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Geology topics

C. W. Holmes

Publications and source records attributed to C. W. Holmes.

At least 19 recordsLinked to original sources
USGS2013

Chronology from sediment cores collected in southwestern Everglades National Park, Florida

Age model data are presented for 10 cores from the southwestern coastal mangrove zone of Everglades National Park, Florida, collected in Common Era (CE) 2004 and 2005 and used for paleoecological analysis. Carbon-14 ( 14 C), lead-210 ( 210 Pb), cesium-137 ( 137 Cs), radium-226 ( 226 Ra), and pollen biostratigraphic information is included, and age models were generated for 6 of the 10 cores. Age reversals and sediment disturbance prevented construction of age models on the remaining four cores. Four cores present a continuous record of the last 50 to 100 years, making them useful for analyzing the impacts caused by changes in water management in south Florida. These cores are Harney River 2A and Harney River 1A, Shark River 2A, and Roberts River.

Florida↗
USGS2007

Synthesis of age data and chronology for Florida Bay and Biscayne Bay cores collected for ecosystem history of South Florida’s estuaries project

210 Pb, 14 C, and pollen biostratigraphic data have been compiled and synthesized to develop age models for cores collected from Florida Bay and Biscayne Bay. These cores are being used to interpret the ecosystem history of south Florida’s estuaries by examining the physical, chemical, and biological record preserved within the cores. The beginning of the 20th century, which marks an important turning point for the natural vs. anthropogenically influenced ecosystem, has been identified based on at least two data points in ten cores. 210 Pb data alone are presented for an additional 38 cores. Age models for older sediments have been developed for seven cores. Comparison of pre-1900 and post-1900 records allows researchers to compare natural ecosystem changes to anthropogenic change. General patterns of sedimentation rates in Florida Bay and Biscayne Bay emerge from the data. Mid-bay mudbanks in both bays show more rapid rates of sedimentation, fewer signs of sediment disruption, and more internal consistency of sediments than cores located closer to shore. Nearshore cores indicate slower average rates of sedimentation, more disruption in the sedimentary sequences, and more indications of “old” carbon effects. Cores in close proximity to each other generally show very similar patterns of deposition, which indicates support for the age models.

Southern Florida↗
USGS2006

Magnesium content within the skeletal architecture of the coral Montastraea faveolata : locations of brucite precipitation and implications to fine-scale data fluctuations

Small portions of coral cores were analyzed using a high-resolution laser ablation inductively coupled plasma mass spectrometer (LA ICP-MS) to determine the geochemical signatures within and among specific skeletal structures in the large framework coral, Montastraea faveolata . Vertical transects were sampled along three parallel skeletal structures: endothecal (septal flank), corallite wall, and exothecal (costal flank) areas. The results demonstrate that trace element levels varied among the three structures. Magnesium (Mg) varied among adjacent structures and was most abundant within the exothecal portion of the skeleton. Scanning electron microscopy (SEM) revealed the presence of hexagonal crystals forming thick discs, pairs or doublets of individual crystals, and rosettes in several samples. High Mg within these crystals was confirmed with energy dispersive spectroscopy (EDS), infrared spectrometry, and LA ICP-MS. The chemical composition is consistent with the mineral brucite [Mg(OH 2 )]. These crystals are located exclusively in the exothecal area of the skeleton, are often associated with green endolithic algae, and are commonly associated with increased Mg levels found in the adjacent corallite walls. Although scattered throughout the exothecal, the brucite crystals are concentrated within green bands where levels of Mg increase substantially relative to other portions of the skeleton. The presence and locations of high-Mg crystals may explain the fine-scale fluctuations in Mg data researchers have been questioning for years.

Florida↗
USGS2005

Historical deposition and fluxes of mercury in Narraguinnep Reservoir, southwestern Colorado, USA

