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C. T. Pierson

Publications and source records attributed to C. T. Pierson.

At least 19 recordsLinked to original sources
USGS1993

An objective replacement method for censored geochemical data

Geochemical data are commonly censored, that is, concentrations for some samples are reported as "less than" or "greater than" some value. Censored data hampers statistical analysis because certain computational techniques used in statistical analysis require a complete set of uncensored data. We show that the simple substitution method for creating an uncensored dataset, e.g., replacement by 3/4 times the detection limit, has serious flaws, and we present an objective method to determine the replacement value. Our basic premise is that the replacement value should equal the mean of the actual values represented by the qualified data. We adapt the maximum likelihood approach (Cohen, 1961) to estimate this mean. This method reproduces the mean and skewness as well or better than a simple substitution method using 3/4 of the lower detection limit or 3/4 of the upper detection limit. For a small proportion of "less than" substitutions, a simple-substitution replacement factor of 0.55 is preferable to 3/4; for a small proportion of "greater than" substitutions, a simple-substitution replacement factor of 1.7 is preferable to 4/3, provided the resulting replacement value does not exceed 100%. For more than 10% replacement, a mean empirical factor may be used. However, empirically determined simple-substitution replacement factors usually vary among different data sets and are less reliable with more replacements. Therefore, a maximum likelihood method is superior in general. Theoretical and empirical analyses show that true replacement factors for "less thans" decrease in magnitude with more replacements and larger standard deviation; those for "greater thans" increase in magnitude with more replacements and larger standard deviation. In contrast to any simple substitution method, the maximum likelihood method reproduces these variations. Using the maximum likelihood method for replacing "less thans" in our sample data set, correlation coefficients were reasonably accurately estimated in 90% of the cases for as much as 40% replacement and in 60% of the cases for 80% replacement. These results suggest that censored data can be utilized more than is commonly realized. ?? 1993 International Association for Mathematical Geology.

Mathematical Geology↗
USGS1988

The aqueous geochemistry of uranium in a drainage containing uraniferous organic-rich sediments, Lake Tahoe area, Nevada, USA

Anomalously uraniferous waters occur in a small (4.2 km2) drainage in the west-central Carson Range, Nevada, on the eastern side of Lake Tahoe. The waters transport uranium from local U-rich soils and bedrock to organic-rich valley-fill sediments where it is concentrated, but weakly bound. The dissolved U and the U that is potentially available from coexisting sediments pose a threat to the quality of drinking water that is taken from the drainage. The U concentration in samples of 6 stream, 11 spring and 7 near-surface waters ranged from <1 to 177 ??g l-1 with an average value of 17 ?? 14 ??g l-1 for stream and spring waters. This value significantly exceeds a reported regional average value of ~5 ??g l-1, and is comparable to proposed maximum contaminant levels of U in drinking water. Calculations that utilize chemical compositions of the waters and thermodynamic data indicate that uranyl-carbonate and uranyl-phosphate complexes are the major inorganic species of dissolved U. In addition, dialysis experiments suggest an association of at least some dissolved U with macromolecular organic matter, particularly in near-surface waters that are in contact with organic-rich sediments. Calculations of the saturation index for uranous and uranyl-bearing minerals indicate that all of the waters are undersaturated with uranium minerals as long as ambient Eh is oxidizing (i.e. > 0.1 V). Possible precipitation of U(IV) minerals is predicted under the more reducing conditions that are particularly likely in near-surface waters, but the inhibitory effects of sluggish kinetics or organic complexing are not considered. These combined results suggest that a process such as adsorption or ion exchange, rather than mineral saturation, is the most probable mechanism for uranium fixation in the sediments. -Authors

Uranium↗
USGS1987

The geochemistry of water near a surficial organic-rich uranium deposit, northeastern Washington State, U.S.A.

