, aluminum, chromium, copper, and mercury concentrations in this fraction temporarily increased by approximately a factor of 2 and then decreased to background. The concentrations of aluminum, barium, cadmium, chromium, copper, iron, lead, manganese, mercury, nickel, organic carbon, vanadium, and zinc in surface sediments of Georges Bank both before and after drilling are low compared to concentrations in average crustal rocks and are characteristic of unpolluted, coarse-grained sediments as found in other Continental Shelf areas.
Of the 12 elements analyzed in bulk (undifferentiated) sediments collected adjacent to drilling rigs on Georges Bank, only barium was found to increase in concentration during the drilling period (July 1981 until September 1982). The maximum postdrilling concentration of barium (a major element in drilling mud) reached 172 ppm in bulk sediments near the drill site in block 410. This concentration is a factor of 5.9 times higher than the predrilling concentration at that location. This maximum postdrilling barium concentration is within the range of predrilling concentrations {28-300 ppm} measured in various sediment types from the regional stations of this program. No drilling-related changes in the concentrations of chromium or other metals have been observed in bulk sediments at any of the locations sampled in this program to date. We estimate that between 21 percent and 31 percent of the barite (principal barium-bearing mineral} discharged at block 312 was present in the sediments within 6 km of the rig, 4 weeks after drilling was completed. The barite deposited near this well was found to decrease in concentration with a half-life of 0.4year. At this rate, the average barium concentration in sediments within 6 km of the drilling rig in block 312 is expected to be only 10 percent higher than the predrilling concentration within approximately 1.5 years. Although the inventory of the barite discharged on Georges Bank is based on only a few data points, most (approximately 69 percent) of the barite discharged by the eight exploratory wells apparently can be found in sediments west of the drilling locations. The increase in barium concentration above background can be measured in the fine fraction of sediment at a distance of 65 km to the west of block 312. Analysis of sediment-trap samples collected 25 m above the bottom in block 312 indicates that the dispersion of barmm-rich fine sediment is enhanced by resuspension from the sea floor and transport to the west with the mean current flow. Evidence exists of small accumulations of barium near the heads of Lydonia and Oceanographer Canyons. However, the increased concentrations can be defined only by analyzing the fine fraction of sediment.
A sediment trap was deployed 3 m from the bottom at a water depth of 62 m on the southern flank of Georges Bank (41°02·2′N, 67°33·5′W) from 30 September 1978 to 10 March 1979 to qualitatively determine the size of sediments resuspended from the bottom by winter storms and to determine if seasonal changes in the phytoplankton could be observed in the trapped sediment. Bulk X-ray analyses of the trapped sediment showed layers of distinctly different textures preserved in the collection vessel. The median grain size of sampled layers ranged from 2·7 to 6·5 φ (fine sand to silt), but all layers contained a pronounced mode in the 3 φ (fine sand) range. Nine layers containing relatively large amounts of sand were present. The sand content was 75% in the coarest layers and about 32% in the fine layers. The median grain size of bottom sediments at the deployment site was considerably coarser than the trap samples, although the dominant grain size was also 3 φ. Average bottom-current speeds during the deployment period were about 30 cm s −1 with a range of 10 to 50 cm s −1 . Bottom stress, computed from the observed currents and waves, suggest that 11 storms caused sufficient stress to resuspend 3 φ-sized sediments, in good agreement with the nine layers of relatively coarse sediments collected in the trap. Surface waves had to be included in the calculation of bottom stress because the bottom currents alone were insufficient to cause the resuspension of 3 φ-sized sediment. The trapped sediments contain numerous diatoms and coccoliths that are typical of late fall and winter assemblages. No clear seasonal difference in the flora was noted among sampled layers, probably due to the large influx of resuspended material and a reduced primary flux during this period. An undescribed species of Thalassiosira (G. Fryxell, personal communication), and siliceous scales of unknown systematic position were observed at all levels.
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