Narraguinnep Reservoir has been identified as containing fish with elevated Hg concentrations and has been posted with an advisory recommending against consumption of fish. There are presently no point sources of significant Hg contamination to this reservoir or its supply waters. To evaluate potential historical Hg sources and deposition of Hg to Narraguinnep Reservoir, the authors measured Hg concentrations in sediment cores collected from this reservoir. The cores were dated by the 137Cs method and these dates were further refined by relating water supply basin hydrological records with core sedimentology. Rates of historical Hg flux were calculated (ng/cm 2/a) based on the Hg concentrations in the cores, sediment bulk densities, and sedimentation rates. The flux of Hg found in Narraguinnep Reservoir increased by approximately a factor of 2 after about 1970. The 3 most likely sources of Hg to Narraguinnep Reservoir are surrounding bedrocks, upstream inactive Au-Ag mines, and several coal-fired electric power plants in the Four Corners region. Patterns of Hg flux do not support dominant Hg derivation from surrounding bedrocks or upstream mining sources. There are 14 coal-fired power plants within 320 km of Narraguinnep Reservoir that produce over 80 ?? 106 MWH of power and about 1640 kg-Hg/a are released through stack emissions, contributing significant Hg to the surrounding environment. Two of the largest power plants, located within 80 km of the reservoir, emit about 950 kg-Hg/a. Spatial and temporal patterns of Hg fluxes for sediment cores collected from Narraguinnep Reservoir suggest that the most likely source of Hg to this reservoir is from atmospheric emissions from the coal-fired electric power plants, the largest of which began operation in this region in the late-1960s and early 1970s.

Applied Geochemistry↗
USGS2004

Anthropogenic and natural variation in ridge and slough pollen assemblages

We present pollen evidence documenting the response of sawgrass ridge and slough systems of the Florida Everglades to hydrologic changes during the last 3,500 years. Sediment cores and surface samples were collected in three transects across sawgrass ridges and sloughs in Water Conservation Area 3A to determine the age of the features, long-term variability in plant community composition, stability of sawgrass ridge and slough size, and their response to 20th century changes in hydrology. Statistically significant differences in abundance of Cladium pollen in surface samples collected throughout the system allow differentiation of these communities in the sedimentary pollen record. Analysis of pollen in cores from the three transects indicates that the general distribution of ridges and sloughs has remained distinct through time. There is evidence the vegetation has responded to past global-scale climate events, such as the Medieval Warm Period, as well as the 20th century anthropogenic alterations to the natural hydrology. The ridge community is more responsive and susceptible to perturbations in hydrology than the slough community. In contrast, the slough plant community is more stable and less likely to demonstrate long-term changes after perturbations to hydrology. Regardless, these data indicate that the ridge and slough landscape is resilient to changes in hydrology and posses the potential to return to a natural state with the return of natural hydrologic conditions.

Florida↗
USGS2003

Ecosystem history of southern and central Biscayne Bay: Summary report on sediment core analyses

During the last century, the environs of Biscayne Bay have been greatly affected by anthropogenic alteration through urbanization of the Miami/Dade County area. The sources, timing, delivery, and quality of freshwater flow into the Bay have been changed by construction of a complex canal system that controls movement of water throughout south Florida. Changes in shoreline and sub-aquatic vegetation and marine organisms have been observed and changes in water delivery are believed to be the cause. Current restoration goals are attempting to restore natural flow of fresh water into Biscayne and Florida Bays and to restore the natural fauna and flora, but first we need to determine pre-alteration baseline conditions in order to establish targets and performance measures for restoration. This research is part of an ongoing study designed to address the needs of the Biscayne Bay Coastal Wetlands Project (BBCW) of the Comprehensive Everglades Restoration Plan (CERP). By establishing the natural patterns of temporal change in salinity, water quality, vegetation, and benthic fauna in Biscayne Bay and the nearby wetlands over the last 100- 500 years the USGS, in collaboration with our partners, will provide the data necessary to set realistic targets to achieve the BBCW Project goals. Six cores from three sites in Biscayne Bay were collected in April 2002 for multidisciplinary multi-proxy analyses. This report details the results of these analyses and compares the 2002 cores to cores collected in 1997. The following are our significant findings to date: The salinity of central Biscayne Bay has become increasingly marine and increasingly stable over the last 100 years. At No Name Bank, prior to approximately 1915, the inter-decadal and decadal salinity fluctuations appear to have been greater than after 1915 when salinities stabilized at that site. Continental shelf/open marine influence on the sites has increased during the 20th century. There is no indication of inter-decadal salinity extremes or periods of hypersalinity. Freshwater and mesohaline salinities have had a minor influence on No Name bank throughout the time of deposition. At Featherbed Bank, the influence is reduced to mesohaline salinities. Card Bank has experienced relatively large swings in salinity over multi-decadal and centennial timescales, compared to central Biscayne Bay, but marine influence at the site has increased over the last century. Indications of regional scale patterns have been found, especially in the shell chemistry data and the pollen assemblages. These regional patterns indicate that the changes are not site specific and may not be limited to Biscayne Bay. Sub-aquatic vegetation has undergone bay-wide patterns of change over the last 200-500 years, which includes expansion prior to 1900 and declines during the last century in central Biscayne Bay. Thalassia appears to have increased at all three core sites sometime between 1550 and 1750 AD. A decline in Thalassia appears to have occurred after 1950 at No Name Bank and slightly earlier in the 20th century at Featherbed Bank. Card Bank does not appear to have experienced any declines in vegetation on an inter-decadal scale during the 20th century. Molluscan faunal abundance and diversity have undergone significant changes in central Biscayne Bay. Indicators of increased organic-rich sediments at No Name occur between 1869 to 1888 and between the 1930’s to 1975. These changes may correlate to human activities (settlement, population growth). These findings represent a first step towards the project’s goal to reconstruct the history of Biscayne Bay and they provide us with a working model to be tested at other sites. It is clear from our findings that Biscayne Bay has been a dynamic environment over the last 500 years, with natural changes occurring in salinity and benthic habitats. However, several significant changes have occurred in the 20th century: 1) increased stabilization of marine salinities; 2) declines in seagrass in central Biscayne Bay; 3) dramatic changes in molluscan abundance and diversity in central Biscayne Bay. The question remains - how do we better differentiate natural cycles of change from anthropogenic change within these observed trends? The preliminary implications from our research are that changes in salinity and benthic habitats have occurred naturally in Biscayne Bay on inter-decadal to centennial scales, perhaps due to climatic changes, changes in sea level, bank migrations, or a combination of factors. However, further work needs to be done to determine which components of change in the 20th century are human-induced and which are natural. By examining the historical records preserved in the sediments of Biscayne Bay, we can provide restoration trust agencies with the information necessary to set realistic targets and performance measures for Biscayne Bay.

