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C. E. Hedge

Publications and source records attributed to C. E. Hedge.

At least 19 recordsLinked to original sources
USGS2012

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth↗
USGS1991

Tritium concentrations in the active Pu'u O'o crater, Kilauea volcano, Hawaii: implications for cold fusion in the Earth's interior

The assertion that deuterium-deuterium fusion may occur at low temperature suggests a potential new source of geothermal heat. If a cold-fusion-like process occurs within the Earth, then a test for its existence would be a search for anomalous tritium in volcanic emissions. The Pu'u O'o crater is the first point at which large amounts of water are degassed from the magma that feeds the Kilauea system. The magma is probably not contaminated by meteoric-source ground water prior to degassing at Pu'u O'o, although mixing of meteoric and magmatic H2O occurs within the crater. Tritium contents of samples from within the crater are lower than in samples taken simultaneously from the nearby upwind crater rim. These results provide no evidence in support of a cold-fusion-like process in the Earth's interior. ?? 1991.

Physics of the Earth and Planetary Interiors↗
USGS1986

Cambrian nepheline syenite complex at Jabal Sawda, Midyan region, Kingdom of Saudi Arabia

The only nepheline syenite complex presently known in the Arabian Shield is at Jabal Sawda, about 30 km S of Haql in the extreme NW of Saudi Arabia. It is a post-tectonic, composite intrusion with a crudely concentric structure. A core of leuco-nepheline syenite, a partial ring of mela-nepheline syenite, and an almost complete outer ring of alkali-feldspar syenite are the main rock units. Several mega-inclusions of porphyritic nepheline syenite, nepheline monzosyenite, malignite and ijolite are present in the leuco-nepheline syenite. The chemical composition is notable for very high values of Al 2 O 3 , Na 2 O, Ba, La, Nb, Sr and Zr. U Pb isotope dating indicates an emplacement age of 553 ± 4 Ma, one of an increasing number of reliable Cambrian isotope dates in the northern Red Sea region.

Journal of African Earth Sciences↗
USGS1985

Isotopic studies of the late Archean plutonic rocks of the Wind River Range, Wyoming

Isotopic studies of the Rb-Sr and U-Th-Pb systems in whole-rock samples and the U-Pb systematics for zircons document the existence of two late Arehean intrusive events in the Wind River Range. All of the systems examined indicate an age of ∼2,630 ± 20 m.y. for the Louis Lake batholith. Apparent ages for the Bears Ears pluton range from 2,504 ± 40 m.y. to 2,575 ± 50 m.y. The scatter in apparent ages for the Bears Ears pluton does not appear to be primarily the result of disturbance by postintrusive events, but it may be explained by an isotopically inhomogenous magma at the time of intrusion. Data for a few samples indicate that the Wind River Range was affected locally by a postmagmatic hydrothermal event that was approximately Tertiary in age. This event lowered δ 18 O values and disturbed parent-daughter relationships in most of the isotopic systems investigated, but it was recent enough that there is no demonstrable effect in the Pb-Pb system. The Bears Ears pluton has some chemical and petrologic features that are similar to those reported for the granites in the Granite Mountains to the east. These granites are spatially associated with low-temperature uranium deposits of Tertiary age and have been shown to have lost large amounts of uranium during the early to middle Tertiary. U-Pb systematics indicate, however, that the low to moderate uranium contents and highly variable Th/U values noted for the Bears Ears pluton are best interpreted as being primary features. If uranium was lost after magma generation, the loss most likely occurred at the time of intrusion. Such a loss could account for uraniferous Precambrian pegmatites southwest of the main part of the Range. The two intrusive units apparently were derived from different protoliths that were formed during early to middle Archean. Initial isotopic ratios and petrochemistry for the Louis Lake batholith are consistent with an early Archean trondhjemitic to tonalitic source. The protolith for the Bears Ears pluton must have been more evolved and somewhat younger. Inconsistencies as to the degree of evolution of this protolith, as inferred from isotopic and trace-element data, suggest that the protolith may have been subjected to high-grade meta-morphism that caused loss of Rb and U prior to generation of the magma.

