Geology topics

Brock J.W. Kamrath

Publications and source records attributed to Brock J.W. Kamrath.

4 recordsLinked to original sources

USGS2026

Evaluating chlorophyll fluorescence sensors as a proxy for chlorophyll a concentrations in the Illinois River, Illinois, water years 2018–24

The U.S. Geological Survey deployed instream chlorophyll fluorescence sensors on the Illinois River in Illinois to better understand the formation, dynamics, and persistence of riverine algal blooms. At five sensor locations across four U.S. Geological Survey streamgages, chlorophyll fluorescence (fChl) sensors were set to measure instantaneous fChl in micrograms per liter as chlorophyll at 15-minute intervals. These sensors estimate fChl based on the fluorescence response of algal pigments but do not directly measure chlorophyll a (Chl) concentrations or algal biomass. To evaluate the reliability of fChl as a proxy for Chl, fChl measurements were compared to laboratory-measured Chl concentrations. These Chl concentrations were obtained from water-quality samples collected at the sensor locations and analyzed using the standard chromatographic-fluorometric method with acetone extraction. A total of 209 paired fChl and Chl observations were analyzed using Pearson’s correlation and model II regression. Statistically significant, positive correlations (Pearson’s correlation coefficient of 0.68–0.95) were detected at all sensor locations, indicating that fChl generally tracked with Chl. However, model II regression detected proportional and fixed bias at three of the five locations and proportional bias at another location. At locations with proportional biases, model II regression slopes were less than 1, indicating that fChl increasingly underestimated Chl as concentrations increased; however, paired observations at high Chl concentrations were sparse. Substantial variability in bias was also observed across sensor locations with slopes ranging from 0.43 to 0.93. Overall, the results indicated that fChl correlates well with Chl in the Illinois River, but fChl may not reliably represent Chl concentrations without adjustment. For applications requiring accurate Chl estimates, a sensor location-specific surrogate model could be beneficial. These findings underscore the importance of field validation, consistent sensor placement, and careful interpretation of fChl data, particularly when reported in micrograms per liter.

Illinois, Indiana, Wisconsin↗

USGS2026

Spatially consistent but temporally divergent changes in nitrate and phosphorus loads and yields in Illinois watersheds, 1997–2022

Illinois contributes substantial nutrient loads to the Gulf of America, warranting watershed-scale assessment. This study estimated nitrate-nitrogen (nitrate-N) and total phosphorus (TP) loads and yields for 49 Illinois 8-digit hydrologic unit code (HUC8) watersheds draining to the Mississippi River Basin from 1997–2022, comparing recent (2018–2022) to baseline (1997–2011) conditions. Estimates included point and nonpoint source contributions, dissolved phosphorus, and water yields. During the recent period, nonpoint sources dominated nutrient export (82% nitrate-N, 78% TP), though point sources drove high yields in the Chicago area. Spatially, nonpoint source nutrient hotspots persisted with nitrate-N yields highest in east-central and northern Illinois and TP yields higher in southern and western Illinois. Temporally, statewide nitrate-N loads decreased 9%, while TP loads increased 27%. Nitrate-N yields increased in 22 HUC8s and decreased in 20, while TP yields increased in 32 HUC8s and decreased in 9. For both nutrients, baseline yields were negatively correlated with yield changes, indicating high-yielding watersheds tended toward larger decreases or smaller increases. Water yields increased 19% on average but were weakly correlated with nutrient yield changes ( r = 0.23 and 0.20 for nitrate-N and TP). These results reveal spatially persistent yet temporally divergent nutrient export across Illinois, with contrasting nitrate-N and TP trajectories for nonpoint sources.

Illinois↗

USGS2025

Temporal changes in nutrient concentrations in the Lower Grand River and selected drainage basins, Missouri and Iowa, during the Mississippi River Basin Healthy Watersheds Initiative (2010–23)

This report describes a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources that evaluated temporal changes in total nitrogen (TN) and total phosphorus (TP) concentrations in the Lower Grand River hydrologic unit. The study focused on trends since 2010, when the basin was designated as a priority drainage basin of the Mississippi River Basin Healthy Watersheds Initiative (MRBI). At three local drainage basins within the Lower Grand hydrological unit (MRBI sites), stream nutrient trends were evaluated using flow-adjusted (FA) TN and TP concentrations for water years 2011 through 2023. FATN concentration trends were not statistically significant for any MRBI site. One site (site 2) showed a statistically significant increasing trend in FATP concentration, indicating a possible increase in phosphorus sources in parts of the basin. Overall, streamflow variability appeared to be the dominant factor affecting nutrient concentrations at MRBI sites. At five regional drainage basins, including the Grand River and nearby rivers with data from 1994 through 2023 (long-term sites), annual flow-normalized (FN) TN and TP concentrations were evaluated for trends before (water years 2000–10) and during (water years 2010–23) the MRBI. For water years 2010 through 2023, annual FNTN and FNTP concentrations decreased in the Grand River, as well as in the Nodaway and Chariton Rivers, which were not targeted by the MRBI. The Grand River (site 9) reversed from increasing to decreasing FNTP concentrations after 2010, with a 26-percent reduction. Annual FNTN and FNTP concentrations also decreased at the Missouri River sites. While nutrient reductions in the Grand River may reflect the effects of implemented conservation practices, similar trends in nearby, nontargeted rivers and the absence of strong decreasing trends at MRBI sites suggest that broader regional factors, instead of or in addition to MRBI efforts, may have contributed to nutrient reductions in the Grand River.

Iowa, Missouri↗

USGS2025

Diverging trends in nitrate and phosphorus loads and yields across Illinois watersheds, 1997–2022

Illinois is a major contributor of nutrients to the northern Gulf of Mexico. As such, the State of Illinois initiated efforts to curb nutrient runoff over the last several decades. To evaluate progress towards these reductions, water-quality data were used to estimate incremental loads and yields of nitrate plus nitrite (NO3) and total phosphorus (TP) from 1997–2022 for 49 Illinois watersheds, defined using eight-digit hydrologic unit codes (HUC8), draining to the Mississippi River Basin. To estimate changes in NO3 and TP loads, recent loads from the period 2018 through 2022 were compared to baseline loads from 1997 through 2011. Nonpoint and point source loads, dissolved phosphorus (DP) loads, and water yields were also estimated. The sum of the incremental NO3 loads from the 49 HUC8s decreased 9% despite a 19% increase in water yield. Much of this decline occurred in HUC8s that had NO3 yields greater than 17 pounds per acre per year (lbs/acre/yr) during a 1997–2011 baseline period. The sum of all incremental HUC8 TP loads increased 25% despite a 27% reduction in point source discharge. Loads and yields were substantially larger for both NO3 and TP in the Chicago area. Outside the Chicago area, central and northern Illinois had higher NO3 yields than southern Illinois and a reverse pattern for TP where higher yields occur in southern Illinois. Nonpoint sources made up an estimated 82% and 78% of the NO3 and TP yields, respectively, across the HUC8s. In general, point source yields have mostly decreased over time, while nonpoint source yields varied depending on location and reflect the changes in the total yield.

Illinois↗