Florida↗
USGS2003

Sedimentation rates in the marshes of Sand Lake National Wildlife Refuge

Impoundments located within river systems in the Northern Great Plains are vulnerable to sediment inputs because intensive agriculture in watersheds has increased soil erosion and sediments in rivers. At the request of the U.S. Fish and Wildlife Service (FWS), we evaluated the vertical accretion of sediment in the Mud Lake impoundment of Sand Lake National Wildlife Refuge (NWR), Brown County, South Dakota. The Mud Lake impoundment was created in 1936 by constructing a low-head dam across the James River. We collected sediment cores from the Mud Lake impoundment during August 2000 for determination of vertical accretion rates. Accretion rates were estimated using cesium-13 7 and lead-210 isotopic dating techniques to estimate sediment accretion over the past 100 years. Accretion rates were greatest near the dam (1.3 cm yr-1) with less accretion (0.2 cm yr-1) occurring in the upper reaches of Mud Lake. As expected, accretion was highest near the dam where water velocities and greater water depth facilitates sediment deposition. Higher rates of sedimentation (accretion> 2.0 cm year-1) occurred during the 1990s when river flows were especially high. Since 1959, sediment accretion has reduced maximum pool depth of Mud Lake near the dam by 55 cm. Assuming that sediment accretion rates remain the same in the future, we project Mud Lake will have a maximum pool depth of 77 and 51 cm by 2020 and 2040, respectively. Over this same time frame, water depths in the upper reaches of Mud Lake would be reduced to< 2 cm. Projected future loss of water depth will severely limit the ability of managers to manipulate pool levels in Mud Lake to cycle vegetation and create interspersion of cover and water to meet current wildlife habitat management objectives. As predicted for major dams constructed on rivers throughout the world, Mud Lake will have a finite life span. Our data suggests that the functional life span of Mud Lake since construction will be < 100 years. We anticipate that over the next 20 years, sediments entering Mud Lake will reduce water depths to the point that current wildlife management objectives cannot be achieved through customary water-level manipulations. Sedimentation impacts are not unique to the Sand Lake NWR. It is widely accepted that impoundments trap sediments and shallow impoundments, such as those managed by the FWS, are especially vulnerable. Given the ecological impacts associated with loss of water depths, we recommend that managers begin evaluating the long-term wildlife management goals for the refuge relative to associated costs and feasibility of options available to enhance and maximize the life span of existing impoundments, including upper watershed management.