Wyoming↗
USGS1982

Evolution of continental crust and mantle heterogeneity: Evidence from Hf isotopes

We present initial 176Hf/177 Hf ratios for many samples of continental crust 3.7-0.3 Gy old. Results are based chiefly on zircons (1% Hf) and whole rocks: zircons are shown to be reliable carriers of essentially the initial Hf itself when properly chosen on the basis of U-Pb studies. Pre-3.0 Gy gneisses were apparently derived from an unfractionated mantle, but both depleted and undepleted mantle are evident as magma sources from 2.9 Gy to present. This mantle was sampled mainly from major crustal growth episodes 2.8, 1.8 and 0.7 Gy ago, all of which show gross heterogeneity of 176Hf/177Hf in magma sources from ??Hf=0 to +14, or about 60% of the variability of the present mantle. The approximate ??Hf=2??Nd relationship in ancient and modern igneous rocks shows that 176Lu/177Hf fractionates in general twice as much as 147Sm/144Nd in mantle melting processes. This allows an estimation of the relative value of the unknown bulk solid/liquid distribution coefficient for Hf. DLu/DHf=??? 2.3 holds for most mantle source regions. For garnet to be an important residual mantle phase, it must hold Hf strongly in order to preserve Hf-Nd isotopic relationships. The ancient Hf initials are consistent with only a small proportion of recycled older cratons in new continental crust, and with quasi-continuous, episodic growth of the continental crust with time. However, recycling of crust less than 150 My old cannot realistically be detected using Hf initials. The mantle shows clearly the general positive ??Hf resulting from a residual geochemical state at least back to 2.9 Gy ago, and seems to have repeatedly possessed a similar degree of heterogeneity, rather than a continuously-developing depletion. This is consistent with a complex dynamic disequilibrium model for the creation, maintenance and destruction of heterogeneity in the mantle. ?? 1981 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1979

Trace element and strontium isotope characteristics of volcanic rocks from Isla Tortuga: A young seamount in the Gulf of California

Isla Tortuga is a small isolated central volcano which is located near an actively spreading trough in the Gulf of California. The basalt lavas from Tortuga which have the highest Mg/Fe and Ni contents have trace element abundances and ratios and 87 Sr/ 86 Sr which are similar to those of mid-ocean ridge tholeiite. The major element, rare earth element and Sr abundances of fractionated tholeiite (low Mg/Fe) and tholeiitic andesite of Tortuga are consistent with an origin by closed-system fractional crystallization. This hypothesis is not supported by K, Na, Rb and Ba abundances in the lavas nor by their variable 87 Sr/ 86 Sr (0.7024–0.7035). It is proposed that the apparent decoupling of light rare earth elements, other incompatible trace elements and 87 Sr/ 86 Sr is due to contamination of some Tortuga magmas while they are fractionated in a high-level crustal magma chamber. The mantle source of least-contaminated, high Mg/Fe basalt lavas of Tortuga is similar, although not identical to the source of normal mid-ocean ridge tholeiite; significant differences exist. The reasons for these differences are not yet known.

Earth and Planetary Science Letters↗
USGS1978

Minor-element and Sr-isotope geochemistry of tertiary stocks, Colorado mineral belt

Rocks of the northeast portion of the Colorado mineral belt form two petrographically, chemically and geographically distinct rock suites: (1) a silica oversaturated granodiorite suite; and (2) a silica saturated, high alkali monzonite suite. Rocks of the granodiorite suite generally have Sr contents less than 1000 ppm, subparallel REE patterns and initial 87Sr/ 86Sr ratios greater than 0.707. Rocks of the monzonite suite are restricted to the northeast part of the mineral belt, where few rocks of the granodiorite suite occur, and generally have Sr contents greater than 1000 ppm, highly variable REE patterns and 87Sr/86Sr initial ratios less than 0.706. Despite forming simple, smooth trends on major element variation diagrams, trace element data for rocks of the granodiorite suite indicate that they were not derived from a single magma. These rocks were derived from magmas having similar REE patterns, but variable Rb and Sr contents, and Rb/Sr ratios. The preferred explanation for these rocks is that they were derived by partial melting of a mixed source, which yielded pyroxene granulite or pyroxenite residues. The monzonite suite is chemically and petrographically more complex than the granodiorite suite. It is subdivided here into alkalic and mafic monzonites, and quartz syenites, based on the textural relations of their ferromagnesian phases and quartz. The geochemistry of these three rock types require derivation from separate and chemically distinct magma types. The preferred explanation for the alkalic monzonites is derivation from a heterogeneous mafic source, leaving a residue dominated by garnet and clinopyroxene. Early crystallization of sphene from these magmas was responsible for the severe depletion of the REE observed in the residual magmas. The lower Sr content and higher Rb/Sr ratios of the mafic monzonites requires a plagioclase-bearing source. The Sr-isotope systematics of the majority of these rocks are interpreted to be largely primary, and not the result of crustal contamination. The positive correlation of Rb/Sr and 87Sr/86Sr ratios for the least fractionated samples indicate that the sources from which parent magmas of both the granodiorite and monzonite suites were derived are Precambrian in age. ?? 1978 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1978

Strontium isotopes in basalts from the Pacific Ocean basin

Basalts being erupted in the Pacific Ocean Basin vary in Sr isotopic composition in a simple geographic pattern. 87 Sr/ 86 Sr increases away from the East Pacific Rise to very high values for islands in the south-central Pacific. The 87 Sr/ 86 Sr variations are almost certainly related to past segregation of Rb, K, and other large cations. The segregation process was probably incipient partial melting which resulted in various mantle zones being enriched or depleted.

