Geology topics

Brian E. Haggard

Publications and source records attributed to Brian E. Haggard.

7 recordsLinked to original sources

USGS2010

Antibiotic fate and transport in three effluent-dominated Ozark streams

Antibiotic transport downstream from a wastewater treatment plant effluent discharge was evaluated along stream reaches on Mud Creek, Spring Creek, and Decatur Branch in northwestern Arkansas, USA. Water and streambed samples were collected during August and September 2006 and analyzed for multiple antibiotics representing five classes (beta-lactams, macrolides, quinolones, sulfonamides, and tetracyclines). Antibiotics within the classes macrolides, quinolones, and sulfonamides were detected in the water column at all three stream reaches. Several of these same antibiotics, as well as antibiotics from the class tetracycline, were measured in streambed material at quantities significantly greater than those observed in the water column. Pseudo-partitioning coefficients ranged from 4 to >8000 L kg −1 . Most of the antibiotics studied were significantly retained in the reaches at Mud Creek and Spring Creek and traveled kilometer-scale distances ( S net , 3.3–20.2 km) with low uptake velocities ( v f-net "> vf-net , 2.9–16.1 × 10 −6 m s −1 ) and rates ( U net 0.01–37.9 × 10 −6 μg m −2 s −1 ). Some antibiotics increased in concentration downstream from the effluent discharge at Decatur Branch, suggesting possible release from within the fluvial channel or additional sources along the stream reach. In general, antibiotics traveled kilometer-scale distances before significant dilution occurred through in-stream processes (e.g., advection, dispersion, sorption, uptake and/or degradation) within the fluvial channel of these effluent-dominated streams.

Arkansas↗

USGS2005

Occurrence of pharmaceuticals and other organic wastewater constituents in selected streams in northern Arkansas, 2004

The U.S. Geological Survey, in cooperation with the University of Arkansas and the U.S. Department of Agriculture, Agricultural Research Service, collected data in 2004 to determine the occurrence of pharmaceuticals and other organic wastewater constituents, including many constituents of emerging environmental concern, in selected streams in northern Arkansas. Samples were collected in March and April 2004 from 17 sites located upstream and downstream from wastewater- treatment plant effluent discharges on 7 streams in northwestern Arkansas and at 1 stream site in a relatively undeveloped basin in north-central Arkansas. Additional samples were collected at three of the sites in August 2004. The targeted organic wastewater constituents and sample sites were selected because wastewater-treatment plant effluent discharge provides a potential point source of these constituents and analytical techniques have improved to accurately measure small amounts of these constituents in environmental samples. At least 1 of the 108 pharmaceutical or other organic wastewater constituents was detected at all sites in 2004, except at Spavinaw Creek near Maysville, Arkansas. The number of detections generally was greater at sites downstream from municipal wastewater-treatment plant effluent discharges (mean = 14) compared to sites not influenced by wastewatertreatment plants (mean = 3). Overall, 42 of the 108 constituents targeted in the collected water-quality samples were detected. The most frequently detected constituents included caffeine, phenol, para-cresol, and acetyl hexamethyl tetrahydro naphthalene.

Arkansas↗

USGS2003

Percentile distributions of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus concentrations in Oklahoma streams, 1973-2001

Nutrients are one of the primary causes of water-quality impairments in streams, lakes, reservoirs, and estuaries in the United States. The U.S. Environmental Protection Agency has developed regional-based nutrient criteria using ecoregions to protect streams in the United States from impairment. However, nutrient criteria were based on nutrient concentrations measured in large aggregated nutrient ecoregions with little relevance to local environmental conditions in states. The Oklahoma Water Resources Board is using a dichotomous process known as Use Support Assessment Protocols to define nutrient criteria in Oklahoma streams. The Oklahoma Water Resources Board is modifying the Use Support Assessment Protocols to reflect nutrient informa-tion and environmental characteristics relevant to Oklahoma streams, while considering nutrient information grouped by geographic regions based on level III ecoregions and state boundaries. Percentile distributions of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorous concentrations were calculated from 563 sites in Oklahoma and 4 sites in Arkansas near the Oklahoma and Arkansas border to facilitate development of nutrient criteria for Oklahoma streams. Sites were grouped into four geographic regions and were categorized into eight stream categories by stream slope and stream order. The 50th percentiles of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus concentrations were greater in the Ozark Highland ecoregion and were less in the Ouachita Mountains ecoregion when compared to other geographic areas used to group sites. The 50th percentiles of median concentrations of nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus were least in first, second, and third order streams. The 50th percentiles of median nitrite plus nitrate as nitrogen, total nitrogen and total phosphorus concentrations in the Ozark Highland and Ouachita Mountains ecoregions were least in first, second, and third order streams with streams slopes greater than 17 feet per mile. Nitrite plus nitrate as nitrogen and total nitrogen criteria determined by the U.S. Environmental Protection Agency for the Ozark Highland ecoregion were less than the 25th percentiles of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus concentrations in the Ozark Highland ecoregion calculated for this report. Nitrite plus nitrate as nitrogen and total nitrogen criteria developed by the U.S. Environmental Protection Agency for the Ouachita Mountains ecoregion were similar to the 25th percentiles of median nitrite plus nitrate as nitrogen and total nitrogen concentrations in the Ouachita Mountains ecoregion calculated for this report. Nitrate as nitrogen and total phosphorus concentrations currently (2002) used in the Use Support Assessment Protocols for Oklahoma were greater than the 75th percentiles of median nitrite plus nitrate as nitrogen and total phosphorus concentrations calculated for this report.