Report↗
USGS2002

A comparison of factors controlling sedimentation rates and wetland loss in fluvial-deltaic systems, Texas Gulf coast

Submergence of coastal marshes in areas where rates of relative sea-level rise exceed rates of marsh sedimentation, or vertical accretion, is a global problem that requires detailed examination of the principal processes that establish, maintain, and degrade these biologically productive environments. Using a simple 210Pb-dating model, we measured sedimentation rates in cores from the Trinity, Lavaca-Navidad, and Nueces bayhead fluvial-deltaic systems in Texas where more than 2000 ha of wetlands have been lost since the 1950s. Long-term average rates of fluvial-deltaic aggradation decrease southwestward from 0.514 ?? 0.008 cm year -1 in the Trinity, 0.328 ?? 0.022 cm year -1 in the Lavaca-Navidad, to 0.262 ?? 0.034 cm year -1 in the Nucces. The relative magnitudes of sedimentation and wetland loss correlate with several parameters that define the differing fluvial-deltaic settings, including size of coastal drainage basin, average annual rainfall, suspended sediment load, thickness of Holocene mud in the valley fill, and rates of relative sea-level rise. There is some evidence that upstream reservoirs have reduced wetland sedimentation rates, which are now about one-half the local rates of relative sea-level rise. The extant conditions indicate that fluvial-deltaic marshes in these valleys will continue to be lost as a result of submergence and erosion. ?? 2002 Elsevier Science B.V. All rights reserved.

Geomorphology↗
USGS2000

Historical trends in Chesapeake Bay dissolved oxygen based on benthic foraminifera from sediment cores

Environmentally sensitive benthic foraminifera (protists) from Chesapeake Bay were used as bioindicators to estimate the timing and degree of changes in dissolved oxygen (DO) over the past five centuries. Living foraminifers from 19 surface samples and fossil assemblages from 11 sediment cores dated by 210 Pb, 137 Cs, 14 C, and pollen stratigraphy were analyzed from the tidal portions of the Patuxent, Potomac, and Choptank Rivers and the main channel of the Chesapeake Bay. Ammonia parkinsoniana , a facultative anaerobe tolerant of periodic anoxic conditions, comprises an average of 74% of modern Chesapeake foraminiferal assemblages (DO-0.47 and 1.72 ml l −1 ) compared to 0% to 15% of assemblages collected in the 1960s. Paleoecological analyses show that A. parkinsoniana was absent prior to the late 17th century, increased to 10–25% relative frequency between approximately 1670–1720 and 1810–1900, and became the dominant (60–90%) benthic formaniferal species in channel environments beginning in the early 1970s. Since the 1970s, deformed tests of A. parkinsoniana occur in all cores (10–20% of Ammonia ), suggesting unprecedented stressful benthic conditions. These cores indicate that prior to the late 17th century, there was limited oxygen depletion. During the past 200 years, decadal scale variability in oxygen depletion has occurred, as dysoxic (DO=0.1–1.0 ml l −1 ), perhaps short-term anoxic (DO<0.1 ml l −1 ) conditions developed. The most extensive (spatially and temporally) anoxic conditions were reached during the 1970s. Over decadal timescales, DO variability seems to be linked closely to climatological factors influencing river discharge; the unprecedented anoxia since the early 1970s is attributed mainly to high freshwater flow and to an increase in nutrient concentrations from the watershed.

Maryland, Virginia↗
USGS2000

A paleoecologic reconstruction of the history of Featherbed Bank, Biscayne National Park, Biscayne Bay, Florida

Using multiple-proxy biological indicators, a paleoecological history of the past 550 years of Featherbed Bank, Biscayne Bay, has been reconstructed from a short (2.26 m) sediment core. Paleoecological changes in ostracode, mollusc, and foraminifer assemblages show that core SEI297-FB-1 can be divided into three distinctly different zones, which together provide evidence for distinct changes in historical environmental conditions at Featherbed Bank. Assemblages from fossil biotic communities within zone 1, representing approximately 1440 to 1550 AD, are characterized by open-marine biota with relatively limited numbers of epiphytic biota. Molluscan faunal indicators suggest the sediment was capable of supporting infaunal organisms and that faunal richness was relatively limited during this time period. A change in the biotic community occurred around 1550 AD and continued until the late 1800's distinguishing zone 2. Fossil biotic indicators from zone 2 show a strong dominance of epiphytic organisms within all of the biotic communities examined. Foraminifers, molluscs, and ostracodes capable of subsisting in salinities slightly lower than normal marine begin to flourish in this time period, and there is a marked decline in infaunal molluscs. Zone 2 assemblages are replaced around 1900 AD by increased numbers of organisms that typify open-marine conditions and a return to decreased epiphytic assemblages, similar to zone 1. Zone 3 assemblages, however, show some strong dissimilarities from zone 1, including limited infaunal molluscs, increased abundances of the ostracode Malzella floridana, and a significant increase in molluscan faunal richness.