Earth and Planetary Science Letters↗
USGS1974

3,800-Myr granitic gneiss in south-western Minnesota

WE have previously arrived at an age of 3,550 Myr for granitic 1 gneiss in the vicinities of Morton and Montevideo in the Minnesota River valley, south-western Minnesota. We now report new Rb–Sr analyses (Table 1) and an age of 3,800 Myr for the fine grained foliated phase of the Montevideo Gneiss of Lund 2 . The rocks have undergone a complex history of metamorphism which remains to be deciphered, but the age determinations reveal that the geological mapping and previous interpretations did not provide a proper basis for sampling.

Minnesota↗
USGS1973

K, Rb, Sr and 87Sr 86Sr in rocks from the Mid-Indian Oceanic Ridge

The 87 Sr/ 86 Sr ratios of Mid-Indian Oceanic Ridge (MIOR) basalts are nearly identical (0.7032 to 0.7035), with the exception of one more highly radiogenic sample (0.7043). These values are consistently higher than the strontium isotopic ratios of the ridge basalts from Atlantic and Pacific Oceans, suggesting that the source of the MIOR basalts was depleted in alkalies more recently and/or to a lesser degree than the basalts from other oceans.

Earth and Planetary Science Letters↗
USGS1973

Effect of sea water interaction on strontium isotope composition of deep-sea basalts

Analyses of rim-to-interior samples of fresh tholeiitic pillow basalts, deuterically altered holocrystalline basalts, and older, weathered tholeiitic basalts from the deep sea indicate that 87 Sr/ 86 Sr ratios of the older basalts are raised by low temperature interaction with strontium dissolved in sea water. 87 Sr/ 86 Sr correlates positively with H 2 O in these basalts; however, there is little detectable modification of the strontium isotope composition in rocks with H 2 O contents less than 1%. The isotope changes appear to be a function of relatively long-term, low-temperature weathering, rather than high-temperature or deuteric alteration. Strontium abundance and isotopic data for these rocks suggest that strontium content is only slightly modified by interaction with sea water, and it is a relatively insensitive indicator of marine alteration. Average Rb-Sr parameters for samples of apparently unaltered basalt are: Rb= 1.11ppm; Sr= 132ppm; 87 Sr/ 86 Sr= 0.70247.

Earth and Planetary Science Letters↗
USGS1973

87Sr/86Sr ratios in basalts from islands in the Indian Ocean

87 Sr/ 86 Sr ratios of basalts from islands in the Indian Ocean (0.7040) are higher than those of basalts dredged from the Mid-Indian Ocean Ridge (0.7034). The sources of the island basalts have apparently not been in equilibrium with the source of the ridge basalts for roughly 10 9 years. Both ridge and island basalts in the Indian Ocean are higher in 87 Sr/ 86 Sr than are rocks from similar settings in the eastern Pacific.

Earth and Planetary Science Letters↗
USGS1971

Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc

Si 87 /Sr 86 ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc—Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si 87 /Sr 86 content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr 87 /Sr 86 values from each center are the same within analytical uncertainty (±0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source — in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization.

Contributions to Mineralogy and Petrology↗
USGS1971

Nickel in high-alumina basalts

New analyses of high-alumina basalts reveal an average nickel content higher than previously indicated. Ni in high-alumina basalts correlates with magnesium in the same way as it does in other basalt types. There is therefore no reason, based on Ni contents, to hypothesize a special origin for high-alumina basalts and it is permissible (based on Ni contents) to form andesites by fractional crystallization from high-alumina basalts.

Geochimica et Cosmochimica Acta↗
USGS1970

The strontium isotopic composition of basalts from the Gordo and Juan de Fuca Rises, northeastern Pacific Ocean

The strontium isotopic compositions have been determined for twelve tholeiitic basalts dredged from the Gordo and Juan de Fuca Rises. Sr 87 /Sr 86 ratios range from 0.7012 to 0.7031 and average 0.7026. These data, combined with other data from the East Pacific Rise indicate that tholeiite basalts being erupted along the active rises, in the Pacific Ocean, contain less radiogenic Sr 87 than basalts erupted on the islands. These isotopic differences between the ocean-ridge tholeiite and the more alkali island basalts indicate that variations in Rb/Sr have persisted in the mantle for billions of years. The possible origins and distribution of these heterogeneties are discussed.

Contributions to Mineralogy and Petrology↗