The chemistry of three stream, three spring and six near-surface waters in the vicinity of a Holocene organic-rich uranium deposit is described, with particular emphasis on the chemistry of U. Results characterize the solution behavior of uranium as U-bearing water interacts with relatively undecomposed, surficial organic matter. Of the measured major and trace chemical species, only U is consistently highly enriched (17-318 ppb) relative to reported values for regional waters, or to literature values for waters in largely granitic terrains. R-mode factor analysis of the chemical data suggests that most U is present in a soluble form, but that some U is also associated with fine suspended particulates of clay, organic matter, or hydrous oxides. Calculations that apply thermodynamic data to predict U speciation in solution indicate the relative importance of uranyl carbonate and uranyl phosphate complexes. Analysis of more finely filtered samples (0.05 ??m vs. 0.45 ??m), and direct radiographic observations using fission-track detectors suspended in the waters indicate the presence of some uraniferous particulate matter. Application of existing thermodynamic data for uranous- and uranyl-bearing minerals indicates that all waters are undersaturated with U minerals as long as ambient Eh ??? +0.1 v. If coexisting surface and near-surface waters are sufficiently oxidizing, initial fixation of U in the deposit should be by a mechanism of adsorption. Alternatively, more reducing conditions may prevail in deeper pore waters of the organic-rich host sediments, perhaps leading to direct precipitation or diagenetic formation of U4+ minerals. A 234U 238U alpha activity ratio of 1.08 ?? 0.02 in a spring issuing from a hillslope above the deposit suggests a relatively soluble source of U. In contrast, higher activity ratios of 234U 238U (??? 1.3) in waters in contact with the uraniferous valley-fill sediments suggest differences in the nature of interaction between groundwater and the local, U-rich source rocks. ?? 1987.

Chemical Geology↗
USGS1983

Statistical treatment and preliminary interpretation of chemical data from a uranium deposit in the northeast part of the Church Rock area, Gallup mining district, New Mexico

Statistical treatment of analytical data from 106 samples of uranium-mineralized and unmineralized or weakly mineralized rocks of the Morrison Formation from the northeastern part of the Church Rock area of the Grants uranium region indicates that along with uranium, the deposits in the northeast Church Rock area are enriched in barium, sulfur, sodium, vanadium and equivalent uranium. Selenium and molybdenum are sporadically enriched in the deposits and calcium, manganese, strontium, and yttrium are depleted. Unlike the primary deposits of the San Juan Basin, the deposits in the northeast part of the Church Rock area contain little organic carbon and several elements that are characteristically enriched in the primary deposits are not enriched or are enriched to a much lesser degree in the Church Rock deposits. The suite of elements associated with the deposits in the northeast part of the Church Rock area is also different from the suite of elements associated with the redistributed deposits in the Ambrosia Lake district. This suggests that the genesis of the Church Rock deposits is different, at least in part, from the genesis of the primary deposits of the San Juan Basin or the redistributed deposits at Ambrosia Lake.

Open-File Report↗
USGS1983

Comparison of the chemical characteristics of the uranium deposits of the Morrison Formation in the Grants uranium region, New Mexico

Statistical treatment of the chemical data of samples from the northeast Church Rock area, Ruby deposit, Mariano Lake deposit, and the Ambrosia Lake district indicates that primary ore-forming processes concentrated copper, iron, magnesium, manganese, molybdenum, selenium, vanadium, yttrium, arsenic, organic carbon, and sulfur, along with uranium. A barium halo that is associated with all of these deposits formed from secondary processes. Calcium and strontium were also enriched in the ores by secondary processes. Comparison of the chemical characteristics of the redistributed deposits in the Church Rock district to the primary deposits in the Grants uranium region indicates that calcium, manganese, strontium, yttrium, copper, iron, magnesium, molybdenum, lead, selenium, and vanadium are separated from uranium during redistribution of the deposits in the Church Rock area. Comparisons of the chemical characteristics of the Church Rock deposits and the secondary deposits at Ambrosia Lake suggest some differences in the processes that were involved in the genesis of the redistributed deposits in these two areas.

Open-File Report↗
USGS1977

A summary of the geology and mineral resources of the Paris Plateau-House Rock Valley area, Coconino County, Arizona

The Paria Plateau-House Rock Valley area of north-central Arizona is located on the southwestern edge Of the Colorado Plateau physiographic province in an area underlain by about 5,000 meters of fossiliferous marine and continental sedimentary rock ranging in age from Precambrian through Quaternary. The area, which lies north of the Grand and Marble Canyons, is bounded on the west by the East Kaibab monocline and on the east by the Echo monocline. The Paria Plateau, bounded on the South by the scenic Vermilion Cliffs, is composed of continental red-beds of Triassic and Jurassic age, which dip gently northward at 2? to ? away from the north end of the Marble Platform upon which the Paria Plateau sits.