Florida↗
USGS1999

Reconnaissance of chemical and physical characteristics of selected bottom sediments of the Caloosahatchee River and estuary, tributaries, and contiguous bays, Lee County, Florida, July 20-30, 1998

This report summarizes a reconnaissance study, conducted July 20-30, 1998, of chemical and physical characteristics of recently deposited bottom sediments in the Caloosahatchee River and Estuary. Recently deposited sediments were identified using an isotopic chronometer, Beryllium-7 (7Be), a short-lived radioisotope. Fifty-nine sites were sampled in an area that encompasses the Caloosahatchee River (River) about three miles upstream from the Franklin Lock (S-79), the entire tidally affected length of the river (estuary), and the contiguous water bodies of Matlacha Pass, San Carlos Bay, Estero Bay, Tarpon Bay, and Pine Island Sound in Lee County, Florida. Bottom sediments were sampled for 7Be at 59 sites. From the results of the 7Be analysis, 30 sites were selected for physical and chemical analysis. Sediments were analyzed for particle size, total organic carbon (TOC), trace elements, and toxic organic compounds, using semiquantitative methods for trace elements and organic compounds. The semiquantitative scans of trace elements indicated that cadmium, copper, lead, and zinc concentrations, when normalized to aluminum, were above the natural background range at 24 of 30 sites. Particle size and TOC were used to characterize sediment deposition patterns and organic content. Pesticides, polychlorinated biphenyls (PCBs), and carcinogenic polycyclic aromatic hydrocarbons (CaPAHs) were determined at 30 sites using immunoassay analysis. The semiquantitative immunoassay analyses of toxic organic compounds indicated that all of the samples contained DDT, cyclodienes as chlordane (pesticides), and CaPAHs. PCBs were not detected. Based on analyses of the 30 sites, sediments at 10 of these sites were analyzed for selected trace elements and toxic organic compounds, including pesticides, PCBs, and PAHs, using quantitative laboratory procedures. No arsenic or cadmium was detected. Zinc was detected at two sites with concentrations greater than the lower limit of the range of sediment contaminant concentrations that are usually or always associated with adverse effects (Florida Department of Environmental Protection's Sediment Quality Assessment Guidelines). Organochlorine pesticides were detected at four sites at concentrations below the reporting limits; there were no organophosphorus pesticides or PCBs detected. PAHs were detected at eight sites; however, only four sites had concentrations above the reporting limit.

Florida↗
USGS1999

Determination of pre-mining geochemical conditions and paleoecology in the Animas River Watershed, Colorado

Determination of the pre-mining geochemical baseline in bed sediments and the paleoecology in a watershed impacted by historical mining activity is of utmost importance in establishing watershed restoration goals. We have approached this problem in the Animas River watershed using geomorphologic mapping methods to identify old pre-mining sediments. A systematic evaluation of possible sites resulted in collection of a large number of samples of pre-mining sediments, overbank sediments, and fluvial tailings deposits from more than 50 sites throughout the watershed. Chemical analysis of individual stratigraphic layers has resulted in a chemical stratigraphy that can be tied to the historical record through geochronological and dendochronological studies at these sites. Preliminary analysis of geochemical data from more than 500 samples from this study, when coupled with both the historical and geochronological record, clearly show that there has been a major impact by historical mining activities on the geochemical record preserved in these fluvial bed sediments. Historical mining activity has resulted in a substantial increase in metals in the very fine sand to clay sized component of the bed sediment of the upper Animas River, and Cement and Mineral Creeks. Enrichment factors for metals in modern bed sediments, relative to the pre-mining sediments, range from a factor of 2 to 6 for arsenic, 4 to more than 10 for cadmium, 2 to more than 10 for lead, 2 to 5 for silver, and 2 to more than 15 for zinc. However, the pre-mining bed sediment geochemical baseline is high relative to crustal abundance levels of many orerelated metals and the watershed would readily be identified as a highly mineralized area suitable for mineral exploration if it had not been disturbed by historical mining activity. We infer from these data that the water chemistry in the streams was less acidic prior to historical mining activity in the watershed. Paleoentologic evidence does not indicate a healthy aquatic habitat in any of the stream reaches investigated above the confluence of the Animas River with Mineral Creek (fig. 1) prior to the impact of historical mining activity. The absence of paleoentologic remains is interpreted to reflect the poor preservation regime of the bed sediment materials sampled. The fluvial sediments sampled in this study represent higher energy environments than are conducive to the preservation of most aquatic organisms including fish remains. We interpret the sedimentological data to indicate that there has been substantial loss of riparian habitat in the upper Animas River above Howardsville as a result of historical mining activity.