Oklahoma↗

USGS2003

Phosphorus concentrations, loads, and yields in the Illinois River Basin, Arkansas and Oklahoma, 1997-2001

The Illinois River and tributaries, Flint Creek and the Baron Fork, are designated scenic rivers in Oklahoma. Recent phosphorus increases in streams in the basin have resulted in the growth of excess algae, which have limited the aesthetic benefits of water bodies in the basin, especially the Illinois River and Lake Tenkiller. The Oklahoma Water Resources Board has established a standard for total phosphorus not to exceed the 30- day geometric mean concentration of 0.037 milligram per liter in Oklahoma Scenic Rivers. Data from water-quality samples from 1997 to 2001 were used to summarize phosphorus concentrations and estimate phosphorus loads, yields, and flowweighted concentrations in the Illinois River basin. Phosphorus concentrations in the Illinois River basin generally were significantly greater in runoff-event samples than in base-flow samples. Phosphorus concentrations generally decreased with increasing base flow, from dilution, and increased with runoff, possibly because of phosphorus resuspension, stream bank erosion, and the addition of phosphorus from nonpoint sources. Estimated mean annual phosphorus loads were greater at the Illinois River stations than at Flint Creek and the Baron Fork. Loads appeared to generally increase with time during 1997-2001 at all stations, but this increase might be partly attributable to the beginning of runoff-event sampling in the basin in July 1999. Base-flow loads at stations on the Illinois River were about 10 times greater than those on the Baron Fork and 5 times greater than those on Flint Creek. Runoff components of the annual total phosphorus load ranged from 58.7 to 96.8 percent from 1997-2001. Base-flow and runoff loads were generally greatest in spring (March through May) or summer (June through August), and were least in fall (September through November). Total yields of phosphorus ranged from 107 to 797 pounds per year per square mile. Greatest yields were at Flint Creek near Kansas (365 to 797 pounds per year per square mile) and the least yields were at Baron Fork at Eldon (107 to 440 pounds per year per square mile). Estimated mean flow-weighted concentrations were more than 10 times greater than the median and were consistently greater than the 75th percentile of flow-weighted phosphorus concentrations in samples collected at relatively undeveloped basins of the United States (0.022 milligram per liter and 0.037 milligram per liter, respectively). In addition, flow-weighted phosphorus concentrations in 1999-2001 at all Illinois River stations and at Flint Creek near Kansas were equal to or greater than the 75th percentile of all National Water-Quality Assessment program stations in the United States (0.29 milligram per liter). The annual average phosphorus load entering Lake Tenkiller was about 577,000 pounds per year, and more than 86 percent of the load was transported to the lake by runoff.The Illinois River and tributaries, Flint Creek and the Baron Fork, are designated scenic rivers in Oklahoma. Recent phosphorus increases in streams in the basin have resulted in the growth of excess algae, which have limited the aesthetic benefits of water bodies in the basin, especially the Illinois River and Lake Tenkiller. The Oklahoma Water Resources Board has established a standard for total phosphorus not to exceed the 30- day geometric mean concentration of 0.037 milligram per liter in Oklahoma Scenic Rivers. Data from water-quality samples from 1997 to 2001 were used to summarize phosphorus concentrations and estimate phosphorus loads, yields, and flowweighted concentrations in the Illinois River basin. Phosphorus concentrations in the Illinois River basin generally were significantly greater in runoff-event samples than in base-flow samples. Phosphorus concentrations generally decreased with increasing base flow, from dilution, and increased with runoff, possibly because of phosphorus resuspension, stream bank erosion, and the addition of phosphorus

Arkansas, Oklahoma↗

USGS2002

Hydrologic characteristics of Bear Creek near Silver Hill and Buffalo River near St. Joe, Arkansas, 1999-2000