Open-File Report↗
USGS1967

Mineral investigations in northeastern Thailand

Fifty-eight mineral prospects of base metals (copper, lead, zinc), iron, manganese, gold, limestone (cement grade), barite, gypsum, and salt were investigated by geological, geophysical, and geochemical surveys, and by pitting, exploratory mining, and diamond drilling from January 1963 to May 1966. Fifty-six of the prospects are in the Loei-Chiengkarn area of northeast Thailand where regional geological, aeromagnetic, and geochemical studies were also performed; the other two prospects are on the Khorat Plateau. The base-metal prospects are in volcanic or carbonate rocks. Four prospects have been tested by diamond drilling; disseminated copper deposits were found at two prospects and local lead-zinc mineralization at the other two.The two copper deposits have estimated proven and probable reserves of 16million tons containing about 1 percent copper, and possible reserves of 62 million tons. The iron prospects are mostly metasomatic, at contacts of granodiorite with sedimentary and volcanic rocks. Four of the iron prospects were tested by diamond drilling; proven, probable, and possible reserves of about 27million tons containing 52 percent iron were developed predominantly in two deposits. Twelve manganese and two gold prospects were investigated, but all are small or low grade. Nonmetallic deposits of barite, gypsum, and limestone (cement grade) were examined in the Loei-Chiengkarn area, and salt was studied at Chaiyaphum. Reserves of approximately 5.5 million tons of barite, half a million tons of gypsum, 12 million tons of limestone (cement grade), and 2,000 million tons of salt were estimated to be present. Economic development of these deposits must await recommended economic feasibility studies and additional geological work, including diamond drilling.

Open-File Report↗
USGS1953

Uranium in the metal-mining districts of Colorado

Many varieties of abnormally radioactive rocks and ores have been found in Colorado as a result of more than eight years of geologic studies by the U. S. Geological Survey, but only a small proportion of these contain uranium in sufficient quantities to be of possible commercial interest.

Colorado↗
USGS1953

Occurrences of uranium-bearing minerals in the St. Kevin District, Lake County, Colorado

Two hundred and seventy-one prospect pits, mine dumps, or mine workings within the Sugar Loaf-St. Kevin mining districts and vicinity were tested for radioactivity by the U.S. Geological Survey in 1951 during six weeks of investigation on behalf of the Division of Raw Materials of the U.S. Atomic Energy Commission. One hundred and twenty-two weak radioactivity anomalies were found in the St. Kevin district and vicinity, and eight slight anomalies were noted in the Sugar Loaf district, which adjoins the St. Kevin district on the south. Most of the radioactivity anomalies were found in igneous and metamorphic rocks of pre-Cambrian age, but some were found in metalliferous veins of Tertiary age. Samples of altered granite or schist contain as much as 0.065 percent uranium, probably in the form of secondary uranium minerals. Samples of vein material contain as much as 0.013 percent uranium, also probably in the form of secondary uranium minerals. At only a few localities has the identity of the uranium-bearing minerals been determined. Torbernite, associated with turquoise, malachite, and chrysocolla, occurs as disseminations and fracture coatings in altered granite at the Josie May turquoise mine; metatobernite is disseminated in granite at the Turquoise Chief mine. Commonly the limonite-stained fractures in the altered granite and schist are radioactive; metatorbernite has been identified in limonite stain at one locality. A uranium-variety of florencite, a hydrous cerium aluminum phosphate, is disseminated in the granite on the dump of a mine just west of the St. Kevin district, and autunite (?) is disseminated in fine-grained, highly silicified rock in the northeastern part of the St. Kevin district. None of the uranium occurrences are of commercial importance. They are for the most part in non-glaciated terrane, which has been subjected to a very long period of weathering. Thus, chemical leaching within the zone of weathering may have greatly reduced the uranium content of material near the surface, and occurrences of even small quantities of secondary uranium minerals might be related to stronger, primary concentrations at depth.

Colorado↗