Colorado↗
USGS1999

Geochemistry of Florida Bay sediments: Nutrient history at five sites in eastern and central Florida Bay

Recent seagrass dieoff and massive microalgal blooms have focused attention on the health of the Florida Bay ecosystem. Changes in nutrient input and the nutrient dynamics of Florida Bay are hypothesized to be linked to these problems, but crucial baseline information is still lacking. Efforts to restore Florida Bay to its natural condition will require information on the nutrient history of the bay. The purpose of this study was to examine distributions of organic C, total N, and total P in carbonate sediments from sites of continuous and known sedimentation rate (210Pb and 137Cs dated), in eastern and central Florida Bay. These sediments provide a record of historical changes in the C, N, and P load to the eastern and central bay. Analyses were conducted on sediments from cores collected at five sites, and on buried seagrass fragments at two sites. At three of the sites, sediments from seagrass-covered and adjacent barren areas were examined to determine differences in sedimentary geochemistry. Stable isotope analyses (??13C and ??15N) of sedimentary organic C and total N and of buried seagrass fragments were also carried out at two sites to examine possible changes in nutrient sources to the estuary. Results were consistent with recent increases in N and P in eastern Florida Bay, beginning in the early to mid 1980's. The timing of the increase in nutrient load observed in the sediment data directly preceded the first observations of massive microalgal blooms and seagrass dieoff in Florida Bay in 1987. The observed nutrification was greater for P than N, and was most pronounced at the most northeasterly site sampled (Pass Key). Isotope data (??15N) suggested that an increase in algal production accompanied the increase in N load at the Pass Key site. Along record of organic C, total N, and total P distributions from Whipray Basin in central Florida Bay showed historical peaks (mid 1700's and late 1800's) in organic C and total N, but not total P; these enrichments were nearly equivalent to recent inputs to the estuary. Barren areas were observed to have generally lower concentrations of organic C, total N, and total P in near surface sediments compared to seagrass-covered areas, but had generally similar concentrations in deeper sediments. This suggested that barren areas adjacent to seagrass-covered sites were places where relict sediment was physically transported and covered seagrass beds. This dataset provides an historical view of changes in nutrient inputs to Florida Bay, and baseline information needed for nutrient modeling of the bay.

Journal of Coastal Research↗
USGS1998

Speciation and isotopic composition of sedimentary sulfur in the Everglades, Florida, USA