The Buffalo River and its tributary Bear Creek are in the White River Basin in the Ozark Plateaus in north-central Arkansas. Analysis of streamflow measurements and water-quality samples at a site on Bear Creek and a site on the Buffalo River in Searcy County, Arkansas, quantify differences between the two sites during calendar years 1999 and 2000. Streamflow and water quality also vary seasonally at each site. Mean annual streamflow was substantially larger at the Buffalo River site (836 and 719 cubic feet per second in 1999 and 2000) than at the Bear Creek site (56 and 63 cubic feet per second). However, during times of low flow, discharge of Bear Creek comprises a larger proportion of the flow of the Buffalo River. Concentrations of nutrients, fecal-indicator bacteria, dissolved organic carbon, and suspended sediment generally were greater in samples from Bear Creek than in samples from the Buffalo River. Statistically significant differences were detected in concentrations of nitrite plus nitrate, total nitrogen, dissolved phosphorus, orthophosphorus, total phosphorus, fecal coliform bacteria, and suspended sediment. Loads varied between sites, hydrologic conditions, seasons, and years. Loads were substantially higher for the Buffalo River than for Bear Creek (as would be expected because of the Buffalo?s higher streamflow). Loads contributed by surface runoff usually comprised more than 85 percent of the annual load. Constituent yields (loads divided by drainage area) were much more similar between sites than were loads. Flow-weighted concentrations and dissolved constituent yields generally were greater for Bear Creek than yields for the Buffalo River and flowweighted concentrations yields were higher than typical flow-weighted concentrations and yields in undeveloped basins, but lower than flow-weighted concentrations and yields at a site in a more developed basin.

Water-Resources Investigations Report↗

USGS2002

Environmental Characteristics and Geographic Information System Applications for the Development of Nutrient Thresholds in Oklahoma Streams

The U.S.Environmental Protection Agency has developed nutrient criteria using ecoregions to manage and protect rivers and streams in the United States. Individual states and tribes are encouraged by the U.S. Environmental Protection Agency to modify or improve upon the ecoregion approach. The Oklahoma Water Resources Board uses a dichotomous process that stratifies streams using environmental characteristics such as stream order and stream slope. This process is called the Use Support Assessment Protocols, subchapter15. The Use Support Assessment Protocols can be used to identify streams threatened by excessive amounts of nutrients, dependant upon a beneficial use designation for each stream. The Use Support Assessment Protocols, subchapter 15 uses nutrient and environmental characteristic thresholds developed from a study conducted in the Netherlands, but the Oklahoma Water Resources Board wants to modify the thresholds to reflect hydrologic and ecological conditions relevant to Oklahoma streams and rivers. Environmental characteristics thought to affect impairment from nutrient concentrations in Oklahoma streams and rivers were determined for 798 water-quality sites in Oklahoma. Nutrient, chlorophyll, water-properties, and location data were retrieved from the U.S. Environmental Protection Agency STORET database including data from the U.S. Geological Survey, Oklahoma Conservation Commission, and Oklahoma Water Resources Board. Drainage-basin area, stream order, stream slope, and land-use proportions were determined for each site using a Geographic Information System. The methods, procedures, and data sets used to determine the environmental characteristics are described.

Water-Resources Investigations Report↗

USGS2001

Phosphorus and nitrogen concentrations and loads at Illinois River south of Siloam Springs, Arkansas, 1997-1999

Water-quality sampling consisting of every other month (bimonthly) routine sampling and storm event sampling (six storms annually) is used to estimate annual phosphorus and nitrogen loads at Illinois River south of Siloam Springs, Arkansas. Hydrograph separation allowed assessment of base-flow and surfacerunoff nutrient relations and yield. Discharge and nutrient relations indicate that water quality at Illinois River south of Siloam Springs, Arkansas, is affected by both point and nonpoint sources of contamination. Base-flow phosphorus concentrations decreased with increasing base-flow discharge indicating the dilution of phosphorus in water from point sources. Nitrogen concentrations increased with increasing base-flow discharge, indicating a predominant ground-water source. Nitrogen concentrations at higher base-flow discharges often were greater than median concentrations reported for ground water (from wells and springs) in the Springfield Plateau aquifer. Total estimated phosphorus and nitrogen annual loads for calendar year 1997-1999 using the regression techniques presented in this paper (35 samples) were similar to estimated loads derived from integration techniques (1,033 samples). Flow-weighted nutrient concentrations and nutrient yields at the Illinois River site were about 10 to 100 times greater than national averages for undeveloped basins and at North Sylamore Creek and Cossatot River (considered to be undeveloped basins in Arkansas). Total phosphorus and soluble reactive phosphorus were greater than 10 times and total nitrogen and dissolved nitrite plus nitrate were greater than 10 to 100 times the national and regional averages for undeveloped basins. These results demonstrate the utility of a strategy whereby samples are collected every other month and during selected storm events annually, with use of regression models to estimate nutrient loads. Annual loads of phosphorus and nitrogen estimated using regression techniques could provide similar results to estimates using integration techniques, with much less investment.

Water-Resources Investigations Report↗