We have studied the sulfur speciation and isotopic composition of two peat cores from Water Conservation Area 2A (WCA 2A) in the Florida Everglades. Core site E1 is affected by agricultural runoff from the Hillsboro Canal which drains the Everglades Agricultural Area; Core site U3 is distant from the canal and relatively unaffected by agricultural runoff. Depth profiles of the total sulfur content of both cores show fairly constant levels (??0.7 wt.%) below about 25-30 cm depth in Core E1 and below 40-45 cm in Core U3. Above these depths, total sulfur increases to as much as 1.52 wt.% in Core E1 and 1.74 wt.% in Core U3, suggesting that more sulfur has entered the sediments and/or that more sulfur is being retained in recent times at both sampling sites. These changes in total sulfur content with depth in Core E1 correlate with changes in total phosphorus that have been observed in other studies at core sites near the Hillsboro Canal. This correlation of total sulfur with phosphorus with depth is not seen in Core U3 located away from the canal, possibly because phosphorus is more effectively retained than sulfur in the organic sediment near the canal. Organic-sulfur (OS) concentrations are at least twice as high as the dusulfide-sulfur (DS) concentrations in the upper parts of both cores suggesting that iron is presently limiting the amount of dusulfide minerals formed in these sediments. The degree of pyritization (DOP) in the upper parts of the cores suggest that sulfide mineralization is limited by the availability of highly reactive iron during the earliest stages of diagenesis. Positive ??34S values for reduced sulfur forms in both cores indicate a relatively restricted sulfate reservoir, consistent with nearly complete reduction of the sulfate available in the sediment at any given time. Differences between the two core appear in the ??34S values for the near-surface sediments. The DS ??34S values in the upper 10.0 cm of sediment are more posotive at site E1, with a mean ??34S value of +12.9???, than at site U3, with a mean ??34S value of +2.9???. These reuslts may indicate that increased rates of organic deposition due to nutrient loading near the canal have increased the rate of sulfate reduction at the E1 site in recent times. Acid-volatile-sulfide (AVS) concentrations are lower than DS and OS concentrations by at least a factor of 10. Increasing ??34S values for AVS with increasing depth in both cores suggests ongoing reduction of a limited porewater sulfate reservoir after deposition. The disulfide and organic-sulfur ??34S values diverge from the ??34S values for AVS with depth, suggesting that most of the transformation of AVS into disulfide minerals or incorporation of sulfur into orgnaic matter occurs in the near-surface sediments. A comparison of organic-sulfur ??34S values in the dominant flora at the U3 site (sawgrass leaves and periphyton) with organic-sulfur ??34S values at the top of the U3 core indicates that there was early incorporation of an isotopically light sulfide species into the orgnaic matter.

Chemical Geology↗
USGS1998

Preliminary paleontologic report on core 37 from Pass Key, Everglades National Park, Florida Bay

Sediments from Pass Key core 37, in eastern Florida Bay (N 25.1478, W 80.5745) record a history of rapid sedimentation during this century. The lowest portion of the core contains benthic fauna indicative of relatively low salinities and sparse seagrass coverage. This period is followed by an increase in salinity and seagrass. In the middle portion of the core, a slight decrease in salinity and an increase in seagrass occur. These shifts in the benthic fauna correspond to a period when the terrestrial flora change, and an increase in dinocyst absolute abundance occurs, indicating changes in factors affecting the entire South Florida ecosystem. These changes may represent a period of increased terrestrial flushing, due to rainfall, water management practices or a combination of both. The benthic faunas in the upper portion of the core indicate an increase in salinity and seagrass density. This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards or with the North American Stratigraphic Code. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Florida↗
USGS1998

Environmental impacts on the southern Florida coastal waters: A history of change in Florida Bay

Analyses of four cores located in the northern transitional, eastern, and central portions of Florida Bay reveal historical patterns of change in salinity and seagrass distribution. Salinity and the distribution of seagrass beds are two critical issues for the restoration of Florida Bay. The distribution of benthic fauna in Bob Allen 6A and Russell Bank 19B cores illustrates changes in environmental parameters prior to 1900. Natural fluctuations occur in salinity, but the amplitude of those fluctuations was limited to a 15–20% shift about the mean. Subtle changes occur in the benthic fauna around 1910, but beginning around 1940, the pattern of salinity fluctuation departs substantially from the pre-1900 pattern. Post-1940, the salinity oscillates 40–60% about the mean. This pattern is seen in all indicators measured. Around 1970, a significant but short term decline occurred in salinity. The Taylor Creek T24 core from the northern transitional zone reflects changes in freshwater flow that have occurred during this century. The upper portion of the core records a significant increase in salinity, with a slight decrease occurring in recent years. The Pass Key 37 core represents an area of very high sedimentation rates; an increase in salinity occurs in the upper portion of the core. Natural fluctuations in seagrass distribution are inferred from the shifts in relative abundance of epiphytal species preserved in the cores. All four cores show an increase in epiphytes and therefore in seagrass coverage during this century. An increase also occurs in epiphytal species that can dwell on either Thalassia or macro-algal mats associated with Thalassia beds. These data suggest an increase in algal-mats has occurred during this century. The Bob Allen 6A core records an extensive period during the 1800's of little to no vegetative cover of the substrate based on the near absence of epiphytic species in that segment of the core. Following this period, the epiphytal species increase rapidly in abundance, implying that vegetation may have the ability to disseminate rapidly.

